WO2010032443A1 - 有機エレクトロルミネッセンス素子及びその製造方法 - Google Patents
有機エレクトロルミネッセンス素子及びその製造方法 Download PDFInfo
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- WO2010032443A1 WO2010032443A1 PCT/JP2009/004624 JP2009004624W WO2010032443A1 WO 2010032443 A1 WO2010032443 A1 WO 2010032443A1 JP 2009004624 W JP2009004624 W JP 2009004624W WO 2010032443 A1 WO2010032443 A1 WO 2010032443A1
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- H10K50/00—Organic light-emitting devices
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
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- H10K50/805—Electrodes
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/805—Electrodes
- H10K50/81—Anodes
- H10K50/813—Anodes characterised by their shape
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- H—ELECTRICITY
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/805—Electrodes
- H10K50/81—Anodes
- H10K50/818—Reflective anodes, e.g. ITO combined with thick metallic layers
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- H10K2102/00—Constructional details relating to the organic devices covered by this subclass
- H10K2102/301—Details of OLEDs
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- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K50/00—Organic light-emitting devices
- H10K50/10—OLEDs or polymer light-emitting diodes [PLED]
- H10K50/17—Carrier injection layers
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- H—ELECTRICITY
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- H10K50/00—Organic light-emitting devices
- H10K50/80—Constructional details
- H10K50/85—Arrangements for extracting light from the devices
- H10K50/856—Arrangements for extracting light from the devices comprising reflective means
Definitions
- the present invention relates to an organic electroluminescence element and a manufacturing method thereof, and more particularly to an organic electroluminescence element used for a display device or illumination and a manufacturing method thereof.
- An organic electroluminescence element (hereinafter referred to as an organic EL element) has a structure in which an organic layer including a light emitting layer is sandwiched between an anode and a cathode, and holes are injected from the anode and electrons are injected from the cathode. It is a device which takes out light emission by recombining.
- Organic EL elements can be easily formed with a wet method such as a printing method, and are suitable for cost reduction and flexibility, and organic EL elements have been actively researched and developed in recent years.
- organic EL elements have already begun to be used for applications such as the main display of mobile phones. However, it is inferior to competing liquid crystal displays in terms of cost reflecting performance such as half life of display brightness and manufacturing method, and needs to be improved.
- the organic layer of the organic EL element currently on the market is formed by a vacuum deposition method, and the characteristics of the organic EL cannot be fully utilized.
- a manufacturing method in which an organic layer is formed by a wet method is advantageous in terms of material use efficiency, manufacturing time, and cost of manufacturing equipment. Further, in application to a display, since a large-area pixel can be separately applied by a printing method, there is no problem of in-plane nonuniformity such as vacuum vapor deposition and a problem of deflection of a metal mask used for patterning a vapor deposition layer.
- Patent Document 1 As a device structure of a multilayer organic EL element using a wet method and a manufacturing method thereof, for example, Patent Document 1 is disclosed.
- a hole injection layer made of an aqueous organic material is formed on a transparent electrode on a substrate. This layer does not dissolve in the organic layer.
- a hole transporting material containing a crosslinking agent is formed from an organic solvent, crosslinked by light treatment after film formation, and insolubilized.
- a third layer made of a light-emitting organic material is formed from an organic solvent as a light-emitting layer.
- a cathode is formed by vapor deposition to form an element.
- the organic EL device having the above structure described in Patent Document 1 is excellent in performance such as drive voltage, light emission efficiency, and lifetime, but the following formula used as a hole injection layer:
- a water-soluble conductive material typified by a mixture of the compound PEDOT (Poly (3,4-ethylene xythiophene)) and PSS (Poly (styrene sulfonate)) is generally an acidic solution and corrodes an apparatus such as an inkjet nozzle. There is a problem that causes In addition, since this is not a complete solution but a dispersion of fine particles, there is a problem of clogging of the ink jet nozzle. Further, since the conductivity is too high, if even a part of this film comes into contact with the cathode, an increase in leakage current is caused.
- PEDOT Poly (3,4-ethylene xythiophene)
- PSS Poly (styrene sulfonate)
- Measures against the problems caused by the use of the above-described ink jet nozzle include omitting the first hole injection layer and injecting holes directly into the second hole transport layer. According to this, not only can the above-mentioned problems be solved, but there are also great advantages from the viewpoint of manufacturing cost such as manufacturing apparatus and manufacturing time.
- the second hole transport layer is formed directly on the anode such as indium tin oxide (hereinafter referred to as ITO) which is generally used, the hole injection is not sufficient, and the luminous efficiency and lifetime are It will drop significantly. This problem is particularly noticeable in coating-type hole transport materials that require mixing of a crosslinking agent and have a reduced hole transport capability.
- ITO indium tin oxide
- Patent Document 2 proposes a structure that prevents problems caused by the use of the above-described ink jet nozzle and a decrease in hole transport capability.
- Patent Document 2 discloses forming a metal oxide layer such as molybdenum oxide or vanadium oxide, which has a large work function and is advantageous for hole injection in terms of energy level, as an inorganic hole injection layer. Since these are insoluble in the organic solvent, there is no problem of elution when the organic solvent is wet-coated from above.
- Patent Document 3 discloses a method of coating an organic material by a wet printing method.
- an insulating layer called a water-repellent bank by using an insulating layer called a water-repellent bank, the effect of defining the light emitting portion of the organic EL element in the opening where the bank is not formed, and the anode of the opening that is hydrophilic are disclosed. There is an effect of holding an organic solution on the surface.
- the metal oxide is water-soluble, so that the water-based material used in the patterning process of the insulating layer is used.
- the elution into the developer or the stripping solution disappears, and the performance such as luminous efficiency and lifetime is reduced due to the decrease in hole injection capability.
- the present invention provides an organic EL element having a simple manufacturing process using a wet film-forming method as the formation of an organic layer and a method for manufacturing the organic EL element. Objective.
- an organic electroluminescence element includes a substrate, an anode metal layer formed on the substrate, and the anode metal layer.
- the surface of the insulating layer formed in the first region and the anode metal layer and the anode metal layer stacked on the substrate is oxidized, whereby the first A metal oxide layer formed at least in a second region other than the region, and an organic material having a hole transporting property formed on the metal oxide layer and in the second region where the insulating layer is not formed.
- a hole transport layer comprising: an organic light emitting layer formed on the hole transport layer; a cathode layer formed on the organic light emitting layer and injecting electrons into the organic light emitting layer;
- the upper surface of the anode metal layer in the second region is the first region. Characterized in that located below the upper surface of definitive said anode metal layer.
- the hole injection property is excellent, the number of organic layers can be reduced, and the organic layer can be formed by wet printing, so that the power consumption and the driving life are excellent.
- An organic EL device having a simple manufacturing process can be provided.
- FIG. 1 is a structural sectional view of an organic EL element according to Embodiment 1 of the present invention.
- FIG. 2 is a structural cross-sectional view illustrating the waveguide loss reduction effect of the organic EL element according to Embodiment 1 of the present invention.
- FIG. 3 is a structural cross-sectional view of an organic EL element showing a modification of the first embodiment of the present invention.
- FIG. 4 is a process diagram for explaining a method of manufacturing an organic EL element in Example 1 according to the present invention.
- FIG. 5A is a top view of an organic EL device including an organic EL element manufactured by using the manufacturing method of Example 1 according to the present invention.
- FIG. 5B is a structural cross-sectional view of an organic EL device including an organic EL element manufactured using the manufacturing method of Example 1 according to the present invention.
- FIG. 6 is a structural cross-sectional view of an organic EL element according to Embodiment 2 of the present invention.
- FIG. 7 is a process diagram for explaining a method of manufacturing an organic EL element according to Embodiment 2 of the present invention.
