Title: 9e 49p

This document was too large to scan as a whole document, 

therefore it required breaking into smaller sections. 

Document number: sb- 

Section, of 

Title: 9e 49p ;x- 

10 ipy eT Foe %4 d,C .7y/-!^ /O^ /^ysH /fir of 

e/72ES Sg? 74 ^9 

Date: lelw /9s Revision: ,Pool 

Originator: 

Co: W/-/c 

Recipient: 

Co: 

References: G^CN- ^,Z383s

TAP 

omimy

WESTINGHOUSE HANFORD COMPANY 

2225 LABORATORY 

INORGANIC ANALYTICAL BATCH AND SUMMARY SHEET 

ANION ANALYSIS ON DIONEX 

SAMPLE e: S95T001890 6 

TEST CODE: @k-01 ANALYST: Ed Colvin 

INSTRUMENT: ICO2 ANALYSIS DATE: 10/12/95 

WORK LIST e: 2953 SAMPLE POINT: 6.104 

BATCH ID: SAMPLE PREP: water digest 

Um. PYY Fluoride Chloride 

Nitrite Nitrate 

Phosphate Sulfate I Bromide Oxalots, 

109NSA 98.1% 87.0% 93.8% 98.0% 91.4% 95.3% 95.4% 95.2% 

3957001860 2.96E+03 2.20E+03

LAS LEADER INFO 

.: .oxd 

.M w0.: 1 

Lola 2003 

Ilnit. 

0.r L: 

LA4133.1 011 D•1 

look NMRMr. 1MN0A 

Saimple 0: 1 

Jonn Frye 

Dr.: 10/17015 

JW Frye 

Ed C.Nb 

DOB: t0M2M 

Co0.: KM 

M30 AM 

0 

WntF/ 

P.YtD 610.1 

ANDARD 1 0fN0.L 

YPIE 1 0067muo 

PIJCA» 1 090700/ 

MPLE2 

PLICATE 2 

MPLl3 

MPLE 0 

7E 3 

PLIG7E 4 

OIIP LICA7E 

M67Mi 

nOrd DM. 67.91 Tul M1 SUAI MAI 03 "U 000.9 

1 D.1. 3.10E-01 237E-01 273E+3 x.x7E+02 1.MEW7 .032 

1 DRObn FMW 10+ 101 +0+ 104-- 01 190 101 »1 101 

1 OF +a» 10.» t0.» t0.» t0.» 10.» 1 0.» +0.» 

1 O.to 3.91E+01 230E-01 500 203E-03 xA1E+02 100E-0x 

1 ObRbn Fr3M 101 101 190 101 101 10+ 190 101 

1 DF 10JN 197090 10AMI Ismm;I 10AMI lomi lo.mi loAM 

VOY.n. 1.00E-01 1AW41 1AOE-01 1.00E-01 +.09E-01 1.00E-0+ 1.99E-01 1AOE-01 

OW VOYrr M 10.10 1 0.10 10.10 10.10 10.10 1 0.10 10.10 10.10 

Cola. M » 033 010 OM al 070 690 

tJMR 0.9 63 a.OM 0.990 0.911111 0.O 0.990 0.970 0.032 0A» 

D.I.e+bn LO.II1 0.90E -02 7.90E-02 0.19E+03 0. 90E+03 0.E-03 00 0.30E-03 5.92E+3 aME-03 

D.rMbn LOnA2 ERR ERR ERR ERR ERR ERR ERR ERR 

D.f e0.n Undt3 ERR ERR ERR ERR ERR ERR ERR ERR 

D.hctlrlLMt1 ERR ERR ERR ERR ERR ERR ERR ERR 

.15.ns..s • M000.wOwM1FM+Y7Rar%+..M%OM.V.L71PW Or715rMY0M1ew 

M^ R> •W ^w^rf •LwM rMYamY Yr^r MCYM YP r MOfrMrl+wYmsJ 

Oytrr AtlM.%DrwMr • R..MY' W41Y11DYMY• 0.7.eM Ip • I..xl 

W Y^ V.Y^ w t+Y.YY.Or.h 0^YlM 11wP0\Ma lO^ 

1 11,2OD)LY/1111 1011790 M:M:M PM P.0.2ot2

----------------------------------------------------------------------------- 

Sample Name: 109N9 -A STD . 1-10 Date: 10/12 / 1995 09:13:04 

Data File : C:\DX \DATA\ 95101271.D03 

Method : C:\DX\METHOD \AS12A.MET 

CI Address: 1 System: 1 Inject #: 3 Detector:CDM-1 

nalyst Ed Colvin Column: AG4A - SC,AS4A - SC, SRS 

Calibration Volume Dilution Points Rate Start Stop Area Reject 

-------------------------------------------------------------------- 

External 1 101 5400 5Hz 0.00 18.00 200 

* r+*+ +++++*r +*+ +r**++ Peak Report: All Peaks 

8.0 

7.0 

6.0 

5.0 

4.0 

US 3.0 

2.0 

1.0 

0.0 

-1.0 

+ rr ***r+ **+ trtr *+ * *t* * 

Pk. Ret Component Concentration Height Area B1. $Del ta 

Num Time Name ug/ml Code 

----------------------------------------------------------------------------- 

1 1.64 

0.000 213 2035 2 

2 2.20 FLUORIDE 57.935 2311 15871 2 -0.45 

3 2.67 FORMATE 22.377 179 1896 2 1.91 

4 3.65 CHLORIDE 76.651 1808 14877 1 -0.27 

5 4.52 NITRITE 500.068 6569 68267 1 0.22 

6 7.11 BROMIDE 548.810 3141 48049 1 3.64 

7 8.30 NITRATE 589.448 3494 66753 2 5.46 

8 9.21 PHOSPHATE 498.967 1223 26758 2 0.33 

9 12.22 SULFATE 601.594 3102 89084 1 1.16 

10 16.25 OXALATE 500.805 1278 48184 1 1.69 

------------------------------------ 

Totals 3396.656 23317 381774 

File: 95101271.D03 Sample: 109N9-A STD .1-10 

Minutes 

SIGNATEME ABOVE REPRESENTS CHEMICAL THC ENOLOGIST/CHEMIST THAT / p 

CM44 E'TED/VERIFIED TH E CALIHHATION/ANALYSIS ON PACES3k&j 1U ^b`D 

344 , Z3 

B 

u ^^ ^, `_'^-

Sample Name PREP BLANK Date 10/12/1995 08:53:47 

Data File : C:\DX\DATA\95101271.D02 

Method : C:\DX\METHOD\AS12A.MET 

ACI Address: 1 System: 1 Inject#: 2 Detector:CDM-1 

Analyst Ed Colvin Column: AG4A-SC,AS4A-SC, SRS 


-------------------------------------------------------------------- 

External 1 1 5400 5Hz 0.00 18.00 200 

f*•rrrrr . r*xrt +**+ ++rw*++* Peak Report: All Peaks rtrer+rt 

**+:* r+:•*+*t+t+tt 

Pk. Ret Component Concentration Height Area B1. tDelta 


----------------------------------------------------------------------------- 

2 3.67 CHLORIDE 0.041 55 400 1 0.27 

3 8.43 NITRATE 0.231 35 519 1 7.12 

------------------------------------ 

Totals 0.272 90 919 

us 

3.0 

2.0 

1.0 

0.0 

-1.0 

-2.0 

File: 95101271.D02 Sample: PREP BLANK 

Minutes 

344. a^n4 

:^^;.-P-131. Fir. l

----------------------------------------------------------------------------- 

Sample Name: INSTR BLANK Date: 10/12/1995 08:33:16 



1CI Address: 1 System: 1 Inject#: 1 Detector:CDM-1 

analyst Ed Colvin Column: AG4A-SC,AS4A-SC, SRS 


-------------------------------------------------------------------- 

External 1 1 5400 5Hz 0.00 18.00 200 

+rrrrr+.x*ter•+*trr+*++mot+ Peak Report: All Peaks*t*+r:***+tttrrrrrt++**++ 

Pk. Ret Component Concentration Height Area B1. %Delta 


----------------------------------------------------------------------------- 

1 1.65 0.000 61 582 1 

2 2.70 FORMATE 0.257 214 2294 1 3.05 

------------------------------------ 

Totals 0.257 275 2876 

us 

0.4 

0.3 

0.2 

0.1 

0.0 

-0.1 

File: 95101271.D01 Sample: INSTR BLANK 

Minutes 

344. r;J 

3

Sample Name: S95T001860 .1-10 Date: 10/12/1995 09:33:25 






-------------------------------------------------------------------- 

External 1 101 5400 5Hz 0.00 18.00 200 

+++++++++++++++++++++++++++ Peak Report: All Peaks ++++++++++++++++++++++++++++ 

Pk. Ret Component Concentration Height Area B1. IDelta 


----------------------------------------------------------------------------- 

1 1.64 

0.000 177 1622 2 

2 2.20 FLUORIDE 31.937 1215 8313 2 -0.45 

3 2.80 FORMATE 43.568 316 4224 2 6.87 

4 3.65 CHLORIDE 23.794 512 4290 1 -0.27 

5 4.52 NITRITE < 54.796 249 2470 1 0.22 

6 8.08 NITRATE 2730.046 15427 331681 2 2.67 

7 9.24 PHOSPHATE 226.777 511 11140 2 0.65 

8 12.27 SULFATE 199.077 932 26461 1 1.57 

16 

------------------------------------ 

Totals 3309.996 19339 390203 

File: 95101271.D04 Sample: S95T001860.1-10 

NITRATE 

I 

14 BESTAVAILABLE COPY 

12 

10 

8 

US 6 

4 

FLUORIDE SULFATE 

2 FgRI1k4h^ROPITEOSFHATE 

-2 

0 2 4 6 8 10 12 14 16 

Minutes 

344e 1106 

nv- 

18

-------------------------------------- 

------------------------- 

Sample Name: S95T001860 DUP .1-10 

Date: 10/12/1995 11:19:04 



'1CI Address: 1 System: 1 Inject#: 8 Detector:CDM-1 

.nalyst Ed Collvin Column: AG4A-SC,AS4A-SC, SRS 

Co 


-------------------------------------------------------------------- 

External 1 101 5400 SHz 0.00 18.00 200 


Pk. 

Num 

Ret Component 

Time Name 

Concentration 

ug/ml 

Height Area B1. 

Code 

%Delta 

----------------------------------------------------------------------------- 

1 

2 

3 

4 

5 

6 

7 

8 

1.64 

2.19 FLUORIDE 

2.79 FORMATE 

3.64 CHLORIDE 

4.51 NITRITE < 

8.05 NITRATE 

9.24 PHOSPHATE 

12.26 SULFATE 

0.000 

34.085 

49.309 

23.577 

55.883 

2832.043 

241.444 

204.746 

194 

1224 

339 

523 

261 

16001 

535 

974 

1904 

8936 

4856 

4247 

2631 

344949 

11975 

27335 

2 

2 

2 

1 

1 

2 

2 

1 

-0.90 

6.49 

-0.55 

0.00 

2.29 

0.65 

1.49 

------------------------------------ 

Totals 3441.087 20052 406834 

16 

14 

12 

10 

8 

US 6 

4 

2 

0 

-2 

File: 95101271.D08 Sample: S95T001860 DUP .1-10 

FLUORIÔSIHATE 

FAR ^ÎTE 

I ► Ii 

BEST AVAILABLE COPY 

SULFATE 

0 2 4 6 8 10 12 14 

Minutes 

344, W-10 

I

Sample Name: S95T001860 SPK 1-10 Date: 10/12/1995 10:38:57 





----------------------------------------------------------------------------- 


-------------------------------------------------------------------- 

External 1 101 5400 5Hz 0.00 18.00 200 


Pk. 

Num. 

Ret Component 

Time Name 

Concentration 

ug/ml 


Code 

IDelta 

----------------------------------------------------------------------------- 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

1.64 

2.19 FLUORIDE 

2.79 FORMATE 

3.64 CHLORIDE 

4.51 NITRITE 

7.08 BROMIDE 

8.02 NITRATE 

9.20 PHOSPHATE 

12.21 SULFATE 

16.25 OXALATE 

0.000 

90.371 

46.103 

97.500 

520.049 

555.599 

3409.505 

756.517 

789.627 

501.644 

347 

3553 

327 

2296 

6864 

3282 

18801 

1847 

4135 

1288 

3308 

25348 

4503 

19098 

71222 

48682 

421322 

41764 

118726 

48270 

2 

2 

2 

1 

1 

1 

2 

2 

1 

1 

-0.90 

6.49 

-0.55 

0.00 

3.21 

1.91 

0.22 

1.08 

1.69 

------------------------------------ 

Totals 6766.915 42741 802244 

40 

30 

US 20 

10 

n 

File: 95101271.D06 Sample: S95T001860 SPK .1-10 

FLUORIDE I 

NITRITE 

FbRUKEgRID^ 

BROMID 


NITRATE 

OS HATE 

SULFATE 

= OXALATE 

0 2 4 6 8 10 12 14 16 18 

Minutes 

344, .103

-V. 

worklistrpt Version 2.1 05115195 Page: 1 

10/11/9511:44 

LABCORE Data Entry Template for Worklist# 2854 

Analyst:}^^ lZ Instrument: IC01 , Book N /L, 1C- Z) 

Method: LA-533-105 Rev/Mod - J 

Worklist Comment: B-104 was originally on 2596. JMF 

GROUP PROJECT S TYPE SAMPLE# R A ------- TEST------ MATRIX ACTUAL FOUND DL UNIT 

1 CCB aIC-0C F- QC QC /' A '! — N A ug/mL 

1 CCB aIC- QC CL-QC QC L, N/A ug/mL 

1 CCB SIC-QC NO2-OC QC .!, Sy -7 N/A ug/mL 

1 CCB aIC- QC BR-OC QC G•(a N/A ug/mL 

1 CCB aIC- QC NO3-0C QC N/A ug/mL 

1 CCB SIC-QC PO4-OC 0C N/A ug/mL 

1 CCB SIC-QC SO4-OC QC

worklistrpt Version 2.1 05115195 Page: 2 

10/11/9511:44 


GROUP PROJECT S TYPE SAMPLE# R A -------TEST------ MATRIX ACTUAL FOUND DL UNIT 

95000085 8-104 3 SAMPLE S95T001824 0 W SIC-01 NO2-02 SOLID N A , 0 - e, ug/g 

95000085 8-104 3 SAMPLE 59ST001824 0 W SIC-01 BR-02 SOLID N/A

worklistrpt Version 2.105115195 Page. 3 

10/11/9511:44 


OUP PROJECT S TYPE 

x5000085 B-104 5 SPK S95T001824 0 N WC-01 0XALATE2 SOLID —fY1J- 

Data Entry Comments: 

Final pagefor worklist # 2854 

yst Signature Date 

N/A u8/B 

Units shown for QC (SPK & STD) may not reflect the actual units. DL = Detection Limit, S = WorNist Slot Number, 

R = Replicate Number, A = Aliquot Code. 

344,r 71

WESTINGHOUSE HANFORD COMPANY 

2225 LABORATORY 

INORGANIC ANALYTICAL BATCH AND SUMMARY SHEET 

ANION ANALYSIS ON DIONEX 

SAMPLE a: s95T001824 8 & 8 

TEST CODE: Qk-01 ANALYST: David Dunham 

INSTRUMENT: IC-01 ANALYSIS DATE: 10/03/95 

WORK UST •: 2854 SAMPLE POINT: 13-104 

BATCH ID: SAMPLE PREP: water digest 

uai. wh Fluoride Chloride Nitrite Nitrate Phosphate I Sulfate Bromide Oxalate 

106N9D 101.4% 98.6% 99.2% 100.1% 98.7% 99.2% 99.7% 99.9% 

s95T001824 3.09E+03 1.55E+03 1.83E+03 2.88E+05 2.18E+04 2.00E+04

LAS LEADER INFO 

lA433 .108 0•t 

.0.a 

.a Coa: 1 

W. 

UNb 

2164 

er L: usla 

"N' OteOk 0-. NmnMr: 10+001) 

r. t 

JOnn 

DOB: 1+072166 

JO1m Frye 

DONO Dunlmm 

Da10: 1010.100 

COOO: "i 

Pm: %%Im 

POIW. 6754 

ANDARD 108 11 01) 

LIPLE1 /fo081624 

PLICATE / INISM18 

MPLE 2 

PLICATE 2 

6NME 2 

PLICATE 

WPIE 4 

PLICATE 4 

PIKE DUPLICATE 

0 

W.Ward SEA 77.91 629.71 gical 639.1 =I 673,51 6x6.0 

WD^3. 

11E+01 1A6E01 1Aa+81 1708+03 177Ewx 2.02E+02 .542 A08 

707 707 21 "l 901 107 H 21 

10.00 10.08 10.08 +0.a 10.08 

76E+01 1.00E+01 221 E+01 3.01E+03 Z; t ! 226E+02 

2 

to to 21 I0. 701 10 27 21 

tae 1aA 10.e 10A 10.0 10.0 10.6 +0.6 

a TO 654 04 546 631 076 

0.062 0.082 0.547 0.608 0.608 0.676 DAM 

%K1 62+0 2E2 6.37E+02 1.14E+03 7.02E+02 0.54E+03 6AtE403 1AZE403 

*2 ERR ERR ERR ERR ERR ERR ERR 

Nt3 ERR ERR ERR ERR ERR ERR ERR 

1/ ERR ERR ERR ERR ERR ERR ERR 4FM@RR 

VDlt^ 

vdlon 

OFOt OmwmF • 6ROr*OtiM4wmpW(r YVaY pwDgM m V+7RF6/OL71YW6 DFW IM4 

Mmt (Fw NYmm^YWr r.Mb mss. Y Yr W O t ft ow YMMlN ---I 

AyYe3tbYIMF%DRS^m^K1^"Ir . D'Me3'1 1 E61%. D '96w." 1 V - 1M4) 

W MY0^wCbY^nwlN Ormllm lM70RAa^FOmr 

. ♦ T o I V 

DIONE]LVVN 1W12108 oA1:37M PO6Ox 0 2 

10

Sample Name BLANK Date 10/03/1995 03:04:49 


Method : C:\DX\METHOD\KIT.MET 

ACI Address . 1 SY em: 1 In j ect#: 3 Detector:CDM-1 

Analyst -J Column: AG4A/AS4A anion column/SRS 

345 


-------------------------------------------------------------------- 

External 1 1 2700 5Hz 0.00 9.00 200 

+++rrrrrtt+++++ret**t++t+ Peak Report: All Peaks **********************•*rrrt 

Pk. Ret Component Concentration Height Area B1. WDelta 


----------------------------------------------------------------------------- 

------------------------------------ 

Totals 0.000 0 0 

us 

0.03 

0.02 

0.01 

0.00 

-0.01 

-0.02 

File: 95100301.D03 Sample: BLANK 

Minutes 

SIGNATURE ABOVE REPRESENTS CHEMICAL THC H DLOGIST/CHEMIST THAT 

COMPLETED/VERIFIED THE CALIBRATICN/ANALYSIS CH PAGESSM.?y TO 

344.74 

F; r'\J I 

9

-------------------------------------- 

Sample Name 106N9-D 



'%CI Address 1 System: 1 Inject#: 

analyst ,,\\ Column: 

Date 10/03/1995 03:14:52 

4 Detector:CDM-1 

AG4A/AS4A- anion- column/SRS-------- 


-------------------------------------------------------------------- 

External 1 101 2700 5Hz 0.00 9.00 200 


Pk. 

Num 

Ret Component 

Time Name 

Concentration 

ug/ml 


Code 

kDelta 

----------------------------------------------------------------------------- 

2 1.04 fluoride 

59.805 1377 7518 2 -1.89 

3 1.53 chloride 77.948 1357 7429 1 0.66 

4 1.83 nitrite 529.789 5648 33836 1 0.55 

5 2.70 bromide 573.567 3687 24519 1 0.00 

6 3.08 nitrate 614.697 4370 33952 1 0.00 

7 4.37 phosphate 539.109 1195 13454 1 -2.46 

8 5.74 sulfate 626.009 3445 44763 1 -2.88 

9 7.53 oxalate 525.581 1487 25501 1 -3.21 

------------------------------------ 

Totals 3546.504 22566 190972 

8.0 

File: 95100301.D04 Sample: 106N9-D 

7.0 BEST AVAILABLE COPY 

nitrite 

6.0 

5.0 

US 3.0 

nitrate 

bromides 

sulfate 

4.0 1 

2.0 fln l ^n 

1.0 

0.0 

-1.0 

I 

Pho 

Minutes 

344,75 

"oxalate

----- --------------- 

Sample Name: S95T001824 SAM Date: 10/03/1995 05:40:35 




Analyst Column: AG4A/AS4A anion column/SRS 

------------- --------- 


-------------------------------------------------------------------- 

External 1 101 2700 5Hz 0.00 9.00 200 


Pk. 

Num. 

Ret Component 

Time Name 

Concentration 

ug/ml 


Code 

$Delta 

----------------------------------------------------------------------------- 

1 1.02 fluoride ova 

31.053 738 3842 2 -3.77 

2 1.20 0.000 138 713 2 

3 1.51 chloride ov 15.659 333 1762 1 -0.66 

4 1.81 nitrite

------------------------------------ -------------------------------------- 

------------------------------------ -------------------------------------- 

Sample Name: S95T001824 SAM Date: 10/03/1995 05:52:57 



\CI Address: 1 System: 1 Inject#: 8 Detector:CDM-1 

.analyst Column: AG4A/AS4A anion column/SRS 


-------------------------------------------------------------------- 

External 1 21 2700 5Hz 0.00 9.00 200 

++*+t*++*+++r+*ttr:++*r Peak Report: All Peaks ** rr*++++**++rrt++*r*+*+*r** 

Pk. 

Num 

Ret Component 

Time Name 

Concentration 

ug/ml 


Code 

$Delta 

----------------------------------------------------------------------------- 

1 0.91 

0.000 115 410 2 

2 1.04 fluoride 33.525 4012 21061 3 -1.89 

3 1.22 0.000 720 3719 4 

4 1.53 chloride 22.180 1892 10093 1 0.66 

5 1.82 nitrite 18.445 895 5284 1 0.00 

6 2.87 bromide 1516.021 80599 923694 1 6.30 

7 4.36 phosphate 213.851 2315 26584 1 -2.68 

8 5.72 sulfate 202.472 5453 70632 1 -3.21 

------------------------------------ 

Totals 2006.494 96002 1061477 

80 

70 

60 

50 

40 

US 30 

20 

File: 95100301.D08 Sample: S95T001824 SAM 

10 fluor3a0wAte 

0 1111 

-10 


pho7hate 

Minutes 

344,'77 

sulfate 

I

Sample Name: S95T001824 DUP Date: 10/03/1995 06:08:53 



ACI Address: 1 System: 1 Inject#: 9 

Detector:CDM-1 

Analyst Column: AG4A/AS4A anion column/SRS 


-------------------------------------------------------------------- 

External 1 101 2700 5Hz 0.00 9.00 200 

#++++++++++++++++++++++++++ Peak Report- All Peaks ++++++++++++++++++++++++++++ 

Pk. Ret Component Concentration Height Area B1. $Delta 


----------------------------------------------------------------------------- 

1 1.03 fluoride 

37.620 953 4676 3 -2.83 

2 1.21 0.000 175 927 4 

3 1.52 chloride 19.756 394 2131 1 0.00 

4 1.81 nitrite 25.418 213 1248 1 -0.55 

5 2.98 nitrate 3044.604 20627 183026 1 -3.25 

6 4.36 phosphate 242.386 501 5736 1 -2.68 

7 5.74 sulfate 225.787 1209 15718 1 -2.88 

------------------------------------ 

Totals 3595.571 24072 213461 

us 

40 

30 

20 

10 

File: 9510030LD09 Sample: S95T001824 DUP 

nitrate 

I 

fluor*o&tpte ph Irate 

0 I 


Minutes 

sulfate 

1. IC-: D ,1h'--D7-LZ, 

344♦ 78

Sample Name: S95T001824 DUP Date: 10/03/1995 06:21:45 



'1CI Address: 1 System: 1 Inject#: 10 Detector:CDM-1 

analyst Column: AG4A/AS4A anion column/SRS 


-------------------------------------------------------------------- 

External 1 21 2700 5Hz 0.00 9.00 200 

+++++++++++++++++++++++++++ Peak Report: All Peaks *+++++++++++++++++++++++++++ 

Pk. 

Num 

Ret Component 

Time Name 

Concentration 

ug/ml 


Code 

%Delta 

----------------------------------------------------------------------------- 

1 0.90 

0.000 145 490 2 

2 1.02 fluoride 41.447 5056 26409 3 -3.77 

3 1.20 0.000 841 4345 4 

4 1.51 chloride 22.072 1829 10044 1 -0.66 

5 1.80 nitrite 22.144 1044 6422 1 -1.10 

6 2.84 bromide 1233.333 90525 1063081 1 5.19 

7 4.34 phosphate 241.554 2701 30251 1 -3.12 

8 5.70 sulfate 232.504 6294 81559 1 -3.55 

------------------------------------ 

Totals 1793.054 108436 1222601 

180 I 

File: 95100301.D10 Sample: S95T001824 DUP 

160 BESTAVAILABLE COPY 

140 

120 

uS 80 

bromide 

100 I 

60 

40 

20 

0 11 

fluor&omdte 

phosphate 

Minutes 

im 

344.'79

1ftP^ 

' oJQ"

y1"o b 12 2 

06/12/95 15:43 Page: 1 

A-0004-1 


. nalyst : J4^v Instrument: ICPO1 Book# I/ ^^ A 

Method: LA-505-151 Rev/Mod 1) 'Z 

Worklist Comment: ICP B-104 Li only DIRECT 

WHGSD-WM-DP-^ REV , . 

S Type Sample# R A Test Matrix Group Project 

1 ICV @ICP-QC QC 

2 ICB @ICP-QC QC 

3 ICSA @ICP-QC QC 

4 ICSAB @ICP-QC QC 

5 SAMPLE S95T001045 0 D @ICP-D03 LIQUID 95000085 B-104 

Analytes Requested: LI-D-01 

6 DUP S95T001045 0 D @ICP-D03 LIQUID 



CCV @ICP-QC QC 

10 CCB @ICP-QC QC 

Final page for worklist # 1555 

Analyst Signature Date Analyst Signature Date 


S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code. 

q 

^,"yYJ

06/12/95 07:10 Page: 1 

A-0004-1 


Analyst: X- 54I L)Instrument: ICPOI Book# Âfk 

Method: LA-505-151 Rev/Mod 


WHGSD-WM-DP- REV. 

S Type Sample# R A Test Matrix Group# Project 





5 SAMPLE S95TOO1045 0 D @ICP-DO3 LIQUID 95000085 B-104 

Analytes Requested: LI-D- 0 1 

6 DUP S95TOO1045 0 D @ICP -DO3 LIQUID 

7 5K- 4 r @ICP-DO3 LIQUID 

8 CCV @ICP-QC QC 


10 SAMPLE 5TO01051 0"D @ICP-003 LIQUID 95000085 B-104 

Ana Requested: LI-D-01 

11 

12 

DUP 

SPK 

0 

J L Ji(S95T00"10 0 D 

S95T001051 0 D 

r 

@ICP-DO3 

@ICP-DO3 

LIQUID 

LIQUID 







IS 4`J

06/12/95 07:10 WHC-SD-WM-DP--^JJ , REV. Page: 2 

A-0004-1 


Type Sample# R A Test Matrix Group# Project 



s ys'roc ô^s_ t j lu.r f v IOs 

,S4STUOM' ,S,lv 

S4Su-vroy,^_JI .5-lv 1^^ 

Jcj rol r 4' G Sp fe. L^hCtl^raô7 ^ SEtiP/e ^ t{ Yigc1 ^ê C^hCcq ^47,uq u7 4^C S^ JC 



J4 i

Identity 1: ICV Identity 2: Quality Control 12:26 PM June 12, 1995 

Task name : TWC93 z 

Sample Weight : 1.0000 Solution volume : 1.00 WHC- SD-WM-DP- 13 , REV.. 

on-Peak Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

ZR 

SR BI SI AL CO Cu L1/ 

( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) ) 

Mean 4.997 5.016 4.977 4.851 5.047 5.159 5.008 5.083 

S.D. 0.007 0.011 0.024 0.009 0.010 0.015 0.021 0.046 

% R.S.D. 0.136 0.219 0.482 0.177 0.194 0.285 0.418 0.911 

ZN NI LA FE CA CR NO 0 

( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 5.040 5.014 4.992 5.057 5.095 5.057 5.132 9.739 

S.D. 0.011 0.020 0.009 0.014 0.008 0.013 0.022 0.018 

% R.S.D. 0.215 0.398 0.186 0.270 0.156 0.263 0.420 0.189 

CE SM BA P S MG AS NA 

( ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 5.054 4.986 5.027 4.973 5.066 5.050 5.036 5.041 

S.D. 0.007 0.017 0.014 0.177 0.109 0.011 0.039 0.041 

R.S.D. 0.138 0.335 0.279 3.557 2.147 0.211 0.774 0.808 

MO SE AG PIT TI CD B K 


Mean 5.101 5.086 4.981 5.033 4.906 5.060 5.033 5.068 

S.D. 0.015 0.034 0.007 0.027 0.008 0.002 0.004 0.026 

R.S.D. 0.294 0.662 0.142 0.542 0.154 0.039 0.089 0.516 

MN SB V BE TL 

( ppm ) (ppm) (ppm) (ppm) (ppm) 

Mean 5.033 4.755 4.982 5.246 4.864 

S.D. 0.008 0.050 0.005 0.005 0.014 

R.S.D. 0.153 1.042 0.096 0.091 0.279 

^-iz•YS 

8 1^'^ S7s%orJIL) .F 

;S lor:,( 

SIGNATURE ABOVE REPRESENTS CHEMICAL TECHWL0GLST/ CHEKIST THAT 

ampLam/VFRIFIED THE CALIBRATICN/ANALYSIS ON PAGES _3,y-g TD 35A. 

,349

Identity 1: ICB Identity 2: Quality Control 12:31 PM June 12, 1995 

Task name : 7VC93 

Sample Weight : 1.0000 Solution Volume 1.00 

r 3k Integrations : 3 Off-Peak Integrations : 1 

- ------------------------------------------------•----------------- 

ZR 

WHC-SD-WM-DP-^^, REV, 

SR BI SI AL CO CU LI 

(PPm ) (PPm) (PPm) (Ppm) (PPm) (PPm) (PPm) ( S 

Mean -0.002 0.001 -0.011 -0.001 0.007 -0.001 -0.004 0.001 

S.D. 0.001 0.000 0.004 0.002 0.008 0.002 0.001 0.001 

% R.S.D. 60.846 29.315 33.817 172.713 114.041 176.447 21.012 43.180 

ZN NI LA FE CA CR NO U 

(PPm ) (PPm) (PPm) (PPm) (Ppa) (PPm) (Pp) (Ppa) 

Mean 0.001 -0.003 -0.000 0.002 0.001 -0.003 -0.015 -0.121 

S.D. 0.001 0.000 0.002 0.002 0.000 0.001 0.003 0.063 

% R.S.D. 36.200 16.235 464.480 110.552 15.051 27.041 16.920 51.867 


( Ppa) (PPm) (Pp) (Pp) (Ppa) (Ppn) (PPm) (PPm) 

Mean -0.005 -0.030 0.001 0.008 0.001 0.001 0.002 -0.005 

S.D. 0.011 0.014 0.000 0.004 0.003 0.000 0.001 0.003 

% R.S.D. 229.604 46.021 49.358 54.414 418.835 23.277 53.430 57.283 

MO SE AG PB TI CD B K 

(Pp ) (Ppa) (PPm) (PPm) (PPm) (PPm) (ppm) (PPm) 

Mean 0.002 0.029 -0.000 0.024 -0.000 0.002 0.001 -0.044 

S.D. 0.001 0.011 0.001 0.005 0.001 0.001 0.001 0.019 

% R.S.D. 45.394 39.319 505.105 21.509 1089.197 38.220 55.459 42.849 

MN SB V BE TL 

(PPm ) (PPm) (Ppa) (PPm) (PPm) 

Mean -0.002 0.029 -0.001 0.001 -0.054 

S.D. 0.000 0.019 0.001 0.000 0.026 

% R.S.D. 10.992 63.344 80.728 27.987 49.149 

34i

Identity 1: ICSA Identity 2: Quality Control 12:34 PM June 12, 1995 

Task name : TWC93 

Sample Weight : 1.0000 Solution volume : 1.00 WHGSD-WM-DP- 1 -51 . , REV 

On-Peak Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

ZR 

SR BI SI AL CO CU 

( ppm ) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean -0.002 0.002 0.000 0.113 208.574 0.003 -0.018 

S.D. 0.000 0.000 0.006 0.007 1.289 0.003 0.001 

% R.S.D. 12.855 26.033 4032.425 6.267 0.618 99.660 3.269 

ZN NI LA FE CA CR NO 

( ppm ) (ppm) (ppm) (Ppm) (ppm) (ppm) (Ppa) 

Mean 0.494 -0.058 0.012 147.099 19.156 -0.011 -0.013 

S.D. 0.003 0.001 0.002 0.476 0.093 0.003 0.005 

% R.S.D. 0.531 1.230 14.217 0.324 0.487 29.165 36.661 

CE SM BA P S MG AS 

(Ppm ) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.021 -0.015 0.001 0.017 0.422 19.167 0.019 

S.D. 0.002 0.003 0.000 0.009 0.011 0.100 0.009 

% R.S.D. 9.807 19.178 38.372 49.972 2.507 0.524 46.383 

MO SE AG PB TI CD B 

( ppm ) (pp) (ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean -0.004 0.058 0.003 0.065 0.004 0.014 -0.036 

S.D. 0.001 0.009 0.000 0.015 0.000 0.002 0.002 

% R.S.D. 30.772 15.476 1.654 23.107 8.647 11.296 4.904 

MN SR y BE TL 

(PPn ) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.006 0.007 -0.004 0.004 -0.058 

S.D. 0.001 0.014 0.000 0.001 0.001 

% R.S.D. 9.287 183.856 4.819 12.377 2.332 

350 

L 

(ppm) 

0.001 

0.000 

27.365 

U 

(Ppm) 

-0.038 

0.008 

22.353 

NA 

(ppm) 

191.827 

K 

1.032 

0.538 

(ppm) 

-0.033 

0.004 

12.245

Identity 1: ICSAB Identity 2: Quality Control 12:36 PM June 12, 1995 

Task male : TWC93 

Sample Weight : 1.0000 solution Volume : 1.00 WK-W-WM-DP-111, REV./ 

eak Integrations : 3 Off-Peak Integrations : 1 

-------------------------------------------------------------------- 

ZR SR BI SI AL CO CO LI 

(PPm ) (PPm) (PPm) (PPm) (Ppa) (PPm) (PPm) (PPm) 

Mean -0.001 0.001 -0.012 0.072 207.706 0.505 0.479 0.915 

S.D. 0.003 0.001 0.013 0.004 0.401 0.003 0.002 0.007 

% R.S.D. 236.452 50.374 115.787 6.072 0.193 0.524 0.415 0.766 

ZN NI LA FE CA CR ND 0 

(PPm) (PPm) (PPm) (ppm) (PPm) (PPm) (PPm) (PPm) 

Mean 1.020 0.923 0.013 148.530 19.084 0.496 -0.007. -0.001 

S.D. 0.002 0.001 0.002 0.125 0.056 0.001 0.003 0.080 

% R.S.D.. 0.226 0.055 17.239 0.084 0.292 0.172 46.021 7134.390 


(PPm ) (PPm) (PPm) (Ppa) (Ppa) (Ppa) (PPm) (PPm) 

Mean 0.017 -0.005 0.495 0.013 0.167 19.303 0.018 188.197 

S.D. 0.018 0.019 0.002 0.010 0.006 0.040 0.004 1.239 

% R.S.D. 103.926 374.848 0.450 78.914 3.695 0.206 19.976 0.659 


(PPm) (PPm) (PPm) (Ppm) (Ppa) (PPm) (PPm) (PPm) 

Mean -0.001 0.068 1.021 1.049 0.003 1.011 -0.039 -0.013 

S.D. 0.001 0.016 0.000 0.013 0.001 0.002 0.001 0.024 

% R.S.D. 104.149 24.111 0.016 1.283 38.202 0.233 2.927 178.619 

MN SB V BE TL 

( PPm) (PPm) (PPm) (PPm) (Ppa) 

Mean 0.508 0.014 0.494 0.500 -0.035 

S.D. 0.001 0.016 0.000 0.001 0.035 

% R.S.D. 0.123 107.919 0.039 0.145 98.245 

u J1

Identity 1: S95T001045 L Identity 2: .5-10-1-4 m( 12:44 PM June 12, 1995 


Sample weight : 1.0000 Solution Volume 105.00 


WHC-SD-WM-DP- , REV. 

---------------------------------------------------------------------- 

2R SR BI SI AL CO Cu 

(Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) ) 

Mean -0.108 0.091 0.577 5.764 5.815 -0.092 -0.347 1985.408 

S.D. 0.143 0.027 0.171 0.328 2.157 0.160 0.030 11.015 

% R.S.D. 133.252 29.782 29.679 5.683 37.089 172.946 8.789 0.555 

2N NI LA FE CA CR NO u 

(ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 0.361 -0.225 -0.075 3.041 4.432 -0.203 0.426 -1.296 

S.D. 0.028 0.081 0.063 1.399 0.217 0.037 0.742 5.593 

It R.S.D. 7.784 35.848 83.628 45.999 4.893 18.370 173.931 431.673 


( ppm ) (PP(n) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -1.527 -1.373 0.072 -1.036 3.055 1.337 0.208 32.411 

S.D. 1.616 1.839 0.040 0.670 0.390 0.215 0.245 2.260 

% R.S.D. 105.832 133.904 55.906 64.672 12.778 16.106 117,702 6.972 

MO SE AG PS TI CD B K 

(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.129 3.119 -0.055 0.211 -0.072 0.102 0.536 1.618 

S.D. 0.076 0.869 0.138 0.731 0.058 0.098 0.055 2.228 

% R.S.D. 58.794 27.868 249.429 346.079 80.774 96.638 10.326 137.689 

MN SB V BE TL 

( ppm ) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.372 1.051 -0.101 0.036 -0.695 

S.D. 0.026 2.746 0.109 0.011 2.151 

% R.S.D. 7.039 261.219 108.038 29.242 309.302 

a JR1 

LI)

Identity 1: S95TOO1045 Identity 2: .5-10 ml 12:48 PM June 12, 1995 

Task new : TWC93 

a le Weight : 1.0000 Solution volume 21.00 WHC-SD-WM-DP-^, REV. 


---------------------------------------------------------------------- 

2R SR el SI AL CO CU 

( ppm ) (ppm) (Ppm) (ppm) (ppm) (ppm) (pp(n ) 

Mean -0.084 0.037 -0.432 1.592 0.974 0.000 -0.101 

S.D. 0.036 0.002 0.107 0.015 0.266 0.000 0.007 

% R.S.D. 42.436 5.812 24.678 0.969 27.281 146.087 6.651 

2N NI LA FE CA CR NO 

( ppin) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 0.063 -0.075 -0.076 0.684 4.572 0.042 -0.272 

S.D. 0.009 0.025 0.023 0.246 0.045 0.021 0.096 

% R.S.D. 14.565 33.787 29.869 36.022 0.983 49.087 35.357 

CE SM BA p S MG AS 

( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean -1.018 -1.002 0.044 0.248 3.093 0.796 -0.002 

S.D. 0.363 0.413 0.007 0.131 0.031 0.033 0.052 

% R.S.D. 35.613 41.210 16.213 52.577 1.009 4.167 2308.273 

MO SE AG PIT TI CO B 

(Ppm ) (Ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.007 1.122 -0.052 -0.010 -0.046 0.074 0.462 

S.D. 0.023 0.042 0.029 0.076 0.008 0.016 0.015 

% R.S.D. 346.410 3.729 56.264 776.729 16.640 22.132 3.157 

MN SB V BE TL 

(Ppm ) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.053 -0.143 -0.076 0.011 -1.843 

S.D. 0.005 0.135 0.032 0.002 0.741 

% R.S.D. 9.964 94.743 41.975 20.270 40.197 

a.i J u 

LIl 

1878.748 

17.312 

U 

0.921 

(Ppm) 

-1.069 

1.622 

151.699 

NA 

(ppm) 

28.889 

K 

0.627 

2.169 

(ppm) 

2.063 

0.444 

21.509

Identity 1: S95TOO1045_D Identity 2: .5-10 ml 12:52 PM June 12, 1995 


Sample Weight : 1.0000 Solution volume : 21.00 WHGSD-WM-DP- , REVS 


ZR SR BI SI AL CO CU 

(Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) (pp(n) 

Mean 0.012 0.049 -0.053 1.879 1.534 -0.001 -0.068 

S.D. 0.036 0.002 0.045 0.068 0.094 0.055 0.007 

% R.S.D. 301.113 4.359 84.684 3.624 6.104 10356.728 9.842 

2N NI LA FE CA CR NO 

(Ppm ) (ppm) (ppm) (Ppm) (pPm) (Ppm) (Ppm) 

Mean 0.071 0.065 0.032 0.981 4.520 0.056 0.050 

S.D. 0.011 0.021 0.035 0.198 0.039 0.016 0.165 

% R.S.D. 16.055 32.594 109.377 20.164 0.857 27.635 331.586 


(Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.217 0.253 0.066 0.386 3.077 0.809 -0.054 

S.D. 0.286 0.375 0.005 0.113 0.174 0.023 0.018 

% R.S.D. 131.756 148.285 7.746 29.396 5.649 2.894 32.801 

MO SE AG PB T1 CD B 

(ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.001 0.612 0.030 0.500 0.004 0.049 0.459 

S.D. 0.027 0.185 0.021 0.127 0.013 0.012 0.013 

% R.S.D. 2851.315 30.180 70.698 25.378 313.086 24.321 2.846 

MN SB 9 BE TL. 

(ppm) (ppm) (Pp(n ) (Ppm) (Ppm) 

Mean -0.050 0.546 0.011 0.016 0.254 

S.D. 0.006 0.204 0.026 0.000 0.565 

% R.S.D. 12.234 37.283 238.887 0.734 222.665 

^, 1 

0 042 

U 

1844.034 

12.061 

U 

(Ppm) 

0.654 

4.019 

1.264 

31.462 

NA 

(ppm) 

29.936 

K 

(Ppm) 

0.365 

1.219 

3.520 

0.191 

5.432



-le Weight : 1.0000 Solution Volume : 1.00 

:ak Integrations : 3 Off-Peak Integrations : 1 

------------------------------ ---------------------------------- 

ZR SR BI SI 

( ppm ) (ppm) (ppm) (ppm) 

Mean -0.005 0.000 0.007 0.108 

S.D. 0.001 0.000 0.008 0.003 

% R.S.D. 14.412 34.359 101.169 2.606 

ZN NI LA FE 

( ppm ) (Ppm) (Ppm) (Ppm) 

Mean 0.494 -0.062 0.012 148.147 

S.D. 0.002 0.001 0.002 0.350 

% R.S.D. 0.464 2.339 16.442 0.236 

CE SM BA P 


Mean 0.017 -0.034 -0.000 0.022 

S.D. 0.003 0.006 0.000 0.005 

% R.S.D. 18.613 19.005 33.889 24.280 

MO SE AG PB 

( ppm ) (Ppm) (ppm) (ppm) 

Mean -0.002 0.042 0.004 0.047 

S.D. 0.001 0.007 0.001 0.006 

% R.S.D. 54.486 17.842 21.262 12.847 

MN SB V BE 

( ppm ) (ppm) (Ppm) (ppm) 

Mean 0.005 -0.003 -0.006 0.003 

S.D. 0.000 0.014 0.001 0.000 

% R.S.D. 2.523 489.289 9.860 0.060 

WHC-SD-WM-DP- /37 REV, / 

AL CO CU L 

(Ppm ) (ppm) (ppm) (ppm) 

210.108 -0.001 -0.020 0.040 

0.547 0.002 0.000 0.009 

0.260 176.625 1.205 21.295 

CA CR NO U 

( ppm ) (Ppm) (ppm) (Ppm) 

19307 -0.013 -0.018 -0.095 

0.053 0.001 0.004 0.017 

0.272 7.455 22.830 17.911 

S MG AS NA 

( ppm ) (pp(n) (ppm) (ppm) 

0.407 19.236 0.021 193.183 

0.015 0.090 0.005 0.097 

3.672 0.469 24.956 0.050 

TI CD B K 


0.002 0.013 -0.043 -0.047 

0.000 0.001 0.001 0.007 

17.662 4.910 3.128 14.817 

TL 

(ppm) 

-0.075 

0.013 

17.295 

355


Task name : TWC93 WHGSD-WM-DP-_/37REV. 



------------------------------------------- ------------- --------- ----- 

ZR SR BI SI AL CO Cu 

(ppm) (Ppm) (Ppm) (Ppm) (Ppn) (ppm) (Ppm) 

Mean -0.004 -0.000 -0.002 0.083 207.993 0.495 0.486 

S.D. 0.001 0.000 0.001 0.003 1.003 0.006 0.002 

% R.S.D. 25.590 0.571 73.045 3.235 0.482 1.112 0.421 


(ppm) (ppn) (ppm) (Ppn) (Ppm) (Ppm) (Ppm) 

Mean 1.055 0.903 0.010 146.572 19.142 0.482 -0.019 

S.D. 0.003 0.001 0.002 0.161 0.052 0.003 0.006 

% R.S.D. 0.326 0.085 16.293 0.110 0.272 0.544 29.621 


(ppm) (ppm) (Ppm) (Ppn) (Ppm) (Ppm) (ppm) 

Mean 0.029 -0.016 0.501 0.008 0.163 18.933 0.009 

S.D. 0.006 0.010 0.002 0.007 0.007 0.038 0.003 

% R.S.D. 19.114 65.399 0.334 85.984 4.566 0.199 32.813 


(Ppm) (Ppm) (ppm) (Ppn) (pPxn) (Ppm) (Ppn). 

Mean -0.005 0.034 0.809 1.010 0.002 0.996 -0.042 

S.D. 0.001 0.011 0.050 0.011 0.000 0.002 0.001 

% R.S.D. 18.149 33.078 6.162 1.061 22.534 0.161 2.501 

MN SB V BE TL 

(ppm) (ppm) (Ppn) (Ppm) (Ppm) 

Mean 0.499 0.008 0.488 0.498 -0.044 

S.D. 0.002 0.002 0.000 0.001 0.022 

% R.S.D. 0.385 32.641 0.020 0.289 49.448 

awl 0 

L 

(ppm) 

U 

(Ppm) 

0.966 

0.016 

1.707 

-0.041 

0.039 

95.978 

NA 

(Ppn) 

193.145 

K 

2.208 

1.143 

(Ppm) 

-0.034 

0.010 

27.922

Identity 1: CCV Identity 2: Duality Control 1:26 PM June 12, 1995 


' le Weight : 1.0000 Solution Volume 1.00 

WHC-SD'WM-DP- _ , REV. 

=ak Integrations : 3 Off-Peak Integrations : 1 

...................................................................... 

ZR SR 81 SI AL CO CU 

(Ppm ) (ppn) (ppm) (Ppm) (Pp^) (Ppm) (ppm) 

Mean 4.986 4.994 4.974 4.851 5.090 5.161 4.971 

S.D. 0.010 0.021 0.010 0.003 0.028 0.012 0.033 

% R.S.D. 0.205 0.417 0.192 0.059 0.546 0.235 0.654 

ZN N1 LA FE CA CR NO 

(Ppm ) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 5.057 5.021 4.982 5.090 5.073 5.061 5.113 

S.D. 0.009 0.020 0.009 0.020 0.017 0.018 0.026 

% R.S.D. 0.173 0.399 0.189 0.387 0.337 0.357 0.512 

CE sM BA P S MG AS 

( ppm ) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 5.020 5.117 4.997 4.949 5.042 5.067 5.015 

S.D. 0.007 0.019 0.028 0.021 0.044 0.012 0.007 

% R.S.D. 0.147 0.381 0.557 0.419 0.868 0.247 0.139 


(ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 5.107 5.041 4.979 5.009 4.886 5.058 5.021 

S.D. 0.017 0.012 0.013 0.002 0.007 0.012 0.020 

% R.S.D. 0.327 0.234 0.255 0.046 0.143 0.228 0.398 

MN SB V BE TL 

(ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 5.033 4.829 4.981 5.231 4.831 

S.D. 0.014 0.018 0.007 0.007 0.017 

% R.S.D. 0.288 0.378 0.131 0.134 0.355 

ai J i 

LI 

U 

(Ppm) 

NA 

(Ppm) 

K 

(Ppm) 

5.024 

0.071 

1.406 

9.697 

0.022 

0.228 

5.046 

0.064 

1.259 

5.040 

0.047 

0.925

Identity 1: CCB Identity 2: Quality Control 1:36 PM June 12, 1995 



on-Peak Integrations : 3 

Off-Peak 

Integrations : 

------------------------- ----- ------- --------------- ---- ----------- -- 

1 

WHC-SD-WM-DP-. _IJ1, REV. 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.000 0.001 0.007 0.004 0.019 -0.001 -0.005 

S.D. 0.002 0.000 0.010 0.006 0.017 0.002 0.001 

% R.S.D. 3491.249 64.156 144.407 151.070 93.810 172.469 23.376 

ZN NI LA FE CA CR ND 

( ppm ) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 0.001 0.002 -0.002 0.009 0.002 -0.001 -0.009 

S.D. 0.001 0.003 0.002 0.005 0.001 0.001 0.007 

% R.S.D. 59.945 185.849 92.603 59.396 34.008 123.142 80.911 


( Ppn) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 0.003 -0.001 0.001 -0.014 0.002 0.002 -0.000 

S.D. 0.025 0.023 0.001 0.005 0.005 0.001 0.001 

% R.S.D. 866.149 1779.353 87.977 35.648 211.597 34.658 214.392 


( Ppm ) (Ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.000 0.016 0.030 0.005 0.001 0.001 0.001 

S.D. 0.002 0.010 0.002 0.006 0.001 0.001 0.001 

% R.S.D. 3515.679 58.912 6.194 136.978 166.813 125.305 80.095 

MN SR V BE TL 

( Ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.003 0.012 -0.000 0.001 0.003 

S.D. 0.001 0.016 0.002 0.000 0.048 

% R.S.D. 17.185 135.793 485.227 39.055 1381.302 

------------------ 

3,508 

u 

(Pqa) 

0.002 

0.001 

51.353 

U 

(Ppm) 

-0.020 

0.100 

505.638 

NA 

(Ppm) 

0.026 

0.011 

44.507 

K 

(Ppm) 

0.004 

0.027 

709.460

7A3H Z J -dQ-WM-QS-QHM 

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06/19/95 15: 08 WHC SD-WM-DP- IS Z- , REV L Page: I 

A-0004-1 


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Method: LA-50545+11 1 Rev/Mod G 








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7 SPK S95T001051 0 D @ICP-003 LIQUID 






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06/13/95 06:52 WHC-SD-WM-DP-1.— -- REV-,L Page: 1 

A-0004-1 


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Page: 2

Analvsis Report Summary Mon 06-19-95 10:58:08 AM page 1 

# 

- 

Sample Name 

File 

--------------- ----- -------- 

Method 

-------- 

Date 

--------- Time 

----- OpID 

---- 

Type 

---- 

Mode 

----- 

I ICV 950619A ICP2 06119195 10:00 DKS Q CONC 

2 ICB 950619A ICP2 06119195 10:06 DKS Q CONC 

3 ICSA 950619A ICP2 06119195 10:09 DKS Q CONC 

4 ICSAB 950619A ICP2 06119195 -10:13 DKS 0 CONC 

5 S95T001051 L 950619A ICP2 06119195 10:18 DKS S CONC 

6 S95T001051 — 950619A ICP2 06119195 10:22 DKS S CONC 

7 S957'001051 D 950619A ICP2 06119195 10:26 DKS S CONC 

8 S95T001051 —A 950619A ICP2 06119195 10:31 DKS S CONC 

9 ICSA — 9506I9A ICP2 06119195 10:39 DKS Q CONC 

10 ICSAB 950619A ICP2 06119195 10:43 DKS q CONC 

11 CCv 1 950619A ICP2 06119195 10:49 DKS Q CONC 

12 CCB- 1 950619A ICP2 06119195 10:54 DKS Q CONC 

c4î^• ys- 

g _/^y S9-sTooiDSl 

WHGSD-WM-DP- /j2, REV_L 

SIGNATURE ABOVE REPRESENTS aM IrAL TZC MVLOGIST/c HEK1sT THAT ^/p 

OpvLE^D/VBRIBIw ME CALI.BRATICH/ANALYSIS ON PACES p:g^ TO - 

> zi

Anai; ,sis Report Averages Mon 06-19-95 10:58:08 AM page 2 

# 

--- 

Sample Name 

-------------------- 

Ag 

-------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

1 ICI I 5.054 4.960 5.300 5.089 5.125 5.362 

2 IC8 .0009 .0102 -.0003 .0053 .0001 .0002 

3 ICSA -.0007 241.8 .0633 .0122 .0038 .0002 

4 ICSAB .9669 241.1 .0889 0047 .4717 .4866 

5 S95T001051 L .5975 19.96 -23.72 29.16 .1627 .3033 

6 S?5T001051 - .5759 5.938 1.726 16.52 .0913 .0762 

7 .S95T001051 D .0129 1.866 -.0507 15.55 .0490 .0309 

8 S95T001051 -A 344.6 394.1 435.2 423.1 393.6 419.4 

9 ICSA - .0007 242.5 .0301 .0053 .0038 .0004 

10 ICSAB .9729 242.2 .0869 .0025 .4724 .4872 

11 CCV 1 5.122 4.969 5.415 5.133 5.168 5.461 

12 CC3-1 .0006 .0009 -.0069 .0063 .0002 .0002 

# 

--- 

Sample Name 

-------------------- 

Bi 

-------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

I ICI I 5.259 5.245 5.240 5.246 5.247 5.245 

2 ICB -.0153 -.0008 .0003 .0038 -.0013 -.0016 

3 ICSA -.0627 253.8 .0036 .0138 .0015 -.0066 

4 ICSAB -.0213 254.1 .9605 .0106 .4743 .4750 

5 S95T001051 L -31.22 -3.926 .6289 12.86 -.2549 11.98 

6 S95T001051 - -10.58 2.906 .0754 3.278 1.135 14.19 

7 S95T001051 D 1.006 -.3464 .1198 1.997 .6457 13.65 

8 S95T001051 -A 420.4 428.0 418.5 409.8 419.7 433.9 

9 ICSA - -.0305 255.7 .0035 .0145 .0019 -.0077 

10 ICSAB -.0374 258.8 .9671 .0129 .4789 .4772 

11 CCV 1 5.269 Q5.536 5.373 5.285 5.379 5.375 

12 CCB - 1 -.0256 .0002 .0005 .0050 -.0008 -.0004 

11 

--- 

Sample Name 

Cu 

------------------ -- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

LI 

-------- 

1 ICI' 5.112 .0063 5.226 4.785 5.201 5.048 

2 ICB -.0007 .0011 .0007 .1268 .0005 .0008 

3 ICSA -.0082 -.0399 94.22 .1318 -.0037 .0031 

4 ICSAB .4782 -.0400 93.26 .1210 -.0033 .9526 

5 S95T001051 L .3880 1.870 2.992 137.8 1.210 1.609 

6 S95T001051 - .4165 .3489 1.459 268.9 .3861 .9654 

7 S95T001051 D .1668 .3598 .4864 207.6 -.0108 .7866 

8 S95T001051 -A 399.5 .9559 416.2 590.9 405.2 391.8 

9 ICSA - -.0082 -.0456 93.99 .0637 -.0023 .0035 

10 ICSAB .4807 -.0494 93.99 .1855 -.0030 .9609 

1 1 CCV 1 5.I26 .0069 5.341 4.768 5.234 4.972 

12 CCB - 1 -.0009 .0016 .0007 -.0586 .0008 .0016 

ll 

--- 

Sample Name 

-------------------- 

Mg 

-------- 

Mn 

-------- 

MO 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

1 ICV 5.019 5.099 5.213 5.026 5.222 5.225 

2 ICB -.0032 .0005 -.0009 .0107 -.0018 .0027 

3 ICSA 244.7 -.0055 -.0122 190.1 .0134 -.0123 

4 ICSAB 243.6 .4540 -.0166 188.8 .0102 .9216 

5 S95T001051 L -7.458 .6770 -2.528 182400. -3.710 -.2932 

REV.. Z 

WHGSD-WM-DP-^, 

36.6

Anaivsis Report Averages Mon 06-19-95 10:58:08 AM page 3 

11 

--- 

Sample Name 

-------------------- 

Mg 

-------- 

Mn 

-------- 

MO 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

5 .S95T001051 3.287 .1924 1.247 173400. .4667 -.2645 

7 S957'001051 D 3.541 .1146 .5114 172200. .8469 1.739 

8 S95T001051 -A 387.3 398.0 421.9 178300. 405.6 411.6 

9 ICSA - 245.3 -.0057 -.0115 191.8 .0126 -.0232 

10 ICSAB 245.1 .4566 -.0165 190.4 .0123 .9148 

11 CCV 1 5.047 5.216 5.329 4.966 5.229 5.311 

12 CCB - 1 -.0053 .0006 -.0005 .0141 -.0008 -.0017 

# 

--- 

Sample Name 

P 

--------------- ----- -------- Pb 

-------- 

S -------- Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 ICP 5.729 5.217 5.143 4.950 Q5.395 4.778 

2 ICB -.0212 -.0094 -.0109 .0038 -.0136 .0124 

3 ICSA -.0407 .0281 .0410 .0046 -.0292 .0207 

4 ICSAB -.0125 .9987 .0441 -.0023 -.0677 .0247 

5 595T001051 L 8696. -28.93 10210. -14.48 77.75 45.45 

6 S95T001051 - 8681. -3.198 10160. -.4970 70.18 26.49 

7 S95T001051 D 8842. -1.934 10120. .1673 65.55 24.33 

8 S95T001051 -A 9422. 419.0 10900. 399.1 500.4 413.2 

9 ICSA - -.0573 .0308 .0468 .0049 -.0528 .0193 

10 ICSAB -.0532 1.007 .0401 .0001 -.0877 .0209 

11 CCV 1 Q5.685 5.330 5.167 5.046 5.473 4.863 

12 CCB - 1 -.0172 .0041 .0012 -.0096 .0019 .0124 

# 

--- 

Sample Name 

Sm 

--------------- ----- -------- 

Sr 

-------- 

Th 

-------- 

Ti 

-------- T1 

-------- 

U 

-------- 

1 ICV 5.062 5.096 .0207 5.043 5.038 9.829 

2 ICB .0117 .0002 -.0035 -.0002 .0025 .0507 

3 ICSA -.0017 -.0046 -.0081 .0019 .0968 -.2582 

4 ICSAB .0006 -.0041 -.0091 .0015 .1070 -.2541 

5 S95T001051 L 12.58 .4078 -2.306 -.4128 28.69 52.67 

6 .S95T001051 - 3.270 .1312 1.939 .1773 7.259 6.943 

7 .S95T001051 D 3.938 .1153 .8145 .0058 8.963 2.244 

8 S95T001051 -A 395.6 397.4 2.097 398.3 393.5 768.1 

9 ICSA - -.0026 -.0047 -.0045 .0019 .0523 -.2680 

10 ICSAB .0001 -.0048 -.0016 .0019 .1186 -.2910 

11 CCV 1 5.073 5.129 .0231 5.096 5.136 9.845 

12 CCB - 1 .0155 .0003 -.0025 .0000 .0020 .0609 

# 

--- 

.Sample Name 

------------------ 

V 

-- -------- 

Y 

-------- 

Zn 

-------- 

1 ICV 5.113 .0133 5.135 5.098 

2 ICB .0036 .0007 -.0005 .0011 

3 ICSA .0036 .0187 -.0038 -.0000 

4 ICSAB .4739 .0186 .9726 -.0000 

5 S95T001051 L 4.888 .9428 6.248 3.141 

6 S95T001051 - 1.118 .1571 10.11 .1933 

7 S95T001051 D .9882 .1571 7.879 .2879 

8 S95T001051-A 409.8 1.289 422.9 402.0 

9 ICSA - .0032 .0187 -.0035 -.0003 

10 ICSAB 4762 .0187 .9804 .0005 

11 CCV 1 5.215 .0139 5.257 5.170 

Zr 

-------- -------- -------- 

WHGSD-WM-DP-ZI L, REV. 

V l7-Y

Analvsis Report Averages Mon 06-19-95 10:58:08 AM page 4 

# Sample Name V Y Zn Zr 

--- -------------------- --------------- -------- -------- ------- 

12 CCB 1 .0043 .0009 -.0014 .0022 

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WHGSD-WM-DP-/_2, REV. /

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06/19/95 15:15 Page: 1 

A-0004-I 


Analyst: 2. e.ck2 Instrument: ICP01 Book# g34vk1t 

Method: LA-505-151 Rev/Mod 4 - Z 


WHGSD-WM-DF-. ^YY , REV 








6 DUP S95T001084 0 D @ICP -D03 LIQUID 






nalyst Signature Date Analyst Signature Date 

S S f i cV/of -/ 

Data Entry Comments: " ^" o 


n 

V !^

Identity 1: ICV Identity 2: Quality Control 8:38 AM June 27, 1995 


5+mple weight : 1.0000 Solution Volume 1.00 

WHGSD-WM-DP-_).U, , 

REV. 


- - " 

.---- _------_. -.--- 

------------------------------. "'----------- 

ZR 

SR 

BI Sl AL CO CU LI 

Mean 

(Ppm) 

5.065 

(PPm) 

5.028 

(Ppm) 

4.997 

(Ppm) 

4.759 

(Ppm) 

4.982 

(Ppm) 

5.098 

(ppm) 

5.094 

(Ppm) 

5.060 

S.D. 0.006 0.011 0.024 0.007 0.013 0.011 0.018 0.044 

% R.S.D. 0.112 0.217 0.481 0.150 0.261 0.214 0.350 0.869 


(Ppm) (ppm) (PP IR ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 4.998 5.120 5.145 5.241 5.224 5.137 5.342 9.805 

S.D. 0.003 0.018 0.012 0.017 0.009 0.007 0.023 0.022 

% R.S.D. 0.053 0.345 0.227 0.325 0.168 0.139 0.438 0.222 


(ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 4.839 4.870 5.069 5.027 4.865 5.034 5.048 4.962 

S.D. 0.015 0.017 0.014 0.195 0.100 0.010 0.026 0.041 

% R.S.D. 0.306 0.348 0.278 3.873 2.053 0.202 0.518 0.824 

mo SE AG PB TI CD 6 K 

(Ppm) (Ppm) (Ppm) (PPm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 5.024 5.000 4.901 5.083 4.918 5.169 5.193 5.119 

S.D. 0.005 0.038 0.004 0.019 0.007 0.009 0.019 0.059 

% R.S.D. 0.096 0.753 0.078 0.382 0.139 0.169 0.357 1.150 

MN SIT V BE TL 

(ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 5.140 4.749 5.042 5.350 4.889 

S.D. 0.008 0.061 0.005 0.008 0.009 

% R.S.D. 0.158 1.275 0.091 0.147 0.181 

5) -710U 

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Identity 1: ICB Identity 2: Quality Control 8:41 AM June 27, 1995 


Sample weight : 1.0000 Solution Vol" : 1.00 WHGSD-WM-DP- REV. 


---------------------------------------------------------------------- 

2R SR BI SI AL CO CO LI 

(Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.004 0.004 -0.016 0.010 -0.019 0.006 0.002 0.004 

S.D. 0.000 0.001 0.007 0.001 0.001 0.000 0.001 0.001 

% R.S.D. 6.816 19.362 46.977 11.098 4.719 0.033 35.539 15.645 

2N N1 LA FE CA CR NO 0 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppn) (ppm) (ppm) 

Mean 0.004 0.001 0.006 0.001 0.004 0.005 -0.018 0.004 

S.D. 0.001 0.002 0.001 0.002 0.001 0.001 0.007 0.015 

% R.S.D. 28.257 113.324 17.685 249.987 18.944 22.480 36.290 413.661 


( ppm) (ppm) (Ppm) (PPm) (ppm) (Ppm) (Ppm) (ppm) 

Mean 0.006 -0.000 0.004 -0.024 0.004 0.004 0.012 -0.014 

S.D. 0.005 0.007 0.001 0.008 0.002 0.001 0.000 0.001 

% R.S.D. 84.037 3013.440 16.540 32.390 47.676 17.641 2.492 7.873 


(ppm) (Ppm) (pPm) (PPm)' (ppm) (ppm) (pp(n) (Ppm) 

Mean 0.005 0.006 0.004 -0.028 0.004 0.004 0.006 0.008 

S.D. 0.001 0.004 0.000 0.015 0.001 0.001 0.000 0.009 

% R.S.D. 13.981 65.015 4.333 52.090- 22.052 32.119 5.815 118.145 

MN SB V BE TL 

(Ppm ) (ppm) (Ppm) (Ppm) (ppm) 

Mean 0.003 -0.008 0.004 0.003 0.003 

S.D. 0.001 0.028 0.001 0.001 0.010 

% R.S.D. 36.344 351.018 31.196 20.664 333.233 

117.1 

6i °S

Identity 1: ICSA Identity 2: Quality Control 8:44 AM June 27, 1995 


-- + le Weight : 1.0000 Solution Vo(uae 1.00 


---------------------------------------------------------------------- 

WHC-SD•WM-DP• 151, REV 

ZR SR BI SI AL CO Cu 

( ppm ) (Ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 0.002 0.006 0.012 0.038 206.600 0.015 -0.011 

S.D. 0.000 0.000 0.005 0.001 0.670 0.002 0.000 

% R.S.D. 17.967 8.670 42.265 1.502 0.325 10.169 - 3.920 

2N NI LA FE CA CR ND 

(ppm) (ppm) (ppm) (PP IR ) (Ppm) (ppm) (ppm) 

Mean 0.179 -0.056 0.025 154.587 19.758 -0.005 -0.012 

S.D. 0.001 0.001 0.002 0.111 0.056 0.000 0.004 

% R.S.D. 0.403 1.474 7.736 0.072 0.283 8.547 31.866 

CE SK BA P S MG AS 

(Ppm ) (ppm) (ppm) (ppm) (ppm) (pp) (ppm) 

Mean 0.015 -0.015 0.005 0.005 0.227 18.986 0.021 

S.D. 0.004 0.005 0.000 0.013 0.009 0.074 0.005 

% R.S.D. 26.981 31.512 9.759 254.826 3.981 0.391 25.833 

MO SE AG P8 TI CD B 

(Ppm ) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.003 0.022 0.013 0.027 0.007 0.018 -0.035 

S.D. 0.001 0.007 0.001 0.004 0.000 0.001 0.000 

% R.S.D. 42.521 31.480 5.865 14.905 5.893 3.885 1.390 

MN SB V BE TL 

(ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.014 -0.052 -0.000 0.007 -0.022 

S.D. 0.001 0.019 0.001 0.000 0.008 

% R.S.D. 4.579 35.834 176.587 6.207 37.129 

.j^J 

L 

(ppm) 

0 

(Ppm) 

0.006 

0.001 

9.745 

-0.020 

0.019 

96.084 

NA 

(Ppm) 

189.664 

K 

1.819 

0.959 

(Ppm) 

-0.048 

0.013 

26.993

Identity 1: ICSAB Identity 2: Quality Control 8:47 AM June 27, 1995 


Sample Weight 1.0000 Solution Volume 1.00 


--------------------------------..-----...------....------------------ 

ZR 

WHC-SD-WM-DP-L, 

REV.L 

SR 81 SI AL CO CU LI 

( ppm ) (ppm) (Ppm) (ppm) (Ppm) (PPR) (ppm) (Ppm) 

Mean 0.002 0.004 0.026 0.017 204.231 0.504 0.489 0.904 

S.D. 0.001 0.000 0.008 0.002 0.686 0.002 0.003 0.011 

% R.S.D. 55.060 4.439 30.729 10.350 0.336 0.308 0.609 1.182 

ZN NI LA FE CA CR ND U 

(ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 1.145 0.954 0.022 156.174 19.579 0.504 -0.013 0.079 

S.D. 0.003 0.005 0.002 0.202 0.076 0.001 0.007 0.047 

% R.S.D. 0.245 0.507 9.009 0.129 0.387 0.242 51.948 59.140 


(gm) (ppm) (ppm) (Ppm) (ppm) (PPI) (ppm) (ppm) 

Mean 0.064 0.007 0.494 0.028 0.207 19.197 0.038 183.450 

S.D. 0.015 0.016 0.002 0.014 0.011 0.041 0.010 1.874 

% R.S.D. 23.621 219.077 0.464 49.844 5.094 0.215 25.139 1.022 

MO SE AG PIT TI CD 8 K 

( Ppm ) (ppm) (ppm) (pPa) (Ppm) (Ppm) (ppm) (ppm) 

Mean 0.004 0.073 1.019 1.016 0.006 1.045 -0.036 -0.033 

S.D. 0.000 0.014 0.001 0.013 0.001 0.001 0.001 0.013 

% R.S.D. 6.316 19.317 0.129 1.293 11.714 0.050 2.669 39.167 

MN SB V BE TL 

(ppm ) (ppm) (ppm) (Ppm) (ppm) 

Mean 0.529 -0.040 0.506 0.512 0.010 

S.D. 0.002 0.019 0.001 0.002 0.028 

% R.S.D. 0.315 48.566 0.236 0.357 277.116 

V I V

Identity 1: S95TOO1084 Identity 2: direct 8:55 AM June 27, 1995 - 


Sample Weight : 1.0000 Solution Votme : 1.00 WHGSD-WM-DP- / , REV. 


'-------------------------------°....-------------------------------- 

ZR 

SR 61 SI AL CO Cu 

(ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.004 0.002 -0.018 0.528 0.225 0.004 0.005 

S.D. 0.002 0.000 0.006 0.006 0.017 0.000 0.000 

% R.S.D. 47.144 7.138 30.470 1.193 7.675 0.187 2.260 


( ppm ) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.026 0.006 0.003 0.220 0.248 0.000 -0.026 

S.D. 0.001 0.001 0.000 0.014 0.006 0.003 0.002 

% R.S.D. 3.473 10.900 0.627 6.227 2.224 30818.139 6.654 


(ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 0.004 0.010 0.003 0.353 0.825 0.070 0.001 

S.D. 0.013 0.018 0.000 0.019 0.021 0.002 0.004 

% R.S.D. 288.253 172.461 8.071 5.469 2.601 2.754 370.868 

MO SE AG PS TI CD B 

(Ppm ) (Ppm) (Ppm) (Pp) (Ppm) (Ppm) (ppm) 

Mean 0.003 -0.012 0.002 -0.016 0.002 0.003 0.722 

S.D. 0.001 0.006 0.001 0.006 0.001 0.000 0.004 

% R.S.D. 33.420 50.399 44.740 37.062 35.629 4.087 0.541 

MN SB V BE TL 

(Ppm ) (Ppm) (ppm) (Ppm) (ppm) 

Mean 0.011 -0.043 0.002 0.001 0.036 

S.D. 0.001 0.034 0.001 0.000 0.018 

% R.S.D. 5.126 78.352 66.124 8.814 49.327 

L 

(Ppo> 

0.017 

u 

0.000 

0.551 

(ppm) 

0.040 

0.051 

128.860 

NA 

(ppm) 

K 

7.644 

0.089 

1.163 

(Ppm) 

0.080 

0.016 

19.518

Identity 1: S95TOO1084_0 Identity 2: direct 


Sample weight : 1.0000 Solution yotme : 1.00 


9:00 AM June 27, 1995 

---------------------------------------------------------------------- 

2R 

SR BI SI AL 

(ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.002 0.002 0.016 0.517 0.162 

S.D. 0.001 0.000 0.008 0.005 0.007 

% R.S.D. 40.583 7.836 47.923 0.914 4.215 

2N NI LA FE CA 

(ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 0.030 0.008 0.000 0.175 0.242 

S.D. 0.001 0.003 0.002 0.001 0.001 

% R.S.D. 2.479 33.920 407.392 0.537 0.362 

CE SM BA P S 

(ppm) (ppm) (ppm) (pprn) (ppm) 

Mean 0.012 0.001 0.003 0.363 0.836 

S.D. 0.013 0.018 0.000 0.005 0.013 

% R.S.D. 104.922 2283.205 12.229 1.396 1.564 

MO SE AG PB TI 


Mean 0.003 -0.035 0.002 -0.016 0.002 

S.D. 0.001 0.012 0.001 0.006 0.001 

% R.S.D. 50.681 35.314 55.262 38.700 27.850 

MN Sa 9 BE TL 

(ppm) (ppm) (ppm) (Ppm) (Ppin) 

Mean 0.011 0.013 0.001 0.001 0.005 

S.D. 0.000 0.008 0.001 0.000 0.025 

% R.S.D. 2.389 59.976 90.901 0.600 532.382 

WHGSD-WM-DP-^1,, REV., 

eliJ 

CO Cu LI 

(ppm) (pPa) (Ppm) 

0.008 0.007 0.017 

0.002 0.000 0.000 

19.295 5.589 1.056 

CR NO 0 

(Ppm ) (ppm) (ppm) 

0.003 -0.014 0.051 

0.001 0.003 0.062 

29.849 20.617 121.751 

MG AS NA 

(Ppm ) (Ppm) (ppm) 

0.063 0.003 7.281 

0.000 0.001 0.074 

0.266 44.350 1.013 

CD 8 K 

(ppm) (Ppm) (Ppm) 

0.002 0.713 0.093 

0.001 0.005 0.012 

38.283 0.644 12.735

Identity 1: ICSA Identity 2: Quality Control 9:03 AM June 27, 1995 


e Weight : 1.0000 Solution VOL" 1.00 

aak Integrations : 3 Off-Peak Integrations : 1 

------------------------------------------------------''-------------- 

WHC-SD-WM-DP-^ REV•_ 

ZR SR BI SI AL CO Cu LI 

( ppm ) (Ppm) (ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean -0.001 0.001 0.024 0.038 205.707 0.004 -0.017 0.001 

S.D. 0.001 0.000 0.006 0.002 0.697 0.002 0.000 0.000 

% R.S.D. 47.057 10.124 26.110 5.498 0.339 34.590 1.737 29.040 

ZN NI LA FE CA CR ND u 

(ppm) (ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 0.178 -0.062 0.022 158.924 19.739 -0.012 -0.019 0.031 

S.D. 0.000 0.001 0.001 0.115 0.036 0.000 0.005 0.029 

% R.S.D. 0.138 1.243 2.858 0.072 0.184 3.133 24.504 93.049 


(ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.059 -0.006 0.000 0.019 0.225 19.337 0.023 183.300 

S.D. 0.006 0.006 0.000 0.007 0.004 0.057 0.008 0.932 

% R.S.D. 9.392 101.506 40.188 38.282 1.974 0.296 34.722 0.508 

MO $E AG PS TI CD B K 

( ppm ) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean -0.001 -0.018 0.012 -0.004 0.004 0.013 -0.034 -0.022 

S.D. 0.000 0.018 0.000 0.006 0.000 0.001 0.001 0.023 

% R.S.D. 52.678 100.623 1.523 135.028 3.847 6.149 1.535 108.458 

MN SB V BE TL 

(pPm) (PPxn) (Ppm) (PPm) (Ppm) 

Mean 0.008 -0.049 -0.006 0.002 -0.019 

S.D. 0.000 0.005 0.001 0.000 0.010 

% R.S.D. 1.862 11.233 10.906 7.586 55.004 

3 1T

Identity 1: ICSAB Identity 2: Quality Control 9:05 AM June 27, 1995 


Sample Weight : 1.0000 Solution Vol" 1.00 

On-Peak Integrations : 3 

Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

WHGSD-WM-DP- /^J, REV;_[- 

2R SR BI SI AL CO CU LI 

(Ppm ) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.002 0.001 0.030 0.025 202.961 0.490 0.486 0.891 

S.D. 0.002 0.000 0.009 0.004 0.250 0.003 0.002 0.009 

% R.S.D. 99.511 12.338 29.350 17.767 0.123 0.635 0.376 0.974 


(Ppm) (ppm) (PP IR ) (ppm) (ppm) (Ppm) (Ppm) (ppm) 

Mean 1.126 0.945 0.021 157.338 19.603 0.500 -0.018 0.175 

S.D. 0.005 0.003 0.001 0.448 0.044 0.000 0.002 0.046 

% R.S.D. 0.462 0.327 5.586 0.285 0.226 0.049 13.535 26.142 


(ppm) (Ppm) (ppm) (ppa) (ppm) (ppo) (ppm) (ppm) 

Mean 0.075 0.033 0.489 0.001 0.194 18.905 0.017 180.915 

S.D. 0.010 0.014 0.001 0.006 0.006 0.076 0.003 1.622 

% R.S.D. 13.419 43.271 0.219 757.492 2.968 0.400 16.489 0.896 


(ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean -0.002 -0.012 1.012 1.021 0.004 1.037 -0.035 0.014 

S.D. 0.001 0.015 0.003 0.008 0.001 0.006 0.001 0.012 

% R.S.D. 46.651 121.605 0.256 0.764 17.099 0.548 3.770 90.726 


(ppm ) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.523 -0.047 0.503 0.508 0.042 

S.D. 0.001 0.031 0.004 0.001 0.022 

% R.S.D. 0.164 65.797 0.723 0.143 52.782 

uc3^J1 

-

Identity 1: CCV Identity 2: Duality Control 9:16 AM June 27, 1995 


" nle Weight : 1.0000 Solution Vol" 1.00 WHC-SD-WM-DP-_/^.j , REV. 


--------------------------------------------""----------------------"- 

2R SR BI SI AL Co CU LI 

( ppM ) (ppm) (ppn) (ppm) (ppm) (PPM) (ppm) (ppm) 

Mean 5.020 4.821 4.819 4.657 5.016 5.021 4.967 4.751 

S.D. 0.004 0.006 0.004 0.008 0.015 0.009 0.007 0.004 

% R.S.D. 0.090 0.127 0.084 0.167 0.306 0.173 0.137 0.080 

2N NI LA FE CA CR ND u 

(PPM ) (ppm) (PPM) (ppm) (PPM) (PPM) (PPM) (ppm) 

Mean 5.003 5.138 5.106 5.493 5.169 5.164 5.379 9.600 

S.D. 0.012 0.005 0.017 0.010 0.005 0.008 0.008 0.017 

% R.S.D. 0.244 0.096 0.327 0.185 0.092 0.148 0.156 0.174 


(ppm) (PPM) (Ppa) (ppa) (PPM) (Ppa) (ppm) (ppm) 

Mean 4.388 4.397 4.857 4.692 4.584 4.983 4.921 4.873 

S.D. 0.008 0.009 0.005 0.109 0.037 0.009 0.001 0.007 

% R.S.D. 0.174 0.203 0.112 2.316 0.804 0.176 0.029 0.149 


(ppm) (PPM) (PPM) (PPM) (ppm) (PPM) (ppm) (ppm) 

Mean 4.839 4.702 4.940 5.183 4.752 5.204 5.166 4.951 

S.D. 0.019 0.010 0.006 0.027 0.007 0.007 0.005 0.023 

% R.S.D. 0.389 0.206 0.126 0.514 0.153 0.136 0.090 0.464 


(ppm) (PPM) (PPM) (ppm) (ppm) 

Mean 5.165 4.680 5.040 5.281 4.889 

S.D. 0.007 0.039 0.009 0.003 0.018 

% R.S.D. 0.141 0.827 0.172 0.058 0.378 

4 C,7y

Identity 1: CCB Identity 2: Quality Control 9:26 AM June 27, 1995 


Sample Weight : 1.0000 Solution Volune : 1.00 

On-Peak Integrations : 3 Off-Peak 

Integrations : 1 

---------------------------------------------------------- ------. 

ZR SR BI SI 

( Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.000 0.002 0.005 0.001 

S.D. 0.000 0.000 0.001 0.001 

% R.S.D. 119.613 6.538 29.277 269.960 

ZN NI LA FE 

(Ppm ) (ppm) (Ppm) (Ppm) 

Mean 0.003 0.002 0.001 0.046 

S.D. 0.001 0.003 0.002 0.003 

% R.S.D. 17.694 128.015 264.369 5.787 

CE SM BA P 

(Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.008 -0.017 0.002 -0.002 

S.D. 0.009 0.008 0.000 0.010 

% R.S.D. 112.549 48.916 8.536 419.064 

MO SE AG PB 


Mean 0.003 -0.065 0.001 -0.019 

S.O. 0.001 0.006 0.000 0.008 

% R.S.D. 30.265 8.709 19.677 40.244 

MN SB V BE 

(Ppm ) (Ppm) (Ppm) (ppm) 

Mean 0.001 -0.034 -0.001 0.002 

S.D. 0.000 0.007 0.000 0.000 

% R.S.D. 29.069 20.076 26.849 19.300 

WHC-SD-WM-DP-1j2, REV 

AL CO Cu 


0.023 0.002 0.002 

0.000 0.002 0.000 

1.039 86.474 10.587 

CA CR NO 

(Ppm) (Ppm) (Ppm) 

0.008 0.005 0.001 

0.000 0.002 0.007 

3.927 34.318 634.179 

S MG AS 

( ppm) (Ppm) (Ppm) 

-0.006 0.008 0.004 

0.003 0.000 0.003 

45.146 3.365 90.787 

TI CD 8 

(Ppm) (ppm) (Ppm) 

0.002 0.002 0.002 

TL 

0.600 0.000 0.001 

8.952 13.351 53.545 

(Ppm) 

-0.025 

0.008 

33.381 

33" 

L 

(ppm) 

u 

(ppm) 

0.003 

0.000 

6.228 

-0.051 

0.028 

54.572 

NA 

(Ppm) 

K 

(Ppm) 

0.068 

0.001 

1.634 

-0.002 

0.011 

585.947

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06/28/95 09:09 WHGSD-WM-DP--J^L REV_L age: 1 

A-0004-1 


1^ 

/ Ate T 10 -7+ x 

Analyst: J ^-.SZ7V Instrument: ICPDt,^ Book# 0h /, 

II-X-77 7 

Method: LA-505-1-5th / Rev/Mod Q-1 

Worklist Comment: ICP B-104 DIRECT (Li only) 






5 SAMPLE S95T001104 0 D @ICP-D03 LIQUID 

Analytes Requested: LI-D- 0 1 


7 SPK S95T001104 0 D @ICP-D03 LIQUID 

8 ICSA @ICP-QC 

9 ICSAB @ICP-QC 

10 CCV @ICP-QC 

11 CCB @ICP-QC 

Analyst Signature Date 

,59,576010- t ,UV-1)-UW-f Jf 7,lX^S 

S4S700/N 1026'111) yvl 

59S7CY)0 q'J 0I.s-/ 1) 

QC 

QC 

QC 

QC 

k^^^ ^ ^ Î:I:I•^[tlI 

Final 1)age 

for worklist # 1716 

y6/ 

v 

0 G- 


.SV700I/ay_ Q (Ju-/o HO( 0V /i f 5Qhpb-+ 4 4l S1is + 94t U. 0 6 .^ 



&JO0

Analysis Report Summary Mon 07-10-95 10:36:30 AM page 1 

# -- 

Sample Name 

File 

--------------- ----- -------- 

Method 

-------- 

Date 

--------- 

Time 

----- 

OpID 

---- 

Type 

---- 

Mode 

----- 

ICV 950710A ICP2 07110195 09:34 DKS Q CONC 

2 ICB 950710A ICP2 07110195 09:41 DKS CONC 

3 ICSA 950710A ICP2 07%10/95 09:45 DKS Q CONC 

4 ICSAB 950710A ICP2 07110195 09:48 DKS p CONC 

5 S95T001104 L 950710A ICP2 07%10/95 09:55 DKS S CONC 

6 S95T0o1104 — 950710A ICP2 07110195 09:59 DKS S CONC 

7 S95T001104 D 950710A ICP2 071 10195 10:03 DKS S CONC 


9 ICSA — 950710A ICP2 07%10/95 10:15 DKS Q CONC 

10 ICSAB 950710A ICP2 07110195 10:18 DKS CONC 

11 CCV 950710A ICP2 07110195 10:27 DKS CONC 

12 CCB 950710A ICP2 07110195 10:32 DKS Q CONC 

A 40 

7-10-V 

P O Y J S—Jo G ilq 

33,7 

WHGSD-WM-DP- i3 1 , REV.. ^

Analysis Report Averages Mon 07-10-95 10:36:30 AM page 2 

# 

--- 

Sample Name 

Ag 

--------------- ----- -------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

1 ICV 5.069 4.885 5.229 4.938 5.031 5.275 

2 ICB .00I0 -.0075 0071 -.0005 .0000 0001 

3 ICSA .0006 237.5 .0683 -.0013 .0016 .0001 

4 ICSAB 9813 138.3 .0875 -.0005 .4690 .4793 

5 S95T001104 L 3.178 12.13 -18.55 8.411 .1767 .0760 

6 S95T001104- .2976 1.463 -4.922 16.60 .0368 .0606 I 

7 S95T001104 D 1290 -1.879 8721 16.61 0228 0295 

8 S95T001104-A 352.8 382.7 415.6 401.5 386.2 402.2 

9 ICSA - .0017 240.1 .0747 -.0045 .0017 .0002 

10 ICSAB 9850 240.3 1006 -.0035 4721 4860 

11 CCV 5.102 4.892 5.231 4.916 5.114 5.265 

12 CCB .0000 -.0071 -.0145 .0019 -.0001 -.0000 

# Sample Name BI Ca Cd Ce Co Cr 

--- ---------------- ---- -------- -------- -------- -------- -------- -------- 

1 ICV 5.161 5.331 5.196 5.170 5.215 5.219 3 

2 ICB -.0093 0022 0007 .0015 -.0016 0011 Q 

3 ICSA -.0353 251.5 .0030 .0124 0008 .0050 

4 ICSAB .0044 257.3 .9581 0108 .4717 4877 U 

5 S95T001104 L -17.94 24.83 -2.074 6.977 -1.578 17.15 = 

6 S95T001104- 5.445 33.60 -.2042 .3725 .8625 15.25 

7 S95T001104 D -3.384 .5809 4898 4806 3139 15.06 

8 S95T001104-A 396.3 424.3 400.8 400.0 406.1 422.4 

9 ICSA - -.0183 258.8 .0021 .0041 .0003 .0055 

10 ICSAB -.0415 260.5 .9634 0081 4757 4913 

11 CCV 5.169 5.500 5.190 5.185 5.231 5.247 

12 CCB -.0306 -.0003 -.0013 .0029 -.0032 .0002 

# 

--- 

Sample Name 

Cu 

---------------- ---- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

1 ICV 4.989 .0066 5.164 4.936 5.089 4.985 

2 ICB .0004 .0008 0002 0377 -.0001 .0009 

3 ICSA -.0093 -.0464 91.75 .1174 -.0040 .0029 

4 ICSAB .4717 -.0532 92.74 0341 -.0040 9446 

5 S95T001104 L -.0434 2.198 7462 352.5 1.561 2.739 

6 S95T001104- .3981 .5602 2.235 172.4 .0290 1.267 

7 S95T001104 D -.0882 .5220 .8938 220.3 0613 1.233 

8 S95T001104-A 388.4 .7294 401.9 595.2 391.9 388.7 

9 ICSA - -.0089 -.0567 93.32 .2549 -.0039 .0032 

10 ICSAB 4793 0565 93.56 1633 -.0031 9602 

11 CCV 5.000 .0068 5.194 4.980 5.107 4.984 

12 CCB -.0008 .0010 -.0004 .0188 -.0005 .0010 

# 

--- 

Sample Name 

-------------------- Mg 

-------- 

Mn 

-------- 

no 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

1 ICV 4.965 5.057 5.149 4.987 5.114 5.134 

2 ICB .0021 .0003 -.0023 0055 .0009 -.0036 

3 ICSA 240.5 -.0045 -.0113 189.0 -.0011 0174 

4 ICSAB 241.6 .4551 0097 188.7 -.0031 .9027 

5 S95T001104 L 20.96 .8714 .0280 180000. 4.817 -6.935 

V V 

J 

Q


# 

--- 

Sample Name 

-------------------- 

Mg 

-------- 

Mn 

-------- 

Mo 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

S95T001104 6.230 .3141 -.5778 171800. .6447 -3.019 

7 S95T001104 D 2.248 .1077 -.2158 170400. .5572 -3.067 

8 S95T001104-A 381.9 385.6 405.3 170500. 395.8 393.3 

9 ICSA - 243.4 -.0044 -.0077 191.0 -.0019 -.0184 

10 ICSAB 243.7 .4570 -.0131 191.3 -.0020 .9163 

11 CCV 4.978 5.106 5.161 4.992 5.128 5.150 

12 CCB 0057 .0004 -.0011 -.0072 .0008 -.0047 

# 

--- 

Sample Name 

-------------------- 

P 

-------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 ICV 5.215 5.217 5.040 4.903 5.066 4.979 

2 ICB -.0187 0127 -.0100 -.0080 .0112 .0073 

3 ICSA -.0322 .0189 -.0508 -.0117 -.0041 .0232 

4 ICSAB -.0543 1.005 .0021 -.0119 -.0091 .0727 

5 S95T001104 L 8401. -31.31 10470. -13.74 -630.5 34.82 

6 S95T001104- 8371. .5397 10400. .8603 -658.7 25.84 

7 S95T001104 D 8368. -2.727 10330. -4.482 -654.6 24.60 

8 S95T001104-A 8699. 400.4 10540. 378.4 -261.6 420.7 

9 ICSA - -.0597 .0126 -.0351 -.0053 .0050 .0238 

10 ICSAB 0420 1.011 .0092 .0168 .0101 .0756 

11 CCV 5.268 5.223 5.025 4.913 5.116 5.005 

12 CCB -.0169 .0058 -.0104 -.0059 .0299 .0051 

# 

--- 

Sample Name 

-------------------- 

Sm 

-------- 

Sr 

-------- 

Th 

-------- 

Ti 

-------- 

T1 

-------- 

U 

-------- 

I ICV 4.940 5.011 .0529 4.938 4.909 9.601 

2 ICB .0134 .0005 -.0056 .0000 -.0284 .0376 

3 ICSA -.0033 .0019 -.0092 .0006 .0959 -.3191 

4 ICSAB -.0028 .0018 -.0021 .0013 .0519 -.3545 

5 S95T001104 L 25.62 1.277 -7.291 .8814 9.228 73.38 

6 S95T001104- 6.111 .4632 -.7698 .1777 -3.259 12.24 

7 S95T001104 D 6.010 .3684 -1.802 .0088 -6.288 8.214 

4 S95T001104-A 383.2 388.0 3.785 384.7 380.3 743.2 

9 ICSA - -.0063 .0018 -.0029 .0002 .0738 -.3680 

10 ICSAB -.0055 .0018 -.0028 .0015 .0879 -.3905 

11 CCV 4.963 5.032 .0567 4.947 4.956 9.637 

12 CCB .0128 .0005 -.0043 .0002 -.0157 .0423 

# 

--- 

Sample Name 

---------------- 

V 

---- -------- 

Y 

-------- 

Zn 

-------- 

I ICV 5.035 .0136 5.1I0 5.014 

2 ICB .0026 .0008 -.0004 .0019 

3 ICSA .0025 .0081 .0010 -.0011 

4 ICSAB .4692 .0081 .9782 -.0018 

5 S95T001104 L 6.888 1.885 8.949 5.214 

6 S95T001104- 1.380 .4085 10.34 .9879 

7 S95T001104 D 1.320 3457 9.020 7203 

8 S95T001104-A 394.4 1.257 411.8 388.3 

9 ICSA - .0030 .0082 .0018 -.0017 

10 ICSAB .4729 .0080 .9827 -.0018 

11 CCV 5.057 .0139 5.136 5.031 

^3J 

Zr 

-------- -------- -------- 

du I 

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co 

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10 SIP ZEOL S"Wo 0000'1 90000 ON 899 

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06/14/95 12:32 Page: 1 

A-0004-1 


.nalyst: ,)X S4/o Instrument: ICPOI Book# WfTC8 

Method: LA-505-151 Rev/Mod J- 2, 

Worklist Comment: ICP B-104 Li only FUSION 

WHGSD-WM-DP-^^ Rte• 

^ 






5 PREPBLKARL @ICP-F03 SOLID 

6 SAMPLE S95T001050 0 F @ICP-F03 SOLID 95000085 B-104 

Analytes Requested: LI-F-01 

7 DUP S95T001050 0 F @ICP-F03 SOLID 

8 SPK S95T001050 0 F @ICP-F03 SOLID 













^3 

/ 

o e.13 -I q

06/14/95 12:32 WHGSD-WM-DP - REV1 Page: 2 

A-0004-1 





pre-ptttrL iy NC 

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SSST(Jo ta o--p .S> y -^' UO I-Y (uvrtul/.5-o4 = Y41 

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t ^ :J

Identity 1: ICV Identity 2: Quality Control 12:32 PM June 28, 1995 


^--lle Weight : 1.0000 Solution Volume 1..00 


...................................................................... 

WHC-SD-WM-DP-/Zf , REV../ 

ZR SR BI SI AL CO Cu LI) 

(ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) ( ) 

Mean 4.937 4.932 4.877 4.745 4.913 4.959 4.957 5.004 

S.D. 0.017 0.028 0.037 0.017 0.024 0.005 0.036 0.066 

% R.S.D. 0.348 0.563 0.755 0.349 0.493 0.098 0.724 1.323 


(Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 4.878 4.945 4.974 5.039 5.068 4.961 5.153 10.360 

S.D. 0.005 0.010 0.016 0.004 0.025 0.005 0.023 0.031 

% R.S.D. 0.106 0.203 0.313 0.081 0.487 0.096 0.452 0.296 

CE SM BA P 5 MG AS NA 

(Pp ) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 4.800 4.819 4.966 5.099 4.926 4.925 4.938 4.921 

S.D. 0.016 0.040 0.032 0.240 0.097 0.004 0.017 0.058 

% R.S.D. 0.329 0.825 0.650 4.705 1.970 0.072 0.351 1.173 


(Ppm) (Ppm) (Ppm) (Ppm) (PPm) (ppm) (ppm) (ppm) 

Mean 4.920 5.618 4.798 4.943 4.759 4.988 5.023 5.014 

S.D. 0.002 0.037 0.008 0.036 0.017 0.007 0.029 0.047 

% R.S.D. 0.033 0.652 0.169 0.718 0.358 0.146 0.587 0.938 

MN SB V BE TL 

(Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 4.981 4.675 4.893 5.176 4.827 

S.D. 0.006 0.035 0.010 0.017 0.010 

% R.S.D. 0.130 0.746 0.199 0.320 0.217 

---------------------------------------------------------------------- 

D 

rrWJ, 

Po If 59s,ao/ww 

(r r 

SVToo IaSn 

oo4 lr-I * /S?1 

SIGNATURE ABDVE REPRESENTS CBEMICAL 7HCML0GIST/CE[EMWT THAT 

ODIPLBTED/VERMIF.D THE CALIBRATION/ANALYSIS ON PAGES &9 r/ TO _46'- 

397

Identity 1: ICB Identity 2: Quality Control 12:39 PM June 28, 1995 


Sample Weight : 1.0000 Solution Volume : 1.00 


------------------------------------------------------------- 

ZR SR 

WHC-SD-WM-DP_ REV. 

BI S) AL CO CU LI I 

(Ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean O.OD6 0.002 0.027 0.010 -0.002 -0.007 0.002 0.002 

S.D. 0.001 0.000 0.006 0.002 0.004 0.000 0.000 0.000 

% R.S.D. 13.966 19.668 20.639 22.226 226.138 0.097 16.663 21.705 


(Ppm ) (PPM) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 0.002 0.006 -0.001 -0.003 0.002 0.003 0.007 0.172 

S.D. 0.000 0.001 0.002 0.001 0.000 0.001 0.002 0.054 

% R.S.D. 6.092 24.265 164.453 38.008 23.118 52.719 33.541 31.728 

CE SM RA P S MG AS NA 

( ppm ) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.047 0.047 0.003 0.002 0.010 0.002 -0.006 -0.009 

S.D. 0.010 0.012 0.000 0.007 0.008 0.000 0.004 0.004 

% R.S.D. 20.579 25.129 17.803 319.771 76.859 24.719 59.697 44.604 


( ppm ) (ppm) (PPM) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.003 0.005 0.004 0.017 0.003 0.004 0.003 0.046 

S.D. 0.001 0.018 0.001 0.008 0.001 0.000 0.001 0.019 

% R.S.D. 20.658 375.833 19.225 46.761 16.475 5.783 17.388 41.604 

MN SB V BE TL 

(PPM ) (PPM) (ppm) (ppm) (ppm) 

Mean 0.002 0.003 0.004 0.002 0.071 

S.D. 0.000 0.008 0.000 0.000 0.021 

% R.S.D. 24.230 249.495 11.367 15.829 29.620 

39(3

Identity 1: ICSA 



eak Integrations : 3 

Identity 2: Quality Control 


---------------------------------------------------- 

ZR SR BI 


Mean 0.001 0.002 0.038 

S.D. 0.002 0.000 0.008 

% R.S.D. 365.975 4.268 20.934 

ZN N) LA 

(ppm) (Ppm) (ppm) 

Mean 0.049 -0.053 0.024 

S.D. 0.000 0.001 0.003 

% R.S.D. 0.541 2.496 12.459 

CE SM BA 

( ppm ) (ppm) (ppm) 

Mean 0.058 0.013 0.002 

S.D. 0.018 0.021 0.000 

% R.S.D. 31.801 164.459 14.561 

MO SE AG 

(ppm) (ppm) (ppm) 

Mean 0.002 0.079 0.015 

S.D. 0.001 0.010 0.001 

% R.S.D. 26.339 12.452 7.638 

MN SB V 


Mean 0.011 -0.047 -0.003 

S.D. 0.001 0.010 0.001 

% R.S.D. 4.791 21.937 26.467 

12:41 PM June 28, 1995 

WHC-SD-WM-DP-/5 9', REV, 

SI AL CO CU L 

( ppm ) (Ppm) (ppm) (ppm) (Ppm) 

0.078 207.766 -0.003 -0.014 0.002 

0.003 0.935 0.002 0.001 0.000 

4.125 0.450 57.574 3.967 17.399 

FE CA CR NO 0 

( ppm ) (ppm) (Ppm) (ppm) (Ppm) 

151.399 19.348 -0.002 -0.018 0.098 

0.499 0.090 0.000 0.005 0.071 

0.330 0.467 20.371 26.686 72.536 

P S MG AS NA 

( Ppm ) (ppm) (ppm) (ppm) (ppm) 

0.049 0.214 19.271 0.029 190.138 

0.006 0.014 0.065 0.005 2.334 

11.430 6.526 0.338 18.758 1.228 

PS TI CD B K 

( ppm ) (Ppm) (Ppm) (ppm) (ppm) 

0.009 0.005 0.017 -0.035 -0.038 

0.009 0.000 0.001 0.001 0.008 

102.455 8.837 3.203 1.760 22.044 

BE TL 

( ppm ) (Ppm) 

0.004 0.003 

0.000 0.032 

2.647 951.883 

A.: J



Sasple Weight : 1.0000 Solution Volume :. 1.00 


-------------------------------------------- ------- -------------. 

2R SR BI S1 


Mean 0.002 0.002 0.033 0.064 

S.D. 0.001 0.000 0.005 0.001 

% R.S.D. 42.040 0.003 16.277 2.310 

2N NI LA FE 


Mean 1.018 0.925 0.020 149.445 

S.D. 0.003 0.004 0.002 0.340 

% R.S.D. 0.259 0.383 8.059 0.228 

CE SM BA P 


Mean 0.048 0.042 0.497 0.054 

S.D. 0.001 0.006 0.001 0.012 

% R.S.D. 2.645 14.091 0.170 22.781 

MO SE AG PB 

(ppm) (Ppm) (ppm) (ppm) 

Mean -0.001 0.124 0.997 1.010 

S.D. 0.001 0.020 0.001 0.012 

% R.S.D. 184.750 16.016 0.127 1.176 

MN SIT V BE 


Mean 0.511 -0.000 0.492 0.499 

S.D. 0.001 0.025 0.002 0.001 

% R.S.D. 0.178 39165.325 0.336 0.109 

îV J 

AL 

WHC-SD-WM-DP- 

(ppm) 

204.791 

CA 

0.498 

0.243 

(Ppm) 

19.151 

S 

(ppm) 

TI 

(ppm) 

0.044 

0.229 

TL 

(ppm) 

0.199 

0.004 

1.984 

0.004 

0.000 

9.117 

0.079 

0.011 

13.938 

REV. L 

CO Cu LI 


0.485 0.485 0.921 

0.002 0.001 0.001 

0.334 0.199 0.133 

CR ND u 

(Ppm) (ppm) (ppm) 

0.489 -0.007 0.207 

0.005 0.010 0.005 

1.060 145.474 2.284 

MG AS NA 


18.912 0.041 186.917 

0.033 0.003 0.186 

0.176 6.364 0.099 

CD B K 


1.008 -0.035 0.006 

0.004 0.002 0.014 

0.436 4.913 230.940

Identity 1: PREPBLK Identity 2: Quality Control 12:51 PM June 28, 1995 




- ------------------------------------------------------------- 

2R 

SR 81 SI 

(ppm) (Ppm) (Ppm) (ppm) 

Mean 0.026 0.012 0.202 0.036 

S.D. 0.013 0.001 0.077 0.005 

% R.S.D. 47.956 8.074 38.288 13.258 

2N NI LA FE 

(ppm) (ppm) (ppm) (ppm) 

Mean 0.050 3.294 -0.036 1.660 

S.D. 0.006 0.106 0.006 0.235 

% R.S.D. 12.723 3.214 17.854 14.148 

CE SM BA P 

(ppm) (ppm) (Ppm) (Ppm) 

Mean 0.053 0.153 0.024 0.160 

S.D. 0.123 0.146 0.003 0.013 

% R.S.D. 232.139 95.377 10.415 7.900 

MO SE AG PB 


Mean 0.006 -0.238 0.029 -0.061 

S.D. 0.019 0.211 0.004 0.037 

% R.S.D. 292.206 88.794 13.942 60.912 

MN SB V BE 

(Ppm ) (Ppm) (ppm) (ppm) 

Mean 0.078 0.149 -0.001 0.010 

S.D. 0.004 0.125 0.008 0.003 

% R.S.D. 5.062 83.474 653.676 26.762 

Fa 

XV7 L 

WHC-SD-WM-DP- j ^1, REV. 

AL CO CU 

(ppm) (Ppm) (ppm) 

1.441 -0.057 0.043 

0.301 0.032 0.006 

20.912 57.243 14.847 

CA CR NO 

(ppm) (ppm) (Ppm) 

0.275 0.031 -0.206 

0.029 0.008 0.089 

10.597 27.030 43.288 

S MG AS 


0.086 0.178 -0.031 

0.014 0.029 0.035 

16.376 16.511 110.698 

TI CD B 


0.016 0.043 0.018 

0.005 0.009 0.006 

27.774 19.964 30.088 

TL 

(ppn) 

0.618 

0.175 

28.263 

LI 

0.009 

0.003 

28.192 

U 

(ppm) 

0.978 

0.462 

47•.260 

NA 

(ppm) 

K 

(ppm) 

5.243 

0.292 

5.578 

10682.270 

41.453 

0.388

Identity 1: S95t00105O_L identity 2: .5614 9 in250,1-9-1-4 




ZR SR BI S( 

( Ppm ) (Ppm) (ppm) (ppm) 

Mean 37.859 125.251 12571.116 4661.399 

S.D. 9.181 1.210 273.612 51.984 

% R.S.D. 24.252 0.966 2.177 1.115 

ZN NI LA FE 

( ppm ) (Ppm) (Ppm) (Ppm) 

Mean 102.377 3483.202 -77.486 13274.623 

S.D. 6.549 10.585 37.140 110.303 

% R.S.D. 6.397 0.304 47.931 0.831 

CE SM BA P 

( Ppm ) (ppm) (ppm) (Ppm) 

Mean 836.053 154.752 25.140 15730.824 

S.D. 133.485 163.919 1.577 756.863 

% R.S.D. 15.966 105.924 6.272 4.811 

MO SE AG PB 

( pPm ) (Ppm) (Ppm) (Ppm) 

Mean 70.422 301.437 24.589 335.585 

S.D. 9.529 435.482 9.282 112.901 

% R.S.D. 13.532 144.469 37.748 33.643 

MN SB V BE 

( Ppm ) (Ppm) (Ppm) (Ppm) 

Mean 56.236 -85.799 9.821 17.414 

S.D. 3.328 51.914 18.713 4.015 

% R.S.D. 5.918 60.506 190.553 23.058 

,A r6- 

12:56 PM June 28, 1995 

WHC-SD-WM-DP-_Z^, REV.-( 

AL CO CU LI 

(PPIR) (Ppm) (Ppm) (ppm) 

5235.137 -125.441 121.922 17.154 

269.587 35.967 6.648 2.476 

5.150 28.672 5.453 14.436 

CA CR NO U 


608.025 534.702 -144.891 2070.549 

31.487 13.232 112.776 578.994 

5.179 2.475 77.835 27.963 

S MG AS NA 


6170.374 439.898 -175.501 127970.521 

142.724 29.870 46.115 572.030 

2.313 6.790 26.276 0.447 

TI CD B K 

(Ppm ) (Ppm) (Ppm) (Ppm) 

24.249 57.647 40.985 4838054.286 

9.403 10.679 34.345 11841.150 

38.776 18.524 83.800 0.245 

TL 

(Ppm) 

812.180 

266.480 

32.810

Identity 1: S95TOO1050 Identity 2: .5614gin250,1 . 9 ml 


,le Weight : 0.5614 Solution Volume 2500.00 


-------------------------------------------------------- 

ZR SR BI SI 


Mean 21.791 112.592 12416.360 5083.917 

S.D. 6.006 0.635 90.786 30.383 

X R.S.D. 27.563 0.564 0.731 0.598 

ZN NI LA FE 

(Ppm) (ppm) (ppm) (Ppm) 

Mean 74.082 3434.170 -10.429 10416.925 

S.D. 1.641 14.303 8.495 88.362 

X R.S.D. 2.485 0.416 81.452 0.848 

CE SM BA P 

(ppm) (ppm) (ppm) (pan) 

Mean -70.051 96.848 14.638 14936.324 

S.D. 62.771 80.125 1.603 649.935 

X R.S.D. 89.608 82.732 10.948 4.351 

MO SE AG PB 

(Ppm) (Ppm) (ppm) (ppm) 

Mean 4.401 58.590 17.968 73.790 

S.D. 1.747 37.770 3.233 12.236 

X R.S.D. 39.686 64.464 17.995 16.583 

MN SB V BE 

( ppm ) (Ppm) (pan) (ppm) 

Mean 55.817 -59.388 -2.159 2.520 

S.D. 1.779 144.779 4.515 0.940 

X R.S.D. 3.188 243.783 209.091 37.316 

1:02 PM June 28, 1995 

ZX0 a 

AL 

(Ppm) 

2933.396 

78.445 

CA 

(Ppm) 

2.674 

370.957 

5 

(pan) 

6.652 

1.793 

6154.199 

128.963 

TI 

2.096 

(Ppm) 

12.949 

1.969 

15.209 

TL 

(Ppm) 

149.666 

112.352 

WHC-SD-WM-DP- 1^ , REV.. i 

75.068 

CO 

(Ppm) 

-8.824 

12.476 

141.393 

CR 

(Ppm) 

467.311 

MG 

(Ppm) 

6.187 

1.324 

166.485 

CD 

7.154 

4.297 

(Ppm) 

23.617 

1.190 

5.041 

Cu LI/ 

(ppm) ( ) 

97.212 2.760 

2.448 1.838 

2.518 66.588 

NO u 

(Ppm ) (ppm) 

-32.137 1451.311 

18.077 249.183 

56.249 17.170 

AS NA 

(Ppm) (ppm) 

-11.933 118362.632 

10.343 534.931 

86.670 0.452 

8 K 

(Ppm ) (ppm) 

39.947 4462230.178 

1.554 19337.339 

3.890 0.433

Identity 1: S95TOO1050_D Identity 2: .5296gin250,1 . 9 ml 1:06 PM June 28, 1995 




---------------------------------------------------------------------- 

ZR 

SR BI SI AL 

( ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 27.518 122.746 13782.244 5566.812 3138.432 

S.D. 6.765 0.440 107.887 20.449 21.834 

% R.S.D. 24.584 0.359 0.783 0.367 0.696 

ZN NI LA FE CA 

(Ppm ) (Ppm) (Ppm) (ppm) (ppm) 

Mean 84.417 3603.541 -2.451 11317.731 294.334 

S.D. 0.955 16.213 7.824 36.914 2.750 

R.S.D. 1.131 0.450 319.194 0.326 0.934 

CE SM BA P S 

(Ppm ) (ppm) (ppm) (Ppm) (ppm) 

Mean 66.467 128.166 15.350 16790.173 6768.909 

S.D. 52.160 62.289 1.121 203.191 39.664 

% R.S.D. 78.475 48.600 7.306 1.210 0.586 



Mean 13.297 17.722 14.893 84.742 15.976 

S.D. 4.499 - 26.976 4.018 31.046 1.277 

% R.S.D. 33.837 152.220 26.980 36.636 7.992 

MN SB V BE TL 

(ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 62.816 12.589 -0.954 2.670 149.555 

S.D. 1.408 121.360 4.452 1.306 90.940 

% R.S.D. 2.241 964.058 466.572 48.913 60.807 

A104 

WHGSD-WM-DP- 131, REV. 

CO Cu 

Cd 

( ppm ) (ppm) (Ppm) 

-9.349 111.582 5.250 

13.213 0.985 1.225 

141.341 0.883 23.326 

CR NO 0 


533.913 -9.114 1523.587 

8.454 38.466 209.630 

1.583 422.050 13.759 

MG AS NA 

(Ppm ) (Ppm) (Ppm) 

166.966 -0.396 127896.972 

2.451 26.580 503.042 

1.468 6705.609 0.393 

CD B K 

( ppm ) (Ppm) (ppm) 

24.990 34.099 4829067.749 

2.733 2.516 14523.788 

10.937 7.378 0.301

Identity 1: S95TOO1050_A Identity 2: .5614gin2SO,1-9 ml 1:09 PH June 28, 1995 



yak Integrations : 3 Off-Peak Integrations : 1 

WHGSD-WM-UP-, 

!) , REV. 

2R SR BI Si AL CO Cu LI 

(ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (Pam) ( ) 

Mean 4522.616 4544.664 17107.060 9585.125 7287.786 4442.754 4565.742 4072.094 

S.D. 8.154 17.259 108.173 13.041 30.175 7.209 20.995 19.000 

% R.S.D. 0.180 0.380 0.632 0.136 0.414 0.162 0.460 0.467 


(ppm) (Ppm) (Ppm) (Ppm) (Pam) (ppm) (ppm) (ppm) 

Mean 4411.365 7844.380 4506.023 14975.769 4846.838 5009.142 4650.976 10397.518 

S.O. 6.127 4.936 5.588 29.011 15.414 7.093 34.907 112.648 

% R.S.D. 0.139 0.063 0.124 0.194 0.318 0.142 0.751 1.083 


(ppm) (Pam) (Pam) (PPm) (ppm) (Ppm) (ppm) (ppm) 

Mean 4242.674 4281.273 4432.420 19916.862 10488.906 4571.590 4346.118 126192.594 

S.D. 39.538 24.212 18.523 456.330 173.275 1.935 22.621 505.482 

4 R.S.D. 0.932 0.566 0.418 2.291 1.652 0.042 0.520 0.401 


(Ppm ) (Ppm) (ppm) (ppm) (ppm) (Pan) (ppm) (ppm) 

Mean 4400.050 4650.808 3253.130 4621.362 4283.868 4464.326 4358.342 4574731.846 

S.D. 2.380 116.609 24.589 39.096 10.254 34.595 9.941 20944.031 

% R.S.D. 0.054 2.507 0.756 0.846 0.239 0.775 0.228 0.458 

MN SB V BE TL 

(Pam) (ppm) (ppm) (PPm) (Ppm) 

Mean 4575.626 4238.526 4456.676 4400.080 4481.847 

S.D. 9.348 46.481 7.203 12.719 65.063 

% R.S.O. 0.204 1.097 0.162 0.289 1.452 

405

X 4- LY 1 f 

Identity 1: CCY_j Identity 2: Quality Control 


Sample Weight : 1.0000 Solution VoLuae 1.00 


ZR SR BI 


Mean 4.974 4.910 4.918 

S.D. 0.024 0.038 0.053 

% R.S.D. 0.487 0.778 1.085 

ZN NI LA 

( per ) (ppm) (ppm) 

Mean 4.974 5.012 5.006 

S.D. 0.001 0.005 0.036 

% R.S.D. 0.024 0.090 0.716 

CE Sm BA 


Mean 4.756 4.677 4.930 

S.D. 0.020 0.057 0.045 

% R.S.D. 0.429 1.221 0.921 

MO SE AG 


Mean 4.944 5.570 2.984 

S.D. 0.009 0.044 0.315 

% R.S.D. 0.179 0.798 10.558 

MN SB V 

( ppm ) (ppm) (pm) 

Mean 5.068 4.728 4.955 

S.D. 0.004 0.057 0.015 

L R.S.D. 0.088 1.201 0.307 

1:16 PM June 28, 1995 

WHC-SD-WM-DP-j, REV 

-- SI --- --- AL. co CO 

CL 

( pin ) (ppm) (ppo) (ppm) (ppm) 

4.786 4.936 4.994 4.944 4.951 

0.020 0.027 0.004 0.049 0.061 

0.409 0.542 0.086 0.994 1.229 

FE CA CR ND 0 


5.184 5.073 5.020 5.144 10.351 

0.024 0.036 0.001 0.052 0.022 

0.462 0.704 0.029 1.018 0.209 

P S MG AS NA 


5.012 4.891 4.991 4.957 4.946 

0.188 0.072 0.003 0.016 0.039 

3.748 1.473 0.057 0.314 0.794 

PB TI CD B K 


5.047 4.740 5.056 5.065 6.101 

0.019 0.023 0.010 0.033 0.260 

0.373 0.483 0.191 0.654 4.265 

BE TL 

(ppm) (ppm) 

5.194 4.912 

0.022 0.019 

0.432 0.381 

400

Sat ov-1r 

Identity 1: CCB_1 Identity 2: Quality Control 1:24 PM June 28, 1995 


t +mple Weight : 1.0000 Solution volume 1.00 WHC-SD-WM-DP-_L^L , REV. 

eak integrations : 3 Off-Peak Integrations : 1 

-.-------------------------- 


( ppm ) (ppm) (ppm) (Pp,n) (ppm) (ppm) (ppm) 

Mean 0.000 0.002 0.015 0.001 0.004 -0.007 0.002 

S.D. 0.001 0.000 0.011 0.002 0.005 0.003 0.000 

% R.S.D. 436.676 12.491 69.530 328.648 144.630 37.380 18.837 


(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.002 0.005 -0.001 0.002 0.002 0.004 0.001 

S.D. 0.000 0.002 0.001 0.002 0.000 0.001 0.007 

% R.S.D. 17.554 31.577 117.012 62.873 16.728 39.447 1115.715 

CE SM BA P S - MG AS 

(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.012 -0.008 0.001 0.023 0.007 0.002 -0.008 

S.D. 0.019 0.019 0.000 0.005 0.007 0.000 0.004 

% R.S.D. 163.207 252.214 28.508 21.618 101.356 24.765 47.784 

MO SE AG PB TI CO B 

( ppm ) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.002 -0.027 0.274 0.003 0.001 0.002 0.003 

S.D. 0.000 0.006 0.029 0.005 0.000 0.000 0.001 

X R.S.D. 11.056 21.255 10.585 140.921 42.683 27.277 29.636 

MN SB V BE TL 

( ppm ) (Ppm) (ppm) (ppin) (ppm) 

Mean 0.001 0.003 -0.001 0.002 0.007 

S.D. 0.000 0.018 0.001 0.000 0.025 

% R.S.D. 27.540 564.153 95.145 19.519 358.350 

407 

L I^ 

0.002 

0.000 

24.957 

u 

(ppm) 

-0.008 

0.071 

840.655 

NA 

(ppm) 

0.026 

0.003 

13.674 

K 

(ppm) 

0.656 

0.087 

13.304

Identity 1: S95TOO1056 L Identity 2: .56929in250,1-9.1-4 




2R SR Bl SI 

(ppm) (ppm) (Ppm) (Ppm) 

Mean 140.198 169.493 14039.676 6329.864 

S.D. 31.584 8.960 392.961 147.318 

% R.S.D. 22.528 5.286 2.799 2.327 

ZN NI LA FE 

( Ppm ) (Ppm) (Ppm) (ppm) 

Mean 118.569 6748.381 -28.082 10695.473 

S.D. 21.050 60.693 73.612 113.191 

X R.S.D. 17.753 0.899 262.130 1.058 

CE SM BA P 


Mean -184.640 1022.040 71.347 15538.081 

S.D. 359.773 469.084 10.473 170.897 

% R.S.D. 194.851 45.897 14.679 1.100 

NO SE AG PB 


Mean 69.457 -139.392 532.544 488.047 

S.D. 49.412 369.552 33.919 218.009 

% R.S.D. 71.141 265.116 6.369 44.670 

MN SB V BE 

( ppm ) (PPn) (ppm) (pp,n) 

Mean 112.643 183.611 54.466 57.914 

S.D. 8.650 399.581 34.235 6.084 

% R.S.D. 7.679 217.624 62.855 10.505 

1:28 PM June 28, 1995 

WHC-SD-WM-DP-^, REV.. ^ 

AL CO Cu LI 

( ppm ) (Ppm) (Ppm) ( ) 

2979.739 39.836 118.088 87.432 

159.684 35.550 21.725 13.450 

5.359 89.240 18.397 15.384 

CA CR NO u 


269.554 626.873 171.522 4587.241 

7.254 17.098 8.630 1563.170 

2.691 2.727 5.031 34.076 

S MG AS NA 


6543.567 234.097 62.523 117508.193 

54.860 10.068 107.331 1065.523 

0.838 4.301 171.666 0.907 

TI CD B K 


79.470 87.581 97.595 4105255.180 

20.950 23.863 29.500 33714.420 

26.362 27.247 30.227 0.821 

TL 

(ppm) 

1710.856 

615.987 

36.005 

4:0 Z3

Identity 1: S95TOO1056 Identity 2: .5692gin250,1-9 m( 


Sampte Weight : 0.5692 Solution Volume : 2500.00 

,ak Integrations : 3 Off-Peak 


1:32 PM June 28, 1995 

WHC-SD-WM-DP-1^, REV. 

------------------------------------------------------------ 

ZR SR BI SI 

AL CO CU LI/l/ 

( pm ) (ppm) (ppm) (ppm) 

(ppm) (ppm) (ppn) U,) 

Mean 38.113 124.646 14308.254 6685.965 2714.812 3.346 40.943 29.240 

S.D. 11.715 1.032 58.306 29.212 

29.296 12.261 4.558 2.190 

% R.S.D. 30.739 0.828 0.408 0.43 7 1.079 366.397 11.133 7.489 

ZN NI LA FE 

CA CR NO U 

(ppm) (pan) (pan) (ppm) 


Mean 81.542 6902.572 -31.015 10981.85 8 301.866 558.353 33.566 1041.787 

S.D. 1.926 37.935 10.085 70.570 

0.663 8.205 40.499 424.556 

% R.S.D. 2.362 0.550 32.516 0.643 

0.220 1.469 120.656 40.753 

CE SM BA P 

S MG AS NA 

(ppm) (ppm) (ppm) (pan) 

( ppm ) (ppm) (ppm) (Ppm) 

Mean 49.016 46.379 19.545 16363.75 9 6807.713 142.440 28.634 112235.758 

S.D. 97.860 117.007 2.507 170.95 4 45.142 1.527 18.446 1289.871 

% R.S.O. 199.649 252.283 12.826 1.045 

0.663 1.072 64.422 1.149 

MO SE AG PB 

TI CD B K 

(Ppm) (pm) (pan) (pan) (pm) (Ppm) (Ppm) (ppm) 

Mean 14.543 88.431 226.013 207.12 2 24.627 21.154 45.537 3850803.886 

S.D. 9.124 21.249 2.130 11.64 7 5.764 5.178 4.388 38553.214 

% R.S.D. 62.740 24.029 0.943 5.623 

MN SB V BE 

(ppm) (ppm) (pan) (ppm) 

Mean 68.301 -79.990 -1.471 5.062 

S.D. 0.641 19.824 6.534 1.397 

% R.S.D. 0.938 24.783 444.152 27.603 

23.406 24.479 9.637 1.001 

TL 

r^J 

(ppm) 

33.515 

122.973 

366.918

Identity 1: S95TOO1056 D Identity 2: .5631gin250,1-9 ml 


Sample Weight : 0.5631 Solution Volune : 2500.00 


Off-Peak Integrations : 

-------------------------------------------- --------------- -----. 

ZR SR BI SI 

(ppm) (PPM) (PPM) (ppm) 

Mean 66.445 137.223 16104.347 7416.272 

S.D. 0.465 0.242 35.647 14.967 

% R.S.D. 0.700 0.176 0.221 0.202 

ZN NI LA FE 

(ppm) (ppm) (ppm) (Ppm) 

Mean 88.406 7827.650 9.560 12374.759 

S.D. 1.592 10.980 8.379 45.249 

% R.S.D. 1.801 0.140 87.649 0.366 

CE SM BA P 

(PP(n ) (PPM) (ppm) (ppm) 

Mean 243.205 317.032 24.373 18575.347 

S.D. 5.048 12.209 0.518 545.494 

% R.S.D. 2.075 3.851 2.125 2.937 

MO SE AG PIT 

( ppM ) (PPM) (ppm) (Ppm) 

Mean 8.337 -26.000 238.388 176.095 

S.D. 4.111 35.863 2.721 41.229 

% R.S.D. 49.303 137.934 1.141 23.413 

MN SB V BE 

( PPM ) (ppm) (pPM) (PPM) 

Mean 79.605 -104.641 13.704 4.426 

S.D. 0.674 101.553 0.758 0.010 

% R.S.D. 0.846 97.049 5.528 0.219 

1 

1:35 PM June 28, 1995 

WHGSD-WM-DP-_1, REV. 