- FIG. 8 is an external view of a TV in which the organic EL element of the present invention is used.
- An organic EL device includes a substrate, an anode metal layer formed on the substrate, an insulating layer formed on the anode metal layer in a first region, A metal oxide layer formed on at least a second region other than the first region by oxidizing the surface of the anode metal layer stacked on the substrate on the anode metal layer; and A hole transport layer including a hole transporting organic material formed on the metal oxide layer in the second region where the insulating layer is not formed, and formed on the hole transport layer.
- An organic light emitting layer, and a cathode layer that is formed on the organic light emitting layer and injects electrons into the organic light emitting layer, and the upper surface of the anode metal layer in the second region is formed in the first region. It is characterized by being located below the upper surface of the anode metal layer.
- the oxidation of the anode metal layer provides a large work function between the anode metal layer and the organic light emitting layer, and the energy barrier against hole injection can be reduced.
- the injection layer can be formed of a metal oxide layer.
- the hole injection layer does not need to be formed of an organic layer, the number of organic layers can be reduced.
- an organic layer can be formed by wet printing on the hole injection layer.
- the metal oxide layer provided on the anode metal layer is related to (1) A form in which a step is generated at the interface between the first region and the second region so that the second region side is positioned below the first region side (the metal oxide layer is formed in the first region and the second region). (When provided) or (2) the side and bottom surfaces of the metal oxide layer are covered with the anode metal layer (when the metal oxide layer is provided only in the second region) become.
- the organic EL device is the organic EL device according to claim 1, wherein the anode metal layer includes an anode metal lower layer having a visible light reflectance of 60% or more, and the anode metal. You may provide the anode metal upper layer laminated
- a metal having high reflectance can be used as the anode metal lower layer independently of the anode metal upper layer to be oxidized. Therefore, the range of material selection for each layer is widened, and it becomes easier to optimize the performance as a top emission type organic EL element.
- the organic EL device is the organic EL device according to claim 2, wherein the anode metal lower layer is an alloy containing at least one of aluminum and silver, and the anode metal upper layer is , Molybdenum, chromium, vanadium, tungsten, nickel, and a metal containing at least one of iridium.
- a metal having a high reflectance can be used as the anode metal lower layer, and optimization of the performance as a top emission type organic EL element becomes easier.
- a metal element whose work function is increased by oxidation is selected as the anode metal upper layer, a hole injection layer having excellent hole injection characteristics can be formed of the metal oxide layer.
- the organic EL element according to one aspect of the present invention is the organic EL element according to claim 2 or 3, wherein the thickness of the upper layer of the anode metal in the second region is preferably 20 nm or less.
- a decrease in reflectance due to the anode metal upper layer that is, attenuation of light emission of the top emission organic EL element can be suppressed, and the high reflectance of the anode metal lower layer can be maximized.
- the organic EL element according to one aspect of the present invention is the organic EL element according to claim 4, wherein the anode metal upper layer may not be formed in the second region.
- the anode metal upper layer is completely converted to the metal oxide layer, it becomes possible to maximize the reflectance of the anode metal lower layer.
- the organic EL element which is one embodiment of the present invention is the organic EL element according to claim 1, wherein the metal oxide layer may be further formed in the first region.
- the surface of the anode metal layer may be oxidized by the air during the manufacturing process and the metal oxide layer may be naturally formed uniformly.
- the opening is artificially oxidized. Therefore, even if the metal oxide layer formed in advance is eluted by the aqueous solvent used for forming the insulating layer pattern, the organic light emitting layer It is possible to secure a hole injection layer that can inject sufficient holes.
- the organic EL element which is one embodiment of the present invention is the organic EL element according to claim 1, wherein the metal oxide layer is formed in a first region and a second region, and the metal in the second region is formed.
- the thickness of the oxide layer is larger than the thickness of the metal oxide layer in the first region.
- the film thickness of the metal oxide layer in the second region is larger than the film thickness of the metal oxide layer in the first region, good hole injectability in the second region is obtained. While satisfy
- the organic EL element which is 1 aspect of this invention is an organic EL element of Claim 1 or 6,
- region is the said metal oxide in the said 1st area
- the lower surface of the metal oxide layer in the second region is positioned lower than the lower surface of the metal oxide layer in the first region.
- a stepped portion is generated between the regions, and this stepped portion provides an effect that the waveguide loss of light emission can be reduced.
- the organic EL element according to one aspect of the present invention is the organic EL element according to claim 1, wherein the metal oxide layer is formed in the second region without being formed in the first region, The metal oxide layer formed in the second region may be coated with the anode metal layer on the side surface and the bottom surface.
- the metal oxide layer has its side surface portion and lower surface portion covered with the anode metal layer, a part of light emission is prevented from leaking out of the device through the metal oxide layer. The effect that the waveguide loss of light emission can be reduced is obtained.
- the organic EL element according to one aspect of the present invention is the organic EL element according to claim 1 or 2, wherein the anode metal layer is at least one of silver, molybdenum, chromium, vanadium, tungsten, nickel, and iridium. It is preferable that it is a metal containing one.
- the metal oxide layer formed by oxidizing part of the anode metal layer in the opening has a high work function. Therefore, the metal oxide layer can have a high hole injection capability, and an organic EL element excellent in performance such as luminous efficiency and lifetime can be realized.
- An illuminating device includes the organic electroluminescence element according to any one of claims 1 to 10.
- an image display device includes the organic electroluminescence element according to any one of claims 1 to 10.
- the organic EL device manufacturing method includes a metal layer stacking step of stacking an anode metal layer on a substrate, and an insulating layer on the anode metal layer after the metal layer stacking step. Forming an insulating layer; forming an opening from which the insulating layer is partially removed by patterning the insulating layer after the insulating layer forming step; and the opening forming step.
- an oxidation treatment step of forming a metal oxide layer on the surface of the opening by oxidizing the surface of the opening, and on the metal oxide layer oxidized in the oxidation treatment step A hole transport layer forming step of forming a hole transport layer containing a hole transporting organic material by a wet method, a light emitting layer forming step of forming an organic light emitting layer on the hole transport layer, and the organic On the surface of the optical layer, characterized in that it comprises a cathode layer formation step of forming a cathode layer which injects electrons into the organic luminescent layer.
- the hole injection layer having a large work function and capable of reducing the energy barrier against hole injection by oxidizing the anode metal layer. Further, since the hole injection layer is a metal oxide layer, the number of organic layers can be reduced, and an organic layer can be formed thereon by wet printing.
- the manufacturing method of the organic EL element which concerns on 1 aspect of this invention
- WHEREIN The manufacturing method of the organic EL element of Claim 13
- WHEREIN The surface of the said anode metal layer is exposed to air after the said metal layer lamination
- a natural oxide film forming step of forming a metal oxide film by natural oxidation, and the insulating layer forming step is a step of forming an insulating layer on the anode metal layer after the natural oxide film forming step. Also good.
- the metal oxide film is formed on the surface of the anode metal layer by natural oxidation by exposure to the atmosphere.
- the manufacturing method of the organic EL element which concerns on 1 aspect of this invention is a manufacturing method of the organic EL element of Claim 14,
- the said insulating layer is formed after the said insulating layer formation step.
- a natural oxide film formed in a region corresponding to the opening may be removed.
- the surface oxide film is formed by natural oxidation of the anode metal layer in the opening which is the second region.
- the surface oxide may be eluted by washing with, for example, and the surface oxide film in the opening may be removed.
- the metal oxide layer in the opening is not continuously formed with the metal oxide layer in the first region, and the side and bottom surfaces of the metal oxide layer in the second region are anode metal layers. Is covered. Therefore, it is possible to completely prevent a part of light emission from leaking out of the element through the metal oxide layer, and the light guide loss reduction effect becomes remarkable.