AL CO CO LI 

(Ppm ) (PPM) (PPM) ) 

2985.811 -5.135 40.570 27.462 

5.268 7.177 1.348 0.916 

0.176 139.757 3.323 3.337 

CA. CR NO u 

(PPM) (PPM) (ppm) (ppm) 

284.190 615.592 -5.562 2136.441 

0.000 2.544 12.061 103.481 

0.000 0.413 216.861 4.844 

S MG AS NA 

(Ppm) (pp(n) (ppm) (Ppm) 

7611.785 157.306 -35.213 125707.194 

181.546 0.444 7.504 558.876 

2.385 0.282 21.310 0.445 

TI CD B K 

(Ppm ) (ppm) (PPM) (pp(n) 

34.802 19.493 45.046 4301529.671 

TL 

(ppm) 

0.664 0.585 2.230 6827.188 

1.909 2.999 4.951 0.159 

465.277 

40.127 

8.624

Identity 1: S95T001056_A Identity 2: .5692gin250,1 . 9 ml 2:05 PM June 28, 1995 


Sample Weight : 0.5692 solution Volume : 2500.00 

,ak Integrations : 3 Off-Peak Integrations : 1 

WHC-SD- WM-DP-,Jj_L REVS 

ZR SR BI SI AL CO Cu LI ) 

( Ppm ) (Ppm) (Ppm) (Ppm) (PP(n ) (pp(a) (ppm) 

Mean 4486.621 4477.445 18705.869 11140.545 6964.403 4365.147 4377.447 3979.716 

S.D. 4.132 2.140 97.815 4.392 13.557 14.217 3.036 13.969 

% R.S.D. 0.092 0.048 0.523 0.039 0.195 0.326 0.069 0.351 


( ppm ) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 4355.907 11328.674 4431.632 15575.294 4800.877 4974.442 4453.276 10129.617 

S.D. 4.646 43.448 9.957 84.840 3.910 23.437 51.297 44.656 

% R.S.D. 0.107 0.384 0.225 0.545 0.081 0.471 1.152 0.441 


( Ppm ) (Ppm) (Ppm) (Ppm) (ppm) (pppa) (ppm) (ppm) 

Mean 4246.966 4216.136 4348.580 20364.181 10915.013 4521.588 4315.960 117260.205 

S.D. 9.965 11.927 2.546 611.324 211.755 3.893 30.434 425.594 

% R.S.D. 0.235 0.283 0.059 3.002 1.940 0.086 0.705 0.363 


( Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) ( Ppm) 

Mean 4336.933 4542.181 3674.609 4620.121 4195.603 4408.406 4303.519 3879672.045 

S.D. 8.245 87.075 16.698 54.711 3.912 1.536 11.020 7563.766 

% R.S.D. 0.190 1.917 0.454 1.184 0.093 0.035 0.256 0.195 

MN SB V BE TL 

( Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 4532.993 4120.617 4403.522 4349.179 4479.649 

S.D. 16.091 113.777 12.618 3.866 28.665 

% R.S.D. 0.355 2.761 0.287 0.089 0.640 

w 

^:1





_______________________________ 

_________________________ 

2R SR 81 


Mean 0.001 0.001 0.037 

S.D. 0.001 0.000 0.010 

X R.S.D. 129.782 36.074 26.170 

2N NI LA 

(PPm) (ppm) (Ppm) 

Mean 0.048 -0.058 0.022 

S.D. 0.001 0.001 0.003 

X R.S.D. 1.794 1.384 12.833 

CE SM BA 

(Ppm ) (ppm) (Ppm) 

Mean 0.079 0.045 0.001 

S.D. 0.017 0.019 0.000 

X R.S.D. 21.959 41.690 38.265 

MO SE AG 


Mean -0.001 0.060 0.019 

S.D. 0.002 0.014 0.002 

X R.S.D. 176.319 23.964 10.573 

MN SE V 


Mean 0.010 0.010 -0.005 

S.D. 0.001 0.035 0.002 

X R.S.D. 7.340 355.360 36.431 

WHC-SD-WM-DP-_Z,^1, REV. 

SI AL CO CU 

(ppm) (Ppm) (Ppm) (ppm) 

0.081 207.773 -0.007 -0.016 

0.004 0.540 0.002 0.001 

4.565 0.260 24.582 3.757 

FE CA CA ND 

(Ppm ) (PPM) (Ppm) (Ppm) 

153.288 19.326 -0.011 -0.020 

0.223 0.055 0.003 0.012 

0.145 0.285 24.990 58.861 

P S MG AS 


0.044 0.206 19.255 0.024 

0.006 0.006 0.047 0.001 

14.015 2.709 0.244 4.203 

PB TI CD 8 

(Ppm ) (ppm) (Ppm) (pp(n) 

-0.013 0.005 0.015 -0.036 

0.004 0.001 0.001 0.001 

28.035 15.199 7.146 2.828 

BE TL 

(Ppm ) (ppm) 

0.003 0.041 

0.000 0.029 

9.786 69.004- 

^X. A. 

L 

(Ppm) 

0.001 

0.000 

60.635 

U 

(Ppm) 

0.174 

0.071 

40.603 

NA 

(Ppm) 

189.186 

K 

1.786 

0.944 

(Ppm) 

0.402 

0.077 

19.048



' nle Weight : 1.0000 Solution Volume 1.00 

eak Integrations : 3 Off-Peak Integrations : 

---------------------------------------------------------------------- 

1 WHGSD-WM-DP-J, REVS 

2R SR BI SI AL CO CO LI 

(Ppm) (ppm) (Ppm) (Ppm) (ppm) (Pp) (Ppm) (ppm) 

Mean 0.004 0.000 0.022 0.070 203.727 0.472 0.482 0.915 

S.D. 0.001 0.000 0.014 0.007 0.702 0.006 0.003 0.009 

% R.S.D. 35.489 52.539 61.215 10.488 0.345 1.187 0.597 1.023 


(ppm) (Ppm) (Ppm) (PPm) (ppm) (ppm) (ppm) (ppm) 

Mean 1.029 0.915 0.026 149.748 19.020 0.476 -0.016 0.381 

S.D. 0.003 0.004 0.001 0.244 0.073 0.003 0.004 0.057 

7. R.S.D. 0.282 0.426 4.745 0.163 0.385 0.733 26.017 15.058 

CE SM BA p S MG AS NA 

(Ppm ) (Ppm) (ppm) (Ppm) (Ppm) (ppn) (Ppm) (Ppm) 

Mean 0.036 0.088 0.494 0.008 0.215 18.699 0.033 186.413 

S.D. 0.016 0.015 0.002 0.006 0.006 0.046 0.006 1.834 

% R.S.D. 44.009 17.203 0.454 71.467 2.673 0.244 18.945 0.984 

MO SE AG PB TI CD 8 K 

(Ppm) (Ppm) (Ppm) (ppm) (prn) (Pp(n) (ppm) (Ppm) 

Mean -0.006 0.098 0.987 0.999 0.004 0.991 -0.039 0.383 

S.D. 0.002 0.012 0.002 0.017 0.001 0.003 0.001 0.114 

% R.S.D. 33.888 12.350 0.160 1.667 19.122 0.325 2.594 29.702 

MN SB V BE TL 

(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.506 -0.019 0.490 0.495 0.132 

S.D. 0.002 0.034 0.002 0.001 0.024 

% R.S.D. 

0.406 181.232 

0.351 

0.115 17.954 

'------------------------------------- --- ----------------------------

'a E-rxrr 

Identity 1: CCV_ Identity 2: Quality Control 2:33 PM June 28, 1995 


Sample Weight : 1.0000 Solution Voluae 1.00 


--------------------------------------- --------------- ----------- ----- 

ZR SR 

81 

SI 

WHC-SD-IIVM-DP- 

, REV. 

AL CO Cu LI 


Mean 5.011 4.934 4.911 4.749 5.003 4.928 4.954 4.895 

S.D. 0.006 0.006 0.015 0.010 0.016 0.010 0.011 0.032 

% R.S.D. 0.117 0.121 0.298 0.204 0.317 0.205 0.222 0.645 


(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 4.900 4.971 5.018 5.250 5.090 4.973 5.237 10.539 

S.D. 0.013 0.013 0.006 0.022 0.006 0.015 0.023 0.018 

% R.S.D. 0.270 0.270 0.115 0.424 0.114 0.309 0.444 0.167 


(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (pp) (ppm) 

Mean 4.730 4.754 4.952 5.122 4.904 4.957 4.915 4.941 

S.D. 0.012 0.013 0.008 0.151 0.057 0.014 0.030 0.027 

% R.S.D. 0.264 0.279 0.162 2.958 1.157 0.281 0.612 0.556 

NO SE AG P8 TI CD 8 K 


Mean 4.884 5.521 4.825 5.069 4.699 5.023 5.047 5.154 

S.D. 0.006 0.027 0.023 0.054 0.005 0.019 0.011 0.025 

% R.S.D. 0.129 0.481 0.476 1.069 0.102 0.387 0.214 0.486 

MN S8 V BE TL 

( ppm ) (ppm) (ppm) (ppm) (ppn) 

Mean 5.050 4.675 4.950 5.194 4.916 

S.D. 0.016 0.037 0.012 0.007 0.027 

% R.S.D. 0.309 0.791 0.243 0.133 0.555 

f i `3

g 17 -t Y-i r 

Identity 1: CCB. - 2, Identity 2: Quality Control 2:39 PM June 28, 1995 


Samp le Weight : 1.0000 Solution Volume 1.00 

3 REV. 

3 Off-Peak Integrations : 1 WHC-SD-WM-DP- , 

ak Integrations : 

( ppm) (pPm) (pPm) (ppm) (pPm) (ppm) (ppm) (ppm) 

Mean 0.003 0.002 0.020 0.006 0.041 -0.003 0.003 0.002 

S.D. 0.001 0.000 0.005 0.003 0.004 0.003 0.000 0.000 

% R.S.D. 33.210 8.513 24.274 41.742 8.927 114.773 8.961 11.263 


(Ppm) (pp(n) (Ppm) (PP(n) (ppm) (Ppm) (Ppm) (ppm) 

Mean 0.002 0.003 -0.000 0.031 0.006 0.006 0.018 0.118 

S.D. 0.000 0.001 0.002 0.008 0.001 0.000 0.004 0.051 

% R.S.D. 4.535 28.792 538.592 24.343 19.609 6.737 19.437 43.148 

CE SN BA P S MG AS NA 

( ppm) (ppm) (ppm) (Ppm) (PP(n) (ppm) (ppm) (ppm) 

Mean 0.035 0.032 0.002 0.014 0.010 0.005 -0.003 0.069 

S.D. 0.014 0.017 0.000 0.002 0.004 0.001 0.001 0.005 

% R.S.D. 39.425 52.726 3.900 16.970 40.055 18.320 52.353 7.330 


(Ppm) - (Ppm) (Ppm) (Ppm) (pp:n) (ppm) (Ppm) (Ppm) 

Mean 0.003 0.025 0.017 0.007 0.002 0.002 0.002 0.130 

S.D. 0.000 0.008 0.003 0.004 0.000 0.000 0.001 0.007 

% R.S.D. 5.085 31.578 20.961 62.180 9.320 21.610 29.248 5.723 

MN SB V BE TL 

(ppm) (Pp) (Ppm) (ppm) (Ppm) 

Mean 0.001 0.017 0.001 0.002 0.049 

S.D. 0.000 0.029 0.001 0.000 0.021 

% R.S.D. 

29.237 170.001 53.752 

_______________________________________ ___________________________ 

6.684 42.318 

____ 

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M I J K L M N O P 

_405 -__- -- 1592 

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468 1592 

409 1592 

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1.0000052595 1439 

1.0000 052895 14:39 

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^=;cE At 9ro7^y f 

06/14/95 12:41Page: 1 

A-0004-1 WHC-SD-WM-DP-j2 REV. 


Analyst: 6. Instrument: ICPO1 Book# '/3.84f-6 

Method: LA-505-151 Rev/Mod ',%S - t 


S Type Sample #R A Test Matrix Group Project 






















t,:2

06/14/95 12:41 WHC-SD-WM-DP - /Î, REV.. 

A-0004-I 


S Type Sample #R A Test Matrix Group# Project 


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Page: 2

Identity 1: ICV Identity 2: Quality Control 1:12 PM July 19, 1995 

,ame : TWC93 

Sa.. ,,te Weight : 1.0000 Solution Vol ume 1.00 


------------------------------------------------------------- - -------- 

ZR 

WHGSD-WM-DP- /3-1, REVS 


( ppm ) (pPm) (Ppm) (Ppm) (pp) (Ppm) (pp) (ppm) 

Mean 4.973 5.033 4.997 4.892 4.962 5.108 4.890 5.074 

S.D. 0.011 0.014 0.020 0.010 0.015 0.008 0.017 - 0.036 

% R.S.D. 0.230 0.287 0.393 0.197 0.307 0.166 0.352 0.709 

2N NI LA FE CA CR ND U 

(Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 5.085 5.010 5.019 5.074 5.212 5.099 5.168 9.730 

S.D. 0.011 0.012 0.012 0.021 0.012 0.007 0.012 0.027 

% R.S.D. 0.207 0.235 0.238 0.422 0.225 0.147 0.241 0.277 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 5.133 5.197 5.032 5.184 5.128 5.082 4.987 5.052 

S.D. 0.005 0.016 0.017 0.137 0.053 0.012 0.020 0.030 

% R.S.D. 0.103 0.308 0.331 2.652 1.027 0.236 0.393 0.599 

MO SE AG PB 11 CD B K 

(Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 5.114 4.993 4.935 5.071 4.930 5.072 5.083 5.076 

S.D. 0.010 0.008 0.008 0.020 0.014 0.017 0.013 0.046 

'.D. 0.189 0.155 0.166 0.397 0.278 0.332 0.258 0.905 

MN SB V BE TL 

(Ppm ) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 5.057 4.647 5.071 5.191 4.888 

S.D. 0.014 0.042 0.010 0.008 0.007 

% R.S.O. 0.277 0.912 0.188 0.148 0.146 

---------------------------------------------------------------------- 

SIGNMR2E BELOW REPRE.SMUS C8@4ICAL MXHNOIrOGIS'P/CHEMIST THAT 

OUIPLEMORUFUM THE CALIBRATION/AMLYSIS as PACES _^3 TO 

423 

oy 

n ^,,: 

/C13î^ÊS 

Sf) 

f^ 

,;S^,îs^ 

La

Identity 1: ICB Identity 2: Quality Control 1:15 PM July 19, 1995 

Task now : TWC93 

Sample Weight : 1.0000 Solution 9oluoe : 1.00 


------------------------ ------- ----------- -------------------- 

--- ----- 

WHGSD-WM-DP-// , REV./ 

ZR SR BI Si AL CO Cu LI 

(ppm) (ppm) (ppn) (ppm) (ppin) (Ppm) (ppm) (ppm) 

Mean 0.002 0.000 -0.000 -0.002 -0.002 -0.003 -0.000 0.000 

S.D. 0.001 0.000 0.010 0.001 0.003 0.003 0.000 0.000 

% R.S.D. 53.978 24.952 4861.090 26.350 154.139 99.588 508.657 51.027 


(Ppm) (PPM) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean -0.000 0.003 0.003 -0.001 -0.002 0.001 -0.009 0.099 

S.D. 0.000 0.002 0.001 0.003 0.000 0.000 0.007 0.023 

% R.S.O. 79.068 62.467 37.021 434.176 4.054 26.818 72.273 23.695 



Mean 0.010 0.026 0.001 0.003 -0.007 -0.000 -0.009 0.002 

S.D. 0.006 0.008 0.000 0.008 0.001 0.000 0.006 0.001 

% R.S.D. 58.542 28.735 10.367 257.804 12.187 50.386 71.148 57.741 


(Ppm) (ppm) (ppM) (Ppm) (pPM) (pprn) (ppm) (Ppm) 

Mean 0.002 -0.056 0.002 0.006 0.000 -0.001 0.000 0.022 

S.D. 0.001 0.012 0.001 0.006 0.000 0.001 0.001 0.013 

% R.S.D. 35.686 21.546 35.671 87.942 25.904 61.143 1009.508 58.823 

MN SB V BE TL 


Mean 0.000 0.008 0.002 0.000 0.064 

S.D. 0.000 0.012 0.001 0.000 0.018 

% R.S.D. 182.187 139.797 47.168 1958.128 28.852 

x ti!.4

Identity 1: ICSA Identity 2: Ouality Contro( 1:17 PM July 19, 1995 

Tao name : TWC93 

S Weight : 1.0000 Solution Volume 1.00 g 

On-.eak Integrations : 3 Off-Peak 


WHGSD-WM-DP- /J ,REV. 

---------------------------------------------------------------------- 

ZR SR BI SI AL CO CO 

(Ppm) (ppm) (Ppm) (ppm) (ppm) (ppFn) (ppFn) 

Mean 0.001 0.000 0.019 0.063 201.372 0.003 -0.013 

S.D. 0.001 0.000 0.006 0.003 0.610 0.000 0.000 

% R.S.D. 136.368 10.752 32.175 5.069 0.303 0.238 3.031 

ZN NI LA FE CA CR ND 

(ppm) (Ppm) (Ppm) (pp) (ppm) (Ppm) (ppm) 

Mean 0.000 -0.043 0.010 147.256 19.367 -0.010 0.008 

S.D. 0.000 0.001 0.001 0.055 0.070 0.000 0.003 

% R.S.D. 3070.685 1.564 6.686 0.038 0.359 4.818 34.641 


(ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.023 0.025 0.004 0.047 0.147 19.156 0.005 

S.D. 0.010 0.011 0.000 0.017 0.002 0.010 0.007 

% R.S.D. 43.485 41.283 5.043 36.568 1.343 0.050 147.420 


(ppm) (ppm) (Ppm) (Ppm) (Ppn) (Ppm) (ppm) 

Mean -0.003 -0.052 -0.000 0.043 0.001 0.011 -0.049 

S.D. 0.001 0.013 0.000 0.032 0.000 0.001 0.001 

% R.S.D. 34.033 26.069 98.017 74.908 30.670 7.261 2.925 

MN S8 V BE TL 

(ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 0.010 0.012 -0.002 0.003 0.048 

S.D. 0.001 0.007 0.001 0.000 0.025 

% R.S.D. 

5.522 58.384 58.594 7.008 

--------------------------------------------------- -------------- ----- 

52.765 

,A Jt 0c..! 

L 

(ppm) 

0.000 

0.000 

95.328 

0 

(Ppm) 

0.138 

0.047 

34.204 

NA 

(Ppm) 

192.826 

K 

1.034 

0.536 

(ppm) 

-0.001 

0.012 

1652.271

Identity 1: ICSAB Identity 2: Quality Control 1:20 PM July 19, 1995 


Sample Weight : 1.0000 Solution 9aluie : 1.00 



WHC-SD-WM-DP- 1-?7, REV. 

---------------------------------------------------------------------- 

2R SR BI SI AL CO Cu LI 

(Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.005 0.001 0.006 0.042 202.042 0.511 0.492 0.962 

S.D. 0.001 0.000 0.005 0.001 0.519 0.004 0.002 0.008 

% R.S.D. 18.387 14.886 82.726 2.164 0.257 0.790 0.344 0.852 


(ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 0.999 0.947 0.007 146.380 19.342 0.498 0.014 -0.024 

S.D. 0.002 0.001 0.002 0.351 0.029 0.000 0.009 0.054 

% R.S.D. 0.214 0.125 28.255 0.240 0.147 0.066 68.786 222.010 


(ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 0.008 -0.022 0.515 0.047 0.145 19.129 -0.006 192.363 

S.D. 0.008 0.011 0.002 0.008 0.002 0.026 0.009 1.529 

% R.S.D. 98.561 47.823 0.334 16.438 1.350 0.135 165.879 0.795 

MO SE AG PB TI CD B • K 

(Ppm) (ppm) (ppm) (Ppm) (Pp) (Ppm) (ppm) (ppm) 

Mean 0.000 0.049 0.752 1.024 -0.000 1.021 -0.049 -0.042 

S.D. 0.002 0.014 0.001 0.023 0.000 0.000 0.001 0.014 

% R.S.D. 560.430 28.679 0.138 2.211 82.974 0.011 2.325 32.733 


(Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 0.517 0.003 0.504 0.510 -0.023 

S.D. 0.001 0.044 0.001 0.001 0.027 

% R.S.D. 0.110 1703.170 0.223 0.179 116.315

Identity 1: PREPBLK Identity 2: Duality Control 1:27 PM July 19, 1995 


e Weight : 1.0000 Solution Vol une 10.00 

0,

Identity 1: S95T001057_L Identity 2: .5525gin250-1-9-1-4 1:34 PM July 19, 1995 





WHC-SD-WM-DP- 7REV. 

------------------------------------------------------- --------------- 

ZR SR BI sl AL CO CO LI 

(ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 21.531 137.895 15849.509 7462.435 2904.712 -100.385 42.710 23.776 

S.D. 25.996 2.443 95.305 49.012 43.528 34.467 3.695 4.358 

% R.S.D. 120.738 1.772 0.601 0.657 1.499 34.335 8.653 18.328 


( ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

"Mean 485.529 6315.088 2.746 11628.705 680.301 643.400 -163.048 1534.185 

S.D. 14.220 87.932 41.339 110.041 4.482 27.039 104.975 539.937 

% R.S.D. 2.929 1.392 1505.457 0.946 0.659 4.203 64.383 35.194 

CE sM BA P S MG AS NA 

(ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 17.427 223.208 23.303 18425.136 7287.146 187.063 -100.884 139451.935 

S.D. 138.968 184.583 2.846 520.950 105.045 4.266 76.667 686.508 

% R.S.D. 797.425 82.696 12.214 2.827 1.442 2.281 75.995 , 0.492 


(ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean -10.168 -442.154 19.673 306.765 8.853 1.694 24.111 5374252.919 

S.D. 7.045 250.452 3.851 156.494 2.100 S.287 18.368 26152.676 

% R.S.D. 69.282 56.644 19.575 51.014 23.724 312.027 76.181 0.487 

MN SB V BE TL 


Mean 52.894 832.842 3.528 2.901 663.351 

S.O. 5.993 96.163 17.412 4.792 365.797 

% R.S.D. 11.330 11.546 493.528 165.190 55.144 

A: ti,

Identity 1: S95TOO1057 Identity 2: .5525gin250-1-9 

Tv • amt : TUC93 

SL Weight : 0.5525 Solution Volume 2500.00 

On-Peak Integrati ons : 3 Off-Peak Integrations : 1 

ZR SR BI 


Mean 22.797 138.469 16380.140 

S.D. 6.655 0.244 93.952 

% R.S.D. 29.193 0.176 0.574 

ZN NI LA 

1:39 PM July 19, 1995 

WHC SD W I-DP- ^°T' 7REV. 

(Ppm ) (ppm) (Ppm) 


Mean 381.306 6334.579 -2.832 1 1841.141 460.218 604.510 15.011 980.299 

S.O. 5.071 23.605 3.070 

72.987 1.634 2.914 40.276 214.488 

% R.S.D. 1.330 0.373 108.407 

CE SM BA 


(Ppm ) (ppm) (Ppm) (ppm) (ppm) 

Mean 11.314 42.583 14.922 1 7705.523 7113.134 183.850 -30.522 132640.573 

S.D. 62.162 65.627 1.242 

% R.S.D. 549.432 154.113 8.321 

NO SE AG 

(Ppm ) (Ppm) (PPm) 

Mean 3.457 -172.908 3.309 

S.D. 8.056 19.915 4.759 

% " S.D. 233.004 11.518 143.828 

MN SB V 


Mean 58.929 233.262 -4.218 

S.D. - 1.209 118.493 7.813 

% R.S.D. 2.051 50.798 185.214 

----------- --- 

51 

AL CO CU L 

(Ppm) (ppm) (ppm) (ppm) (pprn) 

7273.012 3100.843 19.224 31.921 19.592 

36.633 28.452 6.892 1.132 0.917 

0.504 0.918 35.850 3.546 4.683 

FE CA CR NO U 

0.616 0.355 0.482 268.309 21.880 

P S MG AS NA 

590.728 127.981 0.733 14.714 1391.625 

3.336 1.799 0.399 48.207 1.049 

PB it CD 8 K 

( Ppm ) (ppm) (Ppm) (Ppm) (pp) 

107.363 9.120 3.065 42.313 5054810.830 

14.259 2.100 3.675 1.626 43100.562 

13.282 23.031 119.893 3.843 0.853 

BE 

1L 

( ppm ) (ppm) 

0.092 67.831 

0.846 

151.678 

923.375 223.612 

^°x0w

Identity 1: S95TOO1057_D Identity 2: .5615g(n250-1-9 1 :42 PM July 19, 1995 




_______________________ _________________________ ______ 

2R SR BI SI 

( ppM ) (ppm) (ppm) (PPM) 

Mean 17.022 133.046 15617.939 7124.395 

S.D. 1.896 0.418 28.858 10.591 

% R.S.D. 11.141 0.314 0.185 0.149 

2N NI LA FE 

( Pan ) (Ppm) (PPM) (Ppm) 

Mean 256.661 5880.395 6.146 11804.985 

S.D. 2.942 27.838 5.320 65.776 

% R.S.D. 1.146 0.473 86.558 0.557 

CE SM BA P 

(Ppm) (ppm) (Ppm) (PPm) 

Mean 41.565 82.287 14.536 18241.016 

S.D. 31.744 31.203 0.311 819.874 

% R.S.D. 76.371 37.920 2.138 4.495 

MO SE AG PB 

( Pan ) (ppm) (Pan) (Pan) 

Mean 2.401 -161.708 7.590 92.850 

S.D. 1.250 36.273 1.365 43.248 

% R.S.D. 52.042 22.431 17.977 46.578 

MN SB V BE 

(PPM ) (ppm) (Pan) (Ppm) 

New 65.478 20.581 3.562 -0.441 

S.D. 1.362 113.468 1.094 0.465 

% R.S.D. 

2.080 551.334 

30.707 105.531 

________________________-___-_ __-___________--___-____..____- 

WHC-SD-WM-DP- 

REV_,/- 

AL CO Cu L 

(ppm) (Ppm) (Pp) (Ppm) 

3069.976 15.010 37.489 18.716 

12.345. 6.777 1.403 0.324 

0.402 45.149 3.743 1.732 

CA CR NO u 

(Ppm) (ppm) (Ppm) (Ppu) 

353.322 602.383 -8.583 1089.654 

0.333 7.451 2.927 97.839 

0.094 1.237 34.098 8.979 

S MG AS NA 

(Ppm) (PpR) (Pan) (ppm) 

7489.836 177.517 -50.831 128122.830 

172.470 0.422 0.142 524.424 

2.303 0.238 0.279 0.409 

TI CD 8 K 

(ppm) (ppm) (ppn) (Ppm) 

15.129 1.951 51.669 4882162.659 

0.715 2.090 2.239 12069.565 

4.726 107.166 4.334 0.247 

TL 

(ppm) 

160.298 

17.702 

11.043 

^^%3

Identity 1: S957001057 A Identity 2: .5525gin250-1-2-7 1:46 PM July 19, 1995 

T p - D name : TWC93 

On-eeak 

Weight : 0.5525 Solution Vol we 2500.00 WHC-SD-WM-DP- X3 7, REV. , /- 

Integrations : 3 Off-Peak 


-------------------------------- ------------------- ------------------- 

ZR SR BI SI AL 

(PPm ) (Ppm) (Ppm) (PPM) (Ppm) 

Mean 4613.098 4764.960 20893.859 11470.918 7635.073 

S.D. 4.852 16.362 117.243 19.490 24.975 

% R.S.D. 0.105 0.343 0.561 0.170 0.327 


(PPM ) (PPM) (PPM) (PPM) (Ppm) 

Mean 4655.481 10881.424 4643.087 16358.632 5087.047 

S.D. 5.250 24.429 16.117 55.264 18.123 

% R.S.D. 0.113 0.224 0.347 0.338 0.356 

CE SM BA P S 

(Pam ) (ppm) (PPM) (PPM) (Ppm) 

Mean 4721.730 4719.412 4612.894 23294.738 11842.860 

S.D. 33.069 29.619 18.671 760.032 219.895 

X R.S.D. 0.700 0.628 0.405 3.263 1.857 


( Ppm ) (Ppm) (Ppm) (Ppm) (PPM) 

Mean 4673.793 4279.712 2989.164 4773.278 4542.926 

S.D. 14.973 27.019 0.815 92.031 4.754 

X R.S.D. 0.320 0.631 0.027 1.928 .0.105 

MN S8 9 BE TL 

(Ppm ) (Ppm) (ppm) (ppm) (Ppm) 

Mean 4680.770 3965.492 4671.797 4515.776 4501.898 

S.D. 9.146 124.943 7.375 5.636 73.026 

% R.S.D. 0.195 3.151 0.158 0.125 1.622 

1 

4x.31 

CO C0 L 

(PPM') (ppm) (ppm) 

4683.618 4517.116 4247.124 

20.706 23.545 32.924 

0.442 0.521 0.775 

CN NO u 


5312.970 4625.983 9614.551 

4.019 28.433 182.989 

0.076 0.615 1.903 

MG AS NA 


4773.079 4550.737 136026.461 

4.844 24.382 926.367 

0.101 0.536 0.681 

CD B • K 

( Ppm ) (Ppm) (pPM) 

4603.762 4469.828 4983348.823 

9.181 21.042 29669.515 

0.199 0.471 0.595

Identity 1: CCV Identity 2: Quality Control 1:53 PM July 19, 1995 




....................................... .............. ............. .... 

WHGSD-WM-DP-^^ REV1, 

2R SR BI SI AL CO Cu 

(Ppm ) (Ppm) (Ppm) (Ppm) (ppm) (ppn) (ppm) 

Mean 5.033 5.138 5.044 4.870 4.999 5.055 5.024 

S.D. 0.014 0.017 0.013 0.005 0.006 0.010 0.027 

% R.S.D. 0.283 0.339 0.256 0.097 0.120 0.188 0.543 

2N NI LA EE CA CR NO 

( ppm ) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 4.985 4.991 5.121 5.087 5.312 5.025 5.409 

S.D. 0.003 0.009 0.025 0.026 0.019 0.001 0.038 

% R.S.D. 0.054 0.174 0.481 0.502 0.359 0.027 0.706 


(ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 5.224 5.448 5.169 4.984 4.973 5.016 4.992 

S.D. 0.004 0.026 0.022 0.164 0.059 0.006 0.007 

% R.S.D. 0.076 0.469 0.433 3.294 1.181 0.129 0.136 

MO SE AG PB 

IT 

CD e 

(Ppm ) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 5.072 5.009 4.868 5.011 4.973 5.042 5.138 

S.D. 0.016 0.029 0.009 0.028 0.010 0.008 0.016 

% R.S.D. 0.312 0.570 0.182 0.549 0.210 0.160 0.316 

MN SB V BE TL 

(Ppm ) (ppm) (ppm) (ppm) (ppm) 

Keen 5.025 4.817 5.071 5.262 4.952 

S.D. 0.015 0.056 0.010 0.010 0.016 

% R.S.D. 0.307 1.160 0.195 0.183 0.319 

i 

r. ^.. 

L 

(ppm) 

5.220 

u 

0.043 

0.821 

(ppm) 

10.219 

0.057 

0.558 

NA 

(ppm) 

5.196 

K 

0.032 

0.624 

(ppm) 

5.306 

0.039 

0.731

Identity 1: CCB Identity 2: Quality Control 1:57 PM July 19, 1995 

Te-k name : TWC93 

e Weight : 1.0000 solution volute 1.00 

On- p eak Integrations : 3 


----------------------------------------- ----------------------------- 

1 

WHGSD- SD-DP- DP / REV. 

ZR SR BI SI AL CO CO 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.000 0.000 0.002 -0.004 -0.012 0.001 0.001 

S.D. 0.000 0.000 0.009 0.003 0.004 0.003 0.000 

% R.S.O. 124.329 11.543 536.155 86.911 35.105 350.571 24.479 


( Ppm) (PPM) (Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean -0.000 0.005 0.002 0.001 -0.002 0.001 -0.001 

S.D. 0.000 0.001 0.001 0.002 0.000 0.000 0.004 

% R.S.D. 157.931 22.258 43.159 310.577 2.221 26.029 281.418 


(Ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.007 0.025 0.001 0.006 -0.011 -0.000 -0.009 

S.D. 0.005 0.005 0.000 0.012 0.004 0.000 0.005 

% R.S.D. 69.053 18.040 12.310 192.010 34.654 50.430 62.012 


(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.001 -0.061 0.001 0.010 -0.000 -0.000 0.001 

S.D. 0.001 0.002 0.000 0.003 0.000 0.000 0.001 

% R.S.D. 105.882 3.263 28.198 35.571 160.437 91.867 51.603 

MN SB v BE TL 

(ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean -0.000 -0.019 0.000 0.000 0.050 

S.D. 0.000 0.013 0.000 0.000 0.009 

% R.S.D. 164.588 67.286 41.220 34.678 17.663 

5:3:; 

L 

(ppt) 

U 

(ppm) 

0.001 

0.000 

7.763 

0.073 

0.025 

34.678 

NA 

(ppm) 

• K 

(ppm) 

0.024 

0.000 

0.000 

0.082 

0.012 

14.124

Identity 1: 595T001063_L Identity 2: .54059in250-1-9-1-4 2:00 PM July 19, 1995 


Sanple Weight : 0.5405 solution volume : 12500.00 

On-Peak integrations : 3 Off-Peak Integrations : 

1 

WHC-SD-WM-DP /fZ , REV. 

- -------------------------- ------------- ------- ----------------- ------ 

2R 

SR III SI AL CO Cu LI 

(ppm) (ppm) (ppm) (pp,n) (ppm) (ppm) (ppm) (ppm) 

Mean 43.560 164.791 16219.971 8665.366 3426.604 -1.087 38.686 15.061 

S.D. 21.367 1.242 70.234 81.325 118.368 61.036 6.715 4.373 

% R.S.D. 49.052 0.754 0.433 0.939 3.454 5612.888 17.357 29.037 


(ppm) (ppm) (ppm) (ppm) (ppn) (ppm) (ppm) (PPS) 

Mean 306.636 7100.404 49.944 14179.861 482.934 683.363 -286.189 3402.797 

S.D. 5.607 224.641 27.922 143.062 2.291 54.243 269.037 789.402 

% R.S.D. 1.829 3.164 55.906 1.009 0.474 7.499 94.007 23.199 



Mean -138.779 654.094 31.273 21582.525 8062.454 190.004 32.235 136966.109 

S.D. 206.373 231.266 2.954 337.192 63.794 2.197 58.184 460.193 

% R.S.D. 148.706 35.357 9.445 1.562 0.791 1.156 180.502 0.336 


(ppm) (ppm) (ppm) (ppm) (ppm) (PPm) (ppm) (ppm) 

Mean 15.591 -852.266 49.425 231.840 46.843 10.419 128.166 5134637.815 

S.D. 20.762 80.170 12.399 185.548 8.644 3.129 19.933 12590.762 

% R.S.D. 133.167 9.407 25.087 80.033 18.453 30.030 15.553 0.245 

MN SB V BE TL 


Mean 84.542 394.004 15.995 7.365 1440.462 

S.D. 0.053 324.615 14.603 2.370 317.478 

% R.S.D. 0.063 82.389 91.297 32.185 22.040 

7 

X134

Identity 1: S95TOO1063 Identity 2: .5405gin250-1-9 2:04 PM July 19, 1995 

Tr y name : TNC93 

Weight : 0.5405 Solution Vol me 2500.00 

On-reak Integrations : 3 Off-Peak Integrations : 1 

WHC-SD-WM-DP- 

REV. 


(Ppm ) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 4.270 163.953 17184.018 8289.583 3634.489 23.644 31.411 10.692 

S.D. 8.410 0.249 113.340 15.791 19.023 12.219 0.441 1.378 

% R.S.D. 196.946 0.152 0.660 0.190 0.523 51.677 1.404 12.886 

2N N) LA FE CA CR ND u 

(PPM ) (Ppm) (PPR) (PPO) (Ppm) (PPM) (Ppm) (Ppm) 

Mean 313.712 7142.015 -17.125 14431.617 521.829 699.594 -11.011 1150.922 

S.O. 2.192 103.097 8.400 35.430 1.510 9.261 32.322 261.859 

% R.S.D. 0.699 1.444 49.052 0.246 0.289 1.324 293.537 22.752 


(Ppm ) (PPM) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 42.721 -17.131 17.136 21202.040 8133.847 206.802 -38.568 131020.396 

S.D. 51.917 59.319 1.071 379.434 74.043 1.303 3.130 1267.597 

% R.S.D. 121.526 346.264 6.251 1.790 0.910 0.630 8.116 0.967 

NO SE AG PB TI CD B K 

(PPR ) (Ppm) (Ppm) (PPM) (PPM) (PPM) (ppm) (ppm) 

Mean -3.326 -154.763 1.902 212.695 24.242 3.124 40.388 4811789.295 

S.D. 1.905 14.333 5.230 16.229 1.039 1.656 4.427 30625.778 

% R.S.D. 57.282 9.261 274.948 7.630 4.284 53.021 10.960 0.636 

MN SB V BE TL 

(PPM ) (Ppm) (PPM) (Pp") (Ppm) 

Mean 82.573 147.211 1.329 -0.174 -70.706 

S.D. 0.704 156.960 3.616 0.512 77.062 

% R.S.D. 0.853 106.622 272.070 294.098 108.990 

`L 3J

Identity 1: S95TOO1063_D Identity 2: .5407gin250-1-9 2:09 PN July 19, 1995 


saWte Weight 0.5407 Solution Volume 2500.00 WHC-SD-WM- DP. ^^^, REV. 


----- - ------------------------------ 

Off-Peak 

- --------------------------------- 



(PPm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 27.171 38.299 3919.770 3082.747 1882.165 12.002 26.102 16.231 

S.D. 1.681 0.249 32.742 16.325 22.206 0.009 0.977 0.891 

% R.S.D. 6.188 0.651 0.835 0.530 1.180 0.075 3.742 5.488 


(Ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 199.856 1974.765 9.070 8741.307 221.188 22.022 -21.209 261.955 

S.D. 1.886 54.146 8.456 45.070 0.458 2.164 23.115 94,356 

% R.S.D. 0.944 2.742 93.228 0.516 0.207 9.828 108.987 36.020 


(Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 79.745 50.659 5.504 593.960 311.701 82.736 -19.097 4065.964 

S.D. 19.370 10.310 0.552 78.339 14.930 0.437 12.582 46.002 

% R.S.D. 24.290 20.351 10.027 13.189 4.790 0.529 65.883 0 1.131 

NO SE AG PIT TI CD B K 

(Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 4.364 -425.737 2.049 118.258 11.546 4.741 -0.211 125663.079 

S.D. 4.008 49.074 1.133 33.008 0.446 2.159 7.191 1480.036 

% R.S.D. 91.844 11.527 55.287 27.912 3.865 45.542 3404.224 1.178 


(Ppm) (Ppm) (Ppm) (ppm) (pPn) 

Mean 15.028 382.095 -4.976 0.306 95.958 

S.D. 1.232 89.017 0.818 0.481 35.723 

% R.S.D. 8.201 23.297 16.435 157.047 37.228

Identity 1: S95TOO1063_A Identity 2: .5405gin250-1-2-7 2:13 PM July 19, 1995 

Task nine : TWC93 

WM-DP-I 

Weight : 0.5405 

Or, . eak Integrations : 3 

Solution Volume 2500.00 


--- I ------------------------------------ 

WHC-SD- 7, REV_ 

............................. 


( ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 4699.484 4906.456 21581.426 12420.676 8238.670 4730.467 4650.868 4401.410 

S.D. 4.668 16.494 46.683 8.031 44.290 28.189 25.667 42.178 

% R.S.D. 0.099 0.336 0.216 0.065 0.538 0.596 0.552 0.958 

ZN NI LA FE CA CR NO u 

(PPM ) (PPM) (Ppm) (ppm) (PPM) (Ppm) (Ppm) (ppm) 

Mean 4736.875 11490.598 4750.477 18838.280 5401.761 5419.260 4796.321 10429.333 

S.D. 3.980 49.016 22.878 46.334 18.238 23.027 26.606 258.543 

% R.S.D. 0.084 0.427 0.482 0.246 0.338 0.425 0.555 2.479 


(ppm) (PPM) (PPM) (ppm) (ppm) (PPM) (PPM) (ppm) 

Mean 4900.473 4875.744 4747.787 25247.212 12567.874 4861.456 4645.695 135669.355 

S.D. 70.702 61.101 19.421 1310.935 274.645 9.381 32.244 1169.710 

% R.S.D. 1.443 1.253 0.409 5.192 2.185 0.193 0.694 0.862 


(PPM) (PPM) (PPM) (PPM) (PPM) (ppm) (ppm) (PPM) 

Mean 4733.487 4593.078 2954.519 4803.232 4653.593 4667.369 4582.942 4803935.914 

S.D. 13.381 43.445 13.442 9.073 7.280 20.125 18.269 35003.185 

% R.S.D. 0.283 0.946 0.455 0.189 0.156 0.431 0.399 0.729 

MN SB V BE TL 

(PPM ) (PPM) (PPM) (PPM) (PPM) 

Mean 4794.286 4128.890 4759.023 4633.566 4635.437 

S.O. 11.175 88.267 2.537 7.982 165.477 

% R.S.D. 

0.233 2.138 0.053 

-------------------------------------- 

0.172 3.570 

---------------------------.... 

43

Identity 1: ICSA Identity 2: Quality Control 2:20 PM July 19, 1995 

Task name : TVC93 

Sample weight : 1.0000 Solution voluse : 1.00 WHC-SD-WM-DP- REV. 



1 

------------- - ------------------------------ -------- --------------- --- 



Mean 0.001 0.001 0.011 0.061 203.830 0.005 -0.014 0.000 

S.D. 0.000 0.000 0.006 0.004 0.136 0.000 0.000 0.000 

% R.S.D. 44.709 17.679 56.058 5.775 0.067 0.069 0.947 225.851 

2N NI LA FE CA CR ND 0 

(Ppm) (PPM) (Ppm) (Ppm) (ppm) (Ppm) (ppM) (ppm) 

Mean 0.000 -0.045 0.010 148.107 19.366 -0.010 0.006 0.105 

S.D. 0.000 0.003 0.001 0.183 0.058 0.002 0.006 0.026 

% R.S.D. 236.508 5.635 11.431 0.124 0.298 16.681 101.054 24.959 

CE SIR SA P S MG AS NA 

(ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.008 0.017 0.004 0.038 0.141 19.470 -0.009 192.177 

S.D. 0.004 0.005 0.000 0.010 0.004 0.032 0.003 0.706 

% R.S.D. 49.014 30.073 1.287 26.762 2.830 0.165 34.668 0.367 


(ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (pp) 

Mean -0.003 -0.030 -0.001 0.020 0.001 0.010 -0.047 0.105 

S.D. 0.000 0.009 0.000 0.020 0.000 0.000 0.001 0.014 

% R.S.D. 18.333 29.316 80.992 99.844 21.966 1.104 1.455 13.777 

MN SB v BE TL 

(Ppm ) (ppm) (ppm) (ppm) (Pena) 

Mean 0.010 -0.018 -0.004 0.002 0.023 

S.D. 0.000 0.025 0.000 0.000 0.011 

% R.S.D. 1.671 134.865 5.405 0.112 49.706 

A133

Identity 1: ICSAB Identity 2: Duality Control 2:24 PM July 19, 1995 

Task name : TNC93 

F 

0. 

, Weight : 1.0000 

ak Integrations : 3 

Solution Volune : 


1.00 

1 

WHC-SD-WM-DP-/_Z, REV 

---------------------------------------- ------------------- ----------- 


(Ppm ) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.004 0.001 -0.013 0.046 203.943 0.516 0.488 0.951 

S.D. 0.000 0.000 0.004 0.004 0.427 0.002 0.000 0.001 

It R.S.D. 9.806 12.998 28.366 8.638 0.210 0.295 0.083 0.097 


(PPm ) (ppm) (ppm) (Ppm) (pPm) (Ppm) (ppm) (Ppm) 

Mean 1.022 0.962 0.005 148.344 19.331 0.503 0.010 0.020 

S.D. 0.001 0.002 0.002 0.206 0.016 0.002 0.005 0.028 

% R.S.D. 0.131 0.180 37.255 0.139 0.084 0.444 49.535 139.603 

CE SN BA P S MG AS NA 

(Ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.006 -0.006 0.512 0.032 0.147 19.478 -0.006 190.793 

S.D. 0.005 0.006 0.000 0.014 0.011 0.025 0.001 0.261 

% R.S.D. 77.520 112.555 0.082 43.126 7.521 0.127 16.049 0.137 

NO SE AG PB TI CD 8 K 

( ppm) (Ppm) (Ppm) (Ppm) (PPm) (ppm) (ppm) (Ppm) 

Mean -0.003 0.027 0.726 1.042 -0.000 1.035 -0.049 0.082 

S.D. 0.001 0.017 0.001 0.020 0.000 0.002 0.001 0.009 

% R.S.D. 42.402 62.244 0.137 1.906 76.203 0.193 1.705 11.355 

MN 58 V 8E TL 

(Ppm) (ppm) (Ppm) (Ppm) (ppm) 

Mean 0.523 0.030 0.510 0.514 -0.023 

S.D. 0.001 0.027 0.001 0.000 0.011 

% R.S.D. 0.127 89.215 0.282 0.036 50.459 

43J

Identity 1: CCV_I Identity 2: CCV_1 2:28 PM July 19, 1995 




------------------------------------------ ---------------------- --" 

2R SR of 

SI 

" 

WHC-SD-WWDP- / `7 REV•.L 

AL CO CU LI 

( ppm ) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 5.022 5.079 5.033 4.927 5.021 5.159 4.927 5.059 

S.D. 0.008 0.011 0.016 0.003 0.006 0.002 0.014 0.033 

% R.S.D. 0.159 0.220 0.315 0.061 0.115 0.030 0.278 0.645 

2N NI LA FE CA CR NO U 

(ppm) (ppn) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 5.125 5.067 5.081 5.153 5.261 5.147 5.285 9.824 

S.D. 0.005 0.009 0.004 0.021 0.011 0.016 0.040 0.028 

% R.S.D. 0.106 0.176 0.083 0.402 0.210 0.308 0.762 0.281 


(ppm) (ppm) (Ppm) (ppm) (ppm) (ppin) (ppm) (ppm) 

Mean 5.173 5.324 5.077 5.114 5.139 5.132 5.015 5.080 

S.D. 0.007 0.006 0.013 0.057 0.037 0.003 0.018 0.025 

% R.S.D. 0.142 0.109 0.261 1.112 0.714 0.064 0.360 0.488 

MO SE AG P8 TI CD 8 K 

(Ppm) (ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 5.161 5.011 4.975 5.098 4.972 5.122 5.144 5.151 

S.D. 0.006 0.035 0.005 0.039 0.009 0.008 0.011 0.020 

% R.S.D. 0.124 0.692 0.103 0.757 0.174 0.149 0.215 0.391 

MN SB V BE TL 

(ppm) (ppm) (ppm) IDIOM) (ppm) 

Mean 5.106 4.752 5.117 5.249 4.896 

S.D. 0.013 0.064 0.009 0.011 0.018 

% R.S.D. 0.253 1.351 0.171 0.204 0.365 

440

Identity 1: CCB_1 Identity 2: CCB_1 2:33 PM July 19, 1995 

To,' name : TWC93 WHC-SD-WM-DP /,; , REV. 

S Weight : 1.0000 Solution Volume 1.00 

Dn-Peak Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

2R 

SR BI SI AL CO CO LI 

(ppm) (ppm) (ppM) (ppm) (ppm) (ppn) (Ppm) (ppm) 

Mean - 0.001 0.000 0.004 0.002 -0.004 -0.003 0.000 0.000 

S.D. 0.002 0.000 0.005 0.002 0.002 0.000 0.000 0.000 

% R.S.D. 142.498 359.114 139.087 145.320 54.879 0.373 152.983 455.497 

ZN NI LA FE CA CR NO 0 

(ppm) (PPM) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean -0.000 0.008 0.004 -0.001 -0.002 0.000 -0.006 0.105 

S.D. 0.000 0.001 0.001 0.001 0.000 0.001 0.008 0.076 

% R.S.D. 167.340 15.348 27.193 56.924 2.192 227.932 130.249 71.859 


( ppm ) (ppm) (ppm) (Ppm) (PPM) (ppm) (Ppm) (Ppm) 

Mean 0.004 0.036 0.001 0.025 -0.004 -0.000 0.003 0.026 

S.D. 0.014 0.020 0.000 0.005 0.006 0.000 0.003 0.004 

% R.S.D. 357.274 55.721 45.867 19.516 145.806 24.437 85.985 15.789 



Mean 0.002 -0.058 0.003 0.023 0.001 0.001 0.002 0.113 

S.D. 0.000 0.010 0.001 0.007 0.000 0.000 0.001 0.025 

% R.S.D. 25.697 16.850 23.571 29.745 68.884 37.437 25.879 22.331 

MN SB V BE TL 

(ppm) (ppm) (ppm) (ppm) (ppM) 

Mean -0.000 0.034 0.001 -0.000 0.083 

S.D. 0.000 0.032 0.001 0.000 0.023 

% R.S.D. 5162.392 94.234 83.839 42.199 28.089 

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O6 1405 12:49 WHC-SD-WM-DP- 

_L^j_, REV. Page: 1 

A-0004-I 


Analyst: 

JU 7-11-YT 

50.70 Instrument: I PO$-t Book# Y" Y" " 

Method: LA-505-15+h / Rev/Mod (Z-t 







5 PREPBLKTJA @ICP-F03 SOLID 




8 SPK S95TOO1064 0 F @ICP-F03 SOLID 













4: G

06/14/95 12 : 49 WHC-SD-WM-DP-^, REV. Page: 

A-0004-1 


Type Sample#R A Test Matrix Group# Project 



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S = Worklist Slot Number, R Replicate Number, A = Aliquot Code. 

,0 

2

aitai^-s is Report Summary Mon 07-17-95 02:19:33 PM page 1 

41 Sample Name 

--- -------------------- 

1 ICI' 

7 ICE 

3 ICSA 

4 ICSAB 

5 ICSAB 

6 ICSAB 

7 PREPBLKTJA 

8 S95T001064 L 

9 S95T001064- 

10 S95T001064 D 

11 S95T0O1064—A 

12 CCV 

13 CCB 

14 S95T001071 L 

15 S95T001071 - 

16 S95 7'001071 D 

17 S95T001071—A 

18 ICSA 

14 ICSAB 

20 CCV 1 

21 CCiTl 

22 CCB-1 

File 

-------- 

950717B 

950717B 

950717B 

950717B 

950717B 

950717B 

950717B 

950717B 

9507178 

950717B 

950717B 

950717B 

950717B 

950717B 

950717B 

950717B 

9507178 

950717B 

950717E 

950717B 

950717B 

950717B 

Method Date Time OpID 

-------- --------- ----- ---- 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

,x ^,w 

or-/1-Ys 

07717/95 

07/17/95 

07/17/95 

07/17195 

07/17/95 

07%17%95 

07117195 

07/17%95 

07/17/95 

07717/95 

07/17/95 

07 17195 

07%17%95 

07117195 

07/17%95 

071,17195 

071795 

07/17795 

b- 16 Y Ie7OO/W 

5Z! ivc) 1471 

GVIOrkllf7* /S? f 

12:07 DKS 

12:13 DKS 

12:17 DKS 

12:20 DKS 

12:37 DKS 

12:43 DKS 

12:48 DKS 

12:52 DKS 

12:57 DKS 

13:01 DKS 

13:07 DKS 

13:20 DKS 

13:25 DKS 

13:29 DKS 

13:33 DKS 

13:37 DKS 

13:46 DKS 

13:53 DKS 

13:56 DKS 

14:02 DKS 

14:11 DKS 

14:15 DKS 

r r - :• • :^• • o-. a t. «4o- â«a • • aas ^: 

4 'Sj 

Type 

---- 

Mode 

----- 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

Î 

2 

a 2 

N LJS

Anal y sis Report Averages Mon 07-17-95 02:19:33 PM page 2 

Sample Name 

-------------------- 

Ag 

-------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

T(IV 4.879 4.912 5.069 4.863 4.946 5.131 

c',9 -.0033 -.0019 .0048 .0057 .0000 .0002 

3 ICSA 0031 245.2 -.0226 0053 .0018 .0002 

Q.3417 247.3 -.0258 .0024 .4892 .4790 

5 ICSAB .9410 Q-.0018 -.0074 -.0005 .4911 .5047 > 

6 ICSAB .8508 248.6 -.0281 -.0022 .4364 .4559 W 

7 PPEPBLKTJA -.0372 .0611 .1328 .0093 .0128 .0013 Q 

8 S95TOO1064 L -101.3 2615. -165.0 27.59 12.30 4.356 ^) 

9 S=001064- -14.38 2602. -2.830 29.29 13.25 .5103 

IO S95TOO1064 D -10.70 5261. -39.61 56.75 19.15 2663 

11 S95TOO1064-A 40I3. 7094. 4762. 4361. 4249. 4611. 

12 CCV - 4.894 4.853 5.073 4.814 4.858 5.117 a 

13 CCB -.0020 -.0049 .0046 0052 0001 0001 p 

14 S95TOO1071 L -66.99 2005. 15.16 88.21 16.45 2.741 

15 S95T001071 - -14.69 2093. -45.53 45.34 16.64 .3116 

3 

16 S95TOO1071 D -18.91 1920. 26.16 28.39 13.89 3442 

17 S95TOO1071 -A 3997. 6425. 5074. 4540. 4283. 4829. 

18 ICSA - 0033 245.1 .0238 .0004 .0017 .0002 

C.1 

19 ICSAB 9231 246.4 0678 0025 4594 5008 = 

1 0 CC1 71 5.051 4.912 5.294 4.937 4.897 5.313 

21 CCI 7- 1 5.053 4.959 5.361 4.982 4.998 5.343 

22 CCB-1 -.0037 -.0145 -.0014 .0076 -.0001 .0001 

$ 

--- 

Sample Name 

Bi 

-------------- ------ -------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

1 ICV 4.963 5.045 5.025 5.039 5.051 5.061 

2 ICB -.0139 -.0078 .0009 -.0008 .0019 0011 

3 ICSA -.0012 238.5 .0025 .0150 .0026 .0053 

4 ICSAB .0187 259.0 .9428 .0035 .4644 .4782 

5 ICSAB .0160 Q-.0012 1.033 0074 .5131 .5129 

6 ICSAB -.0001 244.3 .8930 .0119 .4363 .4525 

7 PPEPBLKTJA -.0478 .0747 .0026 .0030 .0029 -.0040 

S ) 5i'001064 L 13650. 301.6 -31.17 -83.19 -4.711 562.2 

S95T001064 - 13630. 324.8 -.3057 44.01 22.52 574.5 

10 S95T001064 D 18290. 506.2 2.944 50.89 42.05 1002. 

11 S95T001064-A 18170. 5076. 4673. 4466. 4658. 5252. 

12 CGV - 4.992 5.159 5.055 4.969 5.067 5.100 

13 CCB -.0061 -.0040 .0009 .0028 .0017 .0001 

1a S95TOO1071 L 14680. 317.2 12.51 21.15 43.88 608.1 

15 3 ?5T001071 - 14470. 412.0 7.425 106.9 11.96 616.6 

16 S95TO01071 D 12730. 279.2 1616 -17.80 17.19 538.5 

17 S95TOO1071 -A 18980. 5547. 5077. 4459. 5018. 5688. 

18 ICSA - .0092 262.5 0017 .0151 .0007 .0051 

19 ICSAB 0149 264.0 1.017 0172 4987 5118 

20 CCV 1 5.073 Q5.549 5.382 5.035 5.353 5.387 

21 CCV- 1 5.149 5.124 5.379 5.106 5.360 5.389 

22 CCB-1 -.0293 -.0056 -.0005 -.0058 -.0011 -.0024 

144/9

Analysis Report Averages Mon 07-17-95 02:I9:33 PM page 3 

# 

--- 

Sample Name 

-------------------- Cu 

-------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

1 ICV 4.910 .0075 5.033 4.577 4.993 4.768 

2 ICB -.0001 .0022 -.0025 -.3353 -.0002 .0019 

3 ICSA -.0104 -.0102 91.62 -.0755 -.0034 .0044 

4 ICSAB .4751 0253 93.10 .4785 -.0045 .9342 

5 ICSu .5033 .0018 Q-.0016 0885 -.0012 .9426 

6 ICSAB .4478 -.0170 93.40 .0614 -.0033 .8748 

7 PREPBLKTJA .0117 .0444 .0283 10810. -.0045 .0345 

8 S95T001064 L 17.66 68.14 14080. 5094e3 -24.52 63.17 

9 S95T001064 - 23.58 22.10 13740. 4767e3 -.1142 20.79 

10 S95T001064 D 41.43 23.12 24240. 5075e3 1.807 27.33 

11 S95T001064 -A 4362. 25.05 18400. 4837e3 4375. 4047. 

17 CCV - 4.817 .0084 5.058 Q4.384 4.924 4.612 

13 CCB -.0007 .0039 -.0014 -.0939 .0001 .0034 

14 S95T001071 L 12.13 109.8 13780. 5951e3 1.577 96.32 

15 S95T001071 - 8.915 32.80 13620. 5876e3 10.44 35.02 

16 S95T001071 D 18.53 32.11 12230. 5423e3 -5.961 35.09 

17 S95T001071 -A 4315. 45.24 18580. 5551e3 4396. 3867. 

18 ICSA - -.0113 -.0523 96.88 -.1251 -.0038 .0072 

19 ICSAB 4663 -.0501 97.38 -.0627 -.0037 .8785 

20 CCV 1 4.834 .0112 5.277 Q4.493 4.972 Q4.498 

21 CCI'- 1 4.903 .0108 5.305 4.893 5.026 5.137 

22 CCB- 1 -.0016 .0052 -.0026 -.2422 -.0011 .0047 

# 

--- 

Sample Name 

Mg 

-------------- ------ -------- 

Mn 

-------- 

MO 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

1 ICV 4.903 4.911 5.021 4.956 5.149 4.981 

2 ICB -.0137 .0008 -.0007 .0165 -.0023 -.0046 

3 ICSA 247.1 -.0051 -.0104 192.0 .0004 -.0152 

4 ICSAB 252.1 Q.6091 -.0068 193.2 -.0038 .8975 

5 ICSAB Q.0018 .4894 -.0011 199.0 .0020 1.014 

6 ICSAB 250.9 .4211 -.0111 183.6 .0007 .8558 

7 PREPBLKTJA -.0370 .0212 -.0097 4.397 -.0321 .2803 

8 S95T001064 L -7.907 94.25 -19.12 131900. -37.97 5721. 

9 S95T001064- 167.0 77.72 -6.900 122400. 4.835 5933. 

10 S95T001064 D 273.5 165.1 -8.545 259500. 8.684 16940. 

11 S95T001064 -A 4490. 4495. 4662. 129200. 4469. 10450. 

12 CCV - 4.859 4.930 5.041 4.852 5.060 5.032 

13 CCB -.0092 .0014 -.0026 .0309 -.0017 -.0060 

14 S95T001071 L 171.3 105.2 -36.89 123100. -11.28 6385. 

15 S95T001071 - 136.2 79.88 -22.74 115500. -2.481 6407. 

16 S95T001071 D 132.3 74.42 -8.730 117700. 4.929 4792. 

17 S957'001071 -A 4656. 4821. 5010. 116800. 4492. 11520. 

18 ICSA - 250.5 -.0035 -.0102 184.0 -.0046 -.0299 

19 ICSAB 251.7 .4753 -.0104 187.2 -.0022 .9649 

20 CCI' 1 4.943 5.176 5.309 4.795 5.067 5.291 

21 CCV- 1 5.010 5.212 5.299 4.866 5.125 5.298 

22 CCB-1 -.0278 .0018 -.0006 .0412 -.0046 -.0072 

A,- 

&X J 

.I 

Q 

\I 

2 

O 

3 

U

Analysis Report Averages Mon 07-17-95 02:19:33 PM page 4 

# 

--- 

Sample Name 

P 

-------------- ------ -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 lCV 5.118 4.981 4.947 4.690 4.991 4.725 

2 ICB .0214 .0092 -.0052 -.0023 .0438 .0128 

3 ICSA 0132 .0425 -.0247 -.0034 .0263 .0271 

4 ICSAB .0222 .9942 5.654 -.0138 .0180 .5983 

5 ICSAB .0218 1.025 -.0111 -.0110 7336 .0077 

6 ICSAB .0068 .9342 -.0372 -.0121 .0544 .0062 

7 PPEPBLKTJA .3626 .2999 .0185 -.0170 .6830 .3714 

8 S95T001064 L 19130. 252.3 8030. -348.0 932.5 6328. 

9 S95T001064- 18710. 221.0 7861. -41.39 -57.34 6064. 

10 S95T001064 D 37060. 399.7 17150. -49.57 -642.5 10900. 

11 S95T001064 -A 24100. 4828. 12660. 4413. 4520. 10520. 

12 CCV - 5.005 5.063 4.963 4.708 5.016 4.741 

13 CCB 0161 0255 0173 0147 0765 0239 

14 S95T001071 L 22290. 607.6 7968. -294.7 1203. 6913. 

15 S95T001071 - 21620. 196.7 8101. -25.31 51.18 6584. 

16 S95T001071 D 19510. 120.1 8270. -95.85 40.20 6026. 

17 S95T001071 -A 26690. 5281. 13030. 4617. 5073. 11340. 

18 ICSA - .0063 .0397 -.0409 .0039 .1337 .0440 

19 ICSAB -.0007 1.080 -.0334 -.0108 .1397 .0225 

20 CCV 1 5.280 5.394 5.150 4.914 5.271 4.934 

21 CCIT T 5.327 5.352 5.181 4.944 5.245 4.966 

22 CCB- 1 .0179 .0104 -.0131 -.0159 .0871 .0306 

# 

--- 

Sample Name 

Sm 

--------------- ----- -------- 

Sr 

-------- 

Th 

-------- 

Ti 

-------- 

TI 

-------- 

U 

-------- 

1 ICV 5.022 4.940 -.0082 4.861 4.886 10.04 

2 ICB .0219 .0003 -.0052 -.0010 .0192 .0850 

3 ICSA .0200 .0023 -.0216 .0005 .0781 .0436 

4 ICSAB .0128 .0818 -.0228 .0004 .0779 -.0315 

5 ICSAB .0148 .0004 -.0059 -.0002 .0068 .0646 

6 ICSAB .0198 .0025 -.0199 .0009 .0914 .0166 

7 PPEPBLKTJA .3969 .0132 .0438 -.0016 -.0329 -1.195 

8 S95T001064 L 677.4 147.6 -177.8 -3.952 174.7 2647. 

9 S95T001064- 230.3 133.8 11.15 10.23 -8.866 986.0 

10 S95T001064 D 252.8 243.8 19.25 24.76 73.51 2178. 

11 S95T001064-A 4534. 4453. 51.49 4392. 4495. 9494. 

12 CCV - 4.941 4.868 -.0138 4.829 4.929 9.868 

13 CC3 .0417 .0004 -.0080 -.0006 .0170 .1689 

14 S95T001071 L 1160. 176.5 -155.1 1.702 803.2 5407. 

15 S95T001071 - 353.2 156.6 53.88 6.894 -15.63 2109. 

16 S95T001071 D 349.3 137.9 -34.17 10.10 135.1 1890. 

17 S95T001071 -A 4745. 4506. -32.48 4532. 4713. 10930. 

18 ICSA - .0455 .0020 -.0130 .0007 .0395 -.0345 

19 ICSAB .0448 .0022 -.0060 .0009 .0357 -.0627 

20 CCV 1 4.968 4.916 -.0031 4.957 5.189 9.894 

21 CCV-1 5.027 4.962 -.0018 4.985 5.172 10.03 

22 CCB-1 .0516 .0003 -.0151 -.0010 -.0019 .2138 

Zi. 5L 

\I 

a O 

C 

U x

Analv_is Report Averages Mon 07-17-95 02:19:33 PM page 5 

,' E 

--- 

Sample Name 

V 

----------------- --- -------- 

Y 

-------- 

Zn 

-------- 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

ICV 

ICB 

ICSA 

ICSAB 

ICSAB 

ICSAB 

PP.EPBLKTJA 

S95T001064 L 

S95T001064- 

S95T001064 D 

S95T001064 -A 

CCV - 

CCB 

4.975 

.0058 

.0055 

.4696 

.5027 

.4459 

0999 

170.0 

59.75 

63.20 

4594. 

4.983 

0104 

.0139 

.0013 

.0089 

.0090 

.0012 

.0091 

0235 

39.75 

14.46 

16.40 

24.58 

.0148 

0024 

4.973 

Q-.0223 

-.0225 

1.067 

1.016 

.8891 

-.1973 

-427.8 

-22.08 

44.22 

4714. 

5.022 

Q-.0219 

4.943 

.0042 

.0025 

.0015 

.0033 

.0030 

0511 

134.8 

58.13 

60.50 

4488. 

4.916 

0058 

14 

15 

S95T001071 L 

S95T001071 - 

286.4 

85.84 

71.83 

22.13 

-440.6 

-19.79 

198.5 

63.97 

16 

17 

S95T001071 D 

S95T001071 -A 

85.17 

4888. 

21.40 

38.44 

-23.28 

5120. 

71.45 

4676. 

18 

19 

ICSA 

ICSAB 

- .0132 

.4987 

.0111 

.0110 

-.0246 

1.006 

.0061 

.0054 

20 CCV 1 

21 CCV- 1 

5.184 

5.197 

.0164 

.0160 

5.290 

5.286 

5.049 

5.084 

22 CCB - 1 

.0128 .0032 Q-.0216 .0081 

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06/14/95 13:06 /Page: 1 

A-0004-1 WHC SD-WM-DP- .I , REV. 

LABCORE Data Entry Template for Wor list# 1596 

Analyst: /^ Kai2ki Instrument: ICP01 Book# 3BSYì3 

Method: LA-505-151 Rev/Mod i - L 









Analytes Requested: LI-F- 0 1 

7 OUP S95T001079 0 F @ICP-F03 SOLID 














457

06/14/95 13:06 WHC-SD-WM-DP- REVS 

A-0004-1 




r / ^ 7-.?o-sue — 

X 

ys ignature Date Analyst Signature U Date 

9FE^^ryr C / c - ,mac 

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Page: 2

8 

Identity 1: ICV Identity 2: Quality Control 10:12 AM July 20, 1995 

'-k name : TWC93 

Le Weight : 1.0000 Solution Vol une : 1.00 1 ' 

WHC-SD-WM-DP-_f,L_,_^ 


---------------------------------------------------------------------- 


( Ppm ) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 4.949 5.009 4.931 4.870 4.956 5.068 4.898 5.098 

S.O. 0.002 0.007 0.023 0.008 0.004 0.000 0.013 0.050 

% R.S.D. 0.039 0.149 0.458 0.163 0.083 0.000 0.256 0.987 

ZN NI LA FE CA CA ND u 

(Ppm) (ppm) (Ppm) (pPm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 5.005 4.966 4.994 5.023 5.201 5.044 5.150 9.817 

S.D. 0.004 0.008 0.008 0.011 0.004 0.009 0.028 0.027 

% R.S.O. 0.073 0.166 0.159 0.220 0.080 0.184 0.544 0.270 


(Ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 5.052 5.134 5.027 4.825 4.978 5.020 4.939 5.064 

S.D. 0.015 0.004 0.009 0.132 0.047 0.004 0.002 0.050 

% R.S.O. 0.287 0.086 0.171 2.727 0.940 0.070 0.048 0.985 


(Ppm) (ppm) (ppm) (ppn) (ppm) (ppm) (Ppm) (ppm) 

Mean 5.065 4.934 4.874 4.969 4.918 5.025 5.047 5.061 

S.D. 0.019 0.021 0.002 0.013 0.004 0.013 0.016 0.027 

% R.S.D. 0.366 0.420 0.048 0.262 0.073 0.265 0.313 0.528 

MN SB V BE TL 

( Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 5.011 4.731 5.021 5.179 4.879 

S.D. 0.009 0.046 0.005 0.003 0.013 

% R.S.D. 0.187 0.965 0.103 0.051 0.264 

4J 

^( 

_(J 

y ' 

7^ 

4^° ^ J

Identity 1: ICB Identity 2: Quality Control 10:17 AM July 20, 1995 

Task name : TWC93 - 

Sample Weight : -1.0000 Solution volume : 1.00 


Ott-Peak Integrations : 1 

---------------------------------------------------------------------- 

WHC-SD-WM-DP- , REVJ 

ZR SR BI SI AL CO CU LI 

(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (PPm) (Ppm) (ppm) 

Mean 0.002 0.001 -0.025 0.006 0.002 -0.004 0.001 0.000 

S.D. 0.001 0.000 0.007 0.002 0.003 0.003 0.000 0.000 

% R.S.D. 30.684 20.804 25.879 40.924 189.219 59.846 33.098 39.843 



Mean 0.000 0.004 0.000 0.001 0.002 -0.003 0.003 0.044 

S.D. 0.000 0.001 0.002 0.002 0.000 0.001 0.007 0.026 

% R.S.D. 70.496 35.591 441.507 307.143 7.217 38.294 241.198 58.938 


( ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 0.005 0.019 0.001 0.006 -0.002 0.000 -0.002 -0.008 

S.D. 0.001 0.006 0.000 0.007 0.007 0.000 0.003 0.002 

% R.S.D. 20.476 31.316 13.597 106.627 421.239 28.961 138.767 27.271 


(ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.003 0.011 0.003 0.008 0.001 0.003 0.003 0.002 

S.D. 0.001 0.007 0.001 0.002 0.000 0.000 0.001 0.008 

% R.S.D. 29.561 66.815 19.385 28.645 15.631 12.993 15.555 351.188 

MN SB 9 BE TL 

( ppm ) (ppm) (ppm) (ppm) (PPm) 

Mean 0.000 0.002 0.002 0.001 0.056 

S.D. - 0.000 0.006 0.001 0.000 0.011 

% R.S.D. 60.269 

364.612 55.255 29.801 

---------------------------------------------------------------- - ----- 

19.927 

A;_G0

Identity 1: ICSA Identity 2: Duality Control 10:23 AM July 20, 1995 

T- name : TVL93 

5 Weight : 1.0000 Solution Volume 1.00 

on-Peak Integrations 

: 3 Off-Peak 


---------------------------------------------------------------------- 

WHC-SD-WM-DP- 3 , REV. 

ZR SR BI Sl AL CO CU LI 

( Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.001 0.001 -0.004 0.067 201.000 0.009 -0.013 0.001 

S.D. 0.001 0.000 0.005 0.002 0.437 0.000 0.001 0.000 

% R.S.D. 76.805 14.222 110.292 2.592 0.218 0.061 4.312 29.214 


(Ppm) (Ppm) (ppm) (Plan) (Plan) (Ppm) (Ppm) (ppm) 

Mean 0.001 -0.049 0.007 145.566 19.120 -0.011 0.017 0.057 

S.D. 0.000 0.001 0.002 0.175 0.051 0.002 0.005 0.041 

% R.S.D. 51.253 1.441 27.270 0.120 0.266 16.239 31.586 72.156 


(ppm) (Ppm) (Plan) (Plan) (plan) (Ppm) (ppm) (Ppm) 

Mean 0.014 0.012 0.003 0.020 0.150 19.150 -0.003 191.464 

S.D. 0.007 0.009 0.000 0.011 0.002 0.024 0.002 1.884 

% R.S.D. 47.167 78.534 5.935 54.038 1.188 0.128 49.823 0.984 


( ppm) (ppm) (PPm) (PPn) (Ppm) (ppm) (Plan) (ppm) 

Mean -0.000 -0.020 0.001 0.052 0.001 0.013 -0.045 -0.045 

S.D. 0.001 0.009 0.001 0.005 0.000 0.000 0.002 0.003 

% R.S.D. 780.625 46.441 44.685 9.395 28.713 2.595 3.470 5.774 

MN SB V BE TL 

(Plan) (ppm) (Plan) (Ppm) (ppm) 

Mean 0.010 -0.042 -0.003 0.002 -0.000 

S.D. 0.000 0.024 0.001 0.000 0.015 

% R.S.D. 

1.416 

56.855 

37.569 

9.432 

------------------ ------------ ------ --------------------- --------- 

3921.697

Identity 1: ICSAB Identity 2: Quality Control 10:25 AM July 20, 1995 



On-Peak Integrations : 3 Off-Peak Integrations : 1 WHC-SD-WM-DP- , REV. 

---------------------------------------------------------------------- 


(Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.003 0.001 0.007 0.060 200.972 0.514 0.484 

S.D. 0.001 0.000 0.015 0.003 0.312 0.002 0.001 

% R.S.D. 31.270 9.108 207.960 5.121 0.155 0.300 0.136 

2N NI LA FE CA CR ND 

(Ppm) (ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 1.012 0.950 0.009 146.532 19.178 0.497 0.006 

S.D. 0.001 0.004 0.001 0.131 0.006 0.001 0.003 

% R.S.D. 0.138 0.465 7.799 0.090 0.029 0.270 55.635 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 0.014 -0.004 0.506 0.043 0.168 19.240 0.003 

S.D. 0.002 0.001 0.000 0.005 0.005 0.023 0.006 

% R.S.D. 13.686 24.915 0.065 12.460 2.718 0.118 211.580 

140 SE AG PB TI CD B 

(PPM ) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean -0.000 0.120 0.223 1.039 0.001 1.029 -0.047 

S.D. 0.001 0.004 0.005 0.010 0.000 0.000 0.001 

% R.S.D. 364.496 3.229 2.284 0.955 12.206 0.048 1.464 

MN SB V BE TL 

( ppm ) (Ppm) (Ppm) (Ppm) (PPM) 

Mean 0.519 -0.006 0.507 0.508 -0.018 

S.D. 0.001 0.006 0.001 0.001 0.005 

% R.S.D. 0.222 108.601 0.110 0.192 27.956 

L 

(PPM) 

U 

0.952 

0.002 

0.244 

(PPM) 

0.002 

0.008 

470.700 

NA 

(Ppm) 

190.763 

K 

0.513 

0.269 

(Ppm) 

-0.044 

0.009 

20.550

Identity 1: PREPBLK Identity 2: Quality Control 10:28 AM July 20, 1995 


: Weight : 1.0000 Solution Volume 10.00 

0,. _ak Integrations : 3 Off-Peak Integrations : 1 

-'------------------------------------- ------------------------------- 

2R SR BI 

WHC-SD-WM-DP-_L3 

, 

R^ f 

SI AL CO Cu LI 

(ppm) (ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.005 0.009 -0.244 5.977 0.724 0.027 0.015 0.005 

S.D. 0.004 0.000 0.037 0.015 0.029 0.015 0.001 0.001 

% R.S.D. 85.084 0.037 15.154 0.253 4.038 57.789 8.295 19.110 


(Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 0.419 0.059 -0.036 0.084 0.477 0.013 0.128 0.301 

S.D. 0.005 0.021 0.014 0.007 0.001 0.007 0.046 0.243 

% R.S.D. 1.101 35.422 38.816 8.284 0.208 55.611 35.521 80.788 


(Ppm ) (ppm) (ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.037 0.109 0.012 0.269 0.164 0.081 0.083 4.482 

S.D. 0.030 0.039 0.001 0.011 0.012 0.002 0.038 0.024 

% R.S.D. 80.554 35.681 6.160 4.273 7.184 2.025 45.776 0.530 

MO SE AG PB TI CD B • K 

(PPm ) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.002 -0.052 0.019 0.045 0.003 0.019 0.519 10352.927 

S.D. 0.008 0.006 0.001 0.035 0.002 0.005 0.009 16.931 

% R.S.D. 433.013 10.969 4.466 76.528 58.774 26.019 1.759 0.164 



Mean 0.001 -0.314 0.004 0.002 0.345 

S.D. 0.002 0.094 0.007 0.001 0.197 

% R.S.D. 179.511 

29.901 159.306 55.674 56.958 

------------------------------------------------------------------- 

îVc3

Identity 1: S95T001079_L Identity 2: .4827gin250-1-9-1-4 10:33 AM July 20, 1995 


Sample Weight : 0.4827 Sotution 9otume : 12500.00 

On-Peak Integrations : 3 Off-Peak 


---------------------------------------------------------------- - ----' 

WHGSD-WM-Dp__LLl-, REV. 

ZR SR BI SI AL CO CO LI 

(Ppm ) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 24.019 92.494 9162.704 6599.945 1232.614 -92.747 9.161 -7.212 

S.D. 22.276 1.408 199.589 83.350 112.769 39.869 7.266 2.538 

% R.S.D. 92.742 1.522 2.178 1.263 9.149 42.986 79.312 35.194 


(Ppm ) (Ppm) (ppm) (ppm) (ppm) (PPa) (Ppm) (ppm) 

Mean 260.280 3507.457 -7.846 7965.322 495.003 355.305 -225.509 2461.673 

S.D. 11.570 72.741 30.736 132.125 0.971 54.716 91.255 862.783 

% R.S.D. 4.445 2.074 391.770 1.659 0.196 15.400 40.466 35.049 


(Ppm ) (ppm) (Ppm) (Ppm) (Ppm) (ppa) (ppm) (ppm) 

Mean 47.677 495.507 20.928 13908.471 8084.904 140.184 -193.665 130074.476 

S.D. 171.376 215.895 1.952 252.980 37.147 4.920 80.685 1155.369 

It R.S.D. 359.448 43.571 9.327 1.819 0.459 3.509 41.662 0 0.888 


( ppm ) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 10.627 522.766 56.432 -21.438 38.477 51.303 269.566 5698735.824 

S.D. 26.821 58.091 7.796 110.418 12.094 9,266 22.449 51408.248 

% R.S.D. 252.396 11.112 13.816 515.067 31.431 18.062 8.328 0.902 

MN SB 9 BE TL 

(Ppm ) (ppm) (Ppm) (Ppm) (ppm) 

Mean 56.348 -465.977 -0.613 -2.951 886.604 

S.D. 3.986 121.683 8.912 4.691 186.035 

% R.S.D. 7.073 

26.114 1452.657 158.997 

-------------------------------------------------------- --------- ----- 

20.983 

I U "s

Identity 1: S95TOO1079 Identity 2: .4827gin250-1 . 9 10:36 AM July 20, 1995 

T- name : TWC93 

Weight 0.4827 Solution Volume 2500.00 


____________________________________ ----------------------------- 

WHC-SD-WM-DP- 

...ttt 1 

REV 1 


( ppm ) (Pppa) (ppm) (Ppm) (ppm) (ppa) (ppm) (Ppm) 

Mean 12.422 97.914 9335.872 6142.830 1477.992 13.336 31.448 6.314 

S.D. 5.884 0.282 63.708 0.930 8.301 7.980 2.049 0.692 

% R.S.D. 47.371 0.288 0.682 0.015 0.562 59.837 6.516 10.957 


( ppm ) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 291.812 3525.000 -0.069 8149.310 462.040 377.563 46.615 1234.217 

S.D. 4.079 19.060 16.355 28.821 0.777 10.506 40.528 136.561 

% R.S.D. 1.398 0.541 23593.705 0.354 0.168 2.783 86.941 11.065 


(Ppm ) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 6.142 48.146 13.848 14021.033 7675.568 140.437 -16.792 125056.053 

S.D. 29.281 33.246 0.719 299.565 65.490 0.003 19.996 539.662 

% R.S.D. 476.725 69.053 5.189 2.137 0.853 0.002 119.083 0.432 

140 SE AG p8 TI CD B K 

( ppm ) (Pp) (Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean -2.125 127.221 13.215 54.316 13.374 8.414 230.044 5387181.913 

S.D. 6.108 16.026 1.506 20.355 1.727 3.705 7.418 23466.026 

X D .S.D. 287.389 12.597 11.394 37.475 12.911 44.037 3.225 0.436 

MN s8 V BE TL 

( ppm ) (ppm) (ppm) (Ppm) (Ppm) 

Mean 56.849 -36.530 0.597 -0.839 63.996 

S.D. - 2.096 58.230 4.257 1.111 48.647 

% R.S.D. 3.688 159.401 712.940 132.466 76.015 

4UJ

Id en tity 1: S95TOO1079 D Identity 2: .4853gin250-1-9 10:40 AM July 20, 1995 

Task name a TYC93 



------- ---- - -------------------------- - - ------------------- - -------- 

- I 

2R SR BI SI AL 


Mean 6.395 123.614 11278.058 6546.544 1788.394 

S.D. 6.490 0.003 46.066 14.644 7.211 

% R.S.D. 101.474 0.003 0.408 0.224 0.403 


(ppm) (PPm) (ppm) (Ppm) (ppm) 

Mean 267.323 4465.756 0.285 10018.001 402.802 

S.D. 3.028 25.662 6.222 51.186 1.533 

% R.S.D. 1.133 0.575 2179.476 0.511 0.381 

CE SM BA P S 


Mean -14.007 17.649 13.540 16309.362 8024.015 

S.D. 46.924 54.131 1.289 990.794 158.927 

% R.S.D. 335.012 306.706 9.522 6.075 1.981 


( Ppm ) (ppm) (Ppm) (Ppm) (ppm) 

Mean -1.644 2.262 9.472 110.287 11.562 

S.D. 1.773 50.266 2.160 62.149 1.941 

% R.S.D. 107.855 2221.781 22.806 56.352 16.786 

MN SB V BE TL 

( Ppm ) (Ppm) (ppm) (ppm) (ppm) 

Mean 71.849 -70.601 2.764 0.432 -3.243 

S.D. 0.796 127.595 6.161 0.972 117.632 

% R.S.D. 

1.107 180.728 222.898 

225.144 

----------------------------------------- ------------------------ ----- 

3627.124 

i Ll'J 

WHC-SD-WM-DP- I ^ 1 , REV.I 

CO 

(ppm) 

31.501 

13.756 

43.670 

CR 

(ppm) 

511.896 

8.724 

MG 

1.704 

(ppm) 

161.928 

1.296 

0.800 

CD 

(ppm) 

17.309 

1.844 

10.652 

n 

Cu L 

(ppm) (ppm) 

51.773 5.729 

4.061 0.991 

7.845 17.306 

ND u 

(ppm) (ppm) 

68.114 1232.598 

39.820 242.441 

58.461 19.669 

AS NA 

(ppm) (ppm) 

-19.704 125854.579 

12.568 973.056 

63.782 0.773 

B K 

(Ppm ) (ppm) 

181.319 5263204.968 

4.664 29323.920 

2.572 0.557

Identity 1: S95TOO1079_A Identity 2: .4827gin250-1-2-7 10:43 AM July 20, 1995 

T.-k name : TWC93 

e Weight : 0.4827 Solution 9olme 2500.00 

0,, -Teak Integrations : 3 


WHC-SD-WM-DP- REV. 

---------------------------------------------------------------------- 


(Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) (ppM) (Ppm) 

Mean 5142.554 5211.287 14244.922 10737.052 6421.813 5169.640 5028.808 4704.510 

S.D. 15.338 13.848 118.835 13.112 57.547 23.936 7.920 9.976 

% R.S.D. 0.298 0.266 0.834 0.122 0.896 0.463 0.157 0.212 


(PPm ) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) (ppm) (ppm) 

Mean 5167.095 8573.724 5177.856 13235.616 5679.809 5626.208 5426.171 10779.522 

S.D. 2.390 16.474 9.383 7.603 11.268 16.415 69.956 111.569 

% R.S.D. 0.046 0.192 0.181 0.057 0.198 0.292 1.289 1.035 


( Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (PPM) 

Mean 5101.371 5108.183 5109.926 18849.113 12558.809 5239.194 5016.611 126706.362 

S.D. 24.845 7.108 12.411 249.821 52.039 13.621 43.416 240.686 

% R.S.D. 0.487 0.139 0.243 1.325 0.414 0.260 0.865 . 0.190 

MO SE AG P8 TI CD 8 K 

(PPM ) (Ppm) (Ppm) (PPM) (Ppm) (PPM) (ppm) (Ppm) 

Mean 5168.031 5110.527 3953.138 5175.180 5052.876 5136.543 5202.517 5302329.445 

S.D. 43.222 45.076 10.757 82.494 14.062 12.963 15.873 658.023 

% R.S.D. 0.836 0.882 0.272 1.594 0.278 0.252 0.305 0.012 

MN SB 9 BE TL 

(PPM ) (PPM) (PPM) (Ppm) (PPM) 

Mean 5233.020 4647.149 5222.169 5029.308 5002.334 

S.D. 4.423 128.112 15.674 11.561 46.229 

% R.S.D. 0.085 2.757 0.300 0.230 0.924 

ÂS V I

Identity 1: CCV Identity 2: Quality Control 10:47 AM July 20, 1995 


Sample Weight : 1.0000 Solution Volune 1.00 



(Ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 4.930 4.968 4.932 4.868 4.912 

S.D. 0.005 0.006 0.015 0.010 0.025 

% R.S.D. 0.109 0.117 0.300 0.198 0.517 


( ppm ) (ppm) (Ppm) (Ppm) (ppm) 

Mean 5.058 4.998 4.964 5.025 5.150 

S.D. 0.003 0.001 0.012 0.016 0.005 

% R.S.O. 0.069 0.024 0.249 0.314 0.091 

CE SM BA P S 

( ppa ) (ppm) (ppm) (Ppm) (ppm) 

Mean 5.030 5.027 4.965 5.065 5.066 

S.D. 0.010 0.009 0.005 0.282 0.104 

% R.S.D. 0.198 0.173 0.103 5.564 2.050 


( ppm ) (Ppm) (ppm) (Ppm) (ppm) 

Mean 5.100 4.966 4.900 5.003 4.899 

S.D. 0.009 0.015 0.002 0.006 0.006 

% R.S.D. 0.174 0.302 0.044 0.124 0.133 

MN SB V BE TL 

( ppm ) (ppm) (ppm) (Ppm) (ppm) 

Mean 5.029 4.667 5.030 5.149 4.847 

S.D. 0.008 0.033 0.006 0.005 0.009 

% R.S.D. 0.167 0.707 0.124 0.090 0.177 

WHC-SD-WM-DP ^, REV. 

^X (; ) 

CO Cu LI 


5.101 4.829 4.994 

0.023 0.005 0.037 

0.451 0.098 0.745 

CR NO u 


5.073 5.070 9.628 

0.004 0.029 0.020 

0.087 0.572 0.205 

MG AS MA 


5.060 4.962 5.025 

0.006 0.010 0.042 

0.122 0.196 0.827 

CD R K 


5.046 5.009 5.157 

0.008 0.004 0.032 

0.164 0.083 0.620

Identity 1: CCB Identity 2: Duality Control 10:51 AM July 20, 1995 

Te-` name : TWC93 

! - Weight : 1.0000 Solution Vol une 1.00 

on- peak Integrations : 3 


---------------------------------------------------------------------- 

ZR SR RI SI 


Mean 0.001 0.000 -0.004 0.009 

S.D. 0.001 0.000 0.007 0.005 

% R.S.D. 64.537 86.794 163.481 49.164 

2N NI LA EE 

(Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.001 0.002 -0.002 0.005 

S.D. 0.001 0.002 0.002 0.001 

% R.S.D. 103.791 106.325 154.182 28.872 

CE SM 8A P 

(ppm) (Ppm) (ppm) (Ppm) 

Mean 0.020 0.021 0.001 0.001 

S.D. 0.011 0.010 0.000 0.017 

% R.S.D. 53.691 45.545 37.872 1533.091 

MO SE AG PB 


Mean 0.002 0.027 0.003 0.019 

S.D. 0.001 0.001 0.001 0.004 

% R.S.D. 58.275 5.481 17.512 19.518 

MN SB V BE 


Mean -0.000 -0.015 0.001 0.000 

S.D. _ 0.000 0.024 0.001 0.000 

% R.S.D. 

3338.207 

157.140 

85.249 

1481.303 

----------------- ------------------ - ------ --------------------- ------ 

WHGSD WM-DP-131 , Rv L 

AL CO Cu L 

(Ppm) (ppm) (Ppm) (Ppm) 

0.002 -0.000 0.001 -0.000 

0.005 0.003 0.001 0.000 

230.315 28558.575 93.036 110.021 

CA CR ND U 

(Ppm) (Ppm) (Ppm) (ppm) 

0.000 0.001 0.003 0.080 

0.000 0.001 0.006 0.051 

10.189 102.029 199.043 63.777 

S MG AS NA 

(ppn) (Ppm) (ppm) (Ppm) 

-0.004 -0.000 -0.004 0.017 

0.001 0.000 0.001 0.004 

22.027 476.008 24.861 24.000 

TI CD 8 K 

(Pp) (Ppm) (ppn) (Ppm) 

0.001 0.002 0.004 0.094 

0.000 0.000 0.000 0.015 

38.053 23.143 8.793 15.738 

TL 

(ppm) 

0.069 

0.019 

27.449 

^âJ

Identity 1: 5957001093 L Identity 2: .4800gin250-1-9-1-4 




-- 

---------------------------------------------------------- 

2R SR 81 SI 


Mean 76.539 143.237 1716.146 8940.093 

S.D. 18.727 0.005 130.604 44.132 

% R.S.D. 24.467 0.004 7.610 0.494 

ZN NI LA FE 


Mean 225.983 4821.733 -38.058 11636.290 

S.D. 9.554 7.260 30.889 136.877 

% R.S.D. 4.228 0.151 81.163 1.176 

CE SM BA P 


Mean 388.510 844.703 29.362 17347.942 

S.D. 150.354 159.623 2.316 363.297 

% R.S.D. 38.700 18.897 7.887 2.094 

MO SE AG PB 


Mean 35.621 215.605 73.184 -138.191 

S.D. 7.415 101.419 12.625 150.003 

% R.S.D. 20.817 47.039 17.251 108.548 

MN SB V BE 

(Ppm ) (Ppm) (ppm) (PPM) 

Mean 72.388 -491.825 -13.501 -2.925 

S.D. 6.914 597.399 16.250 4.824 

% R.S.D. 

9.551 121.466 

-•------------------------------- 

120.368 

164.954 

----------------------------- 

10:54 AM July 20, 1995 

WHC-SD-WM-DP- l3 l , REV.1 

AL CO Cu L 


1651.540 -93.446 24.237 19.497 

96.116 40.070 4.885 3.479 

5.820 42.880 20.153 17.846 

CA CR NO U 

(Ppm) (ppm) (ppm) (ppm) 

478.620 589.982 290.293 2931.788 

0.000 40.695 245.690 398.277 

0.000 6.898 84.635 13.585 

S MG AS NA 

(ppm) (Ppm) (Ppm) (Ppm) 

7564.970 175.144 -87.063 124810.118 

224.735 4.938 22.830 649.090 

2.971 2.819 26.223 0.520 

TI CD B K 

(PPm) (Ppm) (ppm) (ppm) 

27.402 177.012 371.899 5896260.021 

12.542 12.177 43.925 20656.657 

45.771 6.879 11.811 0.350 

TL 

(ppm) 

1873.636 

322.495 

17.212 

4;:70

Identity 1: S95TOO1093 Identity 2: .4800 9 in250-1-9 10:57 AM July 20, 1995 

T om - name : TWC93 

e Weight : 0.4800 Solution Volu : 2500.00 

On- peak Integrations : 3 Off-Peak Integrations : 1 

___________________________ _____________________________ 

ZR SR 81 

( Ppm ) (Ppm) (Ppm) 

Mean 13.389 140.463 2113.440 

S.D. 7.382 0.286 16.434 

% R.S.D. 55.137 0.204 0.778 

CE SIR BA 

P S MG AS NA 

( Ppm ) (ppm) (Ppm) 

(Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 18.469 23.973 14.226 1 7698.229 7311.027 178.512 50.770 120345.226 

S.D. 36.298 59.925 0.680 313.055 84.057 0.985 7.541 542.416 

% R.S.D. 196.531 249.964 4.780 

1.769 1.150 0.552 14.853 . 0.451 

MO SE AG 

( Ppm ) (Ppm) (Ppm) 

Mean 6.412 2.481 4.251 

S.D. 2.502 32.617 2.985 

% R.S.D. 39.021 1314.569 70.214 

MN SB V 

(Ppm) (ppm) (ppm) 

Mean 69.703 -169.499 -5.961 

S.D. 0.806 28.200 4.927 

% R.S.D. 1.156 16.637 82.659 

WHGSD-WM-DP-^j L, REVS 

SI AL CO CU LI 

(Ppm ) (Ppm) (Ppm) (Ppm) (ppm) 

8744.087 1776.130 8.705 21.401 17.942 

22.808 26.757 8.001 0.444 0.510 

0.261 1.506 91.908 2.074 2.845 

ZN NI LA 

FE CA CR ND U 

( Ppm ) (ppm) (PPm) 

(ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 277.531 4812.488 10.812 1 1781.847 508.611 604.466 80.128 942.462 

S.D. 2.322 43.479 9.499 

57.670 0.851 5.292 37.067 134.269 

% R.S.D. 0.837 0.903 87.855 

0.489 0.167 0.876 46.259 14.247 

PB TI CD B K 


124.942 12.644 151.761 290.387 5563572.592 

46.335 0.527 3.724 1.580 17222.441 

37.086 4.169 2.454 0.544 0.310 

BE TL 

(Ppm ) (Ppm) 

1.688 36.370 

0.567 41.731 

33.574 114.740

Identity 1: S95TOO1093 D Identity 2: .4958gin250-1-9 11:00 AM July 20, 1995 


Samp le Weight : 0.4958 Solution Vol une 2500.00 

On-Peak Integrations : 3 Oft-Peak Integrations : 1 WHC-SD-WM-DP- 

I 

flEV,L 

---------------------------------------------------------------------- 

2R 

SR 81 51 AL CO Cu LI 

( ppn ) (ppn> (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppn) 

Mean 21.543 140.768 5843.702 7161.858 1786.450 12.522 43.056 18.125 

S.D. 4.800 0.730 40.386 20.479 24.416 20.531 2.238 1.347 

% R.S.D. 22.280 0.519 0.691 0.286 1.367 163.966 5.198 7.434 


(ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 263.374 8707.806 -5.174 13016.900 510.741 614.600 44.422 1105.950 

S.D. 5.359 1.642 6.085 98.317 1.891 8.191 60.458 228.012 

% R.S.D. 2.035 0.019 117.613 0.755 0.370 1.333 136.098 20.617 


(ppm) (ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 77.155 69.607 14.387 17702.888 7356.067 183.300 19.399 119713.187 

S.D. 50.432 62.319 1.087 763.697 122.721 0.476 25.486 1132.045 

% R.S.D. 65.364 89.530 7.558 4.314 1.668 0.260 131.377 0.946 


(Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 7.587 170.766 9.813 86.747 19.636 27.051 117.208 4909276.252 

S.O. 4.157 36.579 3.018 61.500 2.941 1.790 4.174 31004.284 

It Q.S.D. 54.797 21.421 30.751 70.896 14.979 6.617 3.561 0.632 


( ppm ) (pps) (Ppm) (Ppm) (Ppm) 

Mean 91.866 -179.396 0.962 1.652 53.043 

S.D. 1.335 62.845 0.731 0.556 102.699 

% R.S.D. 

1.453 35.032 76.014 

33.686 

----------------------------------------- ----------------------- --- --- 

193.614 

^yh 

^1 / 2

Identity 1: S957001093 A Identity 2: .48009in250-1-2-7 11:03 AM July 20, 1995 

Ta o ` name : TWC93 

S Weight : 0.4800 Solution VoLme 2500.00 

on-reak Integrations : 3 Off-Peak Integrations : 1 

............................................................-----._.-- 

WHC-SD-WM-DP- fV, REV. .L 


(ppm) (Ppa> (Ppo) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 5181.672 5282.757 7317.844 13532.403 6779.054 5268.041 5033.345 4703.218 

S.D. 8.608 6.479 59.093 29.879 15.039 36.760 8.230 15.217 

% R.S.D. 0.166 0.123 0.808 0.221 0.222 0.698 0.164 0.324 


' (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 5241.303 9945.176 5247.035 17014.425 5702.287 5933.798 5283.649 11054.707 

S.D. 14.426 41.006 24.802 29.507 6.614 11.291 103.754 44.916 

% R.S.D. 0.275 0.412 0.473 0.173 0.116 0.190 1.964 0.406 


(Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 5184.615 5112.762 5129.005 22383.535 12450.923 5355.495 5128.173 122943.480 

S.D. 25.000 35.137 6.040 1236.780 353.899 9.600 48.118 503.579 

% R.S.D. 0.482 0.687 0.118 5.525 2.842 0.179 0.938 0.410 

MO SE AG PR TI CD 8 K 

(Ppe) (Ppm) (pp) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 5214.674 5025.037 3886.604 5227.407 5098.626 5336.361 5289.220 5501240.918 

S.D. 6.619 13.355 17.060 54.198 5.106 20.985 5.877 15284.274 

% R.S.D. 0.127 0.266 0.439 1.037 0.100 0.393 0.111 0.278 

MN SB V BE TL 


Mean 5319.718 4837.169 5285.007 5072.013 5202.328 

S.D. 18.796 224.741 12.069 9.158 32.102 

% R.S.D. 

0.353 

4.646 0.228 

0.181 

--- - --- ----------- ---------------------- ---------------- -------------- 

0.617 

101,73

Identity 1: ICSA Identity 2: Quality Control 11:05 AM July 20, 1995 


Sample Weight : 1.0000 Solution volume : 1.00 


off-Peak Integrations : 1 

---------------------------------------------------------------------- 

WHGSD-WM-DP-ja, REV. j 

ZR SR 81 51 AL CO CU LI 

( ppa ) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.000 0.001 0.001 0.062 198.989 0.008 -0.013 0.001 

S.D. 0.000 0.000 0.008 0.001 0.102 0.003 0.000 0.000 

% R.S.D. 254.641 14.284 1044.423 1.263 0.051 38.500 2.006 8.822 


(PPm ) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 0.001 -0.049 0.005 146.884 19.081 -0.010 0.008 0.065 

S.D. 0.000 0.000 0.000 0.164 0.031 0.001 0.007 0.011 

% R.S.D. 17.578 0.854 0.636 0.111 0.162 5.410 82.631 17.708 


(ppm) (pppa) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.013 0.014 0.003 0.045 0.156 19.316 -0.003 189.283 

S.D. 0.005 0.005 0.000 0.006 0.007 0.022 0.004 0.237 

% R.S.D. 38.251 35.302 2.687 14.018 4.289 0.113 134.916 0.125 

NO SE AG PIT TI CD B • K 

(Ppm ) (Ppm) (ppm) (ppn) (ppm) (pprn) (ppm) (ppm) 

Mean -0.001 -0.027 0.003 0.027 0.001 0.013 -0.042 0.263 

S.D. 0.002 0.012 0.000 0.005 0.000 0.001 0.001 0.004 

% R.S.D. 116.580 45.112 3.247 18.432 7.751 8.347 1.579 1.485 



Mean 0.009 -0.027 -0.002 0.002 0.009 

S.D. 0.000 0.028 0.001 0.000 0.011 

% R.S.D. 4.492 101.963 39.716 0.043 118.992 

x'741

Identity 1: ICSAB identity 2: Duality Control 11:08 AM July 20, 1995 


T Weight : 1.0000 Solution Volume 1.00 

Or, _ok Integrations : 3 Off-Peak Integrations : 1 WHC-SD-WM-DP;j,, 

REV. 

----------------------------------------------------'__---------.----- 

2R 

SR BI SI AL CO Cu LI 

( ppm ) (ppn) (ppm) (ppm) (ppm) (Ppm) (Ppm) (ppm) 

Mean 0.000 0.001 0.012 0.067 199.565 0.506 0.485 0.946 

S.D. 0.000 0.000 0.001 0.001 0.215 0.002 0.000 0.006 

% R.S.D. 86.427 9.147 5.093 1.495 0.108 0.304 0.102 0.657 


(Ppm ) (ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 1.006 0.947 0.010 147.274 19.240 0.498 0.029 0.117 

S.D. 0.002 0.005 0.000 0.244 0.046 0.004 0.003 0.014 

% R.S.D. 0.230 0.503 0.446 0.166 0.239 0.863 11.006 12.291 


(ppm) (Ppm) (ppm) (Ppm) (ppm) (ppa) (Ppm) (ppm) 

Mean 0.029 0.024 0.508 0.044 0.159 19.185 .0.003 190.026 

S.D. 0.005 0.004 0.001 0.006 0.004 0.052 0.002 1.008 

% R.S.D. 16.772 15.483 0.150 12.665 2.583 0.270 79.849 0.530 


(ppm) (ppm) (Ppm) (Ppm) (ppm) (ppa) (ppm) (ppra) 

Mean -0.002 0.091 0.212 1.029 0.001 1.026 -0.045 0.202 

S.D. 0.000 0.002 0.005 0.014 0.000 0.004 0.000 0.016 

% R.S.D. 14.869 2.197 2.370 1.322 13.809 0.399 0.892 7.727 


(ppm) (ppm) (ppra) (Ppa) (Ppm) 

Mean 0.518 -0.035 0.509 0.509 0.022 

S.D. 0.002 0.009 0.001 0.001 0.004 

% R.S.D. 

0.344 26.886 0.266 

0.199 

---------------------------------------- ---------------- ---------- ---- 

18.995 

S 7;,

Identity 1: CCV_l Identity 2: CCV_1 11:11 AM July 20, 1995 




Off-Peak -Integrations : 1 

---------------------------------------------------------------------- 

NIHC-SD-WM-DP- 

. REV • 


( ppm ) (ppm) (ppm) (ppin) (ppm) (ppm) (ppm) (ppm) 

Mean 4.998 5.059 4.956 4.848 4.928 5.021 4.960 5.123 

S.D. 0.004 0.009 0.030 0.002 0.020 0.002 0.014 0.037 

% R.S.D. 0.085 0.169 0.610 0.048 0.412 0.031 0.276 0.718 


(Ppm ) (ppm) (ppn) (ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 4.967 4.976 5.074 5.076 5.262 5.022 5.331 10.087 

S.D. 0.002 0.005 0.008 0.018 0.009 0.024 0.028 0.010 

% R.S.D. 0.046 0.110 0.149 0.347 0.162 0.473 0.516 0.098 


(ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 5.062 5.118 5.090 4.896 4.929 4.991 4.930 5.156 

S.D. 0.004 0.009 0.010 0.163 0.069 0.002 0.013 0.048 

% R.S.D. 0.076 0.183 0.200 3.328 1.393 0.049 0.268 . 0.923 

MO SE AG p8 TI CD B K 

( ppm ) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 5.024 4.963 4.864 4.975 4.933 5.034 5.094 5.328 

S.D. 0.001 0.005 0.002 0.020 0.005 0.009 0.011 0.068 

% R.S.O. 0.020 0.111 0.039 0.402 0.110 0.173 0.222 1.280 

MN SB V BE TL 

( ppm ) (ppm) (ppm) (Ppm) (ppm) 

Mean 5.014 4.742 5.047 5.212 4.935 

S.D. - 0.002 0.004 0.005 0.004 0.024 

% R.S.O. 0.038 0.084 0.104 0.074 0.481 

n

Identity 1: CC9_1 Identity 2: CCB_1 11:14 AM July 20, 1995 


t Weight : 1.0000 Solution Volume : 1.00 WHC-SD-WM-DP-_d1, REV, 

6, eak Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

ZR 


( ppm ) (pp(n) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.001 0.001 -0.001 0.007 0.021 0.001 0.002 0.001 

S.D. 0.001 0.000 0.014 0.001 0.004 0.003 0.000 0.000 

% R.S.D. 53.178 32.734 1323.337 19.966 19.591 299.002 6.065 34.466 


(Ppm ) (ppm) (Ppm) (ppm) (ppm) (ppM) (ppm) (Pp) 

Mean 0.001 0.002 0.001 0.012 0.002 0.001 0.027 -0.015 

S.D. 0.000 0.001 0.002 0.002 Q.001 0.001 0.009 0.039 

% R.S.D. 21.850 57.007 154.253 20.296 40.328 88.492 31.174 250.923 


( ppm) (ppm) (PpR) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.001 0.006 0.001 0.014 -0.003 0.001 -0.000 0.051 

S.O. 0.008 0.010 0.000 0.007 0.003 0.001 0.005 0.005 

% R.S.D. 556.871 172.683 31.412 53.062 118.549 47.990 2422.532 9.363 

MO SE AG PB TI CO B K 

( Ppm ) (Ppm) (PPM) (Ppm) (ppm) (Ppm) (Ppm) (ppm) 

Mean 0.004 0.023 0.004 0.011 0.001 0.002 0.004 0.130 

S.D. 0.001 0.004 0.001 0.011 0.000 0.001 0.000 0.002 

% R.S.D. 36.919 18.913 19.471 99.582 16.810 32.170 8.547 1.734 



Mean 0.001 -0.009 -0.001 0.001 0.010 

S.D. 0.000 0.017 0.000 0.000 0.017 

% R.S.D. 51.046 199.069 31.203 56.860 176.506 

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06/14/95 13:17 

A-0004-1 


Analyst: XS4 Instrument: IC' 

Y-W->r 

Method: LA-56-14110 Rev/Mod G - 


Book# Y3hf( 0- 

WHC-SD-WM-DP- /3, REV. ( 


1 ICV 

2 ICB 

3 ICSA 

4 ICSAB zjA 

@ICP-QC QC 

@ICP-QC QC 

@ICP-QC QC 

@ICP-QC QC 

5 PREPBLKMxL @ICP-F03 SOLID 

6 SAMPLE S95T001094 0 F @ICP-F03 SOLID 


7 DUP 

8 SPK 

9 ICSA 

10 ICSAB 

11 CCV 

12 CCB 

S95T001094 0 F @ICP-F03 SOLID 

S95T001094 0 F @ICP-F03 SOLID 

@ICP-QC QC 

@ICP-QC QC 

@ICP-QC QC 

@ICP-QC QC 

95000085 B-104 


Analyst Signature Date Analyst Signaturd Date 

Pvrp Ili 71a 1 Yti^ 

SYÛO1o9^_( .NBUs--, ISÂ^,h9•L •?'tie, (^^KSÎl,vîl=^f7>^ 

sYS7oa/a9Y yrvy— ISO 1, ^^ (ISV r/01/,9r2/ -,S/U. 

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5 W0010H _ a ' qNj->uo I.y j (tsa r/'# ' 9811 =5/V.4 



.13;13 

I at I4.'/L ^ of isTs {- I kt 41^ N/403 

Page: 1

Analysis Report Summary Fri 07-07-95 01:10:49 PM page 1 

- 

Sample Name 

----------------- 

File 

--- -------- 

Method 

-------- 

Date 

--------- 

Time 

----- 

OpID 

---- 

Type 

---- 

Mode 

----- 

ICV 950707B ICP2 07107195 12:09 DKS Q CONC 

2 ICB 950707B ICP2 07/0795 12:14 DKS Q CONC 

3 ICSA 950707B ICP2 07107195 12:17 DKS Q CONC 

4 ICSAB 950707B ICP2 07107195 12:20 DKS Q CONC 

5 PREPBLKTJA 950707B ICP2 070795 12:26 DKS S CONC 

6 S95T001094 L 950707B ICP2 07107195 12:32 DKS S CONC 

7 S95T001094— 950707B ICP2 07107195 12:36 DKS S CONC 

9 S95T001094—A 950707B ICP2 07%107 /95 12:44 DKS S CONC 

95 12:51 DKS CONC 

11 ICSAB 950707B ICP2 07/195 07 12:54 DKS CONC 

12 CCV 950707B ICP2 07 07 95 13:01 DKS CONC 

13 CCB' 950707B ICP2 07/07%95 13:06 DKS CONC 

a7 -67,ys 

1 , / O ^ SY.mo/a?f 

06XV :0 /nI 

WHGSD-WM-DP-1 ^ 

C1S3 

REV

Analysis Report Averages Fri 07-07-95 01:10:49 PM page 2 

# 

--- 

Sample Name 

Ag 

---------------- ---- -------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

1 

2 

3 

4 

5 

6 

7 

8 

9 

10 

11 

12 

13 

ICV 

ICB 

ICSA 

ICSAB 

PREPBLKTJA 

S95T001094 L 

S95T001094- 

S95T001094 D 

S95T001094-A 

ICSA - 

ICSAB 

CCV 

CCB 

5.037 

.0001 

-.0001 

.9620 

0030 

.4761 

.9545 

.2656 

4607. 

- 0006 

9647 

5.100 

-.0011 

4.959 

-.0068 

239.7 

243.5 

3460 

2194. 

2274. 

2093. 

7423. 

239.9 

238.9 

4.959 

.0005 

5.109 

-.0199 

-.0906 

-.0360 

0090 

-115.9 

17.03 

-32.40 

5245. 

-.0449 

-.0026 

5.137 

-.0081 

4.952 

.0009 

-.0039 

-.0062 

0050 

148.3 

252.1 

34.40 

5219. 

-.0117 

-.0082 

4.949 

-.0051 

4.931 

-.0000 

.0016 

.4606 

0132 

9.023 

11.23 

11.64 

4693. 

.0017 

4480 

4.910 

.0001 

5.159 

-.0002 

-.0001 

.4683 

0005 

-1.851 

-.7384 

-.5431 

5073. 

.0001 

4691 

5.191 

-.0001 

cr. 

y 

CL 

# Sample Name Bi 

--- -------------- ------ ----- --- 

1 ICV 5.015 

2 ICB 0148 

3 ICSA .0296 

4 ICSAB .0134 

5 PREPBLKTJA 1446 

6 S95T001094 L 11140. 

7 S95T001094- 10800. 

8 S95T001094 D 9530. 

9 S95T001094-A 17000. 

10 ICSA - .0081 

11 ICSAB -.0189 

12 CCV 5.072 

13 CCB .0095 

Ca 

-------- 

5.100 

0007 

233.9 

237.4 

2602 

303.3 

377.9 

394.2 

5642. 

248.8 

247.0 

5.293 

.0000 

Cd 

-------- 

5.080 

0001 

.0022 

.9204 

0060 

20.46 

17.05 

27.55 

5195. 

.0026 

.9355 

5.146 

-.0005 

Ce 

-------- 

5.055 

.0053 

.0093 

.0067 

0797 

-64.26 

20.27 

24.53 

4973. 

.0133 

.0096 

5.032 

.0059 

Co 

-------- 

5.149 

0008 

.0013 

.4587 

.0310 

-21.48 

10.72 

10.34 

5230. 

.0005 

4664 

5.210 

.0014 

Cr 

-------- 

5104 

.0006 

.0049 

.4671 

0026 

501.3 

470.3 

463.2 

5733. 

.0062 

4756 

5.18I 

-.0012 

3 

N 

# 

--- 

Sample Name 

-------------------- Cu 

-------- 

Eu 

-------- 

Fe 

-------- 

K -------- La 

-------- 

Li 

-------- 

1 ICV 4.956 .0068 5.064 5.078 4.986 4.911 

2 ICB -.0008 .0004 -.0007 .1969 .0002 .0003 

3 ICSA -.0103 -.0060 88.60 .3306 -.0031 .0024 

4 ICSAB .4752 -.0045 89.78 .2483 -.0033 .9825 

5 PREPBLKTJA .0428 .0131 .4801 11020. -.0127 .0096 

6 S95T001094 L 15.66 24.57 8610. 5201e3 -7.244 49.75 

7 S95T001094- 28.49 8.520 8470. 4976e3 -2.298 35.73 

8 S95T001094 D 21.82 10.01 9050. 4978e3 -4.030 38.44 

9 S95T001094-A 4859. 17.30 14530. 5464e3 4839. 4687. 

10 ICSA - 0101 -.0308 91.69 .2822 -.0032 .0030 

11 ICSAB .4588 -.0259 90.86 .1496 -.0033 .9246 

I2 CCV 4.947 .0074 5.120 5.168 4.981 4.959 

13 CCB -.0008 .0011 -.0003 .1485 .0008 .0009 

tiC3ì

Analysis Report Averages Fri 07-07-95 01:10:49 PM page 3 

# 

- 

Sample Name 

Mg 

--------------- ----- -------- 

Mn 

-------- 

Mo 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

I ICV 4.951 4.980 5.080 4.908 5.141 5.028 

2 ICB 0021 .0001 -.0005 0010 0010 .0032 

3 ICSA 240.7 0057 -.0078 188.4 .0029 0210 

4 ICSAB 244.1 .4372 -.0081 193.4 -.0006 8784 

5 PREPBLKTJA 0514 0707 0051 3.914 0218 13.25 

6 S95T001094 L 156.3 65.84 13.70 115600. -5.471 3611. 

7 S95T001094- 102.1 60.58 4.461 111100. -11.46 3575. 

8 S95T001094 D 109.0 71.48 -4.538 105900. 0762 8943. 

9 S95T001094-A 4953. 4999. 5202. 126100. 4967. 9156. 

10 ICSA - 242.4 -.0049 -.0092 184.2 -.0004 - 0069 

11 ICSAB 241.2 4446 -.0082 184.2 -.0007 9015 

12 CCV 4.982 5.020 5.140 4.949 5.130 5.114 

13 CCB -.0009 .0003 -.0001 .0081 .0000 -.0023 

# 

--- 

Sample Name 

P 

--------------- ----- -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 ICV 5.093 5.085 5.103 4.820 5.071 4.723 

2 ICB -.0108 .0044 -.0079 .0069 .0103 .0026 

3 ICSA -.0257 .0312 -.0370 -.0118 -.0294 .0005 

4 ICSAB -.0458 .9598 -.0212 0154 0640 .0414 

5 PREPBLKTJA -.0307 .0840 0073 0118 .2425 0382 

6 S95T001094 L 14530. 509.7 6991. 144.0 -112.1 6569. 

7 S95T001094- 14900. 45.32 7039. -1.819 -337.2 6861. 

B S95T001094 D I4810. 76.60 6934. -10.31 -256.9 4713. 

9 S95T001094-A 21940. 5304. 13190. 5015. 4876. 12740. 

10 ICSA - -.0355 .0338 -.0295 -.0106 .0090 .0062 

11 ICSAB -.0173 .9919 -.0199 -.0069 -.0122 0508 

12 CCV 5.171 5.157 5.156 4.839 5.130 4.781 

13 CCB .0046 -.0003 -.0122 -.0053 .0102 .0048 

11 - 

Sample Name 

Sm 

-------------- ------ -------- 

Sr 

-------- 

Th 

-------- 

Ti 

-------- 

T1 

-------- 

U 

-------- 

1 ICV 4.988 4.917 .0080 4.880 4.899 9.976 

2 ICB .0028 .0000 -.0043 0002 0226 .0095 

3 ICSA -.0039 .0017 -.0238 .0012 .0063 -.0463 

4 ICSAB 0111 .0017 0199 .0010 .0388 0753 

5 PREPBLKTJA .0853 .0014 .1115 .0085 0845 -2.725 

6 S95T001094 L 229.7 100.7 46.69 5.760 -408.2 124.4 

7 S95T001094 - 78.66 103.3 36.60 4.454 -116.0 -171.9 

8 S95T001094 D 96.64 109.7 37.23 33.37 -40.26 -23.04 

9 S95T001094-A 4905. 4887. 90.48 4879. 4834. 9499. 

10 ICSA - .0028 .0015 --0131 .0013 .0222 -.1269 

11 ICSAB .0028 .0015 -.0170 0010 0161 -.1121 

12 CCV 4.973 4.928 .0043 4.902 4.979 9.952 

13 CCB .0112 .0001 .0007 .0002 -.0132 .0372 

^3j 

W 

CL 

O 

3 

D 

U 

3

Analysis Report Averages 

# 

--- 

Sample Name 

-------------------- 

V 

-------- 

Y 

------- 

1 ICV 5.001 .0131 

2 ICB .0005 .0002 

3 ICSA -.0009 .0074 

4 ICSAB .4566 .0071 

5 PREPBLKTJA .0251 0047 

6 S95T001094 L 55.70 10.16 

7 S95T001094- 18.89 4.471 

8 S95T001094 D 29.70 6.828 

9 S95T001094-A 5087. 20.32 

10 ICSA - .0030 .0082 

11 ICSAB .4649 .0083 

12 CCV 5.057 .0139 

13 CCB .0027 .0007 

`1K A 

0 7-0 7- Z5- 

Fri 07-07-95 01:10:49 PM page 4 

Zn 

-------- 

X i cjY s9sTc, ova ^Y 

5.111 4.983 

.0010 .0003 

-.0021 -.0004 

.9505 -.0018 

0581 0023 

106.1 63.68 

82.56 28.59 

74.18 32.46 

5347. 4986. 

-.0018 .0002 

.9671 -.0005 

5.2I2 5.005 

.0002 .0016 

Zr 

-------- -------- -------- 

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06/14/95 13:23 WHC-SD-WM-DP-_L^L, REV, I /Page: I 

A-0004-1 


Analyst: 

JIR I-, rN 

ASrVl J o Instrument: ICPOIJL Book# YVIYU 

â-lt'11 

Method: LA-505-t5tlbl Rev/Mod G-1 










7 OUP S95T001101 0 F @ICP-F03 SOLID 

8 SPK S95T001101.0 F @ICP-F03 SOLID 












S = Worklist Slot Number, R = Replicate Number, A = Aliquot Code. < 

î:3 J

06 /1 4/95 13:23 

A-0004-1 

WHMD-WM-DP^, REV. 


Type Sample #R A Test Matrix Group# Project 



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Page: 2 

_ ,,s joo ll°k` iz , sd0sy pis° l-Y ^^0î°ll^^^%: q?T At 3gylf- 1-114 SSTY t rye Kra #A(6 

Data Entry Comments: 6 

^ 

' .t -n 

4/e ?'0 h.Y-/, 714 X 

iv >Y7,1 


^. 3.:,

Os r°9 t fA. ; ^( 

Analysis Report Summary Ped 07-19-95 11:11:00 AM page 1 

# 

--- 

Sample Name 

---------------- 

File 

---- -------- 

Method 

-------- 

Date 

--------- 

Time 

----- 

OpID 

---- 

Type 

---- 

Mode 

----- 

1 ICV 950719A ICP2 07119195 09:31 DKS Q CONC 

2 ICB 950719A ICP2 07119195 09:38 DKS CONC 

3 ICSA 95O719A ICP2 07119195 09:42 DKS CONC 

4 ICSAB 950719A ICP2 07119195 09:46 DKS p CONC 

5 PREPBLKTJA 9507I9A ICP2 07119195 09:51 DKS S CONC 

6 S95TOO11O1 L 950719A ICP2 07119195 09:56 DKS S CONC 

7 S95T001101 — 950719A ICP2 07119195 10:00 DKS S CONC 

8 S95T001101 D 950719A ICP2 07119195 10:04 DKS S CONC 

9 S95T001101 —A 95O719A ICP2 07119195 10:09 DKS S CONC 

10 CCV — 950719A ICP2 07119195 10:26 DKS CONC 

11 CCB 950719A ICP2 07119195 10:30 DKS CONC 


13 S95T001102 — 950719A ICP2 07%19/95 10:38 DKS S CONC 

14 S95T001102 D 95O719A ICP2 07119195 10:42 DKS S CONC 


16 ICSA — 950719A ICP2 07119195 10:51 DKS CONC 

17 ICSAB 950719A ICP2 07%19/95 10:54 DKS CONC 

18 CCV 1 95O719A ICP2 07119195 11:01 DKS CONC 

19 CCB- 1 950719A ICP2 07119195 11:06 DKS CONC 

07 1 /7- ys 

B •lo Y SSSTo l/o/ 

S^P7v o%a% 

OL 

#/Sys 

W C-MMM-DP-_^, REV. 

r :. :A••:Is 6 :;b :I . • b:19 1 1: 

492

Analvsis Report Averages Wed 07-19-95 11:1I:00 AM page 2 

# - 

Sample Name 

Ag 

---------------- ---- -------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

ICV 5.055 4.833 5.229 4.972 5.003 5.240 

2 ICB .0030 .0019 .0127 .0043 .0002 .0003 

3 ICSA .0011 234.2 .0884 -.0023 .0003 .0004 

4 ICSAB .8780 236.9 .1006 -.0051 .4513 .4753 

5 PREPBLKTJA -.0182 -.0837 .0204 -.0002 .0122 .0006 

6 S95T001101 L 3.927 3903. 194.6 110.1 20.19 2.775 

7 S95T001101 - 10.20 3821. -20.62 46.56 14.49 1.161 

8 S95T001101 D 12.93 3066. -75.06 13.51 11.64 -.3051 

9 S95T001101 -A 2576. 7796. 5393. 4498. 4137. 5019. 

10 CCV - 4.995 4.935 5.081 4.910 4.914 5.083 

11 CCB .0000 -.0086 -.0069 .0018 -.0001 -.0000 

12 S95T001102 L -84.34 593.1 -418.7 4.589 6.588 .2391 

13 S95T001102- -2.394 932.6 -7.084 54.64 13.67 .0822 

14 S95T001102 D -8.848 681.5 -46.85 37.42 9.862 9047 

15 S95T001102-A 2625. 5634. 5163. 4717. 4557. 4903. 

16 ICSA - -.0018 249.5 -.0954 -.0033 .0003 .0002 

17 ICSAB .8364 250.4 -.1440 -.0050 .4596 .4764 

18 CCV 1 5.126 5.077 5.216 5.070 5.078 5.256 

19 CCB -1 -.0011 .0045 -.0107 .0018 -.0000 -.0001 

# 

--- 

Sample Name 

Bi 

----------------- --- -------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

1 ICV 5.187 5.234 5.144 5.149 5.134 5.185 

2 ICB .0236 .0010 .0003 .0001 .0031 .0006 

3 ICSA -.0429 247.0 .0021 .0141 .0008 .0058 

4 ICSAB -.0036 251.6 .9539 .0144 .4674 .4819 

5 PREPBLKTJA -.2115 .1640 -.0097 -.0871 .0298 .0086 

6 S95T001101 L 16790. 680.1 2.250 251.0 43.12 731.1 

7 S95T001101 - 16680. 422.9 -5.749 12.42 39.08 769.9 

8 S95T001101 D 13560. 543.4 -13.81 -12.43 35.79 679.4 

9 S95T001101-A 21560. 6320. 5688. 4346. 5490. 6266. 

7 0 CCV - 4.981 5.143 5.022 5.036 5.057 5.062 

7. CCB -.0179 -.0022 -.0013 -.0092 -.0008 -.0010 

.2 S95T001102 L 13710. 306.1 -43.58 -724.9 24.56 597.7 

13 S95T001102- 13940. 410.4 9.526 97.46 15.97 609.8 

14 S95T001102 D I1860. 309.0 -7.720 -61.63 33.31 528.4 

15 S95T001102-A 18760. 5376. 5014. 4764. 4995. 5612. 

16 ICSA - 0228 245.8 .0010 .0122 .0008 .0059 

17 ICSAB 0143 243.0 .9318 .0069 .4615 4733 

18 CCV 1 5.101 5.261 5.151 5.205 5.175 5.192 

19 CCB - 1 -.0057 .0006 -.0007 .0008 .0000 -.0008 

# 

--- 

Sample Name 

Cu 

---------------- ---- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

1 ICV 4.928 .0064 5.149 4.751 5.074 4.952 

2 ICB .0008 .0010 .0006 -.0179 .0003 .0013 

3 ICSA 0095 -.0307 93.03 .1655 -.0033 .0033 

4 ICSAB .4522 -.0328 94.39 .1647 -.0038 .9073 

5 PREPBLKTJA .0921 .0529 .1208 11650. -.0144 .0458 

6 S95T001101 L 9551 201.4 13040. 7301e3 30.60 175.4 

7 S95T001101 - 28.83 53.99 12930. 6956e3 i -4.837 54.58 

WHGSD-WM-DP- f 7 , REV./ 

433

Analysis Report Averages Wed 07-19-95 11:11:00 AM page 3 

# 

--- 

Sample Name 

Cu 

---------------- ---- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

8 S95TOO1101 D 20.41 75.89 11300. 5774e3 -13.12 70.63 

9 S95TOO1101 -A 4102. 68.09 17890. 6706e3 4256. 3520. 

10 CCV - 4.891 .0071 5.028 5.177 4.975 4.982 

11 CCB -.0011 -.0003 -.0010 1263 0009 0000 

12 S95TOO1102 L 6.073 28.40 12990. 7949e3 -100.8 34.70 

13 S95TOO1102- 24.44 16.61 12720. 7536e3 11.80 28.83 

14 S95TOO1102 D 39.55 17.64 11140. 6528e3 -12.76 28.24 

15 S95TOO1102-A 4663. 18.75 17620. 7626e3 4693. 4654. 

16 ICSA - -.0127 .0098 94.52 .2568 -.0040 0025 

17 ICSAB .4673 .0177 93.69 2572 -.0048 1.001 

18 CCV 1 5.070 .0061 5.156 5.113 5.149 5.147 

19 CCB - 1 -.0006 -.0008 .0000 .0118 .0004 -.0004 

# 

--- 

Sample Name 

Mg 

--------------- ----- -------- 

Mn 

-------- 

Mo 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

1 ICV 4.909 5.022 5.100 4.958 5.094 5.094 

2 ICB .0040 .0008 .0031 0084 .0041 .0010 

3 ICSA 239.8 -.0041 -.0107 191.9 -.0001 0153 

4 ICSAB 243.0 .4487 -.0083 185.3 0027 9031 

5 PREPBLKTJA .2174 .0599 -.0010 3.535 .0389 6.429 

6 S95TOO1101 L 5.908 159.5 16.80 119100. -20.99 9288. 

7 S95T001101- 225.0 105.2 2.214 112600. 37.53 9205. 

8 S95TOO1101 D 201.2 102.3 14.58 103000. 56.91 11730. 

9 S95TOO1101 -A 4497. 5194. 5317. 112200. 4175. 14460. 

10 CCV - 4.926 4.936 5.019 4.963 5.143 5.013 

11 CCB 0080 0001 0009 0026 0033 0095 

12 S95TOO1102 L 151.2 84.35 18.81 125300. -12.52 9017. 

13 S95T001102- 219.3 78.17 12.53 119900. 18.76 9106. 

14 S95TOO1102 D 226.1 80.33 7.063 104200. 34.11 10020. 

15 S95TOO1102-A 4914. 4790. 5009. 127100. 4850. 13980. 

16 ICSA - 254.1 -.0071 -.0045 207.8 .0004 0233 

17 ICSAB 254.1 .4398 -.0100 201.5 0046 8907 

18 CCV 1 5.040 5.041 5.145 5.124 5.335 5.145 

19 CCB - 1 -.00I8 -.0001 .0008 -.0121 -.0010 -.0035 

# 

--- 

Sample Name 

P 

--------------- ----- -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 ICV 5.433 5.153 4.984 4.830 4.952 4.820 

2 ICB .0093 .0165 .0106 .0050 .0149 .0168 

3 ICSA -.0144 .0331 -.0181 0024 0294 .0113 

4 ICSAB .0008 1.015 -.0280 .0071 .0387 .0150 

5 PREPBLKTJA .1041 .0842 .1752 1005 6252 4863 

6 S95TOO1101 L 23810. 271.4 9124. 81.58 1532. 7842. 

7 S95TOO1101 - 24810. 151.4 9481. -79.58 282.8 6960. 

8 S95TOO1101 D 22930. 242.2 9183. -33.56 649.6 6038. 

9 S95TOO1101 -A 31040. 5830. 14610. 4873. 5492. 11810. 

10 CCV - 4.986 5.024 4.991 4.717 4.967 4.945 

11 CCB -.0016 -.0046 -.0052 0003 .0013 0061 

12 S95TOO1102 L 18620. 190.9 7518. -282.6 -389.5 7563. 

13 S95TOOI102- 18720. 100.8 7791. 13.01 -268.8 7436. 

14 S95TOO1102 D 16320. 138.9 6740. -74.12 -165.0 6286. 

15 S95TOO1102-A 23570. 5209. 12790. 4772. 4744. 12290. 

WHGSD-WM-DP--/ZI, REV1 

fl 3 It2


# 

--- 

Sample Name 

-------------------- P 

-------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

ICSA -.0142 .0265 -.0383 -.0037 -.0971 -.0042 

ICSAB .0111 .9656 -.0147 .0060 -.0786 -.0068 

18 CCV 1 5.150 5.134 5.102 4.855 5.131 5.031 

19 CCB-1 .0076 .0023 .0023 -.0046 -.0031 .0004 

# 

--- 

Sample Name 

Sm 

---------------- ---- -------- 

Sr 

-------- 

Th 

-------- Ti 

-------- 

T1 

-------- 

U 

-------- 

1 ICV 4.934 4.980 .0208 4.906 4.955 9.599 

2 ICB .0104 .0001 -.0033 .0004 -.0005 .0470 

3 ICSA .0021 .0018 -.0081 .0015 .1067 -.2481 

4 ICSAB .0069 .0019 -.0026 .0011 .0674 -.2568 

5 PREPBLKTJA .5586 .0133 -.0640 .0116 .1661 -1.291 

6 S95T001101 L 2089. 191.7 -329.1 3.064 -391.8 6882. 

7 S95T001101- 548.4 161.5 -49.21 13.27 -47.57 1111. 

8 S95T001101 D 803.5 134.5 -142.8 14.28 -158.3 2179. 

9 S95T001101 -A 4580. 4339. -111.1 4510. 5138. 9113. 

10 CCV - 4.998 4.903 -.0027 4.809 4.926 9.944 

11 CCB -.0005 -.0000 -.0014 -.0006 .0048 -.0139 

12 S95T001102 L 326.0 144.0 -282.6 15.56 307.0 -1067. 

13 S95T001102- 160.8 128.3 131.5 14.31 40.81 -1099. 

14 S95T001102 D 200.0 110.0 29.93 15.07 -18.41 -787.3 

I5 S95T001102-A 4767. 4745. 80.52 4669. 4829. 7996. 