- the manufacturing method of the organic EL element which concerns on 1 aspect of this invention is the manufacturing method of the organic EL element of Claim 15,
- the thickness of the metal oxide layer formed by the said oxidation treatment step is said natural oxidation. It is larger than the thickness of the metal oxide layer formed by the film forming step.
- the metal oxide layer formed on the surface of the anode metal layer functions as a hole injection layer having excellent hole injection characteristics.
- the manufacturing method of the organic EL element which concerns on 1 aspect of this invention is a manufacturing method of the organic EL element of Claim 14,
- the surface of the said opening part Is oxidized to form a metal oxide layer having a thickness larger than that of the metal oxide film formed in the natural oxide film forming step on the surface of the opening.
- the metal oxide layer provided on the anode metal layer is At the interface between the first region and the second region, a step is formed so that the second region side is located below the first region side.
- so-called waveguide loss in which emitted light leaks outside using the metal oxide layer formed in the first region as an optical waveguide.
- the method for manufacturing an organic EL element according to one aspect of the present invention is the method for manufacturing an organic EL element according to any one of claims 13 to 17, wherein the oxidation treatment in the oxidation treatment step is performed using an ultraviolet ray. It is preferable to include at least one of optical ozone treatment, plasma treatment in an oxidizing gas atmosphere, and treatment with a solution containing ozone.
- the method for producing an organic EL device according to one aspect of the present invention is the method for producing an organic EL device according to any one of claims 13 to 18, wherein the wet method in the hole transport layer forming step is performed. Is preferably a printing method using a nozzle jet.
- the organic electroluminescence element in the present embodiment (hereinafter referred to as an organic EL element) includes an anode metal layer formed on a substrate, an insulating layer formed in a first region on the anode metal layer, Metal oxide layer formed on the anode metal layer in the first region and the second region, and holes formed on the metal oxide layer in a region where the insulating layer is not formed
- a transport layer, an organic light emitting layer formed on the hole transport layer, and a cathode layer formed on the surface of the organic light emitting layer, and the upper surface of the anode metal layer in the second region is The region is located below the upper surface of the anode metal layer in the region.
- FIG. 1 is a structural cross-sectional view of an organic EL element according to Embodiment 1 of the present invention.
- the organic EL element 1 in the figure includes a substrate 11, an anode metal layer 12, a metal oxide layer 13, an insulating layer 14, a hole transport layer 15, an organic light emitting layer 16, and a cathode layer 17.
- the substrate 11 is not particularly limited, and for example, a glass substrate, a quartz substrate, or the like is used.
- bendability can be imparted to the organic EL element using a plastic substrate such as polyethylene terephthalate or polyethersulfone.
- the structure of the present invention is particularly effective for top-emission organic EL elements, so that an opaque plastic substrate or metal substrate can be used.
- a metal wiring or a transistor circuit for driving the organic EL may be formed on the substrate.
- the anode metal layer 12 is an electrode that is laminated on the surface of the substrate 11 and applies a positive voltage to the organic EL element 1 with respect to the cathode layer 17.
- the metal oxide layer 13 is formed by subjecting the anode metal layer in the middle of the manufacturing process to surface oxidation by the manufacturing process described in the examples. Therefore, the anode metal layer 12 is selected in consideration of the required performance of the metal oxide layer 13 formed by oxidation in a later step, and a metal element whose work function is increased by metal oxidation is selected. This is because a metal oxide layer having high hole injection characteristics needs to have a large work function. Examples of such metal element materials include, but are not limited to, any metal of silver, molybdenum, chromium, vanadium, tungsten, nickel, iridium, alloys of these metals, or Stacked ones can be used.
- the metal oxide layer 13 has a function of injecting holes into the hole transport layer 15 to be described later in a stable manner or assisting the generation of holes.
- the metal oxide layer 13 is formed by oxidizing the surface of the anode metal layer by the manufacturing process described in the examples. Moreover, since the metal oxide layer 13 is comprised with the metal element mentioned above, it has a big work function.
- the organic EL element 1 of the present invention has high hole injection characteristics, it can have high luminous efficiency and long life characteristics.
- the interface in the opening which is the second region where the insulating layer 14 is not formed, is insulated by an artificial oxidation process described later.
- the distance from the upper surface of the substrate 11 is smaller than the interface of the first region under the layer 14.
- the thickness of the anode metal layer 12 in the second region is smaller than the thickness of the anode metal layer 12 in the first region.
- the thickness of the metal oxide layer 13 is preferably 0.1 to 20 nm. More preferably, it is 1 to 10 nm. If the metal oxide layer 13 is too thin, the hole injection property is low due to the problem of uniformity, and if it is too thick, the driving voltage becomes high.
- the step of forming the metal oxide layer 13 on the surface of the anode metal layer 12 is not particularly limited, but ultraviolet light ozone treatment on the surface of the anode metal layer during the production, plasma treatment in an oxidizing gas atmosphere Alternatively, treatment with a solution containing ozone can be preferably used.
- the insulating layer 14 has a function as a bank layer for forming the hole transport layer 15 and the organic light emitting layer 16 formed by a wet printing method in a predetermined region.
- the insulating layer 14 is not particularly limited, and a water-repellent substance is used which is a substance having a resistivity of 10 5 ⁇ cm or more.
- the resistivity is a material having a resistivity of 10 5 ⁇ cm or less
- the insulating layer 14 causes a leakage current between the anode and the cathode or a leakage current between adjacent pixels, and various problems such as an increase in power consumption.
- a hydrophilic substance is used as the insulating layer 14
- the surface of the metal oxide layer 13 is generally hydrophilic, so that the hydrophilicity / hydrophobic difference between the surface of the insulating layer 14 and the surface of the metal oxide layer 13 is different. Becomes smaller. If it does so, it will become difficult to selectively hold
- the material used for the insulating layer 14 may be either an inorganic substance or an organic substance, but the organic substance is generally more preferable because it has a higher water repellency.
- examples of such materials include polyimide and polyacryl.
- fluorine may be introduced.
- the insulating layer 14 may be composed of two or more layers, and may be a combination of the above-described materials, or a combination using an inorganic substance as the first layer and an organic substance as the second layer. May be.
- the insulating layer 14 In order to form a site that operates effectively as an organic EL element, the insulating layer 14 needs to be patterned into a predetermined shape and have at least one opening.
- the patterning method is not particularly limited, but it is preferable to apply a photolithography method using a photosensitive material.
- the shape of the opening may be a pixel-shaped design that uses an opening for each pixel, or may be a line-shaped design that includes a plurality of pixels along one direction of the display panel.
- the hole transport layer 15 has a function of transporting holes injected from the metal oxide layer 13 into the organic light emitting layer 16.
- a hole transporting organic material can be used as the hole transport layer 15.
- the hole transporting organic material is an organic substance having a property of transferring generated holes by intermolecular charge transfer reaction. This is sometimes called a p-type organic semiconductor. Therefore, the hole transport layer 15 is located between the metal oxide layer 13 that is an electron injection layer and the organic light emitting layer 16 and has a function of transporting hole charges.
- the hole transport layer 15 may be a high molecular material or a low molecular material, but it is preferable that the hole transport layer 15 can be formed by a wet printing method, so that it is difficult to elute into the organic light emitting layer 16 when the upper layer is formed. It is preferable that a crosslinking agent is included.
- a crosslinking agent is included as an example of the hole transporting material.
- a copolymer containing a fluorene moiety and a triarylamine moiety or a low molecular weight triarylamine derivative can be used.
- dipentaerythritol hexaacrylate or the like can be used.
- the wet printing method for forming the hole transport layer 15 is not particularly limited, and a nozzle jet method typified by an ink jet method and a dispenser layer can be used.