16 ICSA - -.0080 .0023 -.0038 .0012 .0532 .0011 

17 ICSAB -.0162 .0024 -.0076 .0022 .0309 .0073 

18 CCV 1 5.174 5.085 .0044 4.971 5.045 10.30 

19 CCB - 1 -.0078 -.0009 .0070 .0004 .0150 -.0361 

# 

--- 

Sample Name 

-------------------- V 

-------- 

Y 

-------- 

Zn 

-------- 

2 ICB 50033 .0006 50011 40038 

3 ICSA .0039 .0080 -.0020 .00I0 

4 ICSAB .4613 .0085 .9742 .0009 

5 PREPBLKTJA .1395 .0314 .0465 .1017 

6 S95T001101 L 503.0 126.7 125.8 386.4 

7 S95T001101 - 139.5 34.03 106.2 111.8 

8 S95T001101 D 197.3 48.81 86.45 169.6 

9 S95T001101 -A 5097. 52.56 5651. 4733. 

10 CCV - 4.953 .0133 5.003 4.920 

11 CCB -.0004 -.0001 -.0003 -.0001 

12 S95T001102 L 74.82 15.67 136.5 86.20 

13 S95T001102- 41.56 9.793 113.3 27.73 

14 S95T001102 D 43.03 10.36 108.2 30.70 

15 S95T001102-A 4876. 19.98 5155. 4771. 

16 ICSA - -.0026 .0076 .0008 -.0031 

17 ICSAB .4573 .0071 .9983 -.0032 

18 CCV 1 5.105 .0131 5.107 5.075 

19 CCB-1 -.0012 -.0005 .0014 -.0014 

Zr 

-------- -------- -------- 

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06/28/95 09:25 Page: 1 

A-0004-1 


Analyst: 16 Instrument: ICPO1 Book# i>'s 5' 

Method: LA-505-151 Rev/Mod d - Z- 

Worklist Comment: ICP B-104 FUSION (Li only) 

WHGSD WM DP 























REV.

06/28/95 09:25 WHC-SD-WM-DP- I , REV. Page: 2 

A-0004-1 


i Type Sample# R A Test Matrix Group# Project 


ArtAl2jst -Signature Date Analyst Signature Date 

to c /, 4 - 5- C 

b"--. 

5gsrw//o9 -c X..f7,-rJ ;r Z,v.0 -/ c- g-c-i c y_r iZS -^> 

Sgfrw1/vY 1-F^7Sg ,.^ Z^v c -/ c-^C Zy"o 

1; 93-,r ^_ J^ 1. P7^3g y v c -/ L - S ( srvo 

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593-Too 1110 

/. 0IG9f 

59tia^ i 0/s7 '^ 


3sza-- 


r^ 

uUi 

/O

Identity 1: ICV Identity 2: Quality Control 9:56 AM July 21, 1995 


Semple Weight : 1.0000 Solution Volume 1.00 

On-P•ak Integrations : 3 Off-Peek Integrations : 1 WHGSD-WM-DP-I, REV. 

_______________________________________ _______________________________ 

2R SR 81 Si AL CO CU LI 

(Ppm ) (Ppm) (Ppm) (ppm) (Ppn) (Ppm) (ppm) (ppm) 

Mean _ 4.935 4.974 4.936 4.778 4.928 5.055 4.841 5.003 

S.D. 0.008 0.008 0.010 0.012 0.015 0.011 0.019 0.068 

% R.S.D. 0.167 0.171 0.207 0.246 0.308 0.213 0.391 1.351 

ZN NI LA FE CA CA NO U 

(Ppm ) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppn) (PPIR ) 

Mean 5.053 4.999 5.033 5.101 5.174 5.085 5.256 9.645 

S.D. 0.008 0.014 0.010 0.011 0.011 0.011 0.008 0.030 

% R.S.D. 0.160 0.276 0.208 0.207 0.211 0.210 0.146 0.306 

CE SM SA P S MG AS NA 

(Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 4.979 5.007 4.980 5.062 4.952 5.046 4.945 4.972 

S.D. 0.011 0.018 0.012 0.155 0.058 0.008 0.009 0.069 

% R.S.D. 0.219 0.351 0.231 3.054 1.163 0.166 0.178 m 1.382 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 5.048 4.867 4.914 4.969 4.882 5.064 5.063 5.037 

S.D. 0.007 0.006 0.009 0.019 0.004 0.005 0.007 0.093 

% R.S.D. 0.147 0.132 0.193 0.392 0.086 0.096 0.137 1.838 

MN SB V BE TL 


Mean 5.044 4.784 5.046 5.167 4.828 

S.D. 0.012 0.042 0.008 0.005 0.012 

% R.S.D. 0.231 0.868 0.150 0.101 0.246 

• ^• :• • :^• • :^.J (. M:1: 1 iD •:1 • • •:I:r is 

a• ^• 4SI ?: s1 6: • ti • N:ti ^. • 

5 V iV 

1Î1Wt 

Vf 

^ I S, 

^^ 

'7 ^l rJyq r1J 14 

1 l 0 07^ 

Fo , 0 3 cj^ 

557 r L^

Identity 1: te1- Identity 2: Ouality Control 9:58 AM July 21, 1995 

Ta-' name : TWC93 

5 Weight : 1.0000 Solution Volume 1.00 

On-reek Integrations : 3 Ott-Peak Integrations : 1 

---------------------------------------------------------------------- 

ZR SR BI SI 


Mean -0.002 0.000 0.006 -0.004 

S.D. 0.000 0.000 0.015 0.001 

% R.S.D. 22.040 34.532 251.248 26.822 

ZN NI LA FE 


Mean 0.001 0.000 -0.002 0.003 

S.D. 0.000 0.002 0.003 0.001 

K R.S.D. 20.608 620.159 152.525 21.011 

CE SM BA P 


Mean -0.010 -0.017 -0.000 -0.011 

S.D. 0.004 0.003 0.000 0.002 

% R.S.D. 42.235 15.321 4.456 22.565 

NO SE AG PB 

(pp) (pp) (ppm) (ppm) 

Mean 0.003 -0.040 -0.001 -0.019 

S.D. 0.002 0.008 0.000 0.004 

% R.S.D. 66.656 18.652 33.638 23.387 

MN S8 9 BE 

(Ppm) (ppm) (Ppm) (ppn) 

Mean -0.000 0.008 -0.002 0.000 

S.D. 0.000 0.032 0.001 0.000 

% R.S.D. 76.109 389.397 61.928 24.782 

WHGSD-WM-DP- `^ I , REV. I 

AL CO CO L) 


0.001 0.002 0.000 -0.000 

0.001 0.002 0.000 0.000 

130.761 86.024 102.106 199.039 

CA CR ND 0 


0.000 -0.000 0.010 -0.095 

0.000 0.001 0.002 0.024 

25.000 134.397 20.683 25.232 

S MG AS NA 


0.003 0.000 0.002 0.004 

0.005 0.000 0.005 0.003 

166.728 34.915 216.628 76.371 

TI CD B K 

(Ppm) (Ppm) (ppm) (ppm) 

-0.000 -0.000 0.003 -0.031 

0.000 0.001 0.000 0.007 

102.373 410.672 12.847 21.951 

TL 

(ppm) 

-0.036 

0.009 

26.193 

503

Id en tity 1: ICSA Identity 2: Quality Control 10:01 AM July 21, 1995 




Off-Peak Integrations : i 

WHGSD-WM-DP-^, REV. 

--------------------------------------------------------------------- 



Mean -0.001 0.000 0.008 0.059 199.568 0.006 -0.014 -0.000 

S.D. 0.001 0.000 0.007 0.002 0.426 0.002 0.000 0.000 

% R.S.D. 112.838 24.905 85.168 2.912 0.214 24.696 1.549 621.853 


(ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.000 -0.047 0.009 149.577 19.131 -0.011 0.017 0.051 

S.D. 0.000 0.001 0.003 0.482 0.091 0.001 0.006 0.044 

% R.S.D. 985.616 2.763 34.657 0.322 0.474 6.121 34.826 86.668 


( ppm ) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.012 0.002 0.003 0.008 0.151 19.347 -0.001 187.921 

S.D. 0.007 0.013 0.000 0.006 0.005 0.032 0.003 0.677 

% R.S.D. 56.592 855.779 5.753 77.082 3.079 0.163 231.020 0.360 

MO SE AG PIT TI CD e K 

(ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean -0.004 -0.034 -0.001 -0.006 0.000 0.011 -0.047 -0.024 

S.D. 0.001 0.004 0.000 0.022 0.001 0.001 0.000 0.022 

% R.S.D. 15.372 11.488 35.941 355.294 108.901 4.954 0.593 90.409 

MN SB V BE TL 

(Ppm) (Ppm) (ppm) (PPRI ) (Ppm) 

Mean 0.010 -0.029 -0.005 0.003 -0.037 

S.D. 0.000 0.010 0.001 0.000 0.012 

2 R.S.D. 0.545 35.595 11.947 4.123 32.123 

!;O "


T p -' nrae : TWC93 

Weight : 1.0000 Solution Volume 1.00 

On- peak Integrations : 3 


-------------------------------------------------------------------- 

WHGSD-WM-DP-__1jj, REV. 

2R SR BI S( AL CO CU LI 


Mean -0.002 -0.000 -0.016 0.052 200.824 0.510 0.486 0.948 

S.D. 0.001 0.000 0.012 0.002 0.801 0.003 0.002 0.003 

% R.S.O. 57.477 30.357 74.456 2.966 0.399 0.604 0.389 0.342 


(ppm) (Ppm) (ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 1.021 0.958 0.007 152.079 18.922 0.504 0.010 0.073 

S.D. 0.002 0.005 0.002 0.550 0.075 0.004 0.003 0.022 

% R.S.D. 0.164 0.503 25.972 0.361 0.397 0.826 32.010 30.348 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 0.018 0.010 0.512 -0.002 0.171 19.150 0.006 189.573 

S.D. 0.008 0.005 0.002 0.009 0.005 0.024 0.005 0.605 

% R.S.D. 42.629 43.693 0.393 569.513 3.160 0.124 77.164 0.319 

M0 BE AG PB TI CD B K 

(Ppa) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean -0.002 0.093 1.035 1.022 0.001 1.045 -0.046 -0.025 

S.D. 0.001 0.008 0.002 0.011 0.000 0.002 0.001 0.009 

% R.S.D. 40.206 8.785 0.237 1.080 53.718 0.183 1.825 37.848 

MN SB V BE TL 

(ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.527 -0.003 0.513 0.515 -0.013 

S.D. 0.002 0.014 0.001 0.001 0.011 

% R.S.D. 0.391 

490.641 0.198 0.126 

--------------------------------------------------------------- ---- --- 

85.578 

505

Identity 1: PREPBLK Identity 2: Ouality Control 10:07 AM July 21, 1995 


Sample Weight : 1.0000 Solution Voluae 10.00 


WHC-SD-WMREV. 

-DP-^, 

------------------------------------------------------------ - --------- 

2R SR 81 SI AL CO Cu LI 

(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 0.001 0.009 -0.082 1.171 0.395 0.009 0.019 0.000 

S.D. 0.003 0.001 0.046 0.036 0.144 0.015 0.002 0.000 

% R.S.D. 235.829 6.173 55.843 3.075 36.528 177.506 10.689 55356.722 


(Ppm ) (ppm) (ppm) (ppm) Iwo) (ppm) (ppm) (Ppm) 

Mean 0.387 2.578 0.025 0.513 0.376 0.004 -0.062 -0.212 

S.D. 0.005 0.030 0.014 0.127 0.021 0.013 0.119 0.142 

% R.S.D. 1.278 1.172 57.736 24.676 5.687 299.662 190.974 66.921 


(Ppm ) (ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (PPm) 

Mean 0.113 -0.003 0.016 -0.153 0.115 0.148 0.025 4.753 

S.D. 0.013 0.057 0.000 0.198 0.025 0.017 0.036 0.163 

% R.S.D. 11.341 2008.393 3.066 128.928 21.745 11.225 141.674 3.422 

M0 SE AG PI( TI CD 8 • K 


Mean -0.011 -0.193 0.003 -0.035 0.008 0.054 0.032 10980.834 

S.D. 0.003 0.077 0.003 0.067 0.007 0.008 0.006 60.795 

% R.S.D. 31.458 39.972 78.626 190.212 88.806 14.171 19.898 0.554 

MN SB V BE TL 

( pPm ) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.064 -0.321 -0.019 0.005 -0.107 

S.D. 0.002 0.223 0.003 0.001 0.032 

It R.S.D. 2.461 69.309 15.572 21.605 29.895

Identity is S95T001109_L Identity 2: 2.87759in250-1-9 . 1 . 4 10:11 AM July 21, 1995 


s Weight : 2.8775 Setution yatuee : 12500.00 WHC-SD-WM-DP- 

On .-ak Integrations : 3 Off-Peak Integrations : 1 

(^ l , REV.) 

---------------------------------------------------------------------- 

2R 


(Ppm ) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 9.222 129.072 10078.565 4497.370 1237.727 18.962 9.303 3.426 

S.D. 1.743 0.000 25.546 8.934 35.452 6.688 0.621 0.271 

% R.S.D. 18.896 0.000 0.253 0.199 2.864 35.272 6.674 7.909 


(Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 74.130 1053.476 11.419 9802.780 288.897 401.250 -46.022 1857.198 

S.D. 2.825 15.968 16.269 67.087 0.999 4.921 24.955 6.703 

% R.S.D. 3.811 1.516 142.473 0.684 0.346 1.226 54.223 0.361 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean -10.017 -96.405 6.732 17033.129 6848.934 143.377 39.226 125102.119 

S.D. 15.285 14.717 0.136 616.921 54.339 0.415 15.284 367.256 

% R.S.D. 152.600 15.266 2.024 3.622 0.793 0.289 38.964 0.294 

No SE AG PB TI CD B • K 

(Ppm ) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean -12.385 113.337 -4.927 8.139 2.236 2.268 43.237 924443.517 

S.D. 2.383 27.279 0.679 25.604 0.911 2.625 3.169 2195.920 

X R.S.D. 19.245 24.069 13.779 314.570 40.730 115.730 7.330 0.238 

MN SB V BE TL 

(ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 29.175 -17.317 -13.656 0.442 -224.408 

S.D. 1.176 49.065 2.866 0.466 10.425 

% R.S.D. 4.030 283.325 20.984 105.316 4.646 

------------------••--------------------------------------------------

Identity 1: S957001109 Identity 2: 2.8775 9 in250-1-9 10:15 AM July 21, 1995 


Sample Weight : 2.8775 Solution Velure : 2500.00 WHGSD-WM-DP- /Î., REV._j,_ 

On-Peak Integrations : 

3 Off-Peak Integrations : 1 

---.-------------------••---------------•---------------------------- 

ZR SR BI $ I AL CO Cu LI 

(Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 17.118 128.820 10363.732 4574.133 1279.895 0.373 7.686 1.546 

S.D. 1.009 0.426 33.363 11.913 3.308 1.336 0.203 0.195 

X R.S.D. 5.892 0.330 0.322 0.260 0.258 357.985 2.638 12.639 

ZN NI LA FE CA CR ND 0 

(ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 70.273 1071.077 -2.239 9947.305 230.795 416.742 8.752 2295.941 

S.D. 0.574 4.415 1.069 15.470 0.427 6.030 2.408 20.237 

% R.S.D. 0.817 0.412 47.731 0.156 0.185 1.447 27.517 0.881 


(ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 33.797 -3.992 8.462 17398.212 7017.435 125.891 1.005 118029.847 

S.D. 6.154 5.492 0.123 538.896 54.736 0.432 1.153 430.712 . 

% R.S.D. 18.210 137.567 1.448 3.097 0.780 0.343 114.724 , 0.365 


(ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean -0.511 40.127 -0.171 70.753 3.758 3.498 34.545 855736.665 

S.D. 0.447 8.443 0.754 5.884 0.229 0.430 1.038 2671.022 

% R.S.D. 87.368 21.039 441.766 8.316 6.099 12.289 3.004 0.312 


(ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 33.237 1.495 2.791 0.483 -31.795 

S.D. 0.235 17.411 0.210 0.092 7.583 

X R.S.D. 0.708 1164.600 7.520 19.098 23.848 

508

Identity 1: S95TOO1109_D Identity 2: 2.87139in250-1-9 

T•-' name : TWC93 


on-reek Integrations : 3 Off-Peak 


-------------------------------------------------------- 

2R SR BI 


Mean 19.016 133.340 10799.157 

S.D. 0.983 0.547 51.995 

X R.S.D. 5.171 0.410 0.481 

10:19 AM July 21, 1995 

WHC-SD-WM-DP- 131_, REV. 


(ppm) (ppm) (Ppm) (Ppm) (ppm) 

4759.754 1309.030 4.198 10.685 1.422 

18.289 9.558 0.003 0.273 0.113 

0.384 0.730 0.081 2.558 7.954 

2N NI LA 

FE CA CR NO u 


(Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 73.001 1308.439 3.582 1 0284.273 247.661 427.138 8.294 2479.452 

S.D. 0.627 9.778 0.625 

% R.S.D. 0.859 0.747 17.440 

CE SM BA 

26.132 0.742 2.769 3.844 19.284 

0.254 0.300 0.648 46.350 0.778 

P S MG AS NA 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 41.829 23.441 9.315 1 7087.975 6932.878 130.299 6.715 118569.277 

S.D. 3.781 8.940 0.085 

% R.S.D. 9.039 38.137 0.909 

MO SE AG 


Mean 0.827 30.578 1.464 

S.D. 0.583 5.905 0.539 

% R.S.D. 70.470 19.313 36.790 

MN 58 V 


Mean 35.399 -16.468 4.350 

S.D. _ 0.409 9.519 0.372 

% R.S.D. 

1.156 57.803 

8.555 

------------------------------- -------------------- ----- 

320.325 71.751 0.600 2.712 325.209 

1.875 1.035 0.461 40.386 0.274 

PB TI CD B K 


44.146 4.881 2.209 34.307 888045.893 

9.588 0.405 1.050 0.966 3674.816 

21.718 8.299 47.531 2.816 0.414 

BE TL 

( ppm) (Ppm) 

0.609 23.667 

0.093 24.717 

15.315 104.437

Identity 1: S957001109_A Identity 2: 2.8775gin250 . 1 . 2-7 10:22 AN July 21, 1995 


Sample Weight : 2-8775 solution 9oLme : 2500.00 WHC-SD-WM-DP - REV. 



---------------------------------------------------------------------- 

ZR SR III SI AL CO CO LI 


Mean 882.213 996.211 11245.988 5350.657 2140.848 864.771 857.614 795.898 

S.D. 2.024 3.999 34.924 14.765 8.789 6.687 4.480 5.926 

% R.S.D. 0.229 0.401 0.311 0.276 0.411 0.773 0.522 0.745 


(Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (pPm) (Ppm) 

Mean 896.856 1916.809 892.228 10851.814 1133.755 1288.428 921.717 4145.448 

S.D. 0.291 9.372 6.769 26.981 4.560 4.067 5.752 14.777 

% R.S.D. 0.032 0.489 0.759 0.249 0.402 0.316 0.624 0.356 



Mean 895.465 878.583 872.857 18149.560 7796.266 979.310 849.273 121536.775 

S.D. 6.023 1.503 4.127 765.486 138.928 0.659 5.663 914.017 

It R.S.D. 0.673 0.171 0.473 4.218 1.782 0.067 0.667 0.752 


(ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 862.307 906.218 141.563 920.537 851.330 863.852 873.792 878563.710 

S.D. 3.571 6.775 0.843 8.262 1.500 3.012 5.572 5445.531 

% R.S.D. 0.414 0.748 0.596 0.897 0.176 0.349 0.638 0.620 

MN Se V BE TL 

(Ppm ) (PPM) (PPm) (PPM) (PPIN) 

Mean 906.946 771.364 883.612 848.713 872.303 

S.D. 1.418 13.325 0.921 2.103 13.588 

It R.S.D. 

0.156 1.727 0.104 

0.248 1.558 

---------------------------------------- -------------•---------- ------



S Weight : 1.0000 

On,-ak Integrations : 3 

Solution volume : 


1.00 

1 

WHC-SD-WM-DF , REV. 

_______________________________________ _______________ ________________ 


( ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 4.945 4.985 4.933 4.767 4.897 5.011 4.883 5.020 

S.D. 0.019 0.017 0.023 0.003 0.005 0.008 0.011 0.041 

% R.S.D. 0.390 0.344 0.464 0.060 0.100 0.162 0.227 0.812 

2M NI LA FE CA CR ND u 

(Ppm) (PPm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 5.018 4.988 5.112 5.165 5.218 5.056 5.469 9.716 

S.D. 0.005 0.015 0.008 0.009 0.014 0.015 0.020 0.041 

% R.S.D. 0.097 0.299 0.155 0.173 0.269 0.302 0.362 0.423 

CE SM BA P S MG AS MA 

(Ppm) (Ppm) (Ppm) (Ppm) (Piss) (Ppm) (ppm) (PPm) 

Mean 4.952 4.974 5.006 5.485 5.129 5.001 4.923 5.024 

S.D. 0.013 0.014 0.017 0.135 0.052 0.015 0.026 0.038 

It R.S.D. 0.255 0.280 0.341 2.469 1.014 0.304 0.531 0.758 


(Ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 4.988 4.942 5.009 5.012 4.870 5.047 5.121 5.220 

S.D. 0.018 0.019 0.011 0.044 0.016 0.007 0.014 0.058 

% R.S.D. 0.359 0.390 0.214 0.883 0.322 0.138 0.278 1.119 

MN s8 V BE TL 

(Ppm) (Ppm) (Ppm) (Ppm) (Pps) 

Mean 5.043 4.732 5.049 5.170 4.829 

S.D. 0.014 0.022 0.016 0.013 0.011 

% R.S.D. 0.282 0.456 0.314 0.259 0.232 

c s^ 

J.,,i

Identity 1: CCB Identity 2: Quality Control 10:29 AM July 21, 1995 


Sample Weight : 1.0000 Solution voluae : 1.00 



WHC-SD-WM-DP-_jE, REV. 

---------------------------------------------------------------------- 

ZR SR 61 Sl AL CO CU LI 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.000 0.000 -0.005 -0.000 -0.017 0.001 -0.000 0.000 

S.D. 0.001 0.000 0.004 0.004 0.004 0.002 0.000 0.000 

% R.S.D. 1423.760 34.580 74.581 1113.934 24.584 172.716 151.343 98.277 



Mean 0.001 -0.001 -0.000 0.002 0.000 -0.001 -0.004 -0.027 

S.D. 0.001 0.001 0.001 0.001 0.000 0.001 0.008 0.017 

% R.S.D. 103.935 157.T61 14078.016 25.397 41.660 108.300 217.581 61.764 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean -0.001 -0.000 -0.000 -0.018 0.001 0.000 0.003 0.025 

S.D. 0.002 0.007 0.000 0.017 0.002 0.000 0.003 0.003 

% R.S.D. 125.681 2789.355 1501.557 92.872 153.336 173.669 79.653 12.385 

NO SE AG PIT TI CD B • K 


Mean 0.002 -0.033 0.004 -0.009 -0.000 -0.001 0.003 0.076 

S.D. 0.001 0.003 0.001 0.007 0.000 0.000 0.001 0.012 

% R.S.D. 46.176 10.628 30.205 79.447 277.378 16.647 47.504 15.588 

MN SIT v BE TL 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.000 -0.054 -0.002 0.001 -0.029 

S.D. 0.000 0.011 0.001 0.000 0.005 

% R.S.D. 0.989 20.936 33.671 33.761 18.777

Identity 1: S95TOO1110_L Identity 2: 1.01279 in250-1-9-1-4 


S Weight : 1.0127 Solution Volume : 12500.00 

On-.eak Integrations : 3 

Off-Peak Integrate ons : 1 

----------------------------------------------------------------- 

2R SR 8 1 SI 

( Ppm ) (Ppm) (Ppm) (Ppm) 

Mean 3.322 159.881 7790.314 4597.925 

S.O. 22.292 0.664 208.592 34.681 

% R.S.D. 671.067 0.416 2.678 0.754 

2N NI LA FE 


Mean 176.034 3196.371 -27.096 10354.278 

S.D. 9.604 20.098 23.214 60.794 

% R.S.D. S.455 0.629 85.670 0.587 

CE SM BA P 

(ppm) (Ppm) (Ppm) (Ppm) 

Mean -150.762 -159.397 12.355 18229.108 

S.D. 149.283 164.997 3.414 662.717 

% R.S.D. 99.019 103.513 27.629 3.635 

NO SE AO P8 

( Ppm ) (Ppm) (ppm) (PPM) 

Mean -8.379 -411.058 -1.060 179.330 

S.D. 9.819 54.987 5.888 194.228 

% R.S.D. 117.189 13.377 555.275 108.308 

MN SB V BE 

( ppm ) (ppm) (Ppm) (Ppm) 

Mean 45.740 -149.314 -27.228 4.884 

S.D. 3.843 238.891 14.682 0.067 

% R.S.D. 

8.402 159.992 

53.923 1.377 

------------------------------°-. _-----------------------------. 

10:33 AM July 21, 1995 

WHGSD-WM-DP-_L^ I REV. 

AL CO Cu L) 

(Ppn) (Ppm) (Ppm) (Ppm) 

1294.536 10.251 21.713 5.892 

93.909 18.918 9.012 2.774 

7.254 184.539 41.505 47.084 

CA CR ND u 


543.568 380.372 -23.055 3262.252 

1.235 18.377 104.234 719.125 

0.227 4.831 452.116 22.044 

S MG AS NA 


6963.611 215.971 88.249 125609.701 

153.853 2.374 21.515 1090.503 

2.209 1.099 24.380 0.868 

TI CD B K 


-0.974 -8.496 52.540 2642657.484 

10.558 9.015 3.696 24637.176 

1084.372 106.105 7.034 0.932 

TL 

(Ppm) 

-781.328 

204.217 

26.137 

CA •) 

.J ^c.A

Identity 1: S95TOO1110 Identity 2: 1-0127gin250-1-9 10:36 AM July 21, 1995 


Sample Weight : 1.0127 Solution Volune : 2500.00 WHGSD-WM-DP- I REV- 


---------------------------------------------------------------------- 


( ppm ) (Ppm) (Ppm) (Ppm) (ppm) (plan) (plan) (Ppm) 

Mean 17.029 161.736 7912.514 4516.022 1323.133 10.160 23.184 0.398 

S.D. 2.459 0.712 39.828 18.666 9.423 3.795 0.286 0.154 

X R.S.D. 14.437 0.440 0.503 0.413 0.712 37.351 1.234 38.670 


(Ppm) (PPM) (Ppm) (Ppm) (Ppm) (Plan) (ppm) (Ppm) 

Mean 167.364 3303.091 7.514 10575.844 388.286 409.015 2.304 3885.023 

S.D. 1.592 23.109 0.017 23.117 1.570 5.192 18.702 50.581 

X R.S.D. 0.951 0.700 0.226 0.219 0.404 1.269 811.826 1.302 

CE SM BA P S NO AS NA 

(Ppm) (ppm) (PPM) (Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 6.833 29.074 14.244 19138.801 6803.012 163.137 32.732 118847.743 

S.D. 9.868 13.308 0.339 538.794 38.739 0.408 3.496 479.639 

% R.S.D. 144.429 45.772 2.378 2.815 0.569 0.250 10.681 0.404 

Mean 

NO 

( Ppm) 

-2.905 

SE 

(ppm) 

72.099 

AO 

(PPM) 

2.807 

PB 

(PPM) 

265.657 

it 

(ppm) 

9.454 

CD 

(Plan) 

-3.209 

8 

(ppm) 

40.377 

• K 

(Ppm) 

2490082.875 

S.D. 2.039 15.284 1.129 8.736 1.054 1.490 2.692 6455.901 

% R.S.D. 70.186 21.199 40.219 3.289 11.154 46.429 6.667 0.259 

MN SB V BE TL 

( plan ) (Ppm) (Ppm) (PPM) (Ppm) 

Mean 51.735 -22.057 2.913 0.363 22.953 

S.D. 0.386 57.782 1.176 0.457 46.919 

% R.S.D. 0.747 261.972 40.384 125.905 204.411 

r-1 7 

S i

Identity 1: S95T001110 0 Identity 2: 1.0189gin250-1-9 10:40 AM July 21, 1995 


Ss #eight : 1.0189 Solution Volume 2500.00 

on-,integrations 3 Off-Peak Inte rations 1 

_ ____________ 

___ 

_____-_________.__________.___ g 

WHGSD-WM-DP- # / r , REV,. 

ZR SR 8I SI AL CO Cu LI 

(Ppm) (Ppm) (PPM) (Ppm) (ppm) (ppm) (ppm) (PP10) 

Mean 8.702 166.306 8620.472 4579.330 1375.533 12.336 15.939 1.467 

S.D. 3.024 0.135 39.487 11.109 9.127 0.013 0.972 0.930 

% R.S.D. 34.746 0.081 0.458 0.243 0.664 0.108 6.099 63.445 

2N II I LA FE CA CR ND u 

(PP10 ) (Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) 

Mean 162.772 2511.697 1.538 10820.273 361.441 414.569 25.259 3946.997 

S.D. 1.602 11.140 5.258 27.091 0.835 4.171 16.972 106.750 

% R.S.D. 0.984 0.444 341.862 0.250 0.231 1.006 67.193 2.705 


(Ppm) (Ppm) ( 131310) (ppm) (ppm) (Ppm) (Ppm) (ppm) 

Mean -9.100 8.958 14.874 18615.322 6807.963 162.011 6.476 120474.797 

S.D. 17.681 24.686 0.482 191.140 51.730 0.237 9.490 692.518 

% R.S.D. 194.285 275.569 3.239 1.027 0.760 0.146 146.553 0.575 

M0 SE AG PB TI CD B • K 


Mean -5.441 81.065 0.714 272.075 8.847 4.782 34.726 2777749.695 

S.D. 1.539 18.073 0.932 23.533 0.400 0.584 1.899 13369.788 

% R.S.D. 28.278 22.294 130.617 8.650 4.522 12.216 5.469 0.481 

MN SB V BE TL 


Mean 54.722 33.146 1.492 1.431 -5.813 

S.D. 1.390 60.281 1.286 0.266 57.361 

% R.S.D. 2.540 181.865 86.209 18.564 986.820 

[" -o r 

., ^ J

Identity 1: 5957001110 A Identity 2: 1.0127gin2S0-1-2-7 10:43 AM July 21, 1995 


Sample Weight : 1.0127 Solution Volume : 2500.00 q 


WHC-SD-WM-DP- I (, REV. 

---------------------------------------------------------------- - ----- 



Mean 2440.309 2596.322 10306.227 6670.507 3731.291 2451.027 2400.850 2206.830 

S.D. 2.605 5.708 24.808 12.061 3.311 3.807 5.321 10.779 

% R.S.D. 0.107 0.220 0.241 0.181 0.089 0.155 0.222 0.488 

2M M1 LA FE CA CR MD u 

(PPM ) (ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 2491.253 5668.596 2513.395 13064.050 2873.551 2904.964 2656.648 8322.925 

S.D. 5.795 9.508 17.183 22.738 5.339 8.978 8.304 110.655 

% R.S.D. 0.233 0.168 0.684 0.174 0.186 0.309 0.313 1.330 


(ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 2416.130 2349.998 2439.036 19977.000 8946.813 - 2573.733 2378.274 122333.059 

S.D. 27.832 29.690 6.851 413.032 41.659 5.122 33.512 581.737 

% R.S.D. 1.152 1.263 0.281 2.068 0.466 0.199 1.409 0.476 


(ppm) (Ppm) (ppM) (ppm) (ppm) (ppm) (PPM) (ppm) 

Mean 2426.933 2331.104 387.266 2767.473 2387.908 2435.902 2410.474 2512397.100 

S.D. 7.795 13.912 4.231 46.080 2.387 3.459 8.719 8428.877 

% R.S.D. 0.321 0.597 1.093 1.665 0.100 0.142 0.362 0.335 

MM SB V BE TL 

(Ppm) (ppm) (PPM) (Ppm) (ppm) 

Mesh 2515.753 2284.077 2479.174 2396.263 2232.664 

S.D. 3.317 81.126 2.369 4.112 86.716 

% R.S.D. 

0.132 3.552 0.096 

0.172 

3.884 

---------------------------------------- ---------------------- -- ------


Tas' -Mae : TWC93 

So Aeignt : 1.0000 Solution volume 1.00 


Off-Peak 


--------------------------- ----------- -------------- ------- "'--- ----- 

1 

WHC-SD-WM-DP- ^+ REVLl 

ZR SR 61 SI AL CO Cu 

(Ppm ) (Ppm) (Ppm) (Ppm) (Pp) (Ppm) (ppm) 

Mean -0.001 0.000 0.019 0.058 200.031 0.009 -0.014 

S.D. 0.001 0.000 0.008 0.002 0.235 0.002 0.000 

X R.S.D. 55.492 12.307 42.945 3.509 0.118 17.365 1.876 


( ppm ) (Ppm) (pPm) (Ppm) (ppm) (ppm) (Pp^) 

Mean 0.001 -0.047 0.009 150.192 19.158 -0.013 0.008 

S.D. 0.001 0.001 0.002 0.131 0.025 0.001 0.007 

% R.S.D. 73.084 1.306 21.414 0.087 0.129 7.192 84.823 


(Ppm ) (PPM) (Ppm) (Ppn) (Ppm) (Ppa) (ppm) 

Mean 0.011 -0.004 0.003 0.020 0.153 19.342 0.016 

S.D. 0.005 0.006 0.000 0.019 0.001 0.030 0.002 

% R.S.D. 47.817 168.472 3.263 92.579 0.658 0.157 14.543 

NO SE AG PS TI CD B 

( ppm ) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.003 -0.042 -0.001 0.017 0.000 0.009 -0.045 

S.D. 0.001 0.011 0.000 0.003 0.000 0.000 0.001 

% R.S.D. 36.101 27.358 84.055 16.739 52.136 2.319 2.003 

MN 58 9 BE TL 

( ppm ) Opal ) (Ppm) (Ppm) (Ppm) 

Mean 0.010 -0.016 -0.005 0.003 -0.042 

S.D. 0.000 0.004 0.000 0.000 0.009 

% R.S.D. 

2.974 26.192 6.448 

4.031 

---------------------------------------- ------------------ -------- ---- 

21.134 

r^ 'Y 

L 

(Ppm) 

0.000 

0.000 

160.852 

u 

(Ppm) 

0.045 

0.030 

67.496 

NA 

(ppm) 

188.319 

K 

(Ppm) 

0.636 

0.338 

0.223 

0.016 

7.192

Identity 1: ICSAI Identity 2: Quality Control 10:48 AM July 21, 1995 

Task name : TVC93 



WHC-SD-WM-DP-13 REV. 

---------------------------------------------------------------------- 


(Ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.003 0.000 -0.011 0.046 199.414 0.510 0.480 0.932 

S.D. 0.001 0.000 0.010 0.001 0.576 0.002 0.002 0.006 

X R.S.D. 29.650 42.940 82.766 1.613 0.289 0.302 0.431 0.674 


( ppm ) (PPM) (Ppm) (ppm) (Ppm) (PPm) (Ppm) (ppm) 

Mom 1.024 0.950 0.005 153.134 18.784 0.505 0.022 -0.054 

S.D. 0.003 0.001 0.001 0.244 0.046 0.002 0.009 0.012 

% R.S.D. 0.269 0.151 23.112 0.160 0.243 0.426 41.665 22.512 


(PPM ) (PPM) (ppm) (PPM) (PPM) (PPM) (PPM) (PPM) 

Mean 0.004 -0.020 0.503 0.011 0.168 19.086 0.014 186.922 

S.D. 0.007 0.002 0.001 0.013 0.003 0.006 0.006 1.241 

It R.S.D. 196.695 8.995 0.195 114.423 1.931 0.032 38.702 0.664 


(PPM ) (PPM) (PPM) (PPM) (PPM) (PPM) (PPM) (PPM) 

Mean -0.003 0.076 1.037 1.025 -0.000 1.039 -0.046 0.157 

S.D. 0.002 0.008 0.001 0.019 0.000 0.001 0.001 0.013 

% R.S.D. 58.468 10.861 0.096 1.892 452.377 0.089 1.819 7.982 

MN SB V BE TL 

(PPM ) (PPM) (PPM) (PPM) (ppm) 

Mean 0.526 -0.035 0.508 0.509 -0.079 

S.D. 0.001 0.024 0.001 0.001 0.014 

% R.S.D. 0.151 67.601 0.194 0.159 17.810 

.rri^

Identity 1: CCV_1 Identity 2: CCV_1 10:52 AM July 21, 1995 


S4 Weight : 1.0000 Solution Volume 1.00 

On-.-nk Integrations : 3 Off-Peak 


------------------------------------------------------------------- 

2R SR BI SI 

(Ppm ) (Ppm) (ppm) (Ppm) 

Mean 4.973 4.991 4.964 4.824 

S.D. 0.006 0.010 0.025 0.007 

% R.S.D. 0.115 0.207 0.509 0.148 

2N NI LA FE 


Mean 5.117 5.073 5.121 5.213 

S.D. 0.010 0.007 0.025 0.019 

% R.S.D. 0.195 0.140 0.481 0.366 

CE SM BA p 


Mean 4.984 4.987 4.993 5.743 

S.D. 0.003 0.016 0.013 0.176 

% R.S.D. 0.069 0.320 0.268 3.064 

NO SE AG PB 

(ppm) (ppm) (Ppm) (ppm) 

Mean 5.059 4.974 4.981 5.085 

S.D. 0.015 0.030 0.009 0.031 

% R.S.D. 0.303 0.601 0.176 0.618 

MN SB V BE 


Mean 5.124 4.750 5.107 5.195 

S.D. 0.011 0.052 0.007 0.006 

It R.S.D. 0.215 1.085 0.128 0.122 

WHC-SD•WWDP-_l ^L, REV--I 

AL CO Cu L 


4.934 5.096 4.861 4.976 

0.005 0.015 0.018 0.051 

0.093 0.288 0.363 1.029 

CA CR NO U 


5.216 5.143 5.439 9.691 

0.010 0.012 0.002 0.015 

0.198 0.234 0.036 0.155 

S MG AS NA 

(ppm) - (ppm) (ppm) (ppm) 

5.295 5.091 5.000 5.032 

0.048 0.012 0.032 0.044 

0.900 0.244 0.633 0.870 

TI CD 8 • K 


4.902 5.127 5.137 5.272 

TL 

0.006 0.015 0.022 0.033 

0.119 0.286 0.431 0.623 

(PPm) 

4.921 

0.041 

0.830 

t3

Identity 1: CCB_1 Identity 2: CCB_1 10:55 AM July 21, 1995 





---------------------------------------------------------------------- 

ZR SR BI SI 


Mean 0.000 -0.000 -0.004 0.001 

S.D. 0.001 0.000 0.005 0.000 

% R.S.D. 10789.838 43.501 139.493 45.004 

ZN NI LA FE 


Mean 0.001 -0.002 0.001 0.005 

S.D. 0.001 0.001 0.003 0.001 

% R.S.D. 94.943 64.049 321.748 22.020 

CE SM BA P 


Mean 0.005 -0.011 -0.000 -0.022 

S.D. 0.005 0.002 0.000 0.004 

% R.S.D. 100.875 16.496 42.094 18.502 

NO SE AG PIT 

( Ppm ) (Ppm) (Ppm) (ppm) 

Mean 0.000 -0.008 0.001 -0.004 

S.D. 0.001 0.007 0.000 0.005 

% R.S.D. 216.880 85.416 8.205 130.876 

MN 58 V BE 


Mean 0.000 -0.016 -0.001 0.000 

S.O. 0.000 0.007 0.001 0.000 

% R.S.D. 168.636 45.522 52.296 44.760 

WHC-SD-WM-DP- I ^' 

REV• L 

AL CO CU L 


-0.017 -0.001 -0.000 0.000 

0.003 0.002 0.000 0.000 

16.777 174.892 62.690 171.467 

CA CR NO U 

( ppm ) (ppa) (ppm) (ppm) 

0.000 -0.001 0.003 -0.064 

0.000 0.001 0.005 0.011 

15.746 163.118 180.678 16.812 

S MG AS NA 


0.009 0.000 0.004 0.045 

0.003 0.000 0.005 0.002 

31.582 0.080 114.056 4.412 

TI CD B K 

( Ppm ) (Ppm) (ppm) (ppm) . 

-0.000 -0.001 0.004 0.123 

0.000 0.001 0.001 0.001 

1252.336 59.902 24.711 1.069 

TL 

(ppm) 

-0.016 

0.017 

104.231 

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°a> Y°O+a-Yap R°Oaf+baua°SS °2O less B°° 

WHC-SDMWDP-/ 7 , REV._

06/28/95 09:47 age: 1 

A-0004-1 


oalyst: J. (^ Instrument: ICPOI Book# ^3 

Method: LA-505-151 Rev/Mod b -z 


WHC-SD-WM-DP- 






5 PREPBLKARL @ICP-FO3 SOLID 

6 SAMPLE S95TOO1115 0 F @ICP-FO3 SOLID 95000088 B-104 






11 SAMPLE S95TOO1116 0 F @ICP-F03 SOLID 95000088 B-104 


12 DUP S95T001116 0 F @ICP-FO3 SOLID 

13 SPK S95TOO1116 0 F @ICP-F03 SOLID 







525 

REV. ^

00/28/95 '09:47 WHC-SD-WM-DP-^, REV Page: 2 

A-0004-I 




Aqlofst Signature Date Analyst Signature 0 Date 

S S> 7CZ> ///> _ L 

S S s'%w ^ //> 

S S s rch;/'/ f 

S S>-TC %^ ///>-^ 

S s^f7-AJ ///6 _ I- 

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Identity 1: ICV Identity 2: Quality Control 1:19 PM July 21, 1995 

Ta m ' aMe : TNC93 

SL Weight : 1.0000 Solution Volme 1.00 

VfHC-SD-WM-DP- / % / , REV. 

On-Peak Integrations : 3 Off-Peak Integrations : 1 T" 

---------------------------------------------------------------------- 


( Ppm ) (ppm) (Ppm) (PPM) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 4.944 4.982 5.001 4.815 4.924 5.106 4.831 4.994 

S.D. 0.006 0.007 0'.016 0.007 0.005 0.024 0.009 0.019 

% R.S.O. 0.113 0.140 0.323 0.137 0.092 0.479 0.194 0.375 


(Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm). 

New 5.112 5.035 5.076 5.170 5.179 5.121 5.331 9.645 

S.D. 0.009 0.006 0.016 0.025 0.010 0.018 0.023 0.013 

% R.S.D. 0.182 0.126 0.314 0.488 0.191 0.355 0.429 0.132 


(Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 5.049 5.049 4.974 5.904 5.391 5.092 4.987 5.007 

S.D. 0.015 0.010 0.008 0.055 0.035 0.012 0.009 0.013 

% R.S.D. 0.301 0.190 0.166 0.929 0.644 0.236 0.181 , 0.259 


( Ppm ) (PPM) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 5.067 4.942 4.959 5.050 4.883 5.091 5.093 5.196 

S.D. 0.010 0.005 0.008 0.028 0.008 0.006 0.007 0.009 

% R S.D. 0.202 0.092 0.155 0.558 0.162 0.124 0.137 0.183 

MN SB V BE TL 


Mean 5.085 4.774 5.076 5.179 4.888 

S.D. 0.009 0.014 0.007 0.007 0.005 

% R.S.D. 0.178 0.293 0.137 0.126 0.105 

SIGHATIME ABOVE REPRE4ENTS CIUM 1L 1 E CffiJ0wcZM/cHFpIIST THAT 

OOt+IP MW/VERVI® THE MISUMO J/ANALYSIS ON PAGES ,.27 TO 

2`; 

y'^ ^5^ v jih a 

r 6 .^ 

yqs ^cp 

^^^5

Identity 1: ICS Identity 2: Quality Control 1:22 PM July 21, 1995 

Task none : TWC93 

Sample Weight : 1.0000 solution volume : 1.00 WHC-SD-WM-DP-1_j"L , REV.) 


---------------------------------------------------------------------- 


(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm ) (ppa) 

Mean 0.002 0.000 0.003 0.003 -0.004 -0.003 -0.000 0.000 

S.D. 0.001 0,000 0.009 0.000 0.002 0.003 0.000 0.000 

% R.S.D. 20.282 31.597 361.478 7.435 56.224 99.791 46.712 77.314 


(Ppm) (Ppm) (ppa) (Ppm) (Ppm) (PPm) (pPm) (Ppm) 

Mean 0.001 0.005 0.005 0.003 0.000 -0.001 -0.004 0.054 

S.D. 0.000 0.000 0.001 0.001 0.000 0.001 0.005 0.015 

% R.S.D. 9.274 0.023 15.641 24.979 44.096 84.527 119.430 28.369 


(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.016 0.015 0.001 -0.028 -0.003 0.001 0.003 0.018 

S.D. 0.002 0.004 0.000 0.008 0.003 0.000 0.003 0.001 

% R.S.D. 14.146 26.074 26.916 27.514 91.556 34.494 124.564 6.415 


(Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm ) 

Mean 0.001 -0.004 0.003 -0.007 0.001 -0.000 0.004 0.077 

S.D. 0.001 0.002 0.000 0.005 0.000 0.000 0.000 0.009 

% R.S.D. 242.813 47.694 10.640 66.548 20.873 86.621 4.355 11.887 

MN SB y BE TL 


Mean 0.000 -0.036 -0.001 0.000 0.012 

S.D. 0.000 0.016 0.000 0.000 0.010 

% R.S.O. 359.117 45.786 37.475 0.379 86.080 

ti^


Ta• • nrae : TWC93 

£ Weight 1.0000 Solution Volume 1.00 

On, eak Integrations : 3 


---------------------------------------------------------------------- 

^ 

WHCGSD-WM-DP- /_ j 

, REVS 

2R SR BI Si AL CO CU LI 

(ppm) (pp) (ppa) (ppm) (PPm) (PPm) (ppm) (ppm) 

Mean -0.003 0.001 -0.011 0.054 197.788 0.012 -0.013 0.001 

S.D. 0.001 0.000 0.007 0.001 0.427 0.003 0.000 0.000 

% R.S.D. 40.817 6.250 57.944 1.859 0.216 24.673 0.501 42.921 


( ppa ) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (pp) 

Mean 0.000 -0.050 0.009 148.616 19.175 -0.012 0.024 -0.095 

S.D. 0.001 0.002 0.002 0.638 0.043 0.002 0.003 0.051 

% R.S.D. 937.778 3.243 24.150 0.429 0.225 12.974 11.150 53.081 


(ppm) (Ppm) (Ppm) (Ppm) (ppo) (ppm) (ppm) (ppm) 

Mean -0.009 -0.034 0.003 0.043 0.157 18.759 0.016 189.620 

S.D. 0.012 0.015 0.000 0.011 0.005 0.095 0.002 2.095 

% R.S.D. 145.383 44.484 5.126 24.778 3.498 0.508 12.127 1.105 


(Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 0.001 -0.056 -0.002 0.032 -0.001 0.010 -0.046 0.017 

S.D. 0.000 0.008 0.001 0.004 0.000 0.000 0.001 0.010 

% R.S.D. 75.255 13.636 47.854 13.286 56.716 4.346 3.227 62.490 

MN SB v BE TL 


Mean 0.009 -0.015 -0.006 0.003 -0.087 

S.D. 0.000 0.019 0.001 0.000 0.025 

% R.S.D. 3.145 125.659 11.587 3.587 28.340 

^2J



Sample Weight : 1.0000 solution yotuae : 1.00 

WHC-SD-WM-DP-_Ll, REV - -L 


------------------------------------------- ---------- ------------ ----- 

ZR SR 81 SI AL CO CU Ll 

( pp ) (ppm) (ppm) (ppm) (ppm) (pp^) (ppm) (ppm) 

Mean -0.001 0.000 -0.006 0.050 198.356 0.502 0.480 0.936 

S.D. 0.001 0.000 0.007 0.001 0.764 0.006 0.002 0.006 

% R.S.D. 87.976 171.489 108.338 2.514 0.385 1.105 0.3% 0.671 



Mean 1.011 0.939 0.011 151.997 18.723 0.502 0.026 -0.026 

S.D. 0.000 0.005 0.001 0.060 0.042 0.001 0.005 0.040 

% R.S.D. 0.022 0.505 6.551 0.039 0.223 0.285 18.206 155.795 


(ppm) (ppm) (ppm) (ppm) (ppn) (ppm) (ppm) (ppm) 

Mean 0.012 -0.014 0.504 0.032 0.153 18.855 0.010 187.483 

S.D. 0.007 0.008 0.002 0.015 0.011 0.020 0.005 1.125 

% R.S.D. 61.225 57.459 0.328 47.236 7.354 0.105 45.396 0 0.600 

MO SE AG PB Ti CD B K 

( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppin) (ppm) 

Mean 0.001 0.055 1.029 1.025 -0.000 1.029 -0.045 0.010 

S.D. 0.001 0.006 0.001 0.004 0.001 0.001 0.001 0.016 

% R.S.D. 96.044 11.704 0.118 0.420 7118.168 0.116 1.821 161.538 

MN SB 9 BE TL 


Mean 0.519 -0.022 0.505 0.506 -0.060 

S.D. 0.001 0.046 0.001 0.001 0.016 

% R.S.D. 0.199 210.491 0.250 0.168 27.085 

5310

Identity 1: PREPBLK Identity 2: Ouality Control 1:35 PM July 21, 1995 

Task name : TUC93 

Weight : 1.0000 solution Volune 10.00 WHGSD-WM-DP-j^_4, REV1_ 

Or^.,ak Integrations : 3 

Off-Peak 


----------------------------------------------------- 

----------------- 


( ppm ) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.013 0.007 -0.003 1.039 -0.150 0.026 0.009 -0.001 

S.D. 0.013 0.001 0.098 0.022 0.040 0.027 0.005 0.004 

% R.S.D. 103.466 19.819 3691.386 2.125 26.312 103.080 53.944 267.907 


(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 0.379 10.223 -0.012 0.417 0.407 0.008 -0.001 -0.634 

S.D. 0.006 0.048 0.014 0.019 0.001 0.002 0.021 0.478 

% R.S.D. 1.526 0.474 115.244 4.545 0.246 28.625 3453.201 75.384 


( ppm ) (ppm) (pm) (ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean -0.124 -0.128 0.012 -0.098 0.283 0.103 0.075 4.453 

S.D. 0.121 0.132 0.003 0.147 0.042 0.001 0.035 0.061 

% R.S.D. 97.594 102.864 23.069 150.615 14.789 0.937 46.317 1.370 

MO BE AG PB 

IT 

CD B K 

(Ppm) (PPM) (ppm) (ppm) (Ppm) (PPM) (Ppm) (Ppm) 

Mean -0.010 -0.257 0.001 -0.146 0.004 -0.002 0.039 10753.327 

S.D. 0.007 0.106 0.009 0.062 0.005 0.004 0.009 59.244 

% R.S.D. 67.267 41.320 636.961 42.146 -118.255 168.003 22.847 0.551 

MN SB V BE TL 


Mean 0.061 -0.057 -0.029 0.005 -0.226 

S.D. 0.003 0.219 0.006 0.001 0.252 

% R.S.D. 

5.172 384.343 19.652 

22.663 

------------------------------------------ ---------------------- - ----- 

111.386 

531

Identity 1: S95T001115 L Identity 2: 1.7506gin250-1-9 . 1-4 1:40 PM July 21, 1995 


Sample Weight : 1.7506 Solution volume : 12500.00 WHC-SD-WM-DP-./5 I, REV. f 


---------------------------------------------------------------------- 


(Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -6.679 138.300 9504.757 4819.390 1986.384 59.838 13.532 23.598 

S.D. 5.134 1.029 35.289 17.483 35.355 10.987 4.460 0.680 

% R.S.D. 76.868 0.744 0.371 0.363 1.780 18.362 32.958 2.882 

ZN Ni LA FE CA CR ND u 

( ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 67.866 37739.176 -12.015 10488.055 292.621 504.310 21.400 1659.519 

S.D. 3.709 162.768 8.818 52.730 0.540 6.809 44.931 142.127 

% R.S.D. 5.465 0.431 73.390 0.503 0.185 1.350 209.957 8.564 


(ppa) (ppm) (Ppm) (Ppn) (ppm) (ppm) (ppm) (Ppm) 

Mean -115.241 -118.449 6.995 18728.932 7253.008 140.690 38.710 127170.856 

S.D. 40.291 23.146 0.856 1404.122 237.870 1.185 40.174 1533.020 

% R.S.D. 34.963 19.541 12.243 7.497 3.280 0.842 103.782 1.205 

NO SE AG PB IT CD B K 

(Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean -1.939 225.796 -1.915 21.376 11.373 -1.084 42.568 1568275.519 

S.D. 3.918 41.339 5.193 61.760 2.645 2.605 4.958 17275.574 

% R.S.D. 202.073 18.308 271.249 288.930 23.257 240.259 11.647 1.102 

MN SIT 9 BE TL 

(Ppm) (pp) (ppm) (ppm) (Ppm) 

Mean 132.285 -420.594 -18.971 1.038 -222.801 

S.D. 0.013 140.762 9.386 0.758 128.468 

% R.S.D. 0.010 33.467 49.474 73.026 57.660 

U lw

Identity 1: S95TOO1115 Id en tity 2: 1.7506gin250-1-9 1:43 PM July 21, 1995 


F , Weight : 1.7506 Solution Volume : 2500.00 

0^ ak Integrations : 


WHC-SD-WM-DP-.L^ , 

-------------------------- - ------.------------------------------------ 


(Piss) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean -7.232 138.029 9611.809 4778.926 2064.649 40.820 15.663 23.152 

S.D. 0.953 0.077 18.095 4.904 10.552 5.809 0.118 0.421 

It R.S.D. 13.174 0.056 0.188 0.103 0.511 14.231 0.753 1.818 

REV. 


(Ppm) (Ppm) (ppm) (Ppm) (PPM) (Ppm) (Ppn) (Ppm) 

Mean 55.280 37373.901 -1.473 10406.171 271.762 501.759 -7.469 1773.772 

S.D. 0.522 50.739 0.998 28.027 0.054 5.540 8.363 26.053 

% R.S.D. 0.945 0.136 67.736 0.269 0.020 1.104 111.971 1.469 


(Ppm ) (Ppm) (Ppm) (PPm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 6.102 -48.029 7.779 17417.689 6844.737 134.625 13.270 120437.778 

S.D. 4.257 8.156 0.083 586.322 69.639 0.273 4.444 347.138 

% R.S.D. 69.755 16.981 1.065 3.366 1.017 0.202 33.489 0.288 


(Ppm ) (Ppm) (PPM) (PIN") (Ppm) (Ppm) (ppm) (Ppm) 

Mean -1.163 77.358 -0.270 28.299 13.093 15.210 37.010 1463045.070 

S.D. 0.623 9.393 0.456 13.055 0.301 0.525 1.405 3096.809 

% R.S.D. 53.576 12.142 169.042 46.132 2.300 3.454 3.796 0.212 

MN SB V BE TL 


Mean 134.492 43.186 -2.000 0.342 -204.166 

S.D. 0.228 23.365 0.815 0.307 12.175 

% R.S.O. 

0.170 

54.103 40.742 89.561 5.963 

---------------------------------------------------------------------- 

v S .i 

I

Identity 1: S95TOO1115 D Identity 2: 1.70569in250 . 1-9 1:46 PM July 21, 1995 


Sample Weight :. 1.7056 Solution volume : 2500.00 


-------------------------------------- 

-------------------------------- 

WHGSD-WM-DP REV.) 


(ppm) (ppm) (ppm) (Ppm) (ppm) (PPS) (ppm) (ppm) 

Mean -7.151 138.718 10432.636 4880.664 2114.959 37.263 23.843 24.219 

S.D. 1.088 0.348 4.088 26.105 6.069 2.248 0.195 0.190 

% R.S.D. 15.212 0.251 0.039 0.535 0.287 6.032 0.818 0.786 


(ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 54.984 46130.124 2.229 11019.035 275.764 521.064 8.357 2028.918 

S.D. 0.577 179.722 4.535 36.488 0.776 1.002 8.283 20.781 

% R.S.D. 1.049 0.390 203.494 0.331 0.281 0.192 99.117 1.024 


( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 9.805 -5.541 9.063 18684.188 7199.400 141.579 3.348 121230.814 

S.D. 7.562 3.959 0.042 133.447 40.410 0.561 4.157 963.180 

% R.S.D. 77.119 71.450 0.461 0.714 0.561 0.396 124.161 0.795 

MD SE AG PB TI CD B K 

(Ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) (pPs) (ppm) 

Mean -0.929 28.273 0.419 19.589 16.123 15.911 34.344 1437609.333 

S.D. 1.554 6.990 1.075 24.866 0.229 0.804 1.726 8357.544 

% R.S.D. 167.362 24.722 256.457 126.939 1.423 5.053 5.024 0.581 

MN SB y BE TL 

(Ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 157.687 14.961 -0.447 0.371 -166.097 

S.D. 0.456 45.962 0.840 0.155 9.764 

% R.S.D. 0.289 307.215 188.060 41.911 5.878 

E- 3 Z2

identity 1: S95TOO1115 A Identity 2: 1.7506gin250-1 . 2-7 1:50 PM July 21, 1995 


Sr 

On 

Weight : 1.7506 

.R Integrations : 3 

Solution volume : 2500.00 


WHC-SD-WM-DP- 

^3 ^, REV. 

------------------------------------------- 

-------------------------- 


(ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) 

New 1414.806 1562.212 11039.668 6227.719 3475.459 1483.237 1396.978 1312.875 

S.D. 3.298 1.556 35.855 11.751 13.887 2.215 2.919 5.676 

% R.S.D. 0.233 0.100 0.325 0.189 0.400 0.149 0.209 0.432 



Mew 1443.749 39063.23S 1470.997 11876.390 1727.322 1983.730 1515.267 4513.189 

S.D. 3.039 120.252 6.289 59.859 1.521 3.994 8.535 56.445 

% R.S.D. 0.210 0.308 0.428 0.504 0.088 0.201 0.563 1.251 


(Ppm ) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 1443.149 1385.568 1423.513 20742.548 8711.920 1569.157 1423.266 119391.165 

S.D. 14.559 7.608 1.964 404.754 85.794 3.149 17.765 514.844 

% R.S.D. 1.009 0.549 0.138 1.951 0.985 0.201 1.248 0.431 

NO SE AG PIT TI CD 8 K 


Mesas 1434.389 1442.256 1172.769 1483.102 1408.902 1444.987 1422.821 1424648.286 

S.D. 6.549 14.102 9.355 14.312 0.816 2.752 5.784 4573.767 

% R.S.D. 0.457 0.978 0.798 0.965 0.058 0.190 0.407 0.321 

MN S8 V BE TL 

(Ppm) (PPM) (Ppm) (PPM) (PPM) 

Mean 1591.519 1351.758 1457.126 1418.940 1237.262 

S.D. 1.686 38.379 3.726 3.597 28.572 

% R.S.D. 0.106 2.839 0.256 0.254 2.309 

35 

0



Sample Weight : 1.0000 Solution Volune 1.00 


Off-Peak Integrations : 1 WHGSD-WM-DP- , REV. 

---------------------------------------------------------------------- 

ZR SR 81 SI AL CO CU LI 

(Ppm ) (ppm) (ppm) (Ppn) (ppm) (ppm) (ppm) (ppm) 

Mean 4.978 5.025 4.982 4.818 4.925 5.080 4.897 5.069 

S.D. 0.015 0.006 0.023 0.007 0.003 0.026 0.005 0.060 

% R.S.D. 0.301 0.110 0.467 0.153 0.056 0.518 0.098 1.181 


(Ppm) (ppm) Wall (Ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 5.079 5.032 5.131 5.199 5.233 5.108 5.490 9.753 

S.D. 0.009 0.021 0.011 0.011 0.009 0.020 0.026 0.017 

% R.S.D. 0.179 0.424 0.214 0.211 0.176 0.389 0.472 0.179 



Mean 5.041 5.078 5.032 5.628 5.261 5.066 4.996 5.118 

S.O. 0.008 0.007 0.004 0.213 0.079 0.016 0.026 0.064 

% R.S.D. 0.165 0.130 0.078 3.785 1.492 0.316 0.528 1.252 


(pPm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 5.046 4.977 4.957 5.047 4.899 5.089 5.145 5.411 

S.D. 0.008 0.026 0.007 0.032 0.010 0.016 0.010 0.095 

It R.S.D. 0.154 0.525 0.138 0.629 0.197 0.316 0.200 1.752 

MN SB v BE TL 

(Ppm) (ppm) (ppm) (PPM) (Ppm) 

Mean 5.087 4.743 5.089 5.211 4.902 

S.D. 0.014 0.070 0.012 0.008 0.010 

% R.S.D. 

0.281 1.466 0.234 

0.153 0.199 

---------------------------------------- ------------------------- ----- 

V ^^



Sr Weight : 1.0000 Solution Vo(Lm 1.00 

On < Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

2R 

SR III SI AL 

(Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean -0.000 -0.000 -0.007 0.003 -0.017 

S.D. 0.000 0.000 0.004 0.001 0.002 

% R.S.D. 180.662 43.168 51.330 36.633 12.685 


( ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.000 0.002 0.004 0.004 0.000 

S.D. 0.000 0.001 0.002 0.003 0.000 

% R.S.D. 535.791 48.280 52.203 62.304 24.744 

CE SM BA P S 

( ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 0.002 -0.003 -0.000 -0.026 0.006 

S.D. 0.007 0.006 0.000 0.008 0.004 

% R.S.D. 319.910 190.889 83.618 29.907 70.814 

No BE AG PB TI 


Mean -0.001 -0.029 0.002 -0.020 -0.001 

S.D. 0.001 0.010 0.001 0.003 0.000 

% R.S.D. 77.888 35.273 31.797 12.513 51.241 

MN SB V BE TL 

( ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.000 -0.005 -0.002 -0.000 -0.025 

S.O. 0.000 0.023 0.001 0.000 0.008 

% R.S.D. 169.190 515.464 39.935 326.209 30.673 

S .3'o 

WHGSD-WM-DP-_, REV./ 

CO CU LI 

(ppm) (ppm) (Ppm) 

0.004 -0.001 0.000 

0.002 0.000 0.000 

43.217 22.142 98.850 

CR ND U 

( ppm) (ppm) (ppm) 

-0.001 -0.004 -0.033 

0.001 0.008 0.028 

106.551 194.647 84.493 

MG AS NA 

( ppm ) (Ppm) (Ppm) 

-0.000 0.003 0.041 

0.000 0.005 0.003 

86.386 166.064 7.512 

CD B K 


-0.002 0.003 0.157 

0.001 0.000 0.016 

48.198 14.361 9.865

identity 1: S95TO01116_L Identity 2: 1.7975gin250-1 . 9-1-4 2:02 PM July 21, 1995 


Sample weight : 1.7975 


Solution Volume 12500-00 


WHC-SD- 

^^// / 

-DV DV-_LU 

, , Htvl 

---------------------------------------------------------------------- 


(Ppm) (Ppm) (Timm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean -17.871 146.282 7379.500 4440.252 1398.532 34.901 11.842 48.427 

S.D. 6.167 0.654 50.513 19.930 7.385 0.022 2.302 1.301 

% R.S.D. 34.510 0.447 0.685 0.449 0.528 0.064 19.440 2.686 



Mean 83.986 21766.260 16.734 10107.172 341.315 444.647 -5.810 1659.049 

S.D. 1.673 54.189 13.080 25.150 4.913 5.889 12.343 133.975 

% R.S.D. 1.992 0.249 78.162 0.249 1.439 1.324 212.425 8.075 


(Ppm ) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean -8.351 -182.010 7.005 17857.615 6726.477 135.485 79.973 121760.445 

S.D. 32.428 35.777 0.834 787.457 184.519 0.661 35.354 422.658 

% R.S.D. 388.314 19.657 11.901 4.410 2.743 0.488 44.208 0.347 

NO SE AG P8 TI CO B K 

( ppm ) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean -0.944 -52.832 -9.432 42.676 7.347 6.723 63.436 1509532.678 

S.D. 5.532 64.537 5.285 58.171 0.855 1.664 7.571 5843.387 

% R.S.O. 585.947 122.156 56.031 136.308 11.641 24.754 11.935 0.387 . 

MN SB V BE TL 

( ppm ) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 90.961 -276.101 -16.638 1.015 -370.596 

S.D. 1.897 117.727 5.641 1.482 110.152 

% R.S.D. 2.086 42.639 33.906 145.947 29.723 

r-313

Identity 1: S95TOO1116 Identity 2: 1.7975 9 in250-1-9 2:07 PM July 21, 1995 

Teak name : TWC93 


On -ak Integrations : 


---------------------------------------------------------------------- 

^ 2^ 

WK-M-ft-DF-L_L, HLV. 



Mean -1.399 146.666 7629.939 4504.609 1494.846 29.835 12.006 42.410 

S.D. 0.713 0.656 39.199 12.689 3.185 2.126 0.648 0.428 

% R.S.D. 51.012 0.447 0.514 0.282 0.213 7.126 5.393 1.009 


(Ppm) (Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) 

Mean 80.268 22153.622 2.245 10313.371 272.020 461.647 3.999 2324.403 

S.D. 0.425 152.563 1.006 52.260 1.232 4.678 8.286 31.469 

X R.S.D. 0.529 0.689 44.792 0.507 0.453 1.013 207.192 1.354 


(Ppm) (ppm) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 8.776 -15.491 9.331 18810.514 6837.255 132.739 8.410 113544.021 

S.D. 8.911 2.757 0.196 239.068 8.907 0.580 3.129 582.701 

% R.S.D. 101.541 17.797 2.103 1.271 0.130 0.437 37.212 0.513 

MO SE AG PB TI CD 8 • K 

(ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 1.070 46.509 0.408 45.133 9.771 8.030 37.709 1391206.219 

S.D. 0.288 10.964 0.333 12.229 0.143 0.341 1.267 4406.658 

X R.S.D. 26.956 23.575 81.639 27.095 1.461 4.241 3.360 0.317 

MN SB V BE TL 

(Ppm) (Ppm) (PPn). (Ppm) (PPM) 

Mean 96.081 40.503 0.901 0.733 -109.904 

S.D. 1.087 45.251 1.041 0.003 2.501 

% R.S.D. 1.132 111.722 115.482 0.401 2.275 

5LJ

Id en tity 1: $957001116D Identity 2: 1.7935gin2S0-1-9 2:11 PM July 21, 1995 

Task name : TWC93 ^^ ^/ 

Sample Weight : 1.7935 Solution volume 2500.00 WHC-SD-WM-DP- /l 1, REV. ^ 



---------------------------------------------------------------------- 

ZR SR BI 51 AL CO Cu LI 

(Ppm) (Ppm) (Ppm) (Ppm) (Pp) (Ppm) (Ppm) (Ppm) 

Mean -15.089 148.439 8621.511 4611.700 1548.464 35.075 17.395 46.707 

S.D. 0.837 0.263 20.114 9.395 12.901 2.146 0.324 0.181 

% R.S.D. 5.549 0.177 0.233 0.204 0.833 6.118 1.864 0.387 


(Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 68.735 33446.293 1.201 10699.023 286.778 473.825 4.500 2391.207 

S.D. 0.865 99.355 2.613 55.693 0.091 2.215 5.399 26.445 

% R.S.D. 1.258 0.297 217.504 0.521 0.032 0.467 119.981 1.106 


(Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (pp) (ppm) 

Mean 9.774 -23.530 9.446 18673.251 6869.824 137.651 9.753 114047.777 

S.D. 6.734 8.739 0.155 517.458 56.273 0.353 7.119 442.965 

% R.S.D. 68.899 37.142 1.641 2.771 0.819 0.256 72.997 0.388 


(Ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppn) 

Mean -0.315 50.930 -1.045 24.209 13.003 13.991 33.852 1452943.955 

S.D. 0.501 6.759 0.574 12.036 0.503 1.198 1.084 6373.923 

% R.S.D. 158.745 13.272 54.966 49.716 3.869 8.563 3.203 0.439 

MN S8 V BE TL 

(Ppm) (Pp) (ppm) (ppm) (Ppm) 

Mean 125.739 -15.518 -0.751 0.310 -180.839 

S.D. 0.997 18.303 1.161 0.147 18.576 

% R.S.D. 0.793 117.943 154.675 47.456 10.272 

v w} y^

Identity 1: 5951001116 A Identity 2: 1.7975gin250-1-2-7 2:14 PM July 21, 1995 

Task game : TWC93 

Sa /eight : 1.7975 Solutian Vat me : 2500.00 WHGSD-WM-DP-., REV. 

On-Yedk Integrations : 3 


.........................•------....-------------•-------------------- 

ZR SR B) SI AL CO CO LI 


Mean 1380.376 1535.307 8918.655 5753.444 2847.879 1400.069 1366.733 1301.489 

S.D. 0.869 2.093 25.364 14.881 6.909 5.656 4.062 9.663 

% R.S.D. 0.063 0.136 0.284 0.259 0.243 0.404 0.297 0.742 



Mean 1387.699 23026.987 1440.854 11616.426 1721.881 1859.811 1536.393 5072.506 

S.D. 2.102 63.143 3.544 26.966 1.850 3.635 14.894 35.358 

% R.S.D. 0.152 0.274 0.246 0.232 0.107 0.195 0.969 0.697 



Mean 1389.347 1382.779 1393.739 19710.050 8055.823 1498.687 1356.779 115729.815 

S.D. 2.394 7.685 2.433 296.950 33.859 2.526 2.890 764.961 

X R.S.D. 0.172 0.556 0.175 1.507 0.420 0.169 0.213 0.661 

MO SE AG PB T1 CD B K 

(PPRI) (Ppm) (Ppm) (Ppn) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 1373.046 1366.435 998.808 1395.792 1359.174 1386.331 1390.540 1400293.463 

S.D. 7.096 8.636 9.267 19.859 1.570 5.282 5.700 6325.473 

% R.S.D. 0.517 0.632 0.928 1.423 0.116 0.381 0.410 0.452 

MN SB V BE TL 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 1496.792 1307.198 1412.699 1362.803 1264.018 

S.D. 5.695 43.235 1.318 0.909 15.874 

% R.S.D. 0.380 3.307 0.093 0.067 1.256 

54

Identity 1: ICSA Identity 2: Duality Control 2:19 PM July 21, 1995 


Sample Weight : 1.0000 Solution Vol uae 1.00 



---------------------------------------------------------------------- 

ZR SR BI S( AL 


Mean -0.003 0.000 0.013 0.062 199.100 

S.D. 0.001 0.000 0.003 0.002 0.459 

% R.S.D. 28.608 12.304 24.741 3.903 0.230 



Mean 0.000 -0.048 0.006 150.967 19.234 

S.D. 0.000 0.001 0.001 0.265 0.044 

% R.S.D. 77.265 2.162 19.244 0.175 0.229 

CE SM BA P S 

( ppm ) (PPM) (ppm) (ppm) (ppm) 

Mean 0.011 -0.024 0.002 0.017 0.182 

S.D. 0.007 0.008 0.000 0.010 0.002 

% R.S.D. 64.839 34.540 3.403 61.873 1.241 

NO SE AG PIT TI 


Mean -0.005 -0.035 -0.001 -0.005 0.000 

S.D. 0.000 0.009 0.000 0.005 0.000 

% R.S.D. 8.733 25.422 25.535 109.366 91.326 


( ppm ) (ppm) (ppm) (ppm) (Ppm) 

Mean 0.009 -0.035 -0.007 0.003 -0.083 

S.D. 0.000 0.026 0.001 0.000 0.009 

% R.S.D. 3.054 75.084 14.067 11.228 10.281 

WHC-SD-WM-Dr -__LL REV. 

CO CU LI 


0.005 -0.015 0.000 

0.000 0.000 0.000 

0.043 3.134 135442.518 

CR NO U 


-0.014 0.007 -0.063 

0.000 0.005 0.018 

2.811 80.814 28.815 

MG AS NA 

(Ppm ) (Ppm) (PPM) 

19.076 0.003 190.342 

0.027 0.003 0.851 

0.140 100.704 0.447 

CD B K 


0.010 -0.048 0.265 

0.000 0.000 0.013 

2.324 0.743 4.786



Sm ieight : 1.0000 Solution volume : 1.00 WHGSD-WM-DP- , REV../ 

On-.. .. Integrations : 3 Off-Peak Integrations : 1 

-----------------------------------------------------•----...------•-- 


(ppm ) (ppm) (PPS) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.005 -0.000 0.007 0.052 199.889 0.511 0.483 0.943 

S.D. 0.001 0.000 0.013 0.003 0.496 0.003 0.001 0.003 

% R.S.D. 16.486 86.495 189.012 5.424 0.248 0.603 0.217 0.328 


( ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 1.021 0.949 0.011 153.303 18.834 0.505 0.013 -0.016 

S.D. 0.001 0.003 0.001 0.477 0.082 0.001 0.010 0.020 

% R.S.D. 0.106 0.342 6.720 0.311 0.435 0.250 71.380 118.987 


(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (PPM) 

Mean 0.012 -0.015 0.507 0.004 0.155 19.022 0.015 189.004 

S.D. 0.002 0.006 0.002 0.008 0.012 0.050 0.005 0.637 

% R.S.D. 14.893 41.191 0.323 220.536 7.555 0.262 35.312 0.337 

NO SE AD PB TI CD B K 

(Ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean -0.003 0.055 1.428 1.007 -0.000 1.040 -0.046 0.227 

S.D. 0.001 0.009 0.003 0.011 0.000 0.008 0.000 0.013 

% R.S.D. 32.308 17.056 0.242 1.137 552.739 0.780 0.877 5.793 

MN SB v BE TL 

(Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 0.524 -0.066 0.507 0.510 -0.051 

S.D. 0.002 0.061 0.001 0.001 0.008 

% R.S.D. 0.438 92.114 0.292 0.227 15.028

Identity 1: CCV_l Identity 2: CCV 1 2:26 PM July 21, 1995 


Sample Weight : 1.0000 solution Volume : 1.00 



----------------------------------------------•----------------------- 


( Ppm ) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 4.956 4.989 4.986 4.809 4.904 

S.D. 0.015 0.019 0.011 0.011 0.009 

% R.S.D. 0.297 0.386 0.212 0.232 0.189 

2N NI U FE CA 

(PPM ) (PPM) (PPM) (Ppm) (Ppm) 

Neon 5.101 5.030 5.118 5.196 5.200 

S.D. 0.006 0.007 0.009 0.008 0.024 

% R.S.D. 0.127 0.132 0.177 0.163 0.464 

CE SM BA P S 

( ppm ) (ppm) (ppm) (PPM) (PPM) 

Mean 5.020 5.034 4.988 5.772 5.307 

S.D. 0.007 0.027 0.024 0.189 0.067 

% R.S.D. 0.141 0.531 0.472 3.270 1.265 

NO SE AG PB TI 

(Ppm) (ppm) (Ppm) (PPM) (PPM) 

Mean 5.044 4.944 4.962 5.064 4.879 

S.D. 0.002 0.024 0.005 0.035 0.013 

% R.S.D. 0.039 0.488 0.102 0.685 0.259 

MN SB V BE TL 

(ppm) (PPM) (ppm) (Ppm) (ppm) 

Mean 5.088 4.727 5.083 5.183 4.864 

S.D. 0.009 0.032 0.010 0.014 0.019 

% R.S.D. 0.181 0.669 0.206 0.275 0.385 

54'i 

WHGSD-WM-DP- 13 7 1 REV. / 

CO Cu L 

(PPM ) (pPM) (ppm) 

5.080 4.853 5.003 

0.008 0.025 0.038 

0.157 0.517 0.768 

CR NO u 

(PPM ) (Ppm) (Ppm) 

5.108 5.437 9.652 

0.010 0.028 0.004 

0.191 0.520 0.037 

MG AS NA 

(PPM ) (PPM) (ppm) 

5.072 4.990 5.058 

0.005 0.018 0.030 

0.104 0.357 0.586 

CO 8 , K 

( ppm ) (PPM) (PPM) 

5.092 5.132 5.352 

0.014 0.024 0.015 

0.282 0.465 0.283

Identity 1: CCB_l Identity 2: CCB_1 2:29 PM July 21, 1995 


S Weight : 1.0000 Solution Volume : 1.00 WHC-SD-WM-DP-/. , REV. 

On-..ak Integrations 3 Off-Peak Integrations : 1 

--------------------- ------------------------------------------------- 

ZR SR 

BI SI AL CO CU LI 

( Ppm) (ppm) (PPM) (ppm) (Ppm) (pprn) (ppm) (ppm) 

Mean 0.001 -0.000 -0.008 0.002 -0.018 0.002 -0.001 -0.000 

S.D. 0.000 0.000 0.004 0.001 0.004 0.002 0.000 0.000 

% R.S.D. 24.719 43.088 52.928 67.938 23.889 86.785 46.847 129.904 


(PPM ) (PPm) (PPM) (PPM) (PPM) (PPM) (PPM) (ppm) 

Mean 0.000 0.002 0.004 0.004 0.002 -0.002 -0.014 0.010 

S.D. 0.000 0.001 0.001 0.003 0.000 0.001 0.004 0.017 

It R.S.D. 68.483 52.401 19.377 67.042 21.993 42.161 28.332 165.713 


(PPM) (PPM) (Ppm) (PPM) (ppm) (PPM) (PPM) (Ppm) 

Mean 0.016 0.005 0.000 -0.002 0.000 0.000 0.005 0.052 

S.D. 0.002 .0.005 0.000 0.001 0.004 0.000 0.004 0.002 

% R.S.D. 13.664 101.144 94.272 59.433 1491.081 172.508 79.557 r 4.441 

NO BE AG PB TI CD B K 

(PPM) (Ppm) (PPM) (PPM) (ppm) (PPM) (Ppm) (PPM) 

Mean 0.001 -0.014 0.001 -0.025 0.001 -0.001 0.002 0.180 

S.D. 0.001 0.010 0.000 0.001 0.000 0.000 0.000 0.014 

% R.S.D. 68.825 66.563 27.025 4.564 66.476 0.071 16.268 7.734 

MN SB V BE TL 

(PPM) (PPM) (ppm) (PPM) (ppm) 

Mean -0.000 -0.023 -0.001 0.000 -0.014 

S.O. 0.000 0.016 0.001 0.000 0.006 

% R.S.D. 15526.775 71.058 59.541 99.148 42.956 

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06/28/95 09:57 Page: 1 

A-0004-1 


Analyst: S. - c.Pis Instrument: ICPO1 Book# 'Vd fS 

Method: LA-505-151 Rev/Mod L) - L 


WHC-SD-WM-DP- 


I ICV @ICP-QC QC 





















^SO 

REV. ^

06/28/95 09:57 

A-0004-1 

SSs^roo /13 c_ L 

5 Si T^v //3 L 

S9rrvo 113 Z - 

SSi Toy !/3t _ 17 

SSi iW!(3j _ c- 

ss>`rw /{3j 

SSl`TW /{3f_^ 

wHC•SD-WM-DP - I 

L' REV. 


Type Sample#R A Test Matrix Group# Project 


Î^rs ignature Date 8AnalY t SignatureDa e 


{. 76vo Y .;., 

{. )(aYp of ^t^ ^.Ith-L 

^ Y---c -7_c - 7 c 


r—^ 

zrw 

Page: 2

Identity 1: ICV Identity 2: Ouatity Control 

9:50 AM July 24, 1995 


Saopie Weight : 1.0000 


Sotution volume 


1.00 

1 

WHC SD WM DP _3 Ik , REVL 

........................................................ .............. 

2R 

SR BI 

(PPM ) (PPM) (PPM) 

Now 4.889 4.947 4.948 

S.D. 0.004 0.004 0.030 

% R.S.D. 0.076 0.082 0.613 

2N NI LA 


Mean 5.091 4.983 4.937 

S.D. 0.008 0.012 0.010 

% R.S.D. 0.151 0.239 0.203 

CE SM BA 


Mean 5.002 5.099 4.942 

S.D. 0.016 0.005 0.003 

% R.S.O. 0.310 0.092 0.070 

NO BE AG 

(PP M) (PPM) (PPM) 

Mean 5.071 4.903 4.932 

S.D. 0.015 0.009 0.006 

% R.S.O. 0.302 0.177 0.116 

MN SB v 

(PPM) (PPM) (PPM) 

Mean 5.025 4.693 5.011 

S.D. 0.007 0.009 0.008 

% R.S.D. 0.133 0.193 0.154 

SI AL CO Cu L) 

(PPM ) (Ppm) (PPM) (PPM) (PPM) 

4.759 4.977 5.082 4.811 5.058 

0.011 0.008 0.023 0.002 0.026 

0.222 0.160 0.447 0.051 0.508 

FE CA CR ND u 

(PPM) (PPM) (PPM) (PPM) (PPM) 

5.015 5.106 5.073 5.064 9.222 

0.011 0.005 0.018 0.023 0.021 

0.222 0.105 0.360 0.460 0.223 

P S MG AS NA 


5.151 5.098 5.069 4.964 5.043 

0.109 0.060 0.011 0.027 0.027 

2.119 1.170 0.224 0.547 0.540 

PB TI CD B K 


5.035 4.866 5.045 5.010 5.009 

0.035 0.006 0.007 0.004 0.048 

0.701 0.131 0.131 0.088 0.954 

BE TL 

(PPM) 

5.140 

(PPM) 

4.799 

k 

0.008 

0.155 

0.002 

0.048 

Î^ 

1 

SIMATIM ABM REPRWMM CHBI4 M IAGIST/CHH4IST SAT 

oMSU +Tw/VFRIFIH) TM MIBRATMWAMLYSIS C1d PACES S 5^'105^_- 

^F 

X95

Identity 1: ICB Identity 2: Duality Control 


Be Weight : 1.0000 Solution Volume 1.00 

0n-.-.a Integrations : 3 off-Peak Integrations : 1 

......................... ............................... 

2R SR 81 


Mean -0.003 0.000 -0.009 

S.D. 0.001 0.000 0.006 

% R.S.D. 23.486 24.588 62.006 

2N NI LA 

(Ppm ) (PPM) (Ppm) 

Mean 0.001 -0.003 -0.001 

S.D. 0.000 0.002 0.002 

% R.S.D. 16.594 55.004 248.415 

CE SM BA 

(Ppm ) (pPm) (Ppm) 

Mean -0.003 -0.021 -0.000 

S.D. 0.004 0.005 0.000 

% R.S.D. 109.929 22.702 24.494 

MO SE AG 


Mean 0.001 0.011 -0.001 

S.D. 0.001 0.006 0.000 

% R.S.O. 64.418 51.122 0.760 

MN S8 y 


Mean -0.001 0.057 0.002 

S.D. 0.000 0.009 0.000 

% R.S.D. 29.241 15.566 15.680 

9:54 AM July 24, 1995 

WHC-SD-WM-DP-L, REVL 

--- - ---------- 

SI AL co Cu LI 

(Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

-0.001 0.016 -0.002 0.001 0.001 

0.001 0.005 0.002 0.000 0.000 

105.111 28.967 87.235 25.880 19.505 

FE CA CR ND u 

(Ppm) (Ppm) (PPM) (Pps) (PPM) 

-0.001 0.000 0.002 0.016 -0.095 

0.003 0.000 0.000 0.008 0.007 

338.323 37.500 20.895 51.646 7.802 

P S MG AS NA 

(PPM ) (Ppm) (PPM) (Ppm) (ppa) 

-0.025 -0.002 -0.000 0.006 0.002 

0.003 0.008 0.000 0.002 0.002 

11.913 342.874 56.946 30.142 115.456 

PEI TI CD 8 K 

(Ppm) (Ppm) (Ppm) (Ppm) (Pp) 

-0.009 -0.001 -0.000 0.003 -0.054 

0.009 0.000 0.001 0.001 0.008 

104.842 34.459 343.869 29.286 14.637 

BE TL 

(Ppm) (PPM) 

0.000 -0.028 

0.000 

61.123 

0.005 

17.694 

J:D J


Task now : TNC93 

Semple Nefght : 1.0000 Solution Volume : 1.00 WHC-SD-WM-DP-_,L, REVI 

On-Peak Integratt ons : 3 Off-Peak Integrations : 1 

....................................... ............................... 


(ppm) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) 

New -0.002 0.001 -0.004 0.058 198.180 0.007 -0.013 0.000 

S.D. 0.001 0.000 0.015 0.004 0.696 0.000 0.001 0.000 

% R.S.D. 52.858 18.182 351.760 7.023 0.351 0.071 4.178 83.3S1 


(ppm) (PPM) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (PPm) 

Mean 0.000 -0.050 0.007 144.817 18.856 -0.010 0.023 -0.020 

S.D. 0.001 0.001 0.002 0.095 0.042 0.001 0.011 0.038 

% R.S.D. 217.717 1.625 25.088 0.065 0.222 12.419 46.675 193.933 


(Ppm) (ppm) (Ppm) (PPM) (ppm) (ppm) (ppm) (Ppm) 

New -0.010 -0.011 0.003 0.020 0.148 18.889 0.006 189.715 

S.D. 0.005 0.011 0.000 0.025 0.005 0.046 0.005 1.900 

% R.S.D. 50.517 105.474 5.575 127.909 3.148 0.244 81.748 m 1.002 


(Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) 

New -0.001 -0.020 -0.003 0.031 -0.000 0.011 -0.045 -0.080 

S.D. 0.001 0.009 0.000 0.007 0.001 0.002 0.000 0.015 

% R.S.D. 50.518 44.650 12.987 21.531 269.150 13.829 0.610 19.024 

MN BB y BE TL 

(PPM) (ppm) (Ppm) (ppm) (Ppm) 

New 0.010 0.030 -0.003 0.002 -0.038 

S.D. 0.000 0.025 0.000 0.000 0.014 

% R.S.D. 1.632 84.565 10.258 7.447 37.567 

G Z; Id,


Task name : TNC93 i 

Be weight : 1.0000 Solution volume : 1.00 WHC-SD-WM-DP -, 

On ^k Integrations : 3 Off-Peak Integrati ono : 1 

...................................................................... 

ZR 


(Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) (ppm) 

Mean -0.005 0.000 -0.014 0.052 199.373 0.513 0.478 0.937 

S.D. 0.000 0.000 0.013 0.003 0.388 0.004 0.001 0.006 

% R.S.D. 5.123 24.626 92.434 5.622 0.194 0.775 0.154 0.626 

REV. 


WIN) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

New 1.017 0.934 0.005 148.231 18.476 0.507 0.018 -0.026 

S.D. 0.002 0.003 0.001 0.515 0.016 0.001 0.003 0.015 

X R.S.D. 0.203 0.345 13.912 0.347 0.084 0.150 15.006 57.595 


(Pp) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 0.008 -0.019 0.500 0.020 0.151 18.958 0.002 187.460 

S.D. 0.007 0.002 0.000 0.020 0.005 0.048 0.003 1.077 

% R.S.D. 86.015 12.952 0.062 96.718 3.464 0.255 124.127 0.575 

NO SE A0 PS TI CD 8 K 

(ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (PPM) 

Mean -0.002 0.053 1.412 1.001 -0.000 1.028 -0.045 -0.049 

S.D. 0.001 0.015 0.002 0.020 0.001 0.004 0.001 0.012 

X R.S.D. 56.441 28.985 0.122 1.990 510.603 0.430 1.241 24.422 

MN SIT v BE TL 

Mean 

S.D. 

% R.S.D. 

(ppm) 

0.518 

0.001 

0.136 

(Ppm) 

-0.002 

0.029 

1725.849 

(ppm) 

0.503 

0.001 

0.229 

(ppm) 

0.504 

0.001 

0.207 

(Ppm) 

-0.060 

0.004 

7.038 

....................................... ............ ................... 

^; 1)J

Identity 1: PREPBLK Identity 2: Quality Control 

Took nave : TWC93 

10:06 AM July 24, 1995 

Sampte Weight 1.0000 Solution Volume 10.00 

On- ask 

i ntegrattons .. 3 ft-P 0 eak 

I ntegrattone . 1 

MC-M-WM-DP-1^1 , flE11.,^ 

..................... 

......... ...._..........._....._...____. 


(Ppm) (ppm) (ppm) (Ppm) (PPM) 

Mom -0.006 0.008 -0.007 0.688 0.134 

S.D. 0.010 0.001 0.152 0.013 0.066 

% R.S.D. 167.858 13.775 2106.594 1.946 49.148 


(Ppm) (Ppm) (Ppm) (ppm) (PPM) 

Now 0.286 4.858 -0.008 0.274 0.611 

S.D. 0.003 0.053 0.012 0.018 0.004 

It R.S.D. 1.208 1.093 149.645 6.494 0.684 

CE SM BA P S 

(ppm) (PPM) (PPM) (ppm) (PPM) 

Now 0.190 0.014 0.017 0.171 0.280 

S.D. 0.093 0.121 0.002 0.030 0.044 

It R.S.D. 48.888 894.838 12.944 17.288 15.540 

No SE AD PIP TI 

(ppm) (PPM) (ppm) (Ppm) (PPM) 

New 0.004 -0.325 0.013 -0.147 0.009 

S.D. 0.007 0.110 0.006 0.062 0.004 

It R.S.D. 206334 33.772 46.302 42.066 49.946 

MN SB V BE TL 

(ppm) (Ppm) (PPM) (Ppm) (PPM) 

Mean 0.063 0.092 0.033 0.004 0.126 

S.D. 0.005 0.181 0.014 0.001 0.183 

% R.S.D. 7.334 195.775 41.327 28.549 145.049 

âL 

CO Cu L 


-0.000 0.068 0.000 

0.015 0.004 0.004 

3387.701 5.817 916.560 

CR ND u 

(PM) (Ppm) (ppm) 

0.036 0.041 0.062 

0.009 0.043 0.513 

24.468 106.582 826.584 

NO AS NA 


0.072 -0.066 4.179 

0.002 0.053 0.000 

2.589 80.724 m 0.000 

CD B K 

(ppm) (ppm) (PPM) 

0.002 0.018 10268.435 

0.008 0.012 29.738 

556.491 63.854 0.290

Identity 1: $95T001132 L Identity 2: 1.8191gin250 . 1-9-1 . 4 10:18 AM July 24, 1995 

Ts'' -ame - TNC93 

S Weight : 1.8191 Solution volume : 12500.00 WHC-SD-WM-DP-_0, REV. 


---------------------------------------------------------------------- 

2R SR 81 SI AL CO CU LI 

( ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean -10.940 127.875 9061.860 4885.012 1283.376 26.857 23.758 6.163 

S.D. 3.526 0.365 28.688 16.914 34.532 0.001 1.290 0.860 

% R.S.D. 32.235 0.285 0.317 0.346 2.691 0.004 5.430 13.%l 

2M NI LA FE CA CR ND U 

( ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 68.416 30907.659 18.917 10643.238 332.998 489.499 46.364 1447.376 

S.D. 4.711 66.008 4.744 66.750 0.506 2.151 23.642 43.481 

X R.S.D. 6.686 0.214 25.078 0.627 0.152 0.439 50.992 3.004 


(Ppm ) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

New 0.454 -53.521 9.237 15988.992 7060.062 134.040 89.346 127009.901 

S.D. 29.101 15.280 0.281 215.346 76.738 0.642 18.812 243.975 

% R.S.D. 6416.402 28.549 3.043 1.347 1.087 0.479 21.055 0.192 

NO SE AO PS TI CD B K 

( ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) 

New 15.125 -194.449 -1.560 8.148 12.445 27.018 53.052 1732325.214 

S.D. 1.889 65.762 0.604 34.085 2.163 3.682 4.922 3429.124 

X R.S.D. 12.490 33.819 38.701 418.326 17.377 13.627 9.277 0.198 

MN SB 9 BE TL 

(PPM ) (ppm) (Ppm) (ppm) (Ppm) 

Mean 113.962 484.327 11.610 1.379 -282.808 

S.D. 1.046 39.310 3.479 1.436 45.849 

% R.S.D. 

0.918 8.116 29.%9 

104.176 

....................................... .............. ................. 

16.212 

5ZY!

Identity 1: 5957001132 Identity 2: 1.81919in250-1-9 10:22 AM July 24, 1995 

Teak name : 7NC93 

Sample Weight : 1.8191 Solution voluee : 2500.00 

On-Peek Integrations : 3 off-Peak Integrations : 1 

........................---...........- ---....---...------......---... 

WHC-SD-WM-DP- I : REV - 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean -11.946 127.706 9278.214 4864.580 1329.865 30.426 16.901 5.532 

S.D. 0.239 0.127 14.783 5.886 4.938 2.065 0.186 0.086 

% R.S.D. 1.998 0.099 0.159 0.121 0.371 6.787 1.102 1.556 

ZN N1 LA FE CA CR ND u 

(ppm) (Ppm) (ppe) (Ppn) (Ppm) (ppm) (ppn) (ppm) 

Mean 60.521 30990.468 0.377 10767.469 249.047 492.302 13.887 1470.464 

S.D. 1.507 40.954 1.889 20.688 0.253 3.396 5.078 8.089 

% R.S.D. 2.490 0.132 500.741 0.192 0.102 0.690 36.S64 0.550 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppn) (pp") (ppn) 

Mean 8.780 -9.368 8.815 16032.736 7016.351 129.968 5.346 119496.395 

S.D. 2.269 1.251 0.056 470.284 48.556 0.256 2.010 232.615 

% R.S.D. 25.843 13.352 0.638 2.933 0.692 0.197 37.591 0.195 

ND BE AG PB TI CD B K 

(PPO (Ppm) (PPm) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 2.299 23.493 1.766 27.070 12.679 11.267 31.299 1608646.030 

S.D. 0.419 8.175 0.120 13.873 0.281 1.389 1.507 2150.921 

% R.S.D. 18.232 34.796 6.789 51.247 2.219 12.332 4.816 0.134 

MN SB v BE TL 

(ppm) (ppm) (PPm) (Ppa) (ppm) 

Mean 118.071 30.370 3.897 0.552 -112.273 

S.D. 0.757 44.755 0.316 0.249 1.187 

% R.S.D. 

0.641 147.367 8.096 45.178 

1.057 

....................................... .............. .............. 

... 

r- 

. -Li

Identity 1: S95T001132 D Identity 2: 1.8163gin250-1-9 10:28 AN July 24, 1995 

Ta t- now : TNC93 


On-.eak Integrations : 3 

Off-Peek integrations : 1 

1 

I 

INK-0-WM-DP-j^ 

,_ 1 REV. JJ^^^ 

..................................................................."- 


(ppm) (Ppm) (PPm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -22.160 133.523 10858.199 5311.370 1450.668 41.921 30.048 6.114 

S.D. 1.770 0.293 33.880 6.893 13.910 2.062 0.826 0.277 

% R.S.D. 7.988 0.219 0.312 0.130 0.959 4.918 2.750 4.531 


(Ppm) (Ppm) (PPM) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 47.406 49565.440 1.140 11474.102 249.519 513.783 43.968 1697.726 

S.D. 1.754 40.809 2.517 13.637 0.529 2.767 10.560 35.425 

% A.S.D. 3.701 0.082 220.711 0.119 0.212 0.539 24.017 2.087 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (PPM) (ppm) (Ppm) 

Mean 21.959 21.617 9.568 16101.568 7007.418 137.663 7.324 119033.979 

S.D. 9.671 11.212 0.186 883.468 164.804 0.257 5.264 1029.359 

% R.S.D. 44.042 51.867 1.941 5.487 2.352 0.187 71.873 0.865 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppn) 

Mean 3.212 56.284 3.883 40.454 18.830 21.823 33.213 1469574.866 

S.D. 1.065 7.766 1.140 13.741 0.556 0.486 0.544 9414.245 

Z R.S.D.- 33.167 13.798 29.367 33.967 2.952 2.226 1.637 0.641 

NN SB V BE TL 

(ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 164.327 94.583 6.680 0.159 -132.280 

S.D. 0.362 46.911 0.965 0.147 37.329 

% R.S.D. 

0.221 49.598 14.439 

92.618 28.220 

....................................... ............................... 

5.â3

Ident ity 1: S95TOOI132 A Identity 2: 1.8191gin250-1-2-7 10:31 AM Juty 24, 1995 

Task now : TUC93 

$opt* Weight : 1.8191 Solution votuae 2500.00 


....................................... ............................... 

WHC-SD-WM-DP-^. 

..^ REV.-' 

ZR SR 61 


(ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) (mm) (ppm) 

Mean 1345.019 1487.658 10567.593 6167.583 2665.959 1416.492 1341.906 1253.312 

S.D. 1.697 4.606 79.590 23.872 16.284 0.003 5.414 6.041 

% R.S.D. 0.126 0.310 0.753 0.387 0.611 0.000 0.403 0.482 

ZN NI LA FE CA CR RD u 

(Ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 1410.931 32005.143 1385.698 12012.803 1663.763 1887.367 1437.169 3897.498 

S.D. 2.625 11.507 3.290 12.924 3.780 2.617 14.886 30.632 

% R.S.D. 0.186 0.036 0.237 0.108 0.227 0.139 1.036 0.786 

CE SM BA p S NO AS NA 

(Ppm ) (ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 1375.036 1332.184 1360.331 18127.330 8491.483 1506.126 1358.938 120754.737 

S.D. 6.612 6.421 4.095 348.981 49.670 2.354 1.094 629.249 

% R.S.D. 0.481 0.482 0.301 1.925 0.585 ' 0.156 0.080 . 0.521 

NO SE AD pB TI CD B K 

(ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) 

New 1379.618 1343.976 1044.743 1418.080 1351.590 1380.201 1353.164 1605670.804 

S.D. 5.434 16.794 7.358 5.482 3.079 2.711 2.862 8245.925 

% R.S.D. 0.394 1.250 0.704 0.387 0.228 0.196 0.211 0.514 

MN SB v BE TL 


Mean 1504.692 1336.322 1396.704 1339.910 1147.511 

S.D. 1.833 22.573 2.340 3.167 13.506 

% R.S.D. 

0.122 1.689 

0.168 0.236 1.177 

------------------------- 

-------------------------------------------- 

V tJ J)


Tao naeie : 7WC93 

S4 Weight : 1.0000 Solution Volume : 1.00 WHGSD-WM-DP- 

On,. k Integrati ono : 3 Off-Peak Integrations : 1 

' 

REV.(_ 

ZR SR BI SI AL CO CV LI 

(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Now 4.943 4.972 4.983 4.825 4.957 5.107 4.837 5.017 

S.D. 0.004 0.011 0.025 0.005 0.008 0.017 0.018 0.041 

% R.S.D. 0.080 0.217 0.496 0.108 0.163 0.332 0.379 0.810 


(Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 5.117 5.033 5.038 5.116 5.157 5.131 5.241 9.425 

S.D. 0.010 0.010 0.005 0.021 0.013 0.011 0.022 0.009 

% R.S.D. 0.198 0.193 0.095 0.420 0.255 0.206 0.416 0.099 


(Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 4.997 5.025 4.969 4.969 5.030 5.096 4.990 5.049 

S.D. 0.002 0.013 0.016 0.065 0.063 0.010 0.013 0.036 

% R.S.D. 0.039 0.256 0.324 1.307 1.246 0.189 0.266 a 0.721 

NO BE AG PB TI CO B K 

( ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

New 5.086 4.915 4.%3 5.101 4.892 5.101 5.073 5.275 

S.D. 0.010 0.023 0.003 0.037 0.002 0.008 0.009 0.030 

% R.S.D. 0.206 0.467 0.064 0.730 0.034 0.163 0.171 0.574 

MN SB V BE TL 


New 5.082 4.695 5.077 5.180 4.891 

S.D. 0.013 0.045 0.003 0.007 0.017 

% R.S.D. 

0.255 0.958 

0.068 

0.131 

0.346 

....................................... ....... .................... 

. ... 

v1

Identity 1:-CCI Identity 2: Quality Control 

Task news : TNC93 

Sarple Height : 1.0000 Solution Vol" 1.00 

On-Peak Integrations : 3 Off-Peek Integrations : 1 

...................................................°--- 

2R 

SR BI 

(PPM ) (Ppm) (PPM) 

Mean -0.000 0.000 -0.021 

S.D. 0.001 0.000 0.001 

% R.S.D. 30054.895 259.384 2.661 

2N NI LA 


Mean 0.000 -0.001 -0.001 

S.D. 0.000 0.001 0.002 

% R.S.D. 61.438 150.968 154.738 

CE SM BA 

(PPM) (PPM) (PPM) 

New 0.012 0.001 0.000 

S.D. 0.011 0.015 0.000 

% R.S.D. 89.665 2119.045 97.958 

MO BE AG 

(Ppm) (Ppm) (PPM) 

Mean 0.001 -0.032 0.002 

S.D. 0.001 0.011 0.001 

% R.S.D. 97.093 33.175 64.531 

MN SS V 

(Ppm) (PPM) (ppm) 

Mean -0.000 0.016 0.003 

S.D. 0.000 0.025 0.001 

% R.S.D. 

0.786 157.269 

33.951 

......................... ............ ............ 

....... 

10:40 AM July 24, 1995 

WHC-SD-WM-DP- / , REV. I 

SI AL CO Cu L 


0.006 0.001 -0.002 0.001 0.000 

0.002 0.001 0.004 0.000 0.000 

30.332 230.117 228.582 9.521 317.513 

FE CA CR NO u 

(PPa) (PPM) (PPM) (PPM) (PPM) 

-0.003 -0.000 -0.002 0.021 0.014 

0.000 0.000 0.002 0.013 0.055 

15.374 31.492 121.191 59.991 407.369 

P S MG AS NA 


-0.019 -0.003 0.000 0.001 0.029 

0.007 0.002 0.000 0.001 0.003 

34.931 68.533 2.490 96.245 12.084 

PB TI CD B • K 

(PPM) (PpM) (PPM) (PPM) (Ppm) 

-0.015 -0.000 0.001 0.002 0.133 

0.009 0.000 0.001 0.002 0.025 

59.623 166.436 87.813 70.129 18.543 

BE TL 

(Ppm) (Ppm) 

0.000 0.021 

0.000 0.016 

60.160 75.439 

r.2 

.30

Identity 1: S95TOO1133 L Identity 2: 1.7600gin250-1-9-1-4 10:43 AM July 24, 1995 



0, .sk Integrations : 3 Off-Peak Integrations : 1 

...................................................................... 

WHC-SD-WM-D?-M Rol, I 


(pPm) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean -33.461 119.091 9808.425 5151.360 1418.936 51.643 31.811 10.672 

S.D. 2.603 0.753 52.752 24.605 18.492 10.687 3.005 1.429 

% R.S.D. 7.778 0.632 0.538 0.478 1.303 20.694 9.448 13.390 

IN NI LA FE CA CR NO U 

(Ppm) (PPm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 57.950 41665.079 -14.689 10529.510 265.985 471.057 119.565 781.355 

S.D. 1.117 98.730 9.862 29.627 0.261 4.864 43.961 250.399 

It R.S.D. 1.928 0.237 67.138 0.281 0.098 1.032 36.768 32.047 


(ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean -67.925 -118.977 7.908 15439.300 7021.522 124.749 -22.025 125069.565 

S.D. 28.886 51.539 1.198 338.362 81.597 0.657 16.118 1080.515 

% R.S.D. 42.527 43.318 15.154 2.192 1.162 0.527 73.178 0.864 


(Ppm) (Ppm) (ppm) (Pp) (Ppm) (Ppm) (ppm) (ppm) 

Mean 15.946 -87.576 2.254 68.383 12.155 14.807 58.160 1522762.892 

S.D. 7.640 58.065 5.287 34.741 1.791 3.433 9.671 9421.714 

% R.S.D. 47.909 66.302 234.598 50.804 14.732 23.188 16.628 0.619 



Mean 143.579 50.542 0.882 2.215 -346.730 

S.D. 1.083 405.309 4.417 0.023 140.472 

It R.S.D. 

0.754 801.921 500.775 

1.057 40.513 

....................................... ................. .............. 

J %7aj

Identity 1: S95TOO1133 Identity 2: 1.7600gin250-1-9 10:46 AM July 24, 1995 

Task row : TNC93 

Sample Weight : 1.7600 


Solution Valuate 2500.00 


I 

WHC-SD-WM-DP- ! r , REV.. i 

....................°--..._..----------------------------...--------- 

2R 


(Ppm ) (Ppm) (ppm) (ppm) (ppm) (Pps) (Ppm) (Ppm) 

New -13.016 117.469 10048.179 5194.284 1377.150 34.294 16.591 7.912 

S.D. 0.505 0.131 58.225 2.932 6.194 4.276 0.566 0.136 

% R.S.D. 3.879 0.111 0.579 0.056 0.450 12.469 3.413 1.717 


( ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (Ppm) (ppm) 

Mean 40.250 41752.554 4.738 10553.595 268.400 491.068 7.171 1360.269 

S.D. 0.126 53.164 1.702 62.863 0.343 1.329 3.161 6.767 

% R.S.D. 0.313 0.127 35.927 0.596 0.128 0.271 44.084 0.498 

CE SN BA P S MG AS MA 

( ppm ) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

New 36.811 -0.561 8.306 16203.982 7015.182 124.534 3.871 119083.578 

S.D. 0.708 2.440 0.078 326.504 60.084 0.229 6.733 221.039 

% R.S.D. 1.924 434.591 0.934 2.015 0.856 0.184 173.909 0.186 


(PPM ) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (PPM) 

New 5.003 63.303 2.606 16.001 16.315 17.448 31.740 1437353.205 

S.D. 0.963 8.316 0.261 18.000 0.417 1.323 1.905 2475.670 

% R.S.D. 19.264 13.137 10.032 112.491 2.559 7.585 6.001 0.172 

MN SB V BE TL 


Mean 145.176 -0.713 4.563 0.641 -120.744 

S.D. 0.785 42.129 0.780 0.149 8.827 

% R.S.D. 0.541 5905.221 17.086 23.234 7.311 

b'i

Identity 1: S95T001133_D 

Task name : TN693 

Identity 2: 1.76409in250 . 1-9 10:50 AM July 24, 1995 

Be 

On-. 

Height : 1.7640 

,c Integrations : 3 

solution volume 2500.00 


WHC-SD-WM-DP-^, REV. 

........................... _ ------------------------------------------ 


(PPM ) (PPM) (PPm) (PPM) (PPM) (PPM) ( PPm) (PPM) 

Mean 5.818 119.903 7154.364 5418.805 1385.674 28.645 17.919 6.208 

S.D. 1.581 0.420 52.100 16.223 1.313 2.129 0.723 0.400 

% R.S.D. 27.169 0.351 0.728 0.299 0.095 7.431 4.036 6.443 



Mean 64.852 8012.923 0.079 9983.383 229.596 501.373 22.203 1252.932 

S.D. 0.174 26.992 2.594 32.149 1.026 1.554 1.961 46.642 

It R.S.D. 0.268 0.337 3282.527 0.322 0.447 0.310 8.834 3.723 


(PPM ) (PPM) (Ppm) (PPM) (PPM) (PPM) (PPM) (PPM) 

Mean 25.788 11.323 8.214 16474.560 7123.336 117.683 0.882 120428.070 

S.D. 15.266 16.760 0.214 498.868 82.899 0.529 4.267 1021.912 

% R.S.D. 59.197 148.024 2.599 3.028 1.164 0.450 483.685 m 0.849 

M0 SE AG PB 71 CD B K 


Mew 1.248 52.562 1.176 34.210 6.565 6.204 35.898 1527578.547 

S.D. 1.405 9.393 1.298 4.846 0.703 0.985 0.865 11358.030 

% R.S.D. 112.583 17.870 110.315 14.166 10.712 15.882 2.409 0.744 

MN SIT y BE TL 


New 52.977 8.210 5.763 0.459 -;4.088 

S.D. 0.865 25.958 1.333 0.152 42.166 

% R.S.D. 

1.633 316.158 

23.132 33.100 175.047 

................................... ."......--"......_..---- °-"---' 

.rr^J

Identity 1: S95TOO1133_A Identity 2: 1.76009 in250-1-2-7 10:53 AM July 24, 1995 

Task now : Tk'C93 

Sample Height : 1.7600 Solution Volume 2500.00 

On-Peak Integrations : 3 Off-Peek Integrations : 1 

WHC-SD-WM-DP- ^^ , REV 

.................................... ....... ........................... 


(ppm) (ppm) (PPM) (ppm) (ppm) (Ppm) (Ppm) (PPM) 

Mean 1405.688 1545.030 11484.562 6577.523 2807.976 1471.796 1406.384 1327.213 

S.D. 4.998 6.029 75.107 16.501 11.664 4.262 6.528 7.113 

% R.S.D. 0.356 0.390 0.654 0.251 0.415 0.290 0.464 0.536 

ZN NI LA FE CA LR ND u 

(ppm) (ppm) (ppm) (PPM) (ppm) (Ppm) (PPP) (Ppm) 

Mean 1425.171 43029.583 1447.387 11984.519 1710.182 1935.464 1510.990 4011.859 

S.D. 1.734 145.020 10.313 22.508 5.855 5.292 12.461 38.010 

% R.S.D. 0.122 0.337 0.713 0.188 0.342 0.273 0.825 0.947 


(Ppm) (ppm) (Ppm) (ppm) (ppM) (PP^) (Ppm) (PPP) 

Now 1444.694 1423.071 1429.555 17586.335 8347.330 1547.671 1411.433 121958.887 

S.D. 8.326 0.671 6.147 324.201 129.103 2.984 16.599 693.599 

% R.S.D. 0.576 0.047 0.430 1.865 1.547 0.193 1.176 0.569 

ND BE AD PB TI CD B K 

(Ppm) (Ppm) (Ppm) (PPm) (Ppm) (Ppm) (PPM) (Ppm) 

New 1433.199 1475.013 1010.112 1434.125 1413.897 1440.899 1415.745 1444847.290 

S.D. 3.486 5.810 9.402 21.254 2.817 4.802 3.120 6442.037 

% R.S.D. 0.243 0.394 0.931 1.482 0.199 0.333 0.220 0.446 

MR SB V BE TL 

(ppm) (Ppm) (ppm) (Ppm) (ppm) 

Mean 1586.986 1365.293 1450.949 1407.175 1277.747 

S.D. 1.637 10.476 3.546 4.766 23.051 

% R.S.D. 

0.103 0.767 0.244 

0.339 

1.804 

....................................... ............. ............ ...... . 

C7!

Identity 1: ICSA Identity 2: guatfty Control 10:57 AM July 24, 1995 

To" Ivne : TNC93 

Weight : 1.0000 Sotutfon yotme : 1.00 

WHC•SD-WM-DP-__^j , REV.. 

On-reek Integrations : 3 Off-Peak Integratf ons : 1 

...................................................................... 

ZR 


(PPM) (PPM) (PPM) (PPM) (PPM) (PPM) (PPM) (PPM) 

New -0.003 0.000 -0.019 0.063 199.712 0.009 -0.013 0.000 

S.D. 0.001 0.000 0.009 0.003 0.411 0.004 0.000 0.000 

% R.S.D. 24.808 28.620 46.347 4.220 0.206 45.786 2.518 67.335 



New 0.000 -0.049 0.010 147.061 18.963 -0.012 0.028 -0.007 

S.D. 0.001 0.003 0.001 0.576 0.054 0.002 0.003 0.023 

X R.S.D. 275.804 5.425 13.430 0.392 0.282 16.506 11.714 313.645 



New 0.005 -0.015 0.003 0.023 0.147 19.097 0.016 188.427 

S.D. 0.005 0.007 0.000 0.020 0.007 0.042 0.004 0.946 

% R.S.D. 104.334 45.529 3.129 87.640 5.079 0.218 24.483 0 0.502 

NO SE AG PB TI CO 6 K 

(PPM) (PPM) (PPM) (PPM) (PPM) (PPM) (PPM) (PPM) 

New -0.002 -0.013 -0.002 0.011 0.000 0.012 -0.045 0.233 

S.D. 0.001 0.004 0.000 0.014 0.000 0.001 0.002 0.003 

% R.S.D. 52.360 29.559 22.037 120.884 147.868 7.796 4.209 1.498 

MN SB y BE TL 


New 0.010 0.015 -0.004 0.002 -0.065 

S.D. 0.000 0.017 0.001 0.000 0.013 

% R.S.D. 

3.742 111.995 

14.201 0.089 20.457 

..................................... .................. ...°-.----"-- 

J ^ M

Identity 1: ICSAB 


Identity 2: Quality Control 11:00 AM July 24, 1995 

Sample We ight : 1.0000 Solution Volume : 1.00 

On-Peek Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

2R SR BI SI 

(Ppm ) (ppm) (Ppm) (ppm) 

Now -0.006 0.000 0.000 0.054 

S.D. 0.001 0.000 0.003 0.007 

% R.S.O. 13.853 24.424 839.385 12.092 

2N NI LA FE 

(PPM) (ppm) (ppm) (Ppm) 

New 1.023 0.940 0.005 149.491 

S.D. 0.002 0.003 0.002 0.234 

X R.S.D. 0.222 0.316 45.049 0.157 

CE SM BA P 


New 0.007 -0.019 0.503 0.034 

S.D. 0.011 0.010 0.002 0.005 

% R.S.D. 165.812 54.050 0.399 15.482 

NO BE AG PB 

(PPM) (ppm) (ppm ) (Ppm) 

Now -0.001 0.051 1.487 1.044 

S.D. 0.002 0.010 0.002 0.017 

% R.S.D. 119.442 19.800 0.161 1.596 

MM SB V BE 

( pPS ) (PPM) (Ppm) (ppm) 

Mean 0.521 0.036 0.509 0.509 

S.D. 0.002 0.047 0.001 0.001 

% R.S.D. 

0.294 129.584 0.118 

0.266 

......................................... .......... ................... 

WHC-SD.WM-DP- 0 , REV. I 

AL CO Cu LI 


201.082 0.512 0.480 0.942 

0.919 0.000 0.002 0.005 

0.457 0.001 0.440 0.551 

CA CR NO u 


18.576 0.507 0.047 -0.061 

0.079 0.002 0.005 0.042 

0.426 0.296 11.162 68.034 

S MG AS NA 


0.158 19.101 0.003 188.932 

0.000 0.035 0.006 1.082 

0.158 0.183 176.464 0.573 

TI CD 8 K 


-0.000 1.035 -0.044 0.191 

0.001 0.002 0.000 0.003 

132.642 0.236 1.118 1.826 

TL 

(ppm) 

-0.080 

0.018 

22.605 

.ri ^J

Identity 1: CCv_l Identity 2: CCv_l 11:04 AM July 24, 1995 

Task hose : TNC93 

Sr Weight : 1.0000 Solution votme 1.00 

of Integrations : 3 Off-Peak Integrotl ons : 1 

. -------------------------------------- 

............................ 

ZR SR BI SI 

(PPm ) (ppm) (Ppm) (Ppm) 

Mean 4.929 4.966 4.953 4.822 

S.D. 0.010 0.010 0.012 0.004 

% R.S.D. 0.205 0.198 0.245 0.081 

ZN NI LA FE 

. (Ppm) (Ppm) (Ppm) (ppm) 

Mean 5.131 5.035 5.024 5.134 

S.D. 0.002 0.023 0.034 0.028 

% R.S.D. 0.035 0.456 0.678 0.549 

CE SM BA P 


Mean 5.003 5.096 4.960 5.207 

S.D. 0.006 0.017 0.012 0.135 

% R.S.D. 0.123 0.342 0.239 2.600 

NO SE AG pB 

(Ppm) (PPM) (Ppm) (PPM) 

Mean 5.081 4.906 4.975 5.060 

S.D. 0.013 0.006 0.007 0.013 

% R.S.D. 0.254 0.114 0.149 0.264 

MN SB v BE 


Mean 5.076 4.679 5.062 5.170 

S.D. 0.011 0.027 0.006 0.005 

% R.S.D. 0.217 0.575 0.123 0.096 

AL 

(ppm) 

4.984 

0.010 

0.210 

CA 

(Ppm) 

5.145 

0.012 

S 

u r 'v 

- ^ 

0.227 

(Ppm) 

5.131 

0.056 

TI 

1.087 

(Ppm) 

4.880 

0.009 

0.177 

TL 

(PPR) 

4.854 

0.002 

0.036 

WHC-SD-WM-DP-.^, REV. 