- the ink jet method is a method of forming the hole transport layer 15 by jetting an organic film-forming material converted into an ink from the nozzle onto the metal oxide layer 13.
- the organic light emitting layer 16 has a function of emitting light by generating an excited state when holes and electrons are injected and recombined.
- the organic light emitting layer 16 it is necessary to use a light emitting organic material that can be formed by a wet printing method. This makes it possible to easily and uniformly form a film on a large-screen substrate.
- This material may be a high molecular material or a low molecular material.
- the cathode layer 17 is not particularly limited, but it is preferable to use a substance and structure having a transmittance of 80% or more. Thereby, a top emission organic EL element with high luminous efficiency can be obtained, and an organic EL element excellent in power consumption and luminance half life can be obtained.
- the configuration of the cathode layer 17 as such a transparent cathode is not particularly limited.
- the cathode layer 17 includes a layer containing an alkaline earth metal, an electron-transporting organic material, and an alkaline earth metal.
- a structure comprising a layer and a metal oxide layer is used.
- the alkaline earth metal magnesium, calcium, and barium are preferably used.
- the electron transporting organic material is not particularly limited, but an electron transporting organic semiconductor material is used.
- the metal oxide layer is not particularly limited, and a layer made of indium tin oxide (hereinafter referred to as ITO) or indium zinc oxide is used.
- ITO indium tin oxide
- the cathode layer 17 As another example of the cathode layer 17, a structure in which a layer containing an alkali metal, an alkaline earth metal, or a halide thereof and a layer containing silver are laminated in this order can be used.
- the layer containing silver may be silver alone or a silver alloy.
- a refractive index adjustment layer having high transparency may be provided from above this layer.
- the lower surface of the metal oxide layer 13 in the second region is located below the lower surface of the metal oxide layer 13 in the first region.
- the upper surface of the anode metal layer 12 in the second region is positioned below the upper surface of the anode metal layer 12 in the first region.
- the thickness of the metal oxide layer 13 in the second region is larger than the thickness of the metal oxide layer 13 in the first region.
- the oxidation of the anode metal layer 12 can provide a large work function between the anode metal layer 12 and the organic light emitting layer 16 and reduce the energy barrier against hole injection.
- the hole injection layer can be formed of a metal oxide layer.
- the hole injection layer does not need to be formed of an organic layer, the number of organic layers can be reduced.
- an organic layer can be formed on the hole injection layer by wet printing.
- FIG. 2 is a structural cross-sectional view illustrating the waveguide loss reduction effect of the organic EL element according to Embodiment 1 of the present invention.
- the light emitted from the organic light emitting layer 16 is emitted in a uniform spherical distribution, that is, isotropically. Part of the emitted light passes through the hole transport layer 15 and reaches the metal oxide layer 13.
- the metal oxide layer 13 has a refractive index of 2.0 or more because of its composition and structure, and has a higher refractive index than other adjacent layers. Therefore, the light incident on the metal oxide layer 13 is easily reflected at the boundary with other layers. At this time, the light incident on the metal oxide layer 13 easily proceeds to the metal oxide layer 13 in the first region using the metal oxide layer 13 having a high refractive index as a waveguide.
- the metal oxide layer 13 according to the present invention has a stepped portion between the first region and the second region, the light reflected at the boundary between the metal oxide layer 13 and the other layer is The light is reflected again into the second region by the step portion and is emitted from the upper surface of the cathode layer 17. Therefore, the light reflected at the boundary between the metal oxide layer 13 and the other layer is prevented from leaking outside using the metal oxide layer 13 in the first region as a waveguide.
- the effect of reducing the waveguide loss of light emission can be obtained by the step portion between the first region and the second region of the metal oxide layer 13.
- the one having a larger surface energy has higher adhesion to a layer laminated on the surface. This is because the surface having a larger surface energy is unstable and tends to reduce the energy by bonding with another layer.
- the surface energy of the metal oxide surface is larger than that of the metal surface. This is because an assembly consisting of metal atoms and oxygen atoms produces surface charges due to the presence of electronic polarization and an unstable surface appears rather than an assembly consisting only of metal atoms. Therefore, the metal oxide surface has higher adhesion to the upper layer than the metal surface.
- an extremely thin oxide film such as a natural oxide film, since the ratio of the metal surface to the surface is high, the adhesion can be further improved by oxidizing to a thickness of several nanometers.
- FIG. 3 is a structural cross-sectional view of an organic EL element showing a modification of the first embodiment of the present invention.
- the organic EL element 2 in the figure includes a substrate 11, an anode metal lower layer 121, an anode metal upper layer 122, a metal oxide layer 13, an insulating layer 14, a hole transport layer 15, an organic light emitting layer 16, A cathode layer 17.
- the organic EL element 2 shown in FIG. 2 differs from the organic EL element 1 shown in FIG. 1 only in that the anode metal layer 12 is composed of two layers.
- description of the same points as the organic EL element 1 is omitted, and only different points will be described.
- the anode metal lower layer 121 is an electrode that is laminated on the surface of the substrate 11 and applies a positive voltage to the organic EL element 2 with respect to the cathode layer 17.
- the anode metal lower layer 121 preferably has a visible light reflectance of 60% or more.
- a material of the anode metal lower layer 121 silver, aluminum, or an alloy containing them is mentioned, for example. Examples of alloys that can be suitably used include silver-palladium, silver-palladium-copper, and aluminum-neodymium.
- a metal having high reflectance can be used as the anode metal lower layer independently of the anode metal upper layer to be oxidized. Therefore, the range of material selection for each layer is widened, and it becomes easier to optimize the performance as a top emission type organic EL element.
- the anode metal upper layer 122 is laminated on the surface of the anode metal lower layer 121.
- the metal oxide layer 13 is formed by surface oxidation of the anode metal upper layer during the manufacturing process by the manufacturing process. Therefore, for the anode metal upper layer 122, a metal element whose work function is increased by metal oxidation is selected in consideration of the required performance of the metal oxide layer 13 formed by oxidation in a later step. This is because a metal oxide layer having high hole injection characteristics needs to have a large work function. Examples of such metal element materials include, but are not limited to, any metal of molybdenum, chromium, vanadium, tungsten, nickel, iridium, alloys of these metals, or stacked layers thereof. Can be used.
- the metal oxide layer 13 having excellent hole injection characteristics can be formed.
- the thickness of the anode metal upper layer 122 is preferably 20 nm or less. This is because if it is thicker than this, the reflectivity of the organic EL element 2 reflects the reflectivity of the anode metal upper layer 122 and it is difficult to reflect the reflectivity of the anode metal lower layer 121.
- a metal having a high reflectance can be used as the anode metal lower layer 121 independently of the anode metal upper layer 122 to be oxidized. Therefore, the range of material selection for each layer is widened, and it becomes easier to optimize the performance as a top emission type organic EL element.
- the anode metal upper layer 122 may disappear in the final manufacturing stage. In this case, the influence of the reflectance of the anode metal upper layer 122 can be minimized.
- the metal oxide layer 13 has a structure in direct contact with the anode metal lower layer 121 in the final manufacturing stage.
- the anode metal lower layer 121 and the anode metal upper layer 122 may be composed of three or more layers.
- the metal oxide layer 13 may not be formed under the insulating layer 14.
- the metal oxide film formed by natural oxidation is exposed to the air to form the surface of the anode metal layer 12 or the anode metal upper layer 122. Formed.
- the metal oxide film by natural oxidation may not be formed on the anode metal layer 12 by performing the insulating film lamination in the next process without exposing the element in the above process to the atmosphere. In this case, the metal oxide layer 13 is not formed under the insulating layer 14.
- the lower surface of the metal oxide layer 13 in the second region is located below the lower surface of the metal oxide layer 13 in the first region.