CO 

(ppm) 

5.106 

0.012 

0.241 

CR 

(Ppm) 

5.117 

0.013 

0.250 

MG 

(Ppm) 

5.093 

0.004 

CD 

0.069 

(PpR) 

5.083 

0.002 

0.030 

Cu 

(Ppm) 

4.834 

0.008 

NO 

0.176 

(ppm) 

5.239 

0.042 

AS 

0.793 

(ppm) 

5.005 

0.022 

B 

(ppm) 

0.448 

5.089 

0.013 

0.264 

L 

(Ppm) 

5.040 

0.013 

0.262 

u 

(Ppm) 

9.351 

0.045 

NA 

(Ppm) 

0.476 

5.100 

0.019 

0.380 

• K 

(ppm) 

5.341 

0.025 

0.468

Identity is CCB_1 Identity 2: CCB 1 11:07 AM July 24, 1995 

Task 

Sample Weight- 1.0000 Solution Volume 1.00 WHC•SD-WM-DP- I ^ ^ , REV 

On-Peak Integration : 3 Off-Peak Integrations : 1 

--------------------------------------------- 

2R SR 

------- 

BI 

------------------ 


(ppm ) (Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

mean -0.001 0.000 -0.002 0.008 0.000 -0.002 0.001 0.001 

S.D. 0.001 0.000 0.009 0.000 0.008 0.002 0.000 0.000 

% R.S.D. 123.386 0.111 424.986 5.073 2107.463 86.686 28.653 29.025 

ZM NI LA FE CA CR NO u 

(Ppm ) (ppm) (Ppm) (ppm) (mm) (Ppm) (ppm) (PPM) 

Mean 0.001 -0.000 0.002 -0.003 -0.000 0.000 0.021 0.003 

S.D. 0.001 0.001 0.002 0.000 0.000 0.001 0.006 0.021 

% R.S.D. 77.903 263.859 91.769 14.237 15.746 432.113 28.918 789.817 


(Ppm) (ppm) (PPM) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean -0.004 -0.007 -0.000 -0.004 0.004 -0.000 0.009 0.060 

S.D. 0.005 0.007 0.000 0.010 0.005 0.000 0.006 0-DO3 

% R.S.D. 124.827 101.452 78.037 268.313 114.565 86.542 64.916 5.092 


(ppm) (Ppm) (pPM) (ppm) (ppm) (ppm) (ppm) (ppm) 

New 0.002 0.005 0.001 -0.018 0.000 0.001 0.004 0.192 

S.D. 0.001 0.009 0.000 0.005 0.001 0.000 0.001 0.007 

% R.S.D. 50.224 173.073 12.432 30.201 215.182 21.655 15.558 3.557 

MN SB V BE TL 


Mean 0.000 -0.048 0.001 0.000 -0.007 

S.D. 0.000 0.011 0.001 0.000 0.016 

% R.S.D. 

43.481 22.027 123.200 114.637 242.733 

--------------------------------------- ------------------------------- 

5,710

06/28/05 10:05 WHC-SD-WM-D?-LL, REV Page: 1 

A-0003-1 


.nalyst: 13 Czc-z cU" Instrument: ICP01 Book# î36syS 

Method: LA-505-151 Rev/Mod d - Z 








6 SAMPLE S95TOO1138 0 F @ICP-F03 SOLID 95000088 B-104 








12 DUP S95TOO1139 0 F @ICP-F03 SOLID 

13 SPK S95TOO1139 0 F @ICP-FO3 SOLID 







r- M

06/28/95 10:05 WHC-SDVWDP -^, REV--Z Page: 2 

A -0004-1 




n t ignature Date AnaIVAt Signature Date 

/p^^j^ /C ?x ^ ! c - S— c. /O 

Sff 7-00 il1Y_L / - 9•.c -/ -4_ C ihvo 

SSi Tw//3P 7.vS3vf ,32LC C 

y5,"TcaO l/jy-_ . C C 

h2^ 

S9 3-7-00 i/35_ c y.9/yo^ •- -c /-c-5_c - i c v_c /^,^ 

$5)' 7-c;,7//j`/ Y. 57Y3g .v 7sv C -/^C - Sic 1^^ 

59,-7w //35_ Y 9350 y '- by c - l -I c ^^^-' 

57s'Tv /cjS_^ Y. 9rr05 7szJ _L c- R.^-7 C lrvv 



^^ti 

-

Identity 1: ICV Identity 2: Qua lity Control 1:04 PM July 24, 1995 

T p^^ nose : TVC93 

Weight : 1.0000 setution Voluae : 1.00 WHC-SD-WM-DP- 13Z,, REV. 

On-reek Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

ZR SR 81 sl AL CO Cu LI 

(Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 4.889 4.943 4.912 4.753 4.899 4.978 4.828 5.054 

S.D. 0.009 0.014 0.024 0.003 0.008 0.005 0.017 0.024 

% R.S.D. 0.181 0.291 0.481 0.062 0.167 0.109 0.358 0.469 


( Ppm) (PPm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

New 5.010 4.932 5.019 5.075 5.130 5.006 5.348 9.381 

S.D. 0.002 0.003 0.015 0.010 0.015 0.005 0.025 0.031 

% R.S.D. 0.036 0.053 0.301 0.198 0.288 0.092 0.471 0.330 


( ppm) (ppm) (PPN) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 4.958 5.017 4.951 4.843 4.914 4.989 4.929 5.036 

S.D. 0.002 0.016 0.017 0.232 0.095 0.000 0.011 0.025 

% R.S.D. 0.048 0.309 0.336 4.786 1.943 0.004 0.229 • 0.505 

MO SE AG PB T1 CD B K 

(PPm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (PPm) (Ppm) 

Mean 4.978 4.872 4.886 4.976 4.820 5.010 5.070 5.224 

S.D. 0.006 0.023 0.004 0.012 0.011 0.005 0.018 0.037 

% R.S.D. 0.124 0.469 0.078 0.244 0.223 0.095 0.360 0.717 

MM SB V BE TL 

( Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 4.998 4.608 5.000 5.126 4.830 

S.D. 0.004 0.021 0.002 0.014 0.006 

% R.S.D. 

0.085 0.453 0.048 

0.279 0.129 

....................................... ............................... 

^ 17 L1( KIVIJ 

e r :• • :^• • :. u ti eau 1 â4a • • or: 

a is 

57.3 

b^^TCO ^1 13 1 9{Q7y,^P, 

S cy r '

Identity is ICS Identity 2: Quality Control 1:08 PM July 24, 1995 

Task range : TWC93 

Srip(e Weight : 1.0000 Solution Volume 1.00 

On-Peak Integratims : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 


(Ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean -0.002 0.000 -0.003 -0.002 -0.002 

S.D. 0.001 0.000 0.003 0.003 0.006 

X R.S.D. 27.724 37.268 122.725 108.812 367.319 


(Ppm) (Ppm) (PPm) (Ppm) (ppm) 

Mean 0.000 -0.004 -0.000 0.001 -0.000 

S.D. 0.000 0.001 0.001 0.003 0.000 

% R.S.D. 42.003 31.024 2747.548 221.555 9.623 

CE SM BA P S 

(PI N ) (ppm) CPPm) (ppm) (ppm) 

Mean 0.001 -0.016 -0.000 -0.016 -0.004 

S.D. 0.005 0.003 0.000 0.012 0.001 

% R.S.D. 874.383 20.257 18.697 73.748 34.296 

NO SE AO PB TI 

(ppm) (Ppm) (ppm) (ppm) (ppm) 

New 0.002 -0.016 0.000 -0.022 -0.001 

S.D. 0.000 0.010 0.000 0.011 0.000 

It R.S.D. 15.232 61.712 144.931 48.681 52.686 

MN SB v BE TL 


New -0.000 0.018 0.001 -0.000 -0.032 

S.D. 0.000 0.030 0.001 0.000 0.010 

% R.S.D. 34.994 165.798 111.739 1689.118 31.260 

5711 

WHC-SD-WM-DP- /3'7, REV. / 

CO Cu LI 


0.000 0.002 0.000 

0.002 0.000 0.000 

16875.285 20.500 15.766 

CR NO u 


-0.001 0.024 -0.065 

0.000 0.007 0.020 

58.789 30.414 30.099 

NO AS NA 


-0.000 0.011 0.004 

0.000 0.003 0.001 

59.746 29.582 . 28.865 

CD 8 K 


0.000 0.004 0.021 

0.000 0.001 0.012 

262.317 16.342 55.673

Identity 1: ICSA Identity 2: Quality Control 


F t Weight : 1.0000 Solution Volume 1.00 

L. -ak Integrations : 3 Off-Peak integrations : 1 

......................... 

2R 

............................... 

SR BI 

(ppm) (ppm) (Ppn) 

Mean -0.004 0.001 -0.019 

S.D. 0.001 0.000 0.006 

% R.S.D. 33.795 22.431 34.212 

2N NI LA 

(ppm) (ppm) (Ppn) 

Mean 0.001 -0.054 0.011 

S.D. 0.000 0.001 0.002 

% R.S.D. 21.123 1.886 18.912 

CE SM BA 

(Ppm) (ppm) (Pp) 

New 0.004 -0.027 0.003 

S.D. 0.017 0.016 0.000 

' % R.S.D. 402.762 56.928 9.229 

NO SE AG 

(Ppn) (ppm) (Ppm) 

Mean -0.001 -0.038 -0.002 

S.D. 0.001 0.010 0.001 

% R.S.D. 53.927 26.212 50.284 

MN SB V 

( Ppn) (ppm) (ppm) 

Mean 0.010 0.021 -0.004 

S.D. 0.000 0.066 0.001 

% R.S.D. 2.873 314.776 23.040 

1:11 PM July 24, 1995 

------------ -- 

SI 

AL 

(ppm) (Ppm) 

0.059 198.734 

0.002 0.793 

3.389 0.399 

FE CA 

(ppm) (p;n) 

146.699 18.921 

0.136 0.032 

0.093 0.169 

P S 

( ppm) (ppm) 

0.037 0.148 

0.016 0.005 

43.086 3.258 

P8 TI 

(Ppm) (Ppm) 

0.017 -0.000 

0.006 0.001 

38.561 613.981 

BE TL 

(ppm) (ppm) 

0.003 -0.079 

0.000 0.030 

4.107 38.018 

WHGSD-WM-DP- /37 REV.L 

CO Cu L( 


0.010 -0.012 0.001 

0.002 0.000 0.000 

14.460 2.485 74.936 

CR NO u 

(ppm) (Ppn) (ppm) 

-0.009 0.031 -0.068 

0.002 0.008 0.072 

25.388 25.836 105.445 

MG AS NA 

( pr n ) (ppm) (ppm) 

18.996 0.001 190.155 

0.019 0.002 1.862 

0.098 141.367 0.979 

CD B K 

( pFxn) (ppm) (Ppm) 

0.011 -0.047 -0.023 

0.000 0.000 0.028 

2.930 0.772 122.202



Sample Weight : 1.0000 solution volume : 1.00 WHC-SD-WM-DP-REV. 


---------------------------------------------------------------------- 

2R 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.002 0.000 -0.000 0.052 200.597 0.510 0.481 0.947 

S.D. 0.001 0.000 0.008 0.001 0.669 0.002 0.002 0.002 

It R.S.D. 37.200 43.523 3788.357 2.117 0.333 0.295 0.367 0.229 

2M MI LA FE CA CR MD U 

(Ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 1.026 0.946 0.011 150.985 18.622 0.502 0.028 0.066 

S.D. 0.001 0.006 0.002 0.390 0.047 0.002 0.004 0.015 

% R.S.D. 0.051 0.662 15.734 0.258 0.251 0.400 13.452 21.514 


( ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean 0.019 0.003 0.503 0.028 0.165 19.055 0.001 189.414 

S.D. 0.002 0.006 0.002 0.006 0.003 0.023 0.006 0.406 

It R.S.D. 9.838 211.464 0.300 23.203 1.540 0.120 682.691 0.214 

MO SE AD PIT TI co B K 

(Ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (PPR) 

Mean 0.001 0.041 1.499 1.015 0.001 1.033 -0.044 0.055 

S.D. 0.000 0.016 0.002 0.026 0.000 0.006 0.001 0.009 

It R.S.D. 28.641 40.345 0.157 2.521 53.440 0.551 2.399 15.775 

MM S9 v BE TL 


Mean 0.521 0.021 0.511 0.507 -0.029 

S.D. 0.002 0.033 0.002 0.001 0.013 

It R.S.D. 0.336 161.255 0.321 0.206 46.864

Identity 1: PREPBLK Identity 2: Quality Control 1:21 PM July 24, 1995 

Teek neae : TWC93 

t Weight : 1.0000 Solution volume : 10.00 WHGSD-WM-J?- 1,3 1, REV. 

P.. eak Integrations : 3 Off-Peak Integrations : 1 

...................................................................... 

ZR SR BI SI AL CO Cu L1 

( ppm) (Pam) (ppm) (ppm) (ppm) (ppm) (Pan) (ppm) 

Mean 0.007 0.007 0.065 0.760 0.028 0.008 0.109 0.003 

S.D. 0.008 0.001 0.171 0.026 0.083 0.015 0.005 0.003 

% R.S.D. 113.879 7.203 263.272 3.395 297.481 183.565 4.406 119.962 


(PPM) (Pp) (ppm) (ppin) (ppm) (ppm) (ppm) (Pam) 

Meer 0.246 4.670 0.024 0.214 0.365 0.014 0.086 0.469 

S.D. 0.005 0.020 0.025 0.018 0.001 0.015 0.089 0.254 

% R.S.D. 2.015 0.424 103.410 8.234 0.175 107.496 103.845 54.037 


(Ppm) (Ppm) (ppm) (Pan) (ppm) (ppm) (ppm) (ppm) 

Mean 0.066 0.172 0.017 0.013 0.282 0.077 0.100 5.423 

S.D. 0.030 0.042 0.002 0.125 0.019 0.000 0.036 0.012 

% R.S.D. 45.097 24.169 9.379 933.071 6.654 0.008 36.339 0.213 

NO BE AG PB TI CO 6 K 

(ppm) (ppm) (Ppm) (ppm) (Pan) (Ppm) (ppm) (ppm) 

Mean 0.031 -0.250 0.014 0.047 0.011 0.023 0.039 11097.819 

S.D. 0.005 0.108 0.005 0.103 0.005 0.001 0.008 25.989 

% R.S.D. 17.077 43.353 38.036 219.782 47.629 5.790 20.160 0.234 

MN SB v BE TL 


Mean 0.045 0.357 0.019 0.001 0.242 

S.D. 0.002 0.085 0.008 0.000 0.079 

% R.S.D. 3.424 23.900 41.664 1.897 32.463 

J

Identity 1: S95TOO1138_L Identity 2: 5.03309 in250-1-9-1-4 1:25 PM July 24, 1995 

Task rase : TWC93 

Sample weight : 5.0330 Solution Volume 12500.00 WHC-SD-WM-DP-1J^, REV. 


........ ............................... ............................... 


(PPM ) (Ppn) (ppm) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) 

Mean 12.857 76.956 8368.824 3101.077 948.827 8.409 4.803 5.856 

S.D. 4.406 0.265 40.181 11.042 13.128 3.725 0.620 0.546 

% R.S.D. 34.272 0.345 0.480 0.356 1.384 44.299 12.917 9.321 


( Ppm ) (PPM) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 33.427 1236.725 0.563 6711.441 131.654 314.668 1.258 797.762 

S.D. 0.925 7.484 6.207 19.712 0.556 7.456 15.451 142.418 

% R.S.D. 2.768 0.605 1102.139 0.294 0.422 2.369 1228.588 17.852 


(Ppm ) (PPM) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (PPM) 

Mean 14.361 -6.614 5.184 9668.560 4882.128 78.290 0.632 91849.540 

S.D. 25.461 38.129 0.700 318.094 31.748 0.233 14.449 763.950 

% R.S.D. 177.299 576.510 13.511 3.290 0.650 0.298 2287.282 0 0.832 

MO BE AG p8 TI CD 8 K 

(PPM ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 2.952 145.201 1.270 13.099 4.510 5.085 25.455 417421.689 

S.D. 0.501 32.803 2.464 11.988 1.095 1.524 0.946 3806.792 

% R.S.D. 16.973 22.591 194.112 91.522 24.283 29.977 3.717 0.912 

NN SB V BE TL 


New 23.538 32.818 1.884 0.674 51.968 

S.D. 1.008 73.942 1.874 0.267 43.258 

% R.S.D. 4.283 225.309 99.487 39.557 83.240 

S_ 8

Identity 1: S95TOO1138 Identity 2: 5.0330gin250-1 . 9 1:29 PM July 24, 1995 

To' now : TWC93 

S Weight : 5.0330 




WHC-SD-WM-DP-_Z^Z, REVS 

...........................................---•--------•------------'- 


( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (Pp) (Ppm) 

Mean 15.292 76.315 8577.611 3168.624 976.936 4.523 4.676 5.710 

S.D. 0.370 0.317 44.188 12.261 2.967 0.002 0.219 0.118 

% R.S.D. 2.420 0.416 0.515 0.387 0.304 0.041 4.692 2.062 


(Ppm) (Ppm) (PPm) (ppm) (Ppm) (Ppm) (Pp) (Ppm) 

Mean 34.224 1251.325 -0.399 6801.243 134.071 326.694 5.076 817.852 

S.D. 0.314 2.054 1.492 23.384 0.503 1.955 5.770 15.123 

% R.S.O. 0.918 0.164 373.580 0.344 0.375 0.598 113.673 1.849 


(ppm) (Ppa) (ppm) (ppm) (Ppm) (Pp) (Ppm) (pp) 

Mean 10.457 6.411 4.543 10144.604 4987.879 79.334 3.821 86031.538 

S.D. 2.786 3.376 0.069 88.667 29.566 0.122 2.602 805.528 

% R.S.D. 26.642 52.665 1.515 0.874 0.593 0.154 68.095 • 0.936 


( ppm ) (ppm) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) 

New 1.356 48.108 0.463 19.966 3.815 1.690 18.867 389386.357 

S.D. 1.061 2.028 0.379 0.778 0.275 0.065 0.348 3174.830 

% R.S.D. 78.222 4.215 81.903 3.896 7.213 3.853 1.843 0.815 

MN SB V BE TL 

(pp) (ppm) (ppm) (ppm) (Ppm) 

Mean 23.351 -22.465 2.223 0.106 0.121 

S.D. 0.227 4.521 0.066 0.051 10.704 

% R.S.D. 

0.972 20.127 2.981 

47.488 8837.440 

----------------------------------------- ------------- ------------- --- 

r'7J

identity 1: S95TOO1138 D Identity 2: 5.0180gin250-1-9 1:34 PM July 24, 1995 





Off-Peek Integrations : 1 WHC-SD-WM-DR- REVD 

-------------------------------------•-------•---.........-..--------- 


(Ppm) (PpR) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 17.790 91.644 10395.009 4418.918 1207.362 0.280 5.248 6.559 

S.D. 0.547 0.365 40.100 4.879 2.993 0.751 0.408 0.136 

It R.S.O. 3.075 0.398 0.386 0.110 0.248 268.312 7.774 2.072 


(Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

New 42.920 368.650 0.396 7739.167 158.467 405.267 -0.348 905.810 

S.D. 0.294 2.484 0.348 6.314 0.656 1.992 5.309 25.187 

It R.S.D. 0.684 0.674 87.737 0.082 0.414 0.492 1525.780 2.781 


(Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 26.693 -5.365 5.053 12278.749 5890.727 96.025 0.931 97991.652 

S.D. 7.186 7.917 0.092 161.891 20.667 0.242 1.918 743.982 

X R.S.D. 26.919 147.566 1.827 1.318 0.351 0.252 206.027 . 0.759 



New 1.272 67.323 0.075 28.367 4.575 1.511 21.465 444454.296 

S.D. 0.174 5.835 0.639 4.982 0.382 0.602 0.509 2571.831 

It R.S.D. 13.685 8.668 850.732 17.561 8.348 39.835 2.373 0.579 

MN SB V BE TL 


Mean 25.908 15.417 2.659 -0.035 -12.210 

S.D. 0.151 9.599 0.501 0.092 14.102 

It R.S.D. 

0.584 62.264 18.841 260.202 115.489 

.............°-.--......-°.--....... ....--........°---.-- .....----- 

J3:.)

Identity 1: S957001138_A Identity 2: 5.0330gin250-1-2-7 1:37 PM July 24, 1995 


I +Weight : 5.0330 Sotut(on yetune 2500.00 

0,.. eak Integrations : 3 Off-Peak Integrations : 1 

-- ............................^.------------------------...---------- 

WHGSD- SD--,Z, D'r REV, 


(PPM ) (PPM) (PPM) (PPm) (PPm) (Ppm) (ppm) (PPM) 

Mean 511.372 576.040 9073.378 3628.562 1472.287 503.323 491.189 468.365 

S.D. 0.509 0.636 3.896 1.423 3.518 2.692 1.487 2.812 

% R.S.D. 0.100 0.110 0.043 0.039 0.239 0.535 0.303 0.600 

2N NI LA FE CA CR NO W 


Mean 523.649 1754.035 509.997 7270.956 650.983 829.297 531.980 1735.181 

S.D. 0.417 2.522 3.046 20.109 0.999 0.695 5.654 19.866 

% R.S.D. 0.080 0.145 0.597 0.277 0.153 0.084 1.063 1.145 


(PPM ) (PPM) (PPM) (PPM) (PPM) (PPM) (ppm) (PPM) 

Neon 529.581 499.262 501.905 10852.650 5490.069 577.154 494.607 86575.259 

S.D. 2.893 5.029 0.816 263.161 49.536 1.125 3.703 409.686 

% R.S.D. 0.546 1.007 0.162 2.425 0.902 0.195 0.749 0.473 


(PPM ) (PpM) (PPM) (PPM) (PPM) (PPM) (ppm) (PPM) 

Mean 500.369 527.669 434.747 516.596 491.019 500.617 504.684 387805.605 

S.D. 0.512 6.335 2.583 5.845 0.411 0.770 1.542 1934.246 

% R.S.D. 0.102 1.201 0.594 1.131 0.084 0.154 0.305 0.499 

MN SB y BE TL 

(ppm) Oise) (PPM) (PPM) (ppm) 

Mean 526.887 445.845 509.272 491.779 476.190 

S.D. 0.948 12.598 0.654 0.994 14.218 

% R.S.D. 

0.180 2.826 0.128 

0.202 

2.986 

....................................^. ..................-- 

..--....... 

vl'j.i


Task name : TWC93 / 

Sanple Weight : 1.0000 Solution volume : 1.00 

WHC-SD-WM-DP- ^^ REV--Z- 

On- Peak Integrati wo : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (PPn) (Ppm) 

Mean 4.928 4.971 4.945 4.761 4.923 4.990 4.875 5.100 

S.D. 0.008 0.012 0.030 0.004 0.008 0.010 0.012 0.018 

% R.S.D. 0.163 0.233 0.604 0.079 0.153 0.209 0.242 0.350 


(Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 5.028 4.968 5.071 5.123 5.174 5.013 5.461 9.449 

S.D. 0.001 0.011 0.013 0.011 0.010 0.006 0.027 0.027 

% R.S.D. 0.024 0.230 0.252 0.212 0.187 0.115 0.488 0.282 


(Ppm ) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) 

Mew 4.956 4.997 4.986 4.680 4.788 4.999 4.906 5.112 

S.D. 0.009 0.012 0.013 0.083 0.033 0.003 0.023 0.014 

X R.S.D. 0.184 0.244 0.263 1.774 0.693 0.055 0.467 0.266 



Mean 4.968 4.806 4.923 5.026 4.840 5.031 5.126 5.509 

S.D. 0.003 0.007 0.004 0.036 0.009 0.011 0.005 O.D12 

It R.S.D. 0.069 0.148 0.082 0.720 0.179 0.221 0.097 0.212 

MN Sill v BE TL 

(Ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 5.017 4.697 5.031 5.149 4.824 

S.D. 0.003 0.038 0.009 0.009 0.012 

% R.S.D. 0.061 0.805 0.174 0.182 0.242 

32,


Task now : TNC93 

t Weight : 1.0000 Solution Va(ume : 1.00 WHC-SD-WM-DP- 13 Z, REV. 

ON. . oak Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

ZR 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.001 0.000 -0.009 -0.001 -0.003 0.003 0.001 0.000 

S.D. 0.001 0.000 0.005 0.004 0.003 0.004 0.000 0.000 

I R.S.D. 138.267 2S6.645 56.283 350.557 115.474 152.377 28.106 104.318 


(Ppm) (PPM) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.001 -0.006 -0.004 -0.000 -0.000 0.000 0.014 -0.040 

S.D. 0.000 0.002 0.001 0.001 0.000 0.001 0.009 0.046 

% R.S.D. 23.543 32.053 38.562 379.734 13.636 397.352 63.265 114.541 


(Ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -0.002 -0.009 -0.000 -0.001 -0.005 -0.000 0.008 0.033 

S.O. 0.007 0.014 0.000 0.005 0.002 0.000 0.002 0.004 

% R.S.D. 302.083 168.034 593.364 823.128 48.487 1.038 27.179 12.245 

No SE AG PB TI CD B K 

(Ppm) (Ppm) (ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.004 -0.032 0.000 -0.002 0.000 0.001 0.003 0.205 

S.D. 0.000 0.002 0.001 0.011 0.001 0.001 0.001 0.015 

% R.S.D. 4.330 7.680 264.896 717.749 178.220 52.963 38.322 7.398 

Me SB V BE TL 

(PPM) (Ppm) (Ppm) (ppm) (Ppm) 

Mean -0.000 0.041 0.001 0.000 -0.016 

S.D. 0.000 0.006 0.001 0.000 0.024 

% R.S.D. 57.697 14.902 139.291 50.483 153.687 

S53

Identity 1: S95TOO1139 L Identity 2: 4.97409in250 . 1-9-1-4 1:52 PM July 24, 1995 



On-Peek Integrations : 3 

Solution yoluae : 12500.00 


WHC-SD-WM-DF- /37 , REVL, 

----------- -------------- ----- 

--- 

---------------------------- 

"'- - ---_ 

2R SR BI 51 AL CO CU LI 

(ppm) (ppm) (pp:n) (ppm) (ppm) (ppm) (ppm) (pp:n) 

Mean -283.834 90.540 9735.302 3091.795 1006.489 13.867 13.966 22.956 

S.D. 2.400 0.133 36.644 166.698 5.725 3.773 0.395 0.396 

% R.S.D. 0.845 0.147 0.376 5.392 0.569 27.209 2.831 1.725 

2W NI LA FE CA CR NO U 

(Ppm) (ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) 

Now 40.138 9428.666 -189.014 8727.117 193.200 396.549 26.334 -12315.939 

S.D. 0.800 1.176 3.482 47.069 0.278 3.935 19,997 46.126 

% R.S.D. 1.993 0.012 1.842 0.539 0.144 0.992 75.936 0.375 


(ppm) (ppm) (PPM) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Now -1257.282 -3544.637 -60.229 11963.787 5521.636 98.392 16.710 105782.007 

S.O. 13. US 13.907 0.371 364.774 79.299 0.235 10.397 549.957 

% R.S.D. 1.100 0.392 0.615 3.049 1.436 0.239 62.222 8 0.520 

NO BE AG PB TI CD 8 K 

(Ppm) (ppm) (Ppm) (Ppm) (PpM) (Ppm) (ppm) (Ppm) 

Mean 6.195 -653.426 -207.703 -36.039 -96.979 2.310 27.562 506698.281 

S.D. 2.028 17.320 0.870 29.018 0.772 2.540 1.394 2868.487 

It R.S.D. 32.733 2.651 0.419 80.518 0.796 109.965 5.058 0.566 

MN SB y BE TL 


Mean 37.339 -98.571 -187.240 -0.849 -6581.962 

S.D. 1.148 86.617 3.486 0.458 52.168 

% R.S.D. 

3.074 87.872 1.862 53.975 0.793 

....................................... ............................... 

53 ,1

Identity 1: S95T001139 Identity 2: 4.9740g)n250 . 1-9 1:55 PM July 24, 1995 

To, ' 

St 

-age : TWC93 

Weight : 4.9740 Solution 9olune : 2500.00 WHC-SD-WM-DP-_/2j, REV. 


---------------------------------------------------------------------- 


( ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 7.369 91.773 10271.525 3708.931 1105.765 7.718 5.423 21.472 

S.D. 0.851 0.149 18.913 13.949 4.349 0.003 0.082 0.144 

% R.S.D. 11.555 0.162 0.184 0.376 0.393 0.040 1.518 0.672 


( ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) (Ppm) 

Mean 33.666 9615.580 1.454 8802.216 185.465 396.519 11.891 1097.137 

S.O. 0.024 22.398 0.699 5.513 0.337 1.351 1.276 17.824 

% R.S.D. 0.070 0.233 48.087 0.063 0.182 0.341 10.729 1.625 


(ppm) (ppm) (Ppn) (PPM) (ppm) (ppm) (Pan) (Ppm) 

Mean 20.498 5.219 5.564 12147.320 5641.180 98.341 2.477 100722.383 

S.D. 2.700 4.106 0.088 375.873 52.503 0.163 0.626 426.465 

% R.S.D. 13.171 78.668 1.586 3.094 0.931 0.166 25.286 . 0.423 


( ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (pPn) (pp0) 

Mean 2.146 53.264 1.166 29.692 7.103 4.322 21.159 475989.202 

S.D. 0.674 3.994 0.193 2.623 0.178 0.178 0.678 1916.611 

% R.S.D. 31.388 7.499 16.587 8.834 2.507 4.114 3.207 0.403 

MN SB 9 BE TL 

( ppm ) (ppm) (ppm) (PPM) (ppm) 

Mean 50.858 16.938 2.906 0.012 -16.665 

S.D. 0.203 7.905 0.209 0.141 3.116 

% R.S.D. 0.399 46.670 7.198 1205.760 18.696 

51311

identity 1: 5957001139 0 Identity 2: 4.9390gin250-1-9 1:58 PM July 24, 1995 


Sampte Weight : 4.9390 Solution volume : 2500.00 WHC.SD-WM-DP- REV.) 

On-Peak integrations : 3 Off-Peak Integrations : 1 

....................................... ............................... 

ZR SR 

B1 Si AL CO Cu LI 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) 

Mean 5.517 96.311 11064.606 3448.242 1249.316 10.631 7.501 21.677 

S.D. 0.186 0.453 52.900 12.911 3.304 0.761 0.142 0.111 

It R.S.D. 3.373 0.470 0.478 0.374 0.264 7.156 1.890 0.514 

ZN MI LA FE CA CA NO u 

(PPM) (Ppm) (Ppm) (PPM) (Ppm) (PPM) (ppm) (ppm) 

Mean 33.021 12146.973 •0.932 9024.613 173.9S5 420.285 10.189 1074.163 

S.D. 0.313 35.547 0.696 24.698 0.605 2.123 1.477 2.015 

% R.S.D. 0.949 0.293 74.635 0.274 0.348 0.505 14.494 0.188 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

New 15.519 -8.762 5.493 11488.668 5314.933 106.891 0.231 94646.837 

S.D. 3.844 2.262 0.051 472.691 69.295 0.327 1.961 570.296 

% R.S.D. 24.769 25.817 0.922 4.114 1.304 0.306 847.586 0.603 

MO BE AG PB TI CD B K 


Mean 2.162 56.946 0.202 16.744 6.728 5.619 23.170 439771.750 

S.D. 0.116 3.495 0.273 3.643 0.077 0.412 1.040 1069.041 

It R.S.D. 5.357 6.137 134.909 21.756 1.142 7.336 4.487 0.243 

MN Be y BE TL 


Mean 58.528 32.196 2.516 0.009 -52.641 

S.D. 0.132 20.488 0.370 0.106 11.337 

% R.S.D. 0.226 63.635 14.714 1191.218 21.537 

SC,J

Identity 1: S9ST001139_A Identity 2: 4.974Dgin250-1-2-7 2:02 PM July 24, 1995 


+ Weight : 4.9740 Satution yo(ume 2500.00 WHGSD-WM-DP- )3 1, REVL 

Q. -ak Integrations : 3 Off-Peak 


----------------------------------------------------•----------------- 

LR SR BI SI AL CO CU LI 

(PPM ) (Ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (PPM) 

New 512.434 592.919 10698.740 4182.670 1587.508 514.615 495.478 483.845 

S.D. 1.055 2.338 30.775 9.934 8.516 1.999 2.173 3.127 

% R.S.D. 0.206 0.394 0.288 0.238 0.536 0.388 0.439 0.646 

2N NI LA FE CA CA RD u 

(ppm) (ppm) (ppm) (ppm) (Ppm) (PPm) (ppm) (Ppm) 

Mean 534.919 10158.821 516.716 9397.711 705.475 912.915 548.477 1996.221 

S.D. 1.006 11.082 0.912 37.417 2.482 1.536 3.882 12.332 

% R.S.D. 0.188 0.109 0.177 0.398 0.352 0.168 0.708 0.618 


(ppm) (PPM) (ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

New 514.544 496.888 504.754 12512.183 6046.416 605.937 497.275 100105.653 

S.D. 3.178 3.213 2.061 289.350 68.366 0.732 3.341 623.958 

% R.S.D. 0.618 0.647 0.408 2.313 1.131 0.121 0.672 0.623 

MO SE AG PB Ti CD B K 

(ppm) (ppm) (Ppm) (PPM) (Ppm) (ppm) (ppm) (Ppm) 

Mew 505.950 518.422 426.851 542.453 498.607 510.741 517.780 477967.956 

S.D. 3.638 5.194 0.775 8.789 1.698 1.402 0.921 2645.157 

% R.S.D. 0.719 1.002 0.182 1.620 0.341 0.274 0.178 0.553 

MN SB y BE TL 

(Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 565.633 459.480 518.626 495.119 461.064 

S.D. 1.117 7.812 0.269 1.698 10.031 

% R.S.D. 0.197 1.700 0.052 0.343 2.176

Identity 1: ICSA Identity 2: Ouality Control 2:07 PM July 24, 199°task 

name : IMC93 

SaWle Weight : 1.0000 Solutim Volume 1.00 


...................................................................... 


(PPM ) (ppm) (Ppm) (ppm) (ppm) 

Mean -0.001 0.000 0.007 0.073 199.594 

S.D. 0.001 0.000 0.011 0.001 0.838 

% R.S.D. 102.055 11.428 153.617 0.741 0.420 


(ppm) (PPM) (ppm) (PPM) (Ppm) 

Mean 0.001 -0.051 0.009 149.638 19.110 

S.D. 0.000 0.001 0.001 0.139 0.033 

% R.S.D. 19.570 2.253 7.763 0.093 0.173 

CE SM BA P S 

(PPM ) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.038 -0.004 0.003 0.032 0.155 

S.D. 0.008 0.011 0.000 0.007 0.003 

% R.S.D. 22.014 291.280 6.019 20.500 1.803 

NO SE AG PB it 

(PPM ) (Ppm) (PPM) (Ppm) (ppm) 

Mew 0.000 -0.068 0.001 0.003 0.001 

S.D. 0.001 0.010 0.001 0.004 0.000 

% R.S.D. 202.073 14.647 133.894 145.092 36.281 

MN S8 V BE TL 

(Ppm) (PPM) (ppm) (Ppm) (ppm) 

Mean 0.010 -0.085 -0.002 0.002 -0.030 

S.D. 0.000 0.037 0.001 0.000 0.014 

% R.S.D. 

2.819 43.863 43.816 

O.Z39 45.537 

......................................... .......... ................... 

5UJ 

WHGSD-WM-Dp- X37 REV. 

CO Cu LI 

( Ppm) (ppm) (PPM) 

0.004 -0.013 0.000 

0.000 0.000 0.000 

0.165 2.661 50.887 

CR NO u 

(ppm) (PPM) (Ppm) 

-0.013 0.034 0.031 

0.003 0.005 0.054 

23.599 13.250 173.844 

MG AS NA 

( ppn ) (ppm) (ppm) 

19.287 0.006 189.764 

0.032 0.005 2.395 

0.165 91.297 M 1.262 

CD 8 K 


0.010 -0.045 0.340 

0.001 0.001 0.024 

7.232 1.777 7.087


To,' -wom : TWC93 


On-reek Integrations : 3 Off-Peak Integrations : 1 

........................................ ................ .............. 

WHC-SD-WM-DP- /,f/, REV. 


(Ppm) (Ppm) (Ppm) (PPm> (Ppm) (PPS) (ppm) (Ppm) 

Mean -0.003 -0.000 0.013 0.061 198.719 0.500 0.483 0.947 

S.D. 0.000 0.000 0.003 0.004 0.419 0.002 0.001 0.002 

% R.S.D. 11.378 86.062 24.665 5.764 0.211 0.301 0.121 0.214 


(ppm) (Ppm) (PPm) (Ppm) (Ppm) (Ppm) (PPm) (ppm) 

Mean 1.009 0.940 0.009 150.582 18.702 0.501 0.034 0.014 

S.D. 0.002 0.002 0.001 0.189 0.035 0.001 0.004 0.014 

% R.S.D. 0.154 0.197 13.445 0.126 0.189 0.146 11.660 98.241 


( ppm ) (Ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 0.014 -0.013 0.507 0.021 0.154 18.858 -0.001 189.434 

S.D. 0.002 0.001 0.001 0.006 0.003 0.019 0.001 0.491 

% R.S.D. 15.651 6.615 0.139 26.589 2.210 0.099 90.971 • 0.259 

MO BE AG PB TI CD B K 


Now -0.001 0.034 1.487 1.036 0.001 1.029 -0.047 0.293 

S.D. 0.001 0.010 0.003 0.018 0.000 0.005 0.000 0.007 

% R.S.D. 80.869 28.791 0.185 1.775 32.245 0.464 0.533 2.498 

NN Be v BE TL 

(ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.517 -0.014 0.509 0.508 -0.030 

S.D. 0.001 0.020 0.002 0.001 0.003 

% R.S.D. 

0.235 145.428 

0.325 

0.115 10.600 

....................................... ... ............................ 

J ^^

Identity 1: CCV_1 Identity 2: CCV_1 2:13 PM July 24, 1995 


Sample Weight : 1.0000 Solution volume 1.00 


------------------------------------------------------------------- 

2R SR BI SI 

(ppm) (ppm) (Ppm) (ppm) 

Mean 4.931 4.995 4.958 4.753 

S.D. 0.008 0.015 0.016 0.003 

% R.S.D. 0.170 0.300 0.322 0.055 

ZN III LA FE 

( ppm) (ppm) (ppm) (Ppm) 

Mean 4.984 4.933 5.076 5.100 

S.D. 0.002 0.007 0.005 0.006 

% R.S.D. 0.034 0.136 0.089 0.114 

CE SM BA P 

( ppm) (Ppm) (Ppm) (Ppm) 

Mew 5.007 5.067 5.012 3.747 

S.D. 0.007 0.015 0.017 0.051 

% R.S.D. 0.147 0.288 0.338 1.371 

NO SE AG PS 


New 4.963 4.806 4.865 4.958 

S.D. 0.015 0.033 0.003 0.034 

It R.S.D. 0.309 0.687 0.064 0.689 

MM SB v BE 


Mean 4.991 4.728 5.020 5.163 

S.D. 0.004 0.028 0.005 0.013 

% R.S.D. 0.090 0.590 0.101 0.249 

WHGSD-WM-DP- ,/3 7, REV. 

AL CO Cu LI 


4.927 4.974 4.878 5.076 

0.011 0.008 0.017 0.027 

0.231 0.151 0.346 0.531 

CA CR NO u 


5.176 4.997 5.420 9.465 

0.010 0.005 0.027 0.015 

0.184 0.106 0.499 0.159 

S MG AS MA 


4.367 4.978 4.907 5.121 

0.026 0.004 0.015 0.020 

0.604 0.076 0.311 0.390 

TI CD B K 


4.848 5.008 5.081 5.445 

0.009 0.004 0.017 0.010 

0.188 0.076 0.328 0.192 

TL 

(ppm) 

4.795 

0.005 

0.114 

S3-)

Identity 1: CCB 1 Identity 2: CCB_1 2:16 PM July 24, 1995 

Task- name : TWC93 

s Weight : 1.0000 

On-,Qak Integrations : 3 

Solution Volume 

Off-Peak Integrati ona : 

1.00 

1 

WHGSD-WM-DP-_/2Z, REV. 

...................................................................... 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.003 0.000 0.016 0.005 0.004 -0.003 0.001 -0.000 

S.D. 0.002 0.000 0.004 0.001 0.001 0.002 0.001 0.000 

X R.S.D. 60.064 9666.693 27.038 21.134 21.656 58.267 47.290 94.710 


(ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Hem 0.002 0.001 0.002 -0.001 -0.000 -0.001 0.012 -0.111 

S.D. 0.000 0.002 0.003 0.002 0.000 0.002 0.011 0.056 

X R.S.O. 17.862 138.886 147.939 242.509 12.372 143.426 85.545 50.073 


(Ppm) (Ppm) (PPM) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean -0.007 -0.031 -0.000 0.003 -0.008 -0.000 0.006 0.057 

S.D. 0.011 0.013 0.000 0.002 0.003 0.000 0.003 0.003 

% R.S.D. 156.718 42.624 65.939 68.336 36.494 163.138 44.263 m 5.328 


(ppm) (Ppm) (PPM) (Ppm) (ppm) (Ppm) (ppm) (PPM) 

Mean 0.002 -0.060 -0.001 -0.002 -0.000 0.001 0.003 0.280 

S.D. 0.002 0.002 0.001 0.014 0.000 0.000 0.001 0.017 

% R.S.D. 72.581 3.217 95.472 627.635 589.460 35.336 26.230 6.119 

MN SB v BE TL 

(ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean -0.000 0.017 -0.001 -0.000 -0.052 

S.D. 0.000 0.042 0.001 0.000 0.023 

% R.S.D. 89.200 247.135 83.559 34.695 44.755 

53

06/28/95 10:16 

A-0004-1 

WHC-SD-WM-DP- lf^, REV. 


Analyst: 13, 4z;,Cc Instrument: ICPO1 Book# YjdYAe 

Method: LA-505-151 Rev/Mod y_ Z 


S Type Sample R A Test Matrix Group Project 





5 PREPBLKARL @ICP-FO3 SOLID 



7 DUP S95TOO1144 0 F @ICP-FO3 SOLID 














32 

/ Page: 1

06/28/95 10:16 

A-0004-I 

WHC-SD-WM-DP- /.5 /', REV. / 


fype Sample# R A Test Matrix Group# Project 


ArOFFst Signature Date Analyst Signature Date 

^^(peSCKi/KL 

SSS//ti/•I-C /Tc^J . S7Y7s .:3 ZS^C 

/O 

-I-c-F C -/ L- y_.L /ZJUJ 

SS)"TL7J i/vy- /^ 57v7^ ae^ c - l c - Z^c - 7 c 'Z 

Sfrjc^/iYf_ C .sZof} .,^ a^v,c- /_,L- S_ C -/—c - ci c /^û^ 

s Ss j GY7 //•/>' > bo , -. 15?J c - l c - S- c 

Sir7m /lYT- 17` s'^ 03- 



11 

.r,- J 

Page: 2

Identity 1: ICV Identity 2: Ous lity Control 1:33 PM July 25, 1995 


Sample Weight : 1.0000 Sotution Volune : 1.00 


WHC-SD-WM-DP- Z^^7, REVS 

---------------------------------------------------------------------- 


(ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) (ppa) 

Mean -0.000 0.000 -0.030 -0.010 -0.019 0.003 0.000 0.000 

S.D. 0.001 0.000 0.004 0.002 0.005 0.003 0.001 0.000 

% R.S.D. 237.554 26.494 14.158 23.809 23.988 115.705 182.427 59.739 


(Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean -0.000 0.000 -0.000 -0.002 -0.004 0.004 0.018 0.000 

S.D. 0.000 0.002 0.001 0.000 0.000 0.001 0.003 0.054 

% R.S.O. 96.680 468.116 173.058 28.223 1.695 25.527 14.912 10882.400 



Mean -0.003 -0.014 -0.000 0.010 -0.002 0.000 0.002 0.007 

S.D. 0.006 0.011 0.000 0.007 0.000 0.000 0.002 0.005 

% R.S.D. 224.886 79.792 348.271 69.133 0.864 43.828 148.663 72.155 


(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean -0.001 -0.011 -0.001 -0.006 -0.000 0.002 0.001 -0.059 

S.D. 0.001 0.018 0.001 0.011 0.001 0.000 0.002 0.017 

% R.S.D. 61.056 160.803 76.945 173.167 131.366 14.747 273.627 29.004 

MN S8 V BE TL 


Mean 0.000 -0.119 -0.000 0.000 -0.031 

S.D. 0.000 0.045 0.001 0.000 0.019 

% R.S.D. 180504.210 37.628 249.085 263.350 61.355 

---------------------------------------------------------------------- 

SIGNATURE BLOW REPR ONTS CHEMICAL TOCH DLOGI.ST/CHE14M THAT 

aMPL0=/VE[UFIED TRB r'nr.rwx MOM ANALYSIS CN PACES TO 1p^. 

i 

^3r_ 

,Î 

2 

4)U 

i A r J 

b i;- ^5 

011 

T

Identity 1: IN Identity 2: Quality Control 1:36 PM July 25, 1995 

Tao name : TWC93 

S Weight : 1.0000 Solution 9oluie : 1.00 WHC-SD-WM-DP-Z L, REV. 

On,sk Integrations : 3 


--------------------------------------- ------------------------ ------- 


( Ppm) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 4.878 4.919 4.893 4.747 4.908 

S.D. 0.010 0.013 0.017 0.009 0.020 

% R.S.D. 0.204 0.260 0.355 0.191 0.407 

ZM NI LA FE CA 


Mean 5.029 4.942 4.959 5.005 5.097 

S.D. 0.005 0.012 0.017 0.013 0.014 

% R.S.D. 0.104 0.234 0.348 0.269 0.276 

CE SM BA P S 


Mean 4.908 4.896 4.926 4.865 4.944 

S.D. 0.010 0.018 0.015 0.180 0.072 

% R.S.D. 0.201 0.368 0.306 3.701 1.461 

MO SE AS PB TI 

(Ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 4.989 4.854 4.905 5.005 4.830 

S.D. 0.005 0.029 0.008 0.010 0.007 

% R.S.D. 0.108 0.607 0.167 0.204 0.149 

MN SB 9 BE TL 

(Ppm ) (ppm) (ppm) (Ppm) (ppm) 

Mean 4.994 4.658 4.989 5.100 4.804 

S.D. 0.001 0.027 0.003 0.007 0.011 

% R.S.D. 0.022 0.584 0.056 0.141 0.235 

r;9-- 

CO CU L 


5.007 4.809 5.064 

0.007 0.016 0.029 

0.140 0.340 0.570 

CR ND U 


5.019 5.146 9.312 

0.011 0.018 0.012 

0.220 0.351 0.132 

MG AS NA 


5.006 4.920 5.040 

0.004 0.028 0.024 

0.079 0.574 1 0.470 

CD B K 

(Ppm) (Ppm) (ppm) 

5.000 5.039 5.140 

0.011 0.011 0.042 

0.214 0.218 0.816

Identity 1: ICB Identity 2: Duality Control 1:41 PM July 25, 1995 


Sample Weight : 1.0000 Solution volume : 1.00 WHGSD-WM-DP- 477, REV. 


---------------------------------------------------------------------- 


( ppm ) (ppm) (ppm) (PPm) (ppm) (Ppm) (ppm) (ppm) 

Mean -0.000 0.000 -0.008 -0.002 -0.011 0.008 0.001 0.000 

S.D. 0.001 0.000 0.012 0.001 0.006 0.002 0.001 0.000 

% R.S.D. 272.977 37.296 138.415 29.361 57.816 19.240 59.745 64.881 


. (Ppm ) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 0.000 0.001 0.002 -0.001 0.001 0.003 0.012 -0.017 

S.D. 0.000 0.002 0.001 0.003 0.000 0.002 0.003 0.032 

% R.S.D. 55.409 247.955 28.504 318.603 4.949 53.228 26.429 186.932 


( ppm ) (PPM) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.007 -0.006 -0.000 0.005 0.002 0.000 0.005 -0.001 

S.D. 0.007 0.006 0.000 0.005 0.003 0.000 0.003 0.003 

% R.S.D. 93.131 95.932 323.282 107.430 122.170 100.482 76.279 519.640 . 

MO SE AG PIT TI CD B m K 


Mean -0.001 0.046 -0.001 0.018 0.000 0.003 0.004 -0.031 

S.D. 0.000 0.002 0.000 0.005 0.000 0.000 0.000 0.010 

% R.S.D. 50.332 5.228 40.212 25.371 49.337 9.347 7.807 33.531 

MN 58 y BE TL 

(Ppm) (ppm) (ppm) (PPM) (Ppm) 

Mean 0.001 -0.045 -0.001 0.000 -0.019 

S.D. 0.000 0.029 0.000 0.000 0.022 

% R.S.D. 

21.807 65.234 30.385 

173.648 

------------------------------------------------ ---------------- -- ---- 

114.676 

.r.4JJ

Identity 1: ICSA Identity 2: Ouatity Control. 1:46 PM July 25, 1995 

Tas k name : TWC93 

St Weight : 1.0000 

On-rrak Integrations :. 3 

Solution Vol. me 


1.00 

1 WHGSD-WM-DP-/37 REV. 

--------------------------------------- ----------------------------- 

IR SR BI SI AL CO Cu LI 

(PpM) (pp) (pp^) (Ppa) (PpM) (Ppo) (ppm) (ppm) 

Mean -0.002 0.001 -0,008 0.054 196.660 0.011 -0.011 0.001 

S.D. 0.001 0.000 0.013 0.002 0.671 0.002 0.000 0.000 

% R.S.D. 63.951 12.776 164.555 4.566 0.341 14.383 3.481 30.299 


(PPM ) (PpR) (Ppm) (Pp) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 0.000 -0.049 0,008 143.998 18.748 -0.008 0.034 0.015 

S.D. 0.001 0.002 0.003 0.183 0.044 0.002 0.007 0.040 

% R.S.D. 662.357 4.944 36.830 0.127 0.236 28.381 19.382 256.620 


(PPM) (PpM) (Ppm) (Ppin) (Ppm) (PpM) (ppm) (ppm) 

Mean 0.003 -0.015 0.003 0.041 0.150 18.674 0.014 188.404 

S.D. 0.009 0.011 0.000 0.006 0.005 0.022 0.001 0.943 

% R.S.D. 269.928 72.462 5.035 15.455 3.428 0.117 6.470 0.501 


(PPM) (PPM) (PPM) (PPM) (ppm) (Ppm) (ppm) (PPM) 

Mean -0.002 -0.014 -0.002 0.009 -0.000 0.013 -0.047 -0.072 

S.D. 0.001 0.018 0.001 0.024 0.001 0.001 0.000 0.006 

% R.S.D. 44.508 128.517 46.712 254.169 989.851 11.035 1.023 7.864 

MN SR V BE TL 

(ppm) (ppm) (ppm) (PPM) (PPM) 

Mean 0.010 -0.029 •0.004 0.002 -0.055 

S.D. 0.000 0.029 0.001 0.000 0.015 

% R.S.D. 

2.613 100.098 26.660 7.461 

---------------------------------------------------- ------------- ----- 

27.157 

Z) 4


Task name : TUC93 

Sample Weight : 1.0000 Solution volume : 1.00 WHGSD-WM-DP- 13z, REV. 


-------------------------------------------------------- I ----__------- 

ZR SR el SI AL CO CU LI 

( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean -0.004 0.000 -0.018 0.045 199.019 0.510 0.479 0.948 

S.D. 0.001 0.000 0.009 0.004 0.340 0.003 0.001 0.005 

% R.S.D. 12.948 0.040 48.111 9.309 0.171 0.520 0.276 0.480 



Mean 1.009 0.933 0.005 147.911 18.453 0.502 0.035 -0.027 

S.D. 0.002 0.001 0.001 0.055 0.020 0.003 0.003 0.013 

% R.S.D. 0.149 0.137 14.483 0.037 0.111 0.683 7.478 49.693 


( ppm ) (ppm) (ppm) (ppm) (ppm) (ppa) (ppm) (ppm) 

Mean 0.017 -0.024 0.500 0.026 0.155 18.834 -0.006 189.016 

S.D. 0.004 0.003 0.001 0.005 0.010 0.011 0.004 0.964 

% R.S.D. 21.746 13.976 0.231 18.527 6.278 0.058 77.854 0.510 

NO SE AG PIT TI CD B K 

( ppm) (ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) 

Mean -0.001 0.086 1.493 1.026 0.000 1.025 -0.047 -0.059 

S.D. 0.000 0.010 0.001 0.015 0.000 0.000 0.001 0.001 

% R.S.D. 30.929 11.895 0.097 1.419 147.740 0.001 2.343 2.192 

MN so 9 BE TL 

( ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 0.518 -0.068 0.501 0.502 -0.063 

S.D. 0.002 0.023 0.001 0.002 0.011 

% R.S.D. 0.391 33.159 0.147 0.326 16.848 

533

Identity 1: PREPBLK Identity 2: Duality Control 

Task nerve : TNC93 

1:55 PM July 25, 1995 

Sa, Weight : 1.0000 Solution Voiu 10.00 

On Integrations : 3 Off-Peak Integrations : 1 

....................................... ............... ................ 

ZR SR BI SI 


Mean -0.003 0.011 -0.172 0.586 

S.D. 0.017 0.001 0.033 0.036 

% R.S.D. 507.062 9.308 19.054 6.212 

ZN NI LA FE 


Mean 0.200 7.800 0.008 0.217 

S.O. 0.005 0.060 0.007 0.023 

% R.S.D. 2.406 0.773 88.810 10.489 

CE SM BA P 


Mean 0.064 -0.043 0.019 0.236 

S.D. 0.125 0.098 0.002 0.055 

% R.S.D. 196.706 227.291 10.319 23.132 

MO SE AG PIT 

( Ppm ) (ppm) (ppm) (Ppm) 

Mean 0.000 -0.000 -0.005 0.057 

S.D. 0.008 0.088 0.010 0.063 

% R.S.D. 1873.499 146442.109 213.088 112.036 

MN s8 V BE 

( Ppm ) (ppm) (Ppm) (Ppm) 

Mean 0.025 -0.631 -0.007 -0.000 

S.D. 0.002 0.194 0.011 0.001 

% R.S.D. 6.107 30.782 142.064 13489.921 

WHGSD-WM-DP-_2ZZ , REV-.Z 

AL CO Cu LI 


-0.153 0.070 0.044 0.003 

0.013 0.015 0.006 0.003 

8.314 21.777 13.410 83.207 

CA CR NO u 

(Ppm) (ppm) (Ppm) (Ppm) 

0.302 0.028 0.212 -0.084 

0.002 0.017 0.122 0.569 

0.533 62.498 57.514 677.916 

S MG AS NA 


0.217 0.060 -0.028 5.121 

0.019 0.001 0.036 0.040 

8.953 1.573 127.764 0.776 

TI CD B • K 


0.011 0.026 0.022 16545.609 

0.005 0.012 0.010 102.136 

45.925 45.560 46.728 0.617 

TL 

(ppm) 

0.057 

0.209 

368.434 

^JJ

Identity 1: S95T001144_L Identity 2: .5747gin250-1-9-1-4 1:59 PM July 25, 1995 


Sample Weight : 0.5747 solution Volume : 12500.00 WHC-SD-WM-DP- REV- 

On-Peak integrations : 3 Ott-Peak Integrations : 1 

---------------------------------------------------------------------- 


( Ppm) (Ppm) (pPm) (ppm) (Ppm) (ppm) (ppm) (ppm) 

Mean -14.499 180.720 12223.063 6937.434 1378.788 57.294 44.141 22.106 

S.D. 33.226 1.999 92.813 88.061 64.211 33.132 9.222 3.402 

% R.S.D. 229.164 1.106 0.759 1.269 4.657 57.828 20.891 15.390 


(ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 155.150 4492.717 -49.573 11303.776 115548.112 533.163 56.398 155.909 

S.D. 2.990 18.246 40.049 74.589 821.823 12.550 100.574 1447.275 

% R.S.D. 1.927 0.406 80.788 0.660 0.711 2.354 178.328 928.282 


(Ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppa) 

Mean 124.465 -146.969 12.722 16999.465 96333.548 300.956 -15.372 128981.375 

S.D. 251.090 289.230 5.277 712.425 1508.128 0.035 8.036 773.626 

% R.S.D. 201.736 196.796 41.478 4.191 .1.566 0.012 52.277 0.600 


(Ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean -4.895 -166.494 -25.144 374.649 9.480 49.494 75.890 6930593.816 

S.D. 10.174 175.335 19.833 101.851 8.025 5.119 5.124 41175.604 

% R.S.D. 207.846 105.310 78.878 27.186 84.652 10.343 6.752 0.594 

MN SB V BE TL 

( ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 209.529 -442.108 -51.660 0.015 -236.987 

S.D. 5.799 421.790 21.153 2.368 354.966 

% R.S.D. 2.768 

95.404 40.947 16239.286 

-------- - ------------------------------------------------------- - ----- 

149.783

Identity 1: S95TO01144 Identity 2: .57479in250-1-9 2:02 PM July 25, 1995 



ak Integrations : 3 Off-Peak Integrations 1 

.......... .---------------------------------------------- I------------ 

WHC-SD-WM-DP-/_3Z, REV./ 


(Ppn) (Ppm) (Ppm) (Ppm) (Ppm) (ppn) (Ppm) (ppm) 

Mean 9.453 131.263 13010.175 6042.480 1472.301 30.250 25.881 16.689 

S.D. 5.362 0.003 54.302 10.662 5.010 6.642 2.175 1.179 

% R.S.D. 56.722 0.002 0.417 0.176 0.340 21.956 8.403 7.066 


(ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 193.820 4492.704 5.891 11166.923 443.800 529.296 2.037 980.094 

S.D. 0.585 25.067 7.979 34.911 1.428 3.920 42.803 192.829 

% R.S.D. 0.302 0.558 135.449 0.313 0.322 0.741 2101.577 19.675 


(Ppm) (ppm) (Ppm) (Ppm) (Pam) (Ppm) (ppm) (ppm) 

Mean 72.202 -90.758 12.807 15479.795 7043.541 150.022 -27.276 125217.975 

S.D. 45.198 45.362 0.852 436.615 78.726 0.418 5.563 671.356 

% R.S.D. 62.599 49.981 6.651 2.821 1.118 0.278 20.396 0.536 



Mean -4.307 115.031 -6.485 72.993 8.163 12.934 40.389 6564994.607 

S.D. 3.340 31.165 3.285 10.627 2.536 2.583 0.926 30225.646 

% R.S.D. 77.540 27.093 50.654 14.559 31.062 19.973 2.294 0.460 


(ppm) (ppm) (Ppm) (Ppm) (Ppm) 

Mean 50.618 -4.424 -7.608 -1.761 -206.950 

S.D. 1.352 83.906 3.643 0.018 149.174 

% R.S.D. 

2.670 1896.548 47.881 

1.024 

--------------------------------------- ----------------- -------------' 

72.082 

GVa

Identity 1: S957001144_D Identity 2: .5646gin250-1-9 2:07 PM July 25, 1995 


Sanple Weight : 0.5646 Solution yolune : 2500.00 

On-Peak integrations : 3 


---------------------------------------------------------------------- 

WHC-SD-WM-DP-_2,Z.::^ REV. 


(Ppm) (ppm) (Ppn) (ppm) (ppm) (ppm) (ppm) (Ppm) 

Mean -2.492 119..119 11787.825 5492.043 1316.283 34.648 16.723 19.010 

S.D. 3.796 0.238 6.483 16.438 21.784 6.776 0.928 0.318 

% R.S.D. 152.336 0.200 0.055 0.299 1.655 19.557 5.549 1.672 


(ppm) (Plan) (Ppm) (Ppm) (ppm) (Ppm) (Ppm) (PPM) 

Mean 154.359 5911.414 -8.412 10338.340 280.602 510.624 101.406 536.831 

S.D. 3.277 31.989 6.098 48.620 0.866 7.033 20.441 87.971 

% R.S.D. 2.123 0.541 72.484 0.470 0.308 1.377 20.157 16.387 


(ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean -36.132 -136.054 10.715 15217.632 7170.356 137.378 15.429 124762.388 

S.D. 20.267 25.283 0.483 633.281 116.330 0.421 15.367 375.022 

% R.S.D. 56.092 18.583 4.512 4.161 1.622 0.307 99.601 0.301 


(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (PPm) (Ppm) 

Mean -6.975 -55.294 -12.136 128.169 1.953 13.671 45.776 6443402.261 

S.D. 2.156 15.897 2.006 46.726 1.251 0.607 0.747 15669.650 

% R.S.D. 30.905 28.750 16.528 36.457 64.068 4.443 1.631 0.243 

MN SR 9 BE TL 

(Plan) (Ppm) (Ppm) (PPM) (ppm) 

Mean 52.457 -434.338 -14.729 0.858 -390.014 

S.D. 1.192 82.643 1.371 0.926 23.968 

% R.S.D. 2.272 19.027 9.307 107.947 6.145 

Fo. 

os %

Identity 1: 595T001144_A Identity 2: .5747gin250 . 1-2 . 7 2:11 PM July 25, 1995 

Task nerve : TWC93 

5 Weight : 0.5747 

Dr. .ak Integrations : 3 

Solution volume 2500.00 


/ 

WHC•SDVWDP_^ / , REV. 

- -------------------------------------------------------- 

1 

------------- 

2R SR BI ST AL CO Cu LI 

(Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (PPM) j 

Mean 4362.609 4459.482 17170.860 10180.307 5789.115 4465.442 4250.484 3967.784 

S.D. 14.114 21.773 135.198 34.751 16.316 35.274 20.167 20.403 

% R.S.D. 0.324 0.488 0.787 0.341 0.282 0.790 0.474 0.514 


(Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) (Ppm) (Ppm) 

Mean 4493.678 8869.255 4416.249 15593.280 4824.738 5048.662 4446.820 9244.765 

S.D. 9.353 55.874 26.517 81.272 22.042 33.959 36.583 86.852 

% R.S.D. 0.208 0.630 0.600 0.521 0.457 0.673 0.823 0.939 


(Ppm) (PPM) (Ppm) (Ppm) (Ppm) (PPM) (Ppm) (Ppm) 

Mean 4353.826 4237.927 4313.766 20650.227 11655.859 4660.447 4309.023 124996.071 

S.D. 18.093 25.798 22.116 1170.364 288.056 12.457 31.415 603.554 

% R.S.D. 0.416 0.609 0.513 5.668 2.471 0.267 0.729 0.483 


(Ppm) (Ppm) (PPM) (Ppm) (Ppm) (PPM) (Ppm) (PPM) 

Mean 4408.110 4326.905 3073.838 4609.409 4290.913 4393.702 4234.532 6349116.729 

S.D. 8.355 8.614 31.887 33.687 19.628 19.354 25.873 21549.067 

% R.S.D. 0.190 0.199 1.037 0.731 0.457 0.440 0.611 0.339 

MN SB V BE TL 

(Ppm) (PPM) (Ppm) (Ppm) (Ppm) 

Mean 4502.389 3800.559 4445.212 4227.783 4198.614 

S.D. 16.656 59.177 19.718 17.725 118.114 

% R.S.D. 