- the upper surface of the anode metal upper layer 122 in the second region is located below the upper surface of the anode metal upper layer 122 in the first region.
- the thickness of the metal oxide layer 13 in the second region is larger than the thickness of the metal oxide layer 13 in the first region.
- the oxidation of the anode metal upper layer 122 provides a large work function between the anode metal upper layer 122 and the organic light emitting layer 16, and the energy barrier against hole injection can be reduced.
- the injection layer can be formed of a metal oxide layer.
- the hole injection layer does not need to be formed of an organic layer, the number of organic layers can be reduced.
- an organic layer can be formed on the hole injection layer by wet printing.
- FIG. 4 is a process diagram for explaining a method of manufacturing an organic EL element in Example 1 according to the present invention.
- an anode 123 (hereinafter referred to as Mo: Cr (97: 3) having a thickness of 100 nm made of 97% molybdenum and 3% chromium is formed on the surface of a glass substrate 111 (using Matsunami glass-free soda glass) by sputtering. Formed). Then, the anode 123 was patterned into a predetermined anode shape through a patterning process of the anode 123 by photolithography and etching using a photosensitive resist and a peeling process of the photosensitive resist (FIG. 4A).
- etching solution a mixed solution of phosphoric acid, nitric acid and acetic acid was used.
- the outermost surface of the anode 123 is naturally oxidized to form a surface oxide film 131.
- the surface oxide film 131 may not be formed by performing the insulating film lamination in the next process without exposing the element to the atmosphere. In this case, in the next step, the insulating layer 141 is formed on the anode 123.
- photosensitive polyimide was formed as the insulating layer 141 by spin coating, and patterned into a predetermined shape through exposure and development processes using a photomask (FIG. 4B).
- the substrate was cleaned using a neutral detergent and pure water.
- a part of the surface oxide film 131 may be eluted.
- the metal oxide layer as a hole injection layer becomes insufficient, and an organic EL having a low hole injection capability is obtained. End up.
- an artificial oxidation treatment step is introduced after the insulating layer formation step in order to suppress the decrease in hole injection capability.
- UV-ozone treatment irradiation light: 170 nm ultraviolet light, irradiation time: 120 seconds
- the metal oxide layer 132 is in the form of the surface oxide film 131 after the surface treatment, and the surface oxide film 131 before the surface treatment and an oxidation in which part of the anode 123 is artificially oxidized by the surface treatment.
- the anode 124 is in the form of the anode 123 after the surface treatment, and the oxidation region is excluded from the anode 123.
- the film thickness of the metal oxide layer 132 in the opening which is the second region where the insulating layer 141 is not formed, is the surface formed in the first region under the insulating layer 141. It is larger than the film thickness of the metal oxide layer 132 which is an oxide film.
- the hole transport layer 151 was applied to the opening by an inkjet method from a xylene / mesitylene mixed solvent of HT12 manufactured by Summation. And it vacuum-dried for 10 minutes at 50 degreeC, and the crosslinking reaction was performed by heating for 30 minutes at 210 degreeC in nitrogen atmosphere continuously. Although the film thickness is slightly non-uniform depending on the position of the opening, the film was formed to have an average film thickness of 20 nm (FIG. 4D).
- an organic light emitting layer 161 a green light emitting material Lumation Green (hereinafter abbreviated as LGr) manufactured by Summation was applied to the opening by an inkjet method from a mixed solvent of xylene and mesitylene. Then, vacuum drying was performed at 50 ° C. for 10 minutes, followed by baking at 130 ° C. for 30 minutes in a nitrogen atmosphere. The film thickness was slightly non-uniform depending on the position of the opening, but the film was formed to have an average film thickness of 70 nm (FIG. 4E).
- LGr green light emitting material Lumation Green
- barium 5 nm (manufactured by Aldrich, purity 99% or more) was formed by vacuum deposition.
- a film 20 nm of a compound Alq mixed with barium 20% (manufactured by Nippon Steel Chemical Co., Ltd., purity 99% or more) was formed by a co-evaporation method, and finally using a plasma coating apparatus manufactured by Sumitomo Heavy Industries, Ltd.
- the device was sealed in a glass can in a nitrogen dry box having a water and oxygen concentration of 5 ppm or less.
- FIG. 5A is a top view of an organic EL device including an organic EL element manufactured by using the manufacturing method of Example 1 according to the present invention.
- FIG. 5B is a structural cross-sectional view of an organic EL device including an organic EL element manufactured using the manufacturing method of Example 1 according to the present invention.
- the organic EL device described in FIGS. 5A and 5B was manufactured by the manufacturing process described above.
- Example 2 The manufacturing method of the organic EL element in Example 2 according to the present invention is as follows. Barium 5 nm and silver (Aldrich purity 99.9%) 10 nm, refractive index adjustment as the cathode layer 171 described in FIG. The layer was formed in the same manner as in Example 1 except that 80 nm of lithium fluoride was formed as a layer.
- Example 3 The organic EL device manufacturing method in Example 3 according to the present invention was formed in the same manner as in Example 1 except that the oxygen plasma method (plasma time 120 seconds, power 2000 W) was used as the surface treatment method.
- the oxygen plasma method plasma time 120 seconds, power 2000 W
- Example 4 The manufacturing method of the organic EL element in Example 4 according to the present invention is abbreviated as a film having a thickness of 100 nm made of 3% molybdenum and 97% chromium (hereinafter referred to as Mo: Cr (3:97)) as the anode 123 by sputtering. This was formed in the same manner as in Example 1 except that the
- Example 5 In the method of manufacturing an organic EL element in Example 5 according to the present invention, a silver / palladium / copper alloy film 100 nm is first formed as an anode 123 by sputtering, and then a film thickness of 10 nm comprising 3% molybdenum and 97% chromium. Were formed by the same method as in Example 1 except that the anodes 123 (hereinafter sometimes abbreviated as APC / Mo: Cr (3:97)) were formed by sputtering.
- APC / Mo: Cr (3:97) the anodes 123
- Comparative Example 1 The manufacturing method of the organic EL element in Comparative Example 1 was the same as that of Example 1 except that molybdenum trioxide 30 nm was formed by a vapor deposition method as a hole injection layer after surface cleaning, and the surface oxidation treatment was not performed. Formed.
- Comparative Example 2 In the method of manufacturing the organic EL element in Comparative Example 2, a 100 nm film composed of 97% molybdenum and 3% chromium is formed as the anode 123, and then a conventionally used ITO film is formed to 40 nm by the same sputtering method. The etching process for patterning the shape of the anode 123 was performed in the same manner as in Example 1 except that a mixed solvent of hydrochloric acid and nitric acid was used.
- Comparative Example 3 In the manufacturing method of the organic EL element in Comparative Example 3, before the hole transport layer 151, PEDOT: PSS (manufactured by HC Stark), which has been conventionally used, was applied to the opening by an inkjet method. And it vacuum-dried for 10 minutes at 50 degreeC, and performed the vacuum baking for 40 minutes at 200 degreeC succeedingly. Although the film thickness slightly varies depending on the position of the opening, the film was formed in the same manner as in Example 1 except that the film was formed to have an average film thickness of 40 nm.
- PEDOT: PSS manufactured by HC Stark
- Comparative Example 4 The manufacturing method of the organic EL element in Comparative Example 4 was formed in the same manner as in Example 1 except that the manufacturing process of Summation HT12 which is the hole transport layer 151 was omitted.
- Comparative Example 5 The organic EL device manufacturing method in Comparative Example 5 was formed in the same manner as in Example 1 except that the surface-oxidation UV-ozone treatment was omitted.
- the molybdenum trioxide layer was present on the insulating layer, so that the contact angle was 5 ° or less, similar to that on the oxidized metal oxide layer 132. Met.
- the drive voltage and the light emission efficiency at this time were obtained by measuring the drive voltage and luminance when a current of 10 mA / cm 2 was passed through the device with the anode 124 side being positive and the cathode layer 171 side being negative. . Further, these elements were made to emit light at 4000 cd / m 2 , the attenuation of luminance was measured when they were continuously driven at a constant current, and the time when the luminance was reduced to half (2000 cd / m 2 ) was defined as the element lifetime.
- Example 1 based on the present invention, a good driving voltage of about 7.2 V, a high luminous efficiency of 5.0 cd / A, and a long luminance half-life of 560 hours were obtained.
- Example 2 using thin silver as the cathode layer 171 and Example 3 using oxygen plasma treatment as the oxidation treatment, almost the same device performance as in Example 1 was obtained.
- Example 4 in which the ratio of molybdenum and chromium was reversed, the reflectance of the anode was improved by about 10%, so that the loss of light during anode reflection was suppressed and the luminous efficiency was improved by about 10%. As a result, the current required for obtaining 4000 cd / cm 2 can be reduced, and the life is also improved.
- Example 5 in which a high reflectance metal (here, APC), which is a more preferable embodiment of the present invention, was used as an anode metal underlayer and MoCr (3:97) was formed thereon, light loss in the anode metal underlayer was achieved. As a result, the luminous efficiency increased to 9.3 cd / A and the luminance half-life also increased to 910 hours.
- APC high reflectance metal
- Comparative Example 4 having no hole transport layer, the hole injection property was not sufficient as in Comparative Example 2, the light emission efficiency was low, and the lifetime was extremely shortened.
- Comparative Example 5 in which the surface oxidation treatment was not performed, as in Comparative Examples 2 and 4, the hole injection property was not sufficient, the luminous efficiency was low, and the lifetime was extremely shortened.
- the surface oxide film 131 in the opening is artificially oxidized. Accordingly, the hole injection characteristics are excellent, the number of organic layers can be reduced, and the hole transport layer and the organic light emitting layer can be formed by wet printing.
- the oxidation of the surface oxide film 131 in the opening is promoted.
- the film thickness of the anode 124 in the opening region is It becomes smaller than the film thickness of the anode 124 under the insulating layer 141.
- the hole injection layer that has a large work function and can reduce the energy barrier against hole injection by oxidizing the anode 123. Further, since the hole injection layer is the metal oxide layer 132, the number of organic layers can be reduced, and an organic layer can be formed thereon by wet printing.
- the metal oxide layer 132 in the second region is larger than the film thickness of the metal oxide layer 132 in the first region, the metal oxide layer 132 provided over the anode 124 At the interface between the first region and the second region, a step is formed so that the second region side is located below the first region side. As a result, it is possible to reduce so-called waveguide loss, in which emitted light leaks outside using the metal oxide layer 132 formed in the first region as an optical waveguide.
- the thickness of the anode 124 in the opening region which is the structure of the present invention, is smaller than the thickness of the anode 124 under the insulating layer 141. Since the interface with the metal oxide layer 132 can be determined, it can be determined by the distance between the interface and the lower surface of the anode 124.
- a positive hole injection layer made of a metal oxide having a high work function as seen in the above embodiment is formed between the positive electrode and the positive hole transport layer, so that the positive electrode side has a high positive hole injection capability. It becomes possible. Therefore, it is possible to realize an organic EL element having excellent performance such as luminous efficiency and lifetime.
- Example 5 it is possible to form a lower layer with high visible light reflectance and an upper layer with high visible light transparency by laminating the anode metal layer into two layers, an upper layer and a lower layer. Become. Thereby, optimization of the performance as a top emission type organic EL element becomes easier.
- the surface oxide film 131 by natural oxidation of the anode 123 is formed in the opening which is the second region.
- the surface oxide film 131 may be removed by washing the surface of the oxide film 131 with an alkaline solution or the like to elute the surface oxide. Thereafter, the surface of the anode 123 in the opening from which the surface oxide film 131 has been removed is subjected to an artificial oxidation process in the next step so that the surface oxide film 131 due to natural oxidation is not formed in the opening. can do.
- the metal oxide layer 132 in the opening is not continuously formed with the metal oxide layer 132 under the insulating layer 141, and the surface oxide film 131 in the opening has a side surface portion and a lower surface portion. Covered by the anode 124. Therefore, it is possible to completely prevent a part of light emission from leaking out of the element through the metal oxide layer, and the light guide loss reduction effect becomes remarkable.
- the thickness of the metal oxide layer formed by the artificial oxidation process in the next step is preferably larger than the thickness of the surface oxide film 131 formed by natural oxidation. Thereby, the metal oxide layer formed on the metal surface functions as a hole injection layer having excellent hole injection characteristics.
- the organic EL element in the present embodiment includes an anode metal layer formed on a substrate, an insulating layer formed in a first region on the anode metal layer, and an anode metal layer on the first metal layer.
- An organic light emitting layer formed on the surface of the organic light emitting layer and a cathode layer formed on the surface of the organic light emitting layer, the upper surface of the anode metal layer in the second region is more than the upper surface of the anode metal layer in the first region It is located below. Thereby, it is excellent in a hole injection characteristic, the number of layers of an organic layer can be reduced, and organic layer film formation by wet printing is attained.
- FIG. 6 is a structural cross-sectional view of the organic EL element in the second embodiment of the present invention.
- the organic EL element 4 in the figure includes a substrate 11, an anode metal layer 12, a metal oxide layer 43, an insulating layer 14, a hole transport layer 15, an organic light emitting layer 16, and a cathode layer 17. .
- the organic EL element 4 described in FIG. 6 differs from the organic EL element 1 described in FIG. 1 only in that the metal oxide layer is not formed in the first region below the insulating layer. . Description of the same points as those of the organic EL element 1 shown in FIG. 1 is omitted, and only different points will be described below.
- the metal oxide layer 43 has a function of injecting holes into the hole transport layer 15 described later by stabilizing holes or assisting the generation of holes.
- the metal oxide layer 43 is formed by oxidizing the surface of the anode metal layer by a manufacturing process described later. Moreover, since the metal oxide layer 43 is comprised with the metal element mentioned above, it has a big work function.
- the organic EL element 4 of the present invention has high hole injection characteristics, it is possible to have high luminous efficiency and long life characteristics.
- the film thickness of the metal oxide layer 43 is preferably 0.1 to 20 nm. More preferably, it is 1 to 10 nm. If the metal oxide layer 43 is too thin, the hole injection property is low due to the problem of uniformity, and if it is too thick, the drive voltage becomes high.
- the step of forming the metal oxide layer 43 on the surface of the anode metal layer 12 is not particularly limited, but ultraviolet light ozone treatment and plasma treatment in an oxidizing gas atmosphere are performed on the surface of the anode metal layer during the production. Alternatively, treatment with a solution containing ozone can be preferably used.
- the upper surface of the anode metal layer 12 in the second region is located below the upper surface of the anode metal layer 12 in the first region.
- the oxidation of the anode metal layer 12 can provide a large work function between the anode metal layer 12 and the organic light emitting layer 16 and reduce the energy barrier against hole injection.
- a hole injection layer can be formed.
- the hole injection layer does not need to be formed of an organic layer, the number of organic layers can be reduced.
- an organic layer can be formed on the hole injection layer by wet printing.
- the metal oxide layer 43 is formed in the second region without being formed in the first region, and the metal oxide layer 43 formed in the second region has an anode metal layer on its side surface and lower surface. 12 is covered.
- the metal oxide layer 43 is covered with the anode metal layer 12 on the side surface and the lower surface, it is possible to prevent a part of light emission from leaking out of the device through the metal oxide layer 43.
- the effect of reducing the waveguide loss can be obtained.
- FIG. 7 is a process diagram for explaining a method of manufacturing an organic EL element according to Embodiment 2 of the present invention.
- an anode 123 (hereinafter referred to as Mo: Cr (97: 3) having a thickness of 100 nm made of 97% molybdenum and 3% chromium is formed on the surface of a glass substrate 111 (using Matsunami glass-free soda glass) by sputtering. To form). Then, the anode 123 is patterned into a predetermined anode shape through a patterning process of the anode 123 by photolithography and etching using a photosensitive resist and a peeling process of the photosensitive resist (FIG. 7A).
- a mixed solution of phosphoric acid, nitric acid and acetic acid is used as the etchant.
- the surface oxide film 131 is naturally formed, the surface oxide is eluted by washing the surface with an alkaline solution or the like, and the surface oxide film 131 is removed. As a result, in the next step, the insulating layer 141 is formed directly on the anode 123.
- the surface oxide film 131 can be prevented from being formed by performing the insulating film lamination in the next process without exposing the element to the atmosphere.
- photosensitive polyimide is formed as the insulating layer 141 by spin coating, and patterned into a predetermined shape through exposure and development processes using a photomask (FIG. 7C).
- the substrate is cleaned using a neutral detergent and pure water.
- the surface oxide film does not exist at this stage, problems in the form in which the surface oxide film exists are prevented in advance. That is, when the surface oxide film 131 is present, in the substrate cleaning process, the surface oxide film is water-soluble, so that part of the surface oxide film may be eluted. When a hole transport layer is laminated on a state in which a part of the surface oxide film is eluted, the metal oxide layer as the hole injection layer becomes insufficient, resulting in an organic EL element having a low hole injection capability. End up.
- the insulating layer 14 is formed in a state where the surface oxide film 131 does not exist, and then an artificial oxidation treatment process is introduced. .
- UV-ozone treatment irradiation light: 170 nm ultraviolet light, irradiation time: 120 seconds
- the metal oxide layer 432 is an oxidized region in which a part of the anode 123 is artificially oxidized by the surface treatment.
- the anode 124 is in the form of the anode 123 after the surface treatment, and the oxidation region is excluded from the anode 123.
- the metal oxide layer 432 is not formed in the first region corresponding to the insulating layer 14, but is formed only in the second region corresponding to the opening, and the metal oxide layer 432 is formed as shown in FIG. ), The side surface portion and the lower surface portion are covered with the anode 124. According to this embodiment, a part of light emission is prevented from leaking to the outside of the element through the metal oxide layer, and an incidental effect that the waveguide loss of light emission can be reduced is also expected.
- the subsequent steps that is, the step of forming the hole transport layer 151, the organic light emitting layer 161, and the cathode layer 171 (FIGS. 7E, 7F, and 7G) are the same as those in the first embodiment. Since it is the same as that of Example 1, description is abbreviate
- the hole injection layer that has a large work function and can reduce the energy barrier against hole injection by oxidizing the anode 123. Further, since the hole injection layer is the metal oxide layer 432, the number of organic layers can be reduced, and an organic layer can be formed thereon by wet printing.
- the anode metal layer 12 in the second embodiment may be composed of the anode metal lower layer 121 and the anode metal upper layer 122 like the anode metal layer in the modification of the first embodiment.
- the electrode which the organic EL element of this invention has may be uniformly formed in the whole surface or most part on a board
- this electrode may be patterned so that a specific figure and a character can be displayed.
- a characteristic pattern of light emission can be obtained, which can be used for advertising display.
- a large number of the electrodes may be arranged in a matrix.
- the electrode may be formed on the substrate on which the transistor array is arranged so that electrical connection can be obtained in a form corresponding to the transistor array. In this case, as represented by the TV described in FIG. 8, it can be used as an image display device such as an active drive display panel.
- the organic EL device according to the present invention is useful as a pixel light source of a display device, a backlight of a liquid crystal display, various illumination light sources, a light source of an optical device, etc. In particular, it is suitable for application to an active matrix organic EL display panel combined with a TFT.
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Abstract
Description
本実施の形態における有機エレクトロルミネッセンス素子(以下、有機EL素子と記す)は、基板の上に形成された陽極金属層と、当該陽極金属層の上の第1領域に形成された絶縁層と、当該陽極金属層の上であって第1領域及び第2領域に形成された金属酸化物層と、当該金属酸化物層の上であって絶縁層の形成されていない領域に形成された正孔輸送層と、当該正孔輸送層の上に形成された有機発光層と、当該有機発光層の表面上に形成された陰極層とを備え、第2領域における陽極金属層の上面は、第1領域における陽極金属層の上面よりも下方に位置することを特徴とする。これにより、正孔注入特性に優れ、有機層の層数を削減でき、湿式印刷による有機層製膜が可能となる。
次に、実施例及び比較例を挙げながら本発明を説明する。
図4は、本発明に係る実施例1における有機EL素子の製造方法を説明する工程図である。
本発明に係る実施例2における有機EL素子の製造方法は、図4に記載された陰極層171として、真空蒸着法により、バリウム5nmと銀(アルドリッチ製純度99.9%)10nm、屈折率調整層としてフッ化リチウム80nmを形成した以外は、実施例1と同様にして形成した。
本発明に係る実施例3における有機EL素子の製造方法は、表面処理方法として、酸素プラズマ法(プラズマ時間120秒、パワー2000W)を用いた以外は、実施例1と同様にして形成した。
本発明に係る実施例4における有機EL素子の製造方法は、陽極123としてスパッタ法によりモリブデン3%、クロム97%からなる膜厚100nmの膜(以下、Mo:Cr(3:97)と略することがある)を用いた以外は、実施例1と同様にして形成した。
本発明に係る実施例5における有機EL素子の製造方法は、陽極123としてまず、銀/パラジウム/銅合金膜100nmをスパッタ法により形成し、その後にモリブデン3%、クロム97%からなる膜厚10nmを同じくスパッタ法により積層して陽極123(以下、APC/Mo:Cr(3:97)と略することがある)とした以外は、実施例1と同様にして形成した。
比較例1における有機EL素子の製造方法は、表面洗浄後に正孔注入層として三酸化モリブデン30nmを蒸着法により形成したこと、および表面酸化処理を行わなかったこと以外は、実施例1と同様にして形成した。
比較例2における有機EL素子の製造方法は、陽極123としてモリブデン97%、クロム3%からなる100nmの膜を形成し、その上から、従来用いられてきたITO膜を同じくスパッタ法により40nm形成し、陽極123の形状パターニングのためのエッチング工程として、塩酸と硝酸の混合溶媒を用いて行った以外は、実施例1と同様にして形成した。
比較例3における有機EL素子の製造方法は、正孔輸送層151の前に、従来用いられてきた、PEDOT:PSS(HC Stark社製)をインクジェット法により開口部に塗布した。そして、50℃で10分間真空乾燥を行い、引き続き、200℃で40分間真空ベークを行った。開口部の位置によって、若干膜厚の不均一性が生じるが、平均膜厚40nmとなるように形成した以外は、実施例1と同様にして形成した。
比較例4における有機EL素子の製造方法は、正孔輸送層151であるサメイション製HT12の製造工程を省いた以外は、実施例1と同様にして形成した。
比較例5における有機EL素子の製造方法は、表面酸化処理であるUV-オゾン処理を省いた以外は、実施例1と同様にして形成した。
以上の実施例1~5及び比較例1~5において、本発明の効果を示すために以下の評価を行った。
本実施の形態における有機EL素子は、基板の上に形成された陽極金属層と、当該陽極金属層の上の第1領域に形成された絶縁層と、当該陽極金属層の上であって第1領域以外の第2領域に形成された金属酸化物層と、当該金属酸化物層の上であって絶縁層の形成されていない領域に形成された正孔輸送層と、当該正孔輸送層の上に形成された有機発光層と、当該有機発光層の表面上に形成された陰極層とを備え、第2領域における陽極金属層の上面は、第1領域における陽極金属層の上面よりも下方に位置することを特徴とする。これにより、正孔注入特性に優れ、有機層の層数を削減でき、湿式印刷による有機層製膜が可能となる。
11 基板
12 陽極金属層
13、43、132、432 金属酸化物層
14、141 絶縁層
15、151 正孔輸送層
16、161 有機発光層
17、171 陰極層
111 ガラス基板
121 陽極金属下層
122 陽極金属上層
123、124 陽極
131 表面酸化膜
Claims (19)
- 基板と、
前記基板の上に形成された陽極金属層と、
前記陽極金属層の上であって、第1領域に形成された絶縁層と、
前記陽極金属層の上であって、前記基板の上に積層された陽極金属層の表面が酸化されることにより、前記第1領域以外の第2領域に少なくとも形成された金属酸化物層と、
前記金属酸化物層の上であって、前記絶縁層の形成されていない第2領域に形成され、正孔輸送性の有機材料を含む正孔輸送層と、
前記正孔輸送層の上に形成された有機発光層と、
前記有機発光層の上に形成され、前記有機発光層へ電子を注入する陰極層とを備え、
前記第2領域における前記陽極金属層の上面は、前記第1領域における前記陽極金属層の上面よりも下方に位置する
有機エレクトロルミネッセンス素子。 - 前記陽極金属層は、
可視光の反射率が60%以上である陽極金属下層と、
前記陽極金属下層の表面上に積層された陽極金属上層とを備える
請求項1記載の有機エレクトロルミネッセンス素子。 - 前記陽極金属下層は、アルミニウム及び銀のうち少なくとも1つを含む合金であり、
前記陽極金属上層は、モリブデン、クロム、バナジウム、タングステン、ニッケル、イリジウムのうち少なくとも1つを含む金属である
請求項2記載の有機エレクトロルミネッセンス素子。 - 前記第2領域における前記陽極金属上層の膜厚は、20nm以下である
請求項2または3に記載の有機エレクトロルミネッセンス素子。 - 前記第2領域には、前記陽極金属上層が形成されていない
請求項4記載の有機エレクトロルミネッセンス素子。 - 前記金属酸化物層は、さらに、前記第1領域にも形成されている
請求項1に記載の有機エレクトロルミネッセンス素子。 - 前記金属酸化物層は、第1領域および第2領域に形成され、
前記第2領域における前記金属酸化物層の膜厚は、前記第1領域における前記金属酸化物層の膜厚よりも大きい
請求項1に記載の有機エレクトロルミネッセンス素子。 - 前記第2領域における前記金属酸化物層の下面は、前記第1領域における前記金属酸化物層の下面よりも下方に位置する
請求項1または6に記載の有機エレクトロルミネッセンス素子。 - 前記金属酸化物層は、前記第1領域に形成されることなく前記第2領域に形成され、
前記第2領域に形成された前記金属酸化物層は、その側面部および下面部が前記陽極金属層により被覆される
請求項1記載の有機エレクトロルミネッセンス素子。 - 前記陽極金属層は、銀、モリブデン、クロム、バナジウム、タングステン、ニッケル、イリジウムのうち少なくとも1つを含む金属である
請求項1または2に記載の有機エレクトロルミネッセンス素子。 - 請求項1~10のうちいずれか1項に記載の有機エレクトロルミネッセンス素子を備える照明装置。
- 請求項1~10のうちいずれか1項に記載の有機エレクトロルミネッセンス素子を備える画像表示装置。
- 基板上に陽極金属層を積層する金属層積層ステップと、
前記金属層積層ステップの後、前記陽極金属層の上に絶縁層を形成する絶縁層形成ステップと、
前記絶縁層形成ステップの後、前記絶縁層をパターニングすることにより、前記絶縁層が一部除去された開口部を形成する開口部形成ステップと、
前記開口部形成ステップの後、前記開口部の表面を酸化処理することにより前記開口部表面に金属酸化物層を形成する酸化処理ステップと、
前記酸化処理ステップにて酸化処理された前記金属酸化物層の上に、正孔輸送性の有機材料を含む正孔輸送層を湿式法により形成する正孔輸送層形成ステップと、
前記正孔輸送層の上に、有機発光層を形成する発光層形成ステップと、
前記有機発光層の表面上に、前記有機発光層へ電子を注入する陰極層を形成する陰極層形成ステップとを含む
有機エレクトロルミネッセンス素子の製造方法。 - 前記金属層積層ステップの後、大気にさらすことにより前記陽極金属層の表面に自然酸化による金属酸化膜を形成する自然酸化膜形成ステップを含み、
前記絶縁層形成ステップは、前記自然酸化膜形成ステップの後、前記陽極金属層の上に絶縁層を形成するステップである
請求項13記載の有機エレクトロルミネッセンス素子の製造方法。 - 前記開口部形成ステップでは、
前記絶縁層形成ステップの後、前記絶縁層をパターニングすることにより、前記絶縁層が一部除去された開口部を形成するとともに、開口部に対応する領域に形成された自然酸化膜を除去する
請求項14に記載の有機エレクトロルミネッセンス素子の製造方法。 - 前記酸化処理ステップにより形成される金属酸化物層の厚みは、前記自然酸化膜形成ステップにより形成される金属酸化物層の厚みよりも大きい
請求項15記載の有機エレクトロルミネッセンス素子の製造方法。 - 前記酸化処理ステップでは、
前記開口部形成ステップの後、前記開口部の表面を酸化処理することにより前記開口部表面に、前記自然酸化膜形成ステップにより形成される金属酸化物膜の膜厚よりも大きな膜厚である金属酸化物層を形成する
請求項14に記載の有機エレクトロルミネッセンス素子の製造方法。 - 前記酸化処理ステップにおける前記酸化処理は、紫外光オゾン処理、酸化性ガス雰囲気でのプラズマ処理、及びオゾンを含む溶液による処理のうち少なくとも1つを含む
請求項13~17のうちいずれか1項に記載のエレクトロルミネッセンス素子の製造方法。 - 前記正孔輸送層形成ステップにおける前記湿式法は、ノズルジェットによる印刷法である
請求項13~18のうちいずれか1項に記載のエレクトロルミネッセンス素子の製造方法。
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Also Published As
Publication number | Publication date |
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JP2011091459A (ja) | 2011-05-06 |
WO2010032444A1 (ja) | 2010-03-25 |
KR101153037B1 (ko) | 2012-06-04 |
CN101911831A (zh) | 2010-12-08 |
JP4723693B2 (ja) | 2011-07-13 |
JP5490745B2 (ja) | 2014-05-14 |
JPWO2010032443A1 (ja) | 2012-02-02 |
US20100258833A1 (en) | 2010-10-14 |
CN101904220B (zh) | 2013-05-15 |
KR20100075633A (ko) | 2010-07-02 |
CN101904220A (zh) | 2010-12-01 |
KR101148458B1 (ko) | 2012-05-24 |
JP2011119288A (ja) | 2011-06-16 |
US8324617B2 (en) | 2012-12-04 |
KR20100080832A (ko) | 2010-07-12 |
US8334529B2 (en) | 2012-12-18 |
CN101911831B (zh) | 2013-08-14 |
JP2011009242A (ja) | 2011-01-13 |
JP2011091458A (ja) | 2011-05-06 |
JP4723692B2 (ja) | 2011-07-13 |
US20110042703A1 (en) | 2011-02-24 |
JP4750902B2 (ja) | 2011-08-17 |
JPWO2010032444A1 (ja) | 2012-02-02 |
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