0.370 1.557 0.444 

0.419 2.813 

---------------------------------------------- ------------------ ------ 

V03

Identity 1: zzz Identity 2: zzz 2:13 PM July 25, 1995 



On-Peek Integrations : 3 Off-Peak 

------------------------------ ------ 


---------- ---------------------- 

ZR SR 81 SI AL 


Mean 0.003 0.001 -0.005 0.006 0.011 

S.D. 0.001 0.000 0.004 0.001 0.002 

% R.S.D. 31.851 15.756 82.220 20.543 16.461 



Mean 0.001 0.005 -0.001 0.017 0.017 

S.D. 0.000 0.002 0.001 0.003 0.000 

% R.S.D. 21.610 43.480 120.222 17.378 0.854 

CE SM BA p S 

( ppm ) (Ppm) (Ppm) (Ppm) (ppm) 

Mean 0.007 0.018 0.001 -0.004 0.007 

S.D. 0.010 0.011 0.000 0.007 0.001 

% R.S.D. 144.805 59.747 21.361 174.716 11.981 

NO SE AG PB TI 

( ppm ) (PPM) (ppm) (PPM) (pp,n) 

Mean 0.000 0.001 0.041 -0.013 0.002 

S.D. 0.001 0.003 0.003 0.009 0.000 

% R.S.D. 517.301 340.509 7.922 72.395 14.050 

MN SB V BE TL 

(Ppm) (ppm) (PPM) (Ppm) (ppN) 

Mean 0.002 -0.063 0.001 0.001 0.026 

S.D. 0.000 0.038 0.000 0.000 0.017 

% R.S.D. 16.820 59.501 15.994 13.624 63.643 

C©2S 

WHC-SD-WM-D P- /.1, REV.- 

CO Cu LI 


0.006 0.002 0.001 

0.000 0.000 0.000 

0.090 7.689 33.521 

CR ND u 


0.005 0.003 0.079 

0.002 0.003 0.043 

36.873 108.464 53.782 

MG AS NA 

(Ppm ) (Ppm) (PPM) 

0.005 -0.001 0.097 

0.000 0.004 0.004 

3.457 266.993 . 4.109 

CO B K 

( ppm ) (PPM) (ppm) 

0.003 0.003 0.783 

0.000 0.000 0.046 

10.645 11.907 5.843

Identity 1: CCyIdentity 2: Ouatity Control 2:16 PM July 25, 1995 


S I Weight : 1.0000 Sotution yatuae : 1.00 

0. .k Integrations : 3 Off-Peak Integrations : 1 

WHC-SD-WM-DP-_/Z , REV. 


(ppm) (ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (Ppm) 

Mean 4.944 5.007 4.954 4.740 4.932 4.980 4.913 5.136 

S.D. 0.007 0.010 0.023 0.002 0.010 0.011 0.013 0.041 

% R.S.D. 0.144 0.200 0.460 0.038 0.212 0.213 0.272 0.793 

ZN N) LA FE CA CR NO u 

(ppm) (ppm) (ppm) (Ppm) (Ppm) (Ppm) (Ppa) (ppm) 

Mean 4.964 4.939 5.055 5.055 5.193 4.989 5.345 9.727 

S.D. 0.003 0.015 0.00a 0.020 0.008 0.008 0.018 0.015 

% R.S.D. 0.058 0.297 0.154 0.403 0.145 0.167 0.334 0.156 


(ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 4.994 5.024 5.039 4.872 4.915 4.971 4.922 5.140 

S.D. 0.005 0.011 0.013 0.193 0.069 0.009 0.007 0.043 

% R.S.D. 0.106 0.223 0.248 3.957 1.405 0.175 0.133 0.830 

NO SE AG PIT TI CD 8 K 

(Ppm) (PPm) (ppm) (Ppm) (ppm) (ppm) (Ppm) (ppm) 

Mean 4.971 4.927 4.872 4.961 4.878 5.003 5.087 5.545 

S.D. 0.001 0.024 0.005 0.021 0.007 0.011 0.011 0.031 

It R.S.D. 0.022 0.497 0.113 0.414 0.137 0.215 0.226 0.551 


(ppm) (ppm) (Ppm) (ppm) (ppm) 

Mean 5.002 4.755 5.013 5.167 4.883 

S.D. 0.008 0.043 0.008 0.003 0.027 

% R.S.D. 

0.153 0.898 0.169 

....------•----------"-----•--------- 

0.067 

------------ ------------------- 

0.552 

G05i


Task name TNC93 

WHC-SD-WM-DP-^ REV. 

Sample Weight 1.0000 Solution Volume 1.00 ^ 


----------------------------------------------------- ------------ ----- 


(ppm) (Ppm) (ppm) (Ppm) (Ppn) (ppm) (ppm) (ppm) 

Mean -0.000 0.000 -0.014 -0.004 -0.010 0.007 0.001 0.000 

S.D. 0.001 0.000 0.002 0.002 0.004 0.003 0.000 0.000 

% R.S.D. 241.873 28.765 12.603 51.424 36.092 43.310 32.480 43.882 


(Ppm) (Ppm) (ppm) (ppm) (ppm) (Ppm) (ppm) (pPm) 

Mean 0.001 -0.004 -0.000 0.004 0.001 0.003 0.016 -0.011 

S.O. 0.000 0.001 0.001 0.000 0.000 0.001 0.002 0.026 

% R.S.D. 45.508 28.429 169.070 7.407 0.000 39.242 11.554 235.334 

CE SM BA P S M0 AS NA 

( ppm ) (pan) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean -0.008 -0.007 0.000 0.011 0.000 0.000 -0.004 0.036 

S.D. 0.008 0.008 0.000 0.003 0.002 0.000 0.005 0.003 

% R.S.D. 98.465 108.989 284.958 29.589 378.705 34.907 112.561 8.332 

MO SE AO PB TI CD B K 

(ppm) (ppm) (ppm) (pan) (Ppm) (ppm) (ppm) (ppm) 

Mean 0.000 -0.013 0.000 -0.004 -0.000 0.004 0.001 0.280 

S.D. 0.001 0.005 0.001 0.005 0.000 0.001 0.001 0.007 

% R.S.D. 246.644 36.854 500.334 132.957 67.482 16.533 37.054 2.464 

MN SB V BE TL 

(ppm) (ppo) (ppm) (ppm) (ppm) 

Mean -0.000 -0.107 -0.001 -0.000 -0.007 

S.D. 0.000 0.021 0.000 0.000 0.019 

% R.S.O. 

43.468 

20.022 17.085 10289.164 

---------------------------------------------------------------- - ----- 

290.160 

COG

Identity 1: S95T001145_L Identity 2: .5605 9 in250-1-9-1-4 2:24 PM July 25, 1995 

Tas k -, me : TWC93 

Sm )eight : 0.5605 Solution Votum 12500.00 WHC•SD-WM-DP-^3^, REV. / 


---------------------------------------------------------------------- 


(ppm) (Ppa) (Ppm) (Ppm) (Ppm) (pPm) (Ppm) (ppm) 

Mean 0.974 139.128 12493.210 6279.136 746.554 176.802 50.510 

S.D. 21.073 2.381 189.922 77.889 136.886 34.110 5.317 3.491 

% R.S.D. 2164.695 1.711 1.520 1.240 18.336 19.293 10.526 9.554 


(Ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 163.541 6003.538 -32.578 11787.512 436.585 579.114 339.931 1530.832 

S.D. 13.684 19.020 15.304 64.278 0.824 39.108 163.730 509.512 

% R.S.D. 8.367 0.317 46.978 0.545 0.188 6.753 48.166 33.283 


(Ppm ) (ppm) (Ppm) (ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean -280.021 -158.663 17.922 16832.644 7213.627 165.346 -99.041 125926.153 

S.D. 164.738 129.411 2.186 827.889 111.698 3.680 93.051 798.160 

% R.S.D. 58.831 81.564 12.198 4.918 1.548 2.226 93.952 0.634 

M0 SE AG PB TI CD B • K 

(ppm) (ppm) (Ppm) (pPa) (ppa) (Ppm) (ppm) (ppm) 

Mean -29.109 521.992 -3.253 384.162 16.876 47.229 84.099 6692837.986 

S.D. 9.034 92.144 10.867 63.725 2.403 3.045 21.160 46868.355 

% R.S.D. 31.034 17.652 334.092 16.588 14.239 6.446 25.161 0.700 

MN SB V BE TL 

(ppm) (ppin) (ppa) (Ppm) (Ppm) 

Mean 58.641 -1726.748 -10.844 0.143 60.942 

S.D. 5.983 70.759 16.140 2.391 142.127 

% R.S.D. 10.203 4.098 148.847 1669.992 233.216 

co; 

36.539 

./

Identity 1: S95TOO1145 Identity 2: .5605gin250-1-9 2:27 PM July 25, 1995 


Sample Weight : 0.5605 Solution volume : 2500.00 WHGSD-WM-DP-_^L, REV, 

on-Peak Integrations : 


---------------------------------------------------------------------- 

2R SR BI SI AL CO N LI 

(Ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 11.063 135.546 12973.226 6281.659 972.752 46.593 37.808 31.820 

S.D. 6.752 0.479 61.666 16.679 19.353 6.837 1.563 0.555 

% R.S.D. 61.034 0.353 0.475 0.266 1.990 14.675 4.133 1.743 


(ppm) (Ppm) (ppm) (Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 160.997 6120.093 -2.490 12004.149 353.912 556.439 69.725 1527.097 

S.D. 2.209 22.149 6.070 29.920 1.029 12.827 5.320 142.155 

% R.S.D. 1.372 0.362 243.752 0.249 0.291 2.305 7.629 9.309 



Mean 49.430 -12.401 14.645 17181.256 7277.698 160.203 -7.034 120143.950 

S.D. 47.795 51.660 0.888 649.028 107.825 0.734 13.054 1283.285 

% R.S.D. 96.693 416.561 6.061 3.778 1.482 0.458 185.574 1.068 


(ppm) (PPM) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) 

Mean 5.019 29.949 -1.860 105.482 13.008 15.986 34.739 6317100.479 

S.D. 3.949 24.407 3.588 47.457 2.658 1.828 3.602 30700.221 

% R.S.D. 78.689 81.496 192.838 44.990 20.434 11.436 10.368 0.486 

MN SB y BE TL 


Mean 56.615 -499.203 -3.217 -1.214 -1.463 

S.D. 0.692 75.143 3.935 0.483 115.429 

% R.S.D. 1.221 15.053 122.326 39.779 7888.616 

C06

Identity 1: S95TO01145 D Identity 2: .5620gin250-1-9 2:31 PM July 25, 1995 

L1 REV. 

Task name : T WC93 

Sr Weight 0.5620 Solution Vol une 2500.00 WHC-SD-WMDP- - 

^ / 

On- _dk Integrations : 3 Off-Peak Integrations : 1 

---------------------------------------------------------------------- 

ZR 


( ppm ) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 15.304 134.908 13113.981 6375.470 1059.185 34.721 44.815 30.812 

S.D. 2.048 0.239 113.065 19.807 27.748 6.820 0.583 0.576 

% R.S.D. 13.381 0.177 0.862 0.311 2.620 19.641 1.301 1.870 


(Ppm ) (ppm) (Ppm) (Ppm) (Ppm) (Ppm) (Ppm) (pPm) 

Mean 214.190 5351.136 4.612 12043.743 391.111 533.688 40.404 1602.773 

S.D. 2.503 20.443 5.311 69.408 0.986 4.505 16.594 121.653 

% R.S.D. 1.169 0.382 115.161 0.576 0.252 0.844 41.070 7.590 


(PPM ) (Pprn) (Ppm) (Ppm) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 37.014 18.798 17.134 16064.120 7035.685 163.930 -18.766 120023.659 

S.D. 31.578 31.826 0.545 228.049 54.392 0.422 16.910 564.968 

% R.S.D. 85.313 169.303 3.181 1.420 0.773 0.258 90.111 0.471 


(Ppm) (ppm) (PpM) (Ppm) (ppM) (Ppm) (ppm) (Ppm) 

Mean -3.804 76.343 4.090 94.825 11.221 7.539 36.782 7911648.759 

S.D. 6.017 29.732 2.360 21.919 1.791 2.767 4.926 31195.612 

% R.S.D. 158.158 38.945 57.702 23.115 15.957 36.697 13.391 0.394 

MN SB V BE TL 

(Ppm ) (Ppm) (Ppm) (Ppm) (PPM) 

Mean 59.645 -195.225 -0.362 -1.203 -26.055 

S.D. 0.007 94.495 1.562 0.467 45.554 

% R.S.D. 0.011 48.403 431.708 38.780 174.842 

VV J

Identity 1: S95T001145 A Identity 2: .56059in250-1-2-7 2:34 PM July 25, 1995 




Solution volume : 2500.00 


WHGSD-WM-DP-^, REV. 

------------------------- ------------------ - ----------- ---------- ----- 

ZR SR BI St AL CO Cu LI 


Now 4489.729 4648.374 17296.691 10362.298 5374.788 4452.214 4484.018 4186.170 

S.D. 4.625 14.675 33.905 17.979 5.185 23.661 16.182 11.179 

% R.S.D. 0.103 0.316 0.196 0.174 0.096 0.531 0.361 0.267 

2N N1 LA FE CA CR NO u 

(Ppm ) (ppm) (Ppm) (Ppm) (ppm) (PPM) (Ppm) (Ppm) 

Mean 4480.989 10360.774 4568.806 16250.345 4990.449 5040.697 4713.411 9405.813 

S.D. 7.717 20.742 29.490 52.940 15.272 32.425 32.258 169.194 

% R.S.D. 0.172 0.200 0.645 0.326 0.306 0.643 0.684 1.799 



Mean 4511.250 4320.171 4524.108 18621.739 10839.462 4580.879 4433.882 124927.471 

S.D. 17.790 15.170 16.396 763.110 162.100 1.851 37.663 279.786 

% R.S.D. 0.394 0.351 0.362 4.098 1.495 0.040 0.849 0.224 

NO SE AG PO TI CD B K 

(ppm) (Ppm) (ppm) (Ppm) (Ppm) (Ppm) (ppm) (ppm) 

Mean 4454.140 4469.360 3094.111 4525.569 4411.939 4447.112 4369.482 6320644.824 

S.D. 14.154 36.909 21.343 29.777 7.978 18.104 11.259 17323.122 

% R.S.D. 0.318 0.826 0.690 0.658 0.181 0.407 0.258 0.274 

MN SB v BE TL 


Mean 4554.788 3887.784 4527.672 4352.521 4134.999 

S.D. 4.335 181.268 0.288 13.370 134.482 

It R.S.D. 0.095 4.663 0.006 0.307 3.252 

fr? ( 1J



T Weight 1.0000 Solution Volume 1.00 

Oh -ak Integrations : 3 


---------------------------------------------------------------------- 


(Ppm ) (Ppm) (ppm) (ppm) (Ppm) 

Mean -0.001 0.001 0.011 0.055 199.924 

S.D. 0.002 0.000 0.009 0.002 0.783 

% R.S.O. 155.515 25.874 80.752 3.015 0.392 



Mean -0.000 -0.051 0.010 146.967 18.927 

S.D. 0.001 0.002 0.002 0.053 0.046 

% R.S.D. 491.013 3.892 21.472 0.036 0.242 

CE SM BA P 5 

(Ppm) (Ppm) (ppm) (ppm) (Ppm) 

Mean 0.021 -0.013 0.003 0.028 0.154 

S.D. 0.014 0.017 0.000 0.010 0.005 

% R.S.D. 64.554 126.495 7.916 34.537 3.222 

MO SE AG PS TI 

(Ppm ) (ppM) (Ppm) (ppM) (ppm) 

Mean -0.003 0.012 -0.002 0.027 0.000 

S.D. 0.001 0.004 0.001 0.014 0.001 

% R.S.D. 23.345 31.974 53.873 51.807 150.901 


( ppm ) (Ppm) (Ppm) (ppm) (Ppm) 

Mean 0.010 -0.145 -0.005 0.002 -0.036 

S.D. 0.000 0.012 0.001 0.000 0.023 

% R.S.D. 4.089 8.580 12.814 8.091 64.552 

WHC SD WM DP _ZE, REV_ 

C1i 

CO CU L 

(ppm ) (ppm) (ppm) 

0.007 -0.013 0.000 

0.002 0.001 0.000 

21.593 4.891 130.322 

CR ND U 

(Ppm) (Ppm) (PPM) 

-0.007 0.024 0.028 

0.002 0.007 0.058 

31.196 27.249 209.403 

MG AS NA 


19.100 0.008 188.889 

0.018 0.002 1.915 

0.093 23.126 1.014 

CD B K 


0.014 -0.047 0.494 

0.001 0.000 0.020 

3.857 0.483 4.143



Sasp(e Weight : 1.0000 Solution Volume 1.00 WHC-SD-WM-DPI, REV.. 


------------------------------------------ ---------------------------- 


(PPM ) (PPM) (Ppn) (ppm) (ppa) 

Mean -0.003 0.001 -0.006 0.044 201.101 

S.D. 0.002 0.000 0.008 0.001 0.967 

It R.S.D. 47.590 35.159 137.938 1.983 0.481 


(PPM ) (PPM) (Ppm) (PPM) (Ppm) 

Mean 1.020 0.931 0.007 149.204 18.556 

S.D. 0.001 0.002 0.002 0.200 0.065 

% R.S.D. 0.146 0.215 24.695 0.134 0.353 

CE SM BA P 5 

(PPM ) (PPM) (PPM) (Ppm) (PPM) 

Mean 0.028 -0.017 0.503 0.050 0.165 

S.D. 0.015 0.016 0.003 0.008 0.007 

% R.S.D. 54.134 95.502 0.505 15.644 4.167 


(PPM ) (PPM) (PPM). (PPM) (Ppm) 

Mean -0.001 0.097 1.511 1.020 0.000 

S.D. 0.001 0.004 0.003 0.018 0.000 

% R.S.D. 140.517 3.987 0.216 1.801 181.627 


(PPM ) (PPM) (PPM) (ppo) (Ppm) 

Mean 0.520 -0.077 0.506 0.506 -0.063 

S.D. 0.001 0.045 0.001 0.001 0.034 

% R.S.D. 0.133 58.176 0.158 0.167 53.614 

iti 

CO Cu L 

(PPM ) (Ppm) (ppe) 

0.515 0.481 0.946 

0.002 0.002 0.011 

0.297 0.425 1.135 

CR NO u 


0.506 0.020 0.009 

0.002 0.004 0.059 

0.405 20.604 683.427 

MG AS NA 

(Ppm ) (PPM) (ppm) 

19.039 0.000 188.992 

0.038 0.003 1.885 

0.202 17759.588 0.997 

CD B • K 


1.034 -0.046 0.438 

0.005 0.000 0.025 

0.450 1.034 5.654

Identity 1: CCV_I Identity 2: CCV_1 


2:47 PM July 25, 1995 

e Weii gnt 1 0.-0 0 S o l ution Vo Iune 

. 1.00 

u >ak integrations 3 off-Peak Integrations : 1 

ZR SR BI Si AL 

(ppm) (ppm) (ppm) (PPM) (Ppm) 

Mean 4.937 4.981 4.947 4.751 4.945 

S.D. 0.005 0.010 0.020 0.004 0.010 

It R.S.D. 0.093 0.208 0.404 0.092 0.194 


(PPM) (PPM) (ppm) (Ppm) (ppm) 

Mean 5.013 4.977 5.037 5.063 5.161 

S.D. 0.002 0.016 0.020 0.009 0.013 

% R.S.D. •0.033 0.318 0.397 0.169 0.248 

CE SM BA P S 

(ppm) (Ppm) (ppm) (Ppm) (Ppm) 

Mean 4.999 5.006 4.997 4.922 4.953 

S.D. 0.014 0.015 0.013 0.035 0.053 

% R.S.D. 0.271 0.297 0.254 0.719 1.077 

MO SE AG PS TI 

(Ppm) (Ppm) (Ppm) (PPM) (Ppm) 

Mean 5.009 4.905 4.904 5.015 4.876 

S.D. 0.015 0.015 0.002 0.045 0.005 

% R.S.D. 0.302 0.305 0.035 0.905 0.106 

MN SB V BE TL 

(Ppm) (Ppm) (PPm) (Ppm) (PPM) 

Mew 5.026 4.747 5.035 5.159 4.917 

S.D. 0.004 0.050 0.002 0.005 0.022 

% R.S.D. 0.084 1.046 0.033 0.088 0.444 

WHGSD-WM-DP- 

REV. 

co CU L 


5.025 4.865 5.058 

0.005 0.010 0.014 

0.091 0.204 0.274 

CR ND u 


5.045 5.265 9.677 

0.011 0.023 0.016 

0.223 0.438 0.166 

(;:13 

MG AS NA 

(PPM ) (Ppm) (Ppm) 

5.015 4.924 5.087 

0.002 0.020 0.018 

0.043 0.409 . 0.363 

CD B K 


5.032 5.066 5.517 

0.004 0.007 0.046 

0.077 0.140 0.836

Identity 1: CCB_1 Identity 2: CCB_1 2:52 PM July 25, 1995 




--------------------------------------- ---------------------------- 

ZR SR BI SI 

( ppm) (ppm) (ppm) (Ppm) 

Mean -0.002 0.001 -0.017 -0.007 

S.D. 0.000 0.000 0.002 0.002 

% R.S.D. 4.665 14.945 12.449 30.815 

ZN NI LA FE 


Mean -0.000 0.000 -0.004 -0.002 

S.D. 0.000 0.001 0.002 0.001 

% R.S.D. 10956.310 319.633 50.277 46.645 

CE SM BA P 


Mean -0.014 -0.029 -0.000 0.036 

S.D. 0.001 0.005 0.000 0.008 

% R.S.D. 6.030 16.245 11.133 21.175 

MO SE AG p8 

( Ppm) (Ppm) (ppm) (Ppm) 

Mean -0.001 -0.007 -0.001 0.005 

S.D. 0.001 0.005 0.000 0.003 

% R.S.O. 57.735 68.573 6.274 58.490 

MN SB V BE 


Mean 0.000 -0.079 -0.002 0.000 

S.D. 0.000 0.002 0.001 0.000 

% R.S.D. 326.919 2.726 30.207 0.582 

AL 

(Ppm) 

-0.001 

0.003 

291.514 

CA 

(Ppm) 

0.001 

0.001 

81.620 

S 

(ppm) 

-0.001 

0.002 

236.708 

TI 

(ppm) 

-0.001 

0-000 

16.066 

TL 

(ppm) 

-0.060 

0.005 

7.562 

WHC-SD-WM-DP- Imo, REV. 

CO 

(ppm) 

0.004 

0.002 

34.535 

CR 

(Ppm) 

0.003 

0.001 

22.574 

MG 

(ppm) 

0.001 

0.000 

17.459 

CD 

(ppm) 

CIA 

0.003 

0.001 

28.891 

Cu 

(Ppm) 

NO 

(ppa) 

0.002 

0.000 

7.135 

0.015 

0.002 

13.496 

AS 

(ppm) 

-0.003 

0.001 

24.182 

B 

(ppm) 

0.003 

0.001 

26.567 

O 

07I.P /f- 

LI 

(ppm) 

0.001 

0.000 

14.515 . 

u 

(ppm) 

-0.097 

0.018 

18.990 

NA 

(ppm) 

K 

(Ppm) 

0.046 

0.002 

4.949 

0.254 

0.017 

6.721

1 III 111 III III 

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A-0004-1 

analyst: 


X 7-r41V 

Asr, J Instrument: ICPOII^ Book# y3 K15 

Method: LA-505-i-5-F V Rev/Mod Q-1 


WHGSD-WM-DP- REV. 

S Type Sample #R A Test Matrix Group Project 





5 PREPBLKTJA @ICP-FO3 SOLID 

















619

06/28/95 10:23 

A-0004-1 

WHGSD-WM-DP-_o I. REV.L 



Final page for worklist # 1726 3^ 


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Analysis Report Summary Wed 07-26-95 10:28:00 AM page 1 

# 

--- 

Sample Name 

File 

------------------ -- -------- 

Method 

-------- 

Date 

--------- 

Time 

----- 

OpID 

---- 

Type 

---- 

Mode 

----- 

ICV 950726A ICP2 07126195 08:35 DKS Q CONC 

2 ICB 950726A ICP2 07126195 08:38 DKS Q CONC 

3 ICSA 950726A ICP2 07126195 08:42 DKS CONC 

4 ICSAB 950726A ICP2 CONC 

5 PREPBLKTJA 950726A ICP2 07/126%95 08:53 DKS $ CONC 


7 S95T001150— 950726A ICP2 07126195 09:02 DKS S CONC 



10 CCB — 950726A ICP2 07126195 09:32 DKS CONC 

11 CCB 950726A ICP2 07126195 09:36 DKS CONC 


I3 S95T001151 — 950726A ICP2 07%26/95 09:44 DKS S CONC 


15 S95T001151 —A 950726A ICP2 07%26/95 09:52 DKS S CONC 

16 ICSA — 950726A ICP2 07 26195 10:00 DKS CONC 

17 ICSAB 950726A ICP2 07%26/95 10:04 DKS CONC 

18 CCV 1 950726A ICP2 07 26195 10:20 DKS Q CONC 

19 CCB-1 950726A ICP2 07%26/95 10:24 DKS Q CONC 

J^ ),^ 

G 7-1(- ss- 

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WHC-SD-WM-DP- 2I , REV:L 

- r J P N ^z 1 TAIo- • al M 6:r •. #. • •• r:. ffNMM fffAi a k• r, 

L f:Ny


# 

--- 

Sample Name 

Ag 

--------------- ----- -------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

1 ICV 5.028 4.965 5.174 4.968 5.036 5.235 

2 ICB .0009 .0028 -.0018 .0029 .0000 .0000 

3 ICSA .0000 242.5 .0098 -.0001 .0017 .0001 

4 ICSAB .9746 242.4 .0132 0095 .4664 .4791 

5 PREPBLKTJA .0218 1796 0851 .0043 0158 .0014 

6 S95TOO1150 L -22.61 1849. -42.96 -62.98 14.19 -4.495 

7 S95T001150- 4.536 1941. -21.25 47.93 13.78 .3996 

8 S95TOO1150 D 4.765 2018. -58.26 32.39 13.26 5713 

9 S95TOO1150-A 4477. 6417. 5349. 4641. 4277. 5030. 

10 CCV - 5.004 4.946 5.092 4.961 4.946 5.088 

11 CCB .0008 .0024 -.0052 0024 0001 -.0000 

12 S95TOO1151 L -34.34 1729. -71.71 54.48 12.52 3.804 

13 S95T001151 - -19.66 1400. -49.64 22.04 11.30 -.0909 

14 S95TOO1151 D -5.604 1691. -111.2 16.05 11.18 2637 

15 S95TOO1151 -A 3840. 5338. 4601. 4051. 3819. 4323. 

16 ICSA - -.0021 237.1 -.0398 -.0003 .0018 .0000 

17 ICSAB .9874 243.4 -.0473 -.0020 4603 4912 

18 CCV 1 4.970 4.920 5.057 4.910 4.908 5.063 

19 CCB- 1 .0011 -.0133 .0059 .0028 .0001 -.0002 

# 

--- 

Sample Name 

Bi 

--------------- ----- -------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

1 ICV 5.033 5.212 5.148 5.109 5.163 5.165 

2 ICB .0230 0011 0004 0020 .0024 .0003 

3 ICSA -.0172 242.7 .0019 .0078 .0008 .0067 

4 ICSAB -.0285 247.2 .9516 .0052 .4733 .4818 

5 PREPBLKTJA 0374 2058 0098 0130 .0073 0063 

6 S95TOO1150 L 14390. 294.0 -44.45 30.00 -3.297 625.8 

7 S95T001150- 14080. 350.3 -8.493 5530 17.98 636.8 

8 S95TOO1150 D 14420. 354.7 -8.930 29.29 36.12 678.1 

9 S95TOO1150-A 19250. 6289. 5492. 4522. 5400. 6074. 

10 CCV - 5.031 5.096 5.014 5.063 5.058 5.061 

11 CCB 0180 0023 0001 0099 0016 0014 

12 S95TOO1151 L 11590. 227.8 33.54 200.0 26.38 519.2 

13 S95T00115I - 11320. 284.2 -4.078 -36.04 5.929 484.1 

14 S95TOO1151 D 10480. 258.2 -5.017 10.51 18.05 491.8 

15 S95TOO1151 -A 15780. 4967. 4626. 4070. 4523. 4979. 

16 ICSA - -.0277 253.0 -.0002 .0269 0004 .0080 

1.7 ICSAB -.0250 254.6 .9996 .0215 4860 5000 

18 CCV 1 4.978 5.081 5.009 5.018 5.056 5.043 

19 CCB_-1 -.0149 .0021 .0002 .0072 -.0009 -.0024 

# 

--- 

Sample Name 

Cu 

----------------- --- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

I ICV 4.969 .0056 5.130 5.024 5.051 4.943 

2 ICB .0004 .0003 .0003 .0639 -.0002 .0006 

3 ICSA -.0085 -.0174 91.43 .0339 -.0035 .0027 

4 ICSAB .4733 -.0223 91.93 .1213 -.0039 .9428 

5 PREPBLKTJA .1099 .0276 .3277 14280. 0019 0189 

6 S95TOO1150 L 18.83 58.46 13150. 7372e3 -11.01 65.97 

7 S95T001150- 22.85 18.59 12850. 6975e3 -1.548 22.13 

G2;." 

I 

\> 

W 

2 

Î 

d 

C 

C 

u, 

U 

2 

3


# 

--- 

Sample Name 

-------------------- Cu 

-------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

S95T001150 D 32.63 32.16 13040. 6244e3 -4.000 32.59 

S95T001150-A 4292. 47.10 18830. 6775e3 4388. 3811. 

10 CCV - 4.935 .0051 5.029 4.858 4.999 5.018 

11 CCB -.0002 -.0001 0009 0253 0009 0006 

12 S95T00115I L 34.98 -7.994 10320. 6847e3 3.858 -21.97 

13 S95T001151 - 15.84 15.67 10180. 6485e3 -12.40 17.58 

14 S95T001151 D 17.49 29.81 9943. 6117e3 -7.690 32.01 

15 S95T001151 -A 3879. 40.35 14670. 6262e3 3946. 3769. 

16 ICSA - -.0125 -.02I7 94.34 .0849 -.0032 .0074 

17 ICSAB 4607 0157 95.15 -.2065 -.0058 9365 

18 CCV 1 4.908 .0067 5.013 4.617 4.964 4.940 

19 CCB-I -.0002 .0007 -.0009 -.2197 -.0005 .0014 

# 

--- 

Sample Name 

Mg 

--------------- ----- -------- 

Mn 

-------- 

Mo 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

1 ICV 4.958 5.028 5.128 4.957 5.195 5.081 

2 ICB .0005 .0004 .0013 0007 0013 -.0009 

3 ICSA 243.6 0052 -.0063 188.2 .0027 0273 

4 ICSAB 243.9 .4519 0052 188.3 -.0006 9101 

5 PREPBLKTJA 1575 0346 0183 4.073 0069 8.794 

6 S95T001150 L 138.6 91.24 44.24 135300. -33.56 9434. 

7 S95T001150- 179.9 76.95 2.572 128300. 1.809 9281. 

8 S95T001150 D 249.4 81.37 9.049 124200. 27.12 9539. 

9 S95T001150-A 4684. 5104. 5267. 126100. 4425. 15320. 

10 CCV - 4.934 4.933 5.031 5.004 5.160 5.027 

11 CCB .0122 0001 0032 0020 0009 0058 

12 S95T001151 L 438.8 51.11 2.456 118600. 85.19 7557. 

13 S95T001151- 170.3 56.70 3876 112000. 3.464 7543. 

14 S95T001151 D 224.6 51.63 5.624 106300. 33.97 5246. 

15 S95T001151 -A 4242. 4257. 4452. 111300. 4041. 12180. 

16 ICSA - 247.3 -.0053 -.0056 180.7 .0015 0152 

17 ICSAB 251.7 4634 -.0038 188.7 0028 9540 

18 CCV 1 4.912 4.917 5.011 4.959 5.142 4.971 

1 CCB - 1 -.0014 .0001 .0009 .0041 -.0018 .0010 

# 

--- 

Sample Name 

P 

--------------- ----- -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

I ICV 5.052 5.110 5.015 4.825 5.048 4.992 

2 ICB .0359 0147 .0104 .0019 .0018 .0123 

3 ICSA -.0062 .0101 -.0165 -.0033 -.0003 .0494 

4 ICSAB -.0074 .9736 -.0164 0030 0022 .0466 

5 PREPBLKTJA .1810 -.0812 -.0111 .0574 .4069 3901 

6 S95T001150 L 20590. -495.6 8553. -136.0 -34.58 7413. 

7 S95T001150- 20130. 77.81 8367. -31.45 -247.7 7137. 

8 S95T001150 D 20440. 57.80 8573. -31.88 -58.18 7271. 

9 S95T001150-A 27860. 5529. 14270. 4869. 5209. 12710. 

10 CCV - 5.013 5.005 4.972 4.746 4.945 4.662 

11 CCB -.0205 -.0016 -.0089 .0028 0131 0038 

12 S95T001151 L 15460. 101.9 6510. -96.79 -709.3 5249. 

13 S95T001151- 15700. 42.56 6878. -62.12 -209.5 5276. 

14 S95T001151 D 15910. 27.03 6832. -6.248 -133.9 5789. 

15 S95T001151 -A 20990. 4692. 11510. 4243. 4494. 9570. 

Gw 3 

W 

CL 

d 

3 C 

cn 

3


# 

--- 

Sample Name 

-------------- 

P 

------ -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

16 ICSA -.0026 .0329 -.0215 .0037 .0490 .0522 

17 ICSAB -.0110 1.034 -.0320 .0003 .0388 .0398 

18 CCV 1 5.065 5.011 4.989 4.748 4.988 4.652 

19 CCB- 1 -.0125 -.0061 .0053 -.0047 .0189 .0078 

# Sample Name Sm Sr Th Ti TI U 

1 ICV 5.067 4.991 .0080 4.933 4.970 10.11 

2 ICB .0013 .0000 .0043 .0000 -.0103 .0129 

3 ICSA -.0110 .0026 -.0174 .0015 .0555 -1177 

4 ICSAB 0075 .0025 0127 .0015 .0570 .1412 

5 PREPBLKTJA 2268 0188 2147 .0068 0323 -3.102 

6 S95T001150 L 578.6 169.1 7.233 -14.53 157.8 1623. 

7 S95T001150- 183.0 140.5 78.32 11.55 -9.098 18.98 

8 S95T001150 D 330.9 139.5 41.16 13.92 -172.2 739.1 

9 S95T001150-A 4627. 4473. 53.78 4630. 5093. 9325. 

10 CCV - 5.022 4.924 -.02I7 4.849 4.996 10.04 

11 CCB -.0015 .0003 .0054 .0006 -.0151 -.0059 

12 S95T001151 L -68.45 110.9 277.2 17.98 -195.2 -1444. 

13 S95T001151 - 173.7 102.4 50.65 7.488 -81.09 -455.9 

14 S95T001151 D 347.9 99.25 8.102 14.19 -114.1 301.8 

15 S95T001151 -A 4267. 3972. 2.589 4037. 4395. 8254. 

16 ICSA .0541 .0023 -.0097 .0022 .0382 .1839 

17 ICSAB .0335 .0022 -.0080 .0013 .0327 .1253 

18 CCV 1 4.994 4.890 -.0225 4.826 4.909 9.995 

19 CCB 1 .0046 .0001 -.0064 -.0002 -.0049 .0290 

# 

--- 

Sample Name 

V 

--------------- - --- -------- 

Y 

-------- 

Zn 

-------- 

1 ICV 5.060 .0127 5.081 5.028 

2 ICB -.0000 .0001 .0001 -.0004 

3 ICSA -.0011 .0074 -.0021 -.0018 

4 ICSAB .4676 .0074 .9693 -.0018 

5 PREPBLKTJA 0531 0133 0565 0157 

6 S95T001150 L 141.8 42.66 71.76 126.0 

7 S95T001150- 44.26 11.50 76.98 46.11 

8 S95T001150 D 79.90 20.18 83.18 73.12 

9 S95T001150-A 5085. 37.84 5529. 4797. 

10 CCV - 4.975 .0125 5.014 4.954 

11 CCB -.0010 -.0001 .0005 -.0004 

12 S95T001151 L -31.95 -6.772 65.03 -21.34 

13 S95T001151 - 33.73 9.480 49.93 38.74 

14 S95T001151 D 69.01 18.44 50.00 67.09 

15 S95T001151 -A 4337. 33.52 4609. 4170. 

16 ICSA - .0091 .0107 -.0017 .0058 

17 ICSAB 4854 .0096 1.013 0017 

18 CCV 1 4.952 .0133 5.001 4.928 

19 CCB-1 .0014 .0005 -.0002 .0005 

Zr 

-------- -------- -------- 

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06/28/95 10:32 /Page: l 

A-0004-1 


.nalyst: 

JJ 

J^sr.Id Instrument: 

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ICPOt^ Book# Y3hWb 

Method: 

J(P,rrr 

LA-5054ft&1 Rev/Mod G-1 _ n 


WHGSD-WM-DP- 























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,REV• 

I

06/28/95 10:32 

A-0004-1 

WHC-SD-WM-DP- I I REV. 

LABCORE Data Ent ry Template for Worklist# 1729 


Analyst Signature 

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Page: 2

Analysis Report Summary Thu 07-20-95 10:49:38 AM page I 

# Sample Name 

File 

--- -------------- ------ -------- 

1 ICV 

2 ICB 

3 ICSA 

4 ICSAB 

5 PREPBLKTJA 

6 S95T001156 L 

7 S95T001156- 

8 S95T001156 D 

9 S95T001156-A 

10 CCV 

11 CCB 

12 S95T001157 L 

13 S95T001157- 

14 S95T001157 D 

15 S95T001157-A 

16 ICSA 

17 ICSAB 

18 CCV 1 

19 CCB=1 

Method Date Time 

-------- --------- ----- OpID 

---- 

950720A ICP2 07120195 

950720A ICP2 07120195 

950720A ICP2 07%20/95 

950720A ICP2 07120195 

950720A ICP2 07%20/95 

950720A ICP2 07120195 

950720A ICP2 07120195 

950720A ICP2 07120195 

950720A ICP2 07%20/95 

950720A ICP2 07120195 

950720A ICP2 07%20/95 

950720A ICP2 07120195 

950720A ICP2 07120195 

950720A ICP2 07120195 

950720A ICP2 07%20/95 

950720A ICP2 07 20195 

950720A ICP2 07/20/95 

950720A ICP2 07/20/95 

950720A ICP2 07120 195 

jK ^4p 

67-0 ,, I 

bgoo 5?SToO //S 4 

S^5TOO /(.Sr 

44 

td"41, 14 / 141 

Type 

---- 

Mode 

----- 

08:48 DKS Q CONC 

08:52 DKS CONC 

08:56 DRS CONC 

08:59 DKS O CONC 

09:05 DKS S CONC 















SIGNATM ABDVE REBRESEM CH MICAL TWMLOGIST/CHHMT_= THAT 

COI UMM/VSRIFIED THE CALIBRATICM/AHALYSIS CH PAGES & 3/ To 

Cal 

WHC-SD-WM-DP- )3 7, REV.

Analysis Report Averages Thu 07-20-95 10:49:38 AM page 2 

# 

--- 

Sample Name 

-------------------- 

Ag 

-------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

1 ICV 5.105 4.988 5.179 5.007 5.061 5.218 

2 ICB .0004 0104 0058 .0019 0000 - 0001 

3 ICSA 0008 242.2 .0218 .0035 .0017 .0001 

4 ICSAB .9866 242.5 0135 0087 .4663 .4750 Lu Q 

5 PREPBLKTJA -.0097 .1500 .1521 .0140 .0144 .0017 

6 S95TOO1156 L 36.61 1219. 17.81 83.92 15.46 - .9350 

7 S95T001156- -11.50 1306. 25.68 8.909 11.71 3585 

8 S95TOO1156 D 10.06 1310. 15.31 49.68 13.48 3696 

9 S95TOO1156-A 2237, 5856. 5519. 4707. 4349. 5183. 

10 CCV - 5.113 5.106 5.114 5.048 5.125 5.197 CL 

11 CCB .0004 -.0139 -.0130 .0019 -.0001 -.0001 

12 S95TOOI157 L -13.44 1795. 547.8 3.824 18.51 -4.415 2 

13 S95T001157- -23.99 1480. -84.22 25.45 11.32 .0590 3 

14 S95TOO1157 D 14.93 1440. -10.00 55.30 15.46 .0346 p 

15 S95TOO1157-A 

2854, 6744. 5426. 5109. 5075. 5240. fl? 

16 ICSA - 

0004 166.8 -.2085 -.0080 .0019 .0001 U 

17 ICSAB 1.024 264.3 -.1848 -.0064 5098 5019 = 

18 CCV 1 5.008 4.927 5.034 4.905 4.917 5.056 3 

19 CCB-1 .0018 -.0070 -.0007 .0048 .0000 -.0002 

# 

--- 

Sample Name 

Bi 

-------------- ------ -------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

1 ICV 5.033 5.308 5.136 5.122 5.150 5.172 

2 ICB .0172 -.0034 -.0007 -.0113 .0008 .0002 

3 ICSA -.0122 246.6 .0025 .0023 .0016 .0058 

4 ICSAB -.0559 249.7 .9511 -.0021 .4699 .4845 

5 PREPBLKTJA -.0979 .1970 .0000 -.0701 .0357 .0248 

6 S95TOO1156 L 10520. 687.9 -6.749 212.9 30.30 563.6 

7 S95T001156 - 10470. 647.2 -1.535 14.52 10.64 552.7 

8 S95TOO1156 D 11270. 458.0 5.820 61.81 2.504 544.1 

9 S95TOO1156-A 15690. 6736. 5742. 4584. 5586. 6176. 

10 CCV - 5.061 5.142 5.028 5.232 5.080 5.103 

11 CCB .0199 -.0003 -.0003 -.0072 -.0020 -.0001 

12 S95TOO1157 L 12230. 542.0 29.02 420.9 -24.72 466.9 

13 S95T001157- 11850. 357.3 -13.77 -202.5 -11.12 494.3 

14 S95TOO1157 D 10990. 399.4 7.552 86.49 1.988 487.1 

15 S95TOO115 TA 17070. 5495. 5125. 5252. 5149. 5689. 

16 ICSA - .0044 239.8 -.0017 .0146 -.0016 .0050 

17 ICSAB 0418 238.7 9464 0074 4697 4870 

18 CCV 1 4.950 5.098 4.979 5.047 5.012 5.029 

19 CCB-1 .0360 .0023 .0009 .0011 .0000 .0005 

# 

--- 

Sample Name 

-------------------- 

Cu 

-------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- Li 

-------- 

1 ICV 4.965 .0061 5.119 4.892 5.071 4.962 

2 ICB -.0002 .0007 -.0019 -.1755 -.0013 .0007 

3 ICSA -.0102 -.0264 91.61 .0334 -.0039 .0029 

4 ICSAB .4679 -.0285 91.96 -.0065 -.0051 .9385 

5 PREPBLKTJA .0589 .0365 .5416 13500. -.0144 .0271 

6 S95TOO1156 L 51.62 126.0 10990. 5293e3 21.12 111.3 

7 S95T001156- 48.73 39.94 11110. 5053e3 -2.248 35.09 

G3w 

> 

Î


# 

--- 

Sample Name 

Cu 

---------------- ---- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

i S95T001156 D 6.706 57.79 11320. 5994e3 6.488 50.50 

1 S95T001156-A 4358. 55.49 16730. 5006e3 4460. 3751. 

10 CCV - 5.082 .0023 5.095 4.914 5.170 5.266 

11 CCB -.0002 -.0013 -.0003 .0080 -.0013 -.0012 

12 S95T001157 L 18.26 -19.55 10890. 6572e3 71.27 -14.86 

13 S95T001157- 15.36 -10.73 11050. 6727e3 -34.37 -7.727 

14 S95T001157 D 22.06 -4.360 10970. 7939e3 10.93 1.164 

15 S95T00115 TA 5176. -6.866 16320. 6759e3 5196. 5285. 

16 ICSA - -.0128 .0184 96.08 .1288 -.0043 -.0027 

17 ICSAB .5157 .0203 95.12 .0709 -.0051 1.114 

18 CCV 1 4.895 .0090 4.994 5.073 4.985 4.992 

19 CCB-1 .0002 .0002 .0000 .0673 .0005 .0002 

# 

--- 

Sample Name 

-------------------- 

Mg Mn Mo Na Nd Ni 

-------- 

1 ICV 4.988 5.039 5.120 4.960 5.211 5.114 

2 ICB -.0076 .0004 .0009 .0048 -.0023 .0016 

3 ICSA 243.7 0051 -.0064 186.1 .0004 - 0185 

4 ICSAB 244.0 .4521 -.0111 187.3 -.0027 .9143 

5 PREPBLKTJA .1293 0926 0141 3.859 .0075 10.49 

6 S95T001156 L -20.08 117.2 -27.11 119800. -4.838 5510. 

7 S95T001156- 80.42 89.08 -5.107 112700. -18.23 5518. 

8 S95T001156 D 12.50 83.27 -4.058 108800. -24.36 7482. 

9 S95T001156 -A 4699. 5283. 5427. 115300. 4478. 11220. 

10 CCV - 5.034 4.986 5.061 5.182 5.365 5.044 

11 CCB -.0065 -.0005 -.0039 -.0070 .0008 0045 

12 S95T001157 L 154.2 48.44 -72.23 134100. -13.23 4867. 

13 S95T001157- 44.87 58.67 -18.63 138200. -50.36 4885. 

14 S95T001157 D 140.2 57.64 -16.85 134200. -12.26 8468. 

15 S95T00115 TA 5186. 4972. 5205. 144800. 5392. 10100. 

16 ICSA - 267.2 -.0100 -.0076 217.3 .0078 -.0196 

17 ICSAB 264.8 .4547 -.0126 216.2 .0058 9193 

18 CCV 1 4.904 4.898 4.974 4.974 5.154 4.949 

9 CCB-1 -.0002 .0001 -.0004 .0058 .0022 .0009 

# 

--- 

Sample Name 

----------------- 

P 

--- -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 ICV 5.023 5.093 5.040 4.809 5.074 4.950 

2 ICB 0090 -.0017 -.0041 0083 .0249 .0134 

3 ICSA -.0045 .0345 -.0254 .0066 .0215 .0521 

4 ICSAB -.0319 .9977 -.0338 .0004 .0291 .0518 

5 PREPBLKTJA -.1410 .1080 -.0353 .0167 .7712 7229 

6 S95T001156 L 17470. 273.7 8027. -39.35 1406. 6798. 

7 S95T001156 - 17690. 62.29 8422. -54.93 165.9 6191. 

8 S95T001156 D 17890. 78.51 8676. 27.42 445.3 6184. 

9 S95T001156-A 24740. 5941. 14010. 4997. 5650. 11550. 

10 CCV - 5.099 5.010 5.077 4.784 5.018 4.969 

11 CCB .0067 .0066 -.0036 -.0012 0161 0008 

12 S95T001157 L 16370. 228.7 7652. 51.93 -1110. 5830. 

13 S95T001157- 16530. 83.51 7643. -82.49 -484.0 6084. 

14 S95T001157 D 17660. 97.57 7720. 40.79 -534.1 5927. 

15 S95T00115 TA 23130. 5244. 13320. 5003. 4599. 11200. 

C3:3 

>.+ 

W 

Î 

CL 

3 

0 

U 

3


# 

--- 

Sample Name 

P 

-------------- ------ -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

16 ICSA -.0I90 .0072 -.0214 .0048 -.1864 .0085 

17 ICSAB -.0232 .9781 -.0185 -.0057 -.1906 .0055 

18 CCV 1 4.926 4.979 4.937 4.682 4.891 4.906 

19 CCB-1 -.0028 -.0073 .0052 .0081 .0033 .0073 

# 

--- 

Sample Name 

Sm 

-------------- ------ -------- 

Sr 

-------- 

Th 

-------- 

Ti 

-------- 

T1 

-------- 

U 

-------- 

1 ICV 5.083 5.004 .0057 4.904 4.993 10.10 

2 ICB .0076 .0007 -.0074 0006 .0157 .0251 

3 ICSA -.0004 .0022 -.0202 .0009 .1026 -.1355 

4 ICSAB 0015 .0022 0245 .0013 .0715 - 1475 

5 PREPBLKTJA 3611 0163 .1150 0091 1621 -2.406 

6 S95T001156 L 1378. 155.5 -139.7 12.14 49.38 5128. 

7 S95T001156- 432.9 126.2 -38.36 5.691 119.0 1552. 

8 S95T001156 D 606.3 123.5 -11.71 3.924 90.83 1932. 

9 S95T001156-A 4777. 4527. -12.13 4689. 5243. 10310. 

10 CCV - 5.203 5.101 0439 4.954 5.003 10.35 

11 CCB -.0128 -.0002 .0024 -.0004 .0031 -.0647 

12 S95T001157 L -232.4 125.7 424.8 -.3410 622.9 -1488. 

13 S95T001157- -120.5 131.4 52.87 -1.236 -23.67 -837.0 

14 S95T001157 D -33.05 128.0 178.5 4.090 91.83 -949.7 

15 S95T001157-A 5078. 5261. 69.01 5050. 5046. 9687. 

16 ICSA - -.0607 .0021 -.0118 .0016 .0643 .0340 

17 ICSAB -.0589 .0020 -.0127 .0010 .0277 .0488 

18 CCV 1 5.011 4.905 .0443 4.807 4.830 9.966 

19 CCB-1 .0065 .0000 -.0009 .0000 -.0084 .0099 

# 

--- 

Sample Name 

V 

----------------- --- -------- 

Y 

-------- 

Zn 

-------- 

1 ICV 5.054 .0130 5.078 5.022 

2 ICB .0014 .0005 .0004 .0018 

3 ICSA .0016 .0077 -.0009 .0001 

4 ICSAB .4685 .0079 .9716 .0003 

5 PREPBLKTJA 0867 0204 0493 0468 

6 S95T001156 L 322.1 81.57 137.3 218.0 

7 S95T001156- 101.6 25.58 142.9 73.31 

8 S95T001156 D 150.0 37.08 125.3 107.7 

9 S95T001156 -A 5223. 45.23 5756. 4876. 

10 CCV - 5.044 .0117 5.011 5.053 

11 CCB -.0033 -.0008 -.0004 -.0025 

12 S95T001157 L -49.59 -15.62 69.79 -62.44 

13 S95T001157- -21.35 -7.421 66.08 -14.04 

14 S95T001157 D -4.228 -2.294 59.07 -6.588 

15 S95T001157-A 5122. 5.858 5208. 5105. 

16 ICSA - -.0134 .0045 .0040 -.0114 

17 ICSAB .4751 .0043 .9739 -.0104 

18 CCV 1 4.927 .0138 4.963 4.901 

19 CCB-1 .0009 .0002 .0006 .0003 

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07/21/95 07:16 Page: 1 

A-0004-1 


^nalyst: -)610 Instrument: ICP0'1' Book# 

1fYir-zf- lfI Ai 

Method: LA-505-t5T W Rev/Mod A -/ 

WHC-SD-WM-DP- 15 1 ., REV. I 

Worklist Comment: 1CP B-104 (RE-RUN)FUSION Li only 











ICSA @ICP-QC QC 




4i 

Analyst Signature 


q 0 7- ;0-^^ 

Date Analyst Signature Date 



639

Analysis Report Summary Thu 07-20-95 02:00:14 PM page 1 

# 

--- 

Sample Name 

--•------------- 

File 

---- -------- 

Method 

-------- 

Date 

--------- 

Time 

----- 

OpID 

---- 

Type 

---- 

Mode 

----- 

1 ICV 95O720B ICP2 07120195 12:46 DKS Q CONC 

2 ICB 95O720B ICP2 07120195 12:50 DKS CONC 

3 ICSA 95O720B ICP2 07120195 12:53 DKS (^ CONC 

4 ICSAB 950720B ICP2 07120195 12:57 DKS QQ CONC 

5 PREPBLKTJA 95O720B ICP2 07120195 13:03 DKS S CONC 

6 S95TOO1101 L 9507208 ICP2 07120195 13:07 DKS S CONC 

7 S95T001101 — 950720B ICP2 07%20/95 13:11 DKS S CONC 

8 S95T001101 D 950720B ICP2 07/20/95 13:16 DKS S CONC 

9 S95T001101 —A 95O720B ICP2 07/20/95 13:20 DKS S CONC 

10 ICSA — 95O720B ICP2 07120195 13:35 DKS CONC 

11 ICSAB 950720B ICP2 071201 95 13:39 DKS CONC 

12 CCV 950720B ICP2 07120195 13:51 DKS CONC 

13 CCB 950720B ICP2 07120195 13:55 DKS CONC 

3-1 0 f sisTucy1mv 

•• r - ô-^ a •s^ gy m: • ^. • ra. 

640 

WHGSD-WM-DP- 151_, REV.)

Analysis Report Averages Thu 07-20-95 02:00:14 PM page 2 

# 

--- 

Sample Name 

-------------------- 

Ag 

-------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

ICV 5.026 4.924 5.051 4.912 4.925 5.069 

2 ICB .0019 0125 .0036 .0004 .0001 0002 

3 ICSA .0021 245.1 -.1413 -.0094 .0019 .0001 

4 ICSAB .9739 244.0 -.1283 -.0030 .4657 .4727 

5 PREPBLKTJA .0114 -.I326 .1117 .0087 0141 .0008 

6 S95T001101 L -14.60 3668. 46.82 25.76 15.43 .8059 

7 S95T001101 - -1.131 3888. 11.24 34.03 14.59 -.I353 

8 S95T001101 D -3.584 3394. 15.66 28.60 12.75 1242 

9 S95T001101 -A 4187. 8235. 4771. 4340. 4134. 4481. 

10 ICSA - -.0001 240.1 -.1111 -.0035 .0018 .0001 

11 ICSAB .9591 238.0 -.0985 -.0052 4482 4642 

12 CCV 4.982 4.831 4.982 4.791 4.772 4.985 

13 CCB .0014 -.0020 .0063 -.0004 .0001 .0000 

# 

--- 

Sample Name 

Bi 

--------------- ----- -------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

1 ICV 4.888 5.133 4.998 5.054 5.037 5.054 

2 ICB -.0170 .0019 .0004 .0095 .0005 .0010 

3 ICSA -.0435 235.3 0011 .0223 .0035 .0084 

4 ICSAB -.0399 239.1 .9308 .0186 .4622 .4759 

5 PREPBLKTJA 2085 2162 0095 .0638 0621 0411 

6 S95T001101 L 14570. 400.1 1.762 -24.75 38.98 672.2 

7 S95T001101- 14700. 387.4 5.219 114.8 23.18 644.3 

8 S95T001101 D 12430. 440.6 2.451 67.09 4.274 564.4 

9 S95T001101 -A 19180. 5149. 4645. 4469. 4626. 5293. 

10 ICSA - -.0179 240.4 -.0016 .0165 .0036 .0069 

11 ICSAB -.0211 238.3 .9226 0189 4565 4707 

12 CCV 4.816 5.214 4.991 4.913 5.016 5.033 

13 CCB -.0288 .0022 .0011 .0132 .0011 .0015 

# 

--- 

Sample Name 

Cu 

--------------- ----- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

1 ICV 4.902 .0090 5.010 4.968 4.985 4.988 

2 ICB .0000 .0004 -.0002 .1720 .0008 .0005 

3 ICSA -.0106 .0338 90.55 .0914 -.0038 .0021 

4 ICSAB .4709 .0303 91.02 1854 -.0038 .9901 

5 PREPBLKTJA .0962 .0801 .0881 II640. 0040 0771 

6 S95T001101 L 19.44 49.48 11650. 7787e3 -21.14 65.33 

7 S95T001101 - 22.99 23.87 11320. 7265e3 5.363 34.17 - 

8 S95T001101 D 10.63 23.82 10100. 6550e3 -3.778 30.24 - 

9 S95T001101 -A 4214. 30.64 15790. 7304e3 4289. 4221. 

10 ICSA - -.0108 .0209 90.80 .2052 -.0040 .0041 

11 ICSAB .4538 .0252 89.76 0942 -.0037 9442 

12 CCV 4.768 .0102 4.966 4.833 4.865 4.788 

13 CCB -.0003 .0025 -.0003 .0947 .0007 .0026 

G 4 i 

c 

y 

î 

CL 

D 

N 

O 

U 

2 

3

AnalYsis Report Averages Thu 07-20-95 02:00:14 PM page 3 

# 

--- 

Sample Name 

Mg 

---------------- ---- ------ - 

Mn 

-------- 

Mo 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

1 ICV 4.939 4.914 5.008 4.970 5.153 5.001 

2 ICB 0024 .0001 .0001 0019 .0020 .0030 

3 ICSA 248.0 -.0073 -.0047 194.9 .0068 -.0177 

4 ICSAB 247.5 .4421 0094 194.1 .0051 9054 

5 PREPBLKTJA .3137 .0587 .0116 3.852 .0917 6.455 

6 S95TOO1101 L 210.2 87.79 25.91 132200. 12.33 8097. 

7 S95T001101- 154.1 80.83 -2.911 123600. 4.080 7820. 

8 S95TOO1101 D 104.3 72.44 -10.55 123500. -10.53 9946. 

9 S95TOO110I-A 4540. 4433. 4609. 128600. 4411. 12350. 

10 ICSA - 245.0 -.0065 -.0062 187.9 .0062 -.0188 

11 ICSAB 242.9 .4355 -.0095 187.4 .0040 .8860 

12 CCV 4.847 4.869 4.961 4.820 5.006 4.976 

13 CCB .0018 .0007 .0010 .0229 .0011 -.0036 

# 

--- 

Sample Name 

-------------------- P 

-------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

------- - 

Si 

-------- 

1 ICV 4.958 5.012 5.008 4.707 4.964 4.902 

2 ICB -.0284 -.0031 -.0180 .0029 -.0142 .0089 

3 ICSA -.0513 .0157 -.0339 .0116 -.0903 .0386 

4 ICSAB -.0463 .9653 -.0348 -.0034 -.0874 .0379 

5 PREPBLKTJA -.0314 .4004 .0667 -.0163 .6157 .5240 

6 S95TOO1101 L 20040. -23.72 8469. -74.95 -164.1 6393. 

7 S95T001101- 19530. 146.0 8389. 47.00 -280.0 6168. 

8 S95TOO1101 D 18550. 109.2 8396. 21.53 -193.9 5418. 

9 S95TOO1101-A 25700. 4790. 13430. 4393. 4358, 10820. 

10 ICSA - -.0436 .0359 -.0099 -.0140 -.0455 .0461 

11 ICSAB -.0396 .9650 -.0215 -.0016 -.0481 .0413 

12 CCV 4.907 5.022 4.927 4.674 4.940 4.860 

13 CCB -.0165 .0066 -.0071 .0032 .0227 .0152 

# 

--- 

Sample Name 

-------------------- Sm 

-------- 

Sr 

-------- 

Th 

-------- 

Ti 

-------- 

TI 

-------- 

U 

-------- 

1 ICV 5.010 4.904 .0282 4.811 4.925 9.983 

2 ICB .0072 .0000 -.0033 .0000 -.0032 .0089 

3 ICSA -.0113 .0020 -.0053 .0019 .0482 .0271 

4 ICSAB -.0076 .0019 .0029 .0017 .0604 -.0035 

5 PREPBLKTJA .8067 .0166 -.0147 .0187 .1721 -.1587 

6 S95TOO1101 L 483.3 159.2 -155.1 14.78 137.8 945.2 

7 S95T001101- 251.7 153.0 75.37 9.749 42.25 78.94 

8 S95TOO1101 D 251.0 135.6 45.40 4.010 -23.90 95.82 

9 S95TOO1101-A 4457. 4342. 120.6 4274. 4529. 8392. 

10 ICSA - .0067 .0018 -.0050 .0014 .0767 .0271 

11 ICSAB .0084 .0019 -.0099 .0018 .0382 .0342 

12 CCV 4.871 4.786 .0238 4.733 4.856 9.740 

13 CCB .0250 -.0000 -.0055 -.0001 .0168 .1079 

fi 2 

W 

3 

3 

d 

co 

U 

S 

C

Analysis Report Averages 

Sample Name V 

ICV 4.944 

2 ICB -.0002 

3 ICSA -.0035 

4 ICSAB .4598 

5 PREPBLKTJA 1609 

6 S95T001101 L 77.34 

7 S95T001101 - 51.15 

8 S95T001101 D 51.32 

9 S95T001101-A 4503. 

10 ICSA - .0003 

11 ICSAB .4549 

12 CCV 4.896 

13 CCB .0044 

Y 

-------- 

Thu 07-20-95 02:00:14 PM page 4 

Zn 

-------- 

Zr 

-------- 

.0139 4.992 4.913 

.0001 -.0009 .0002 

.0073 .0010 -.0043 

.0076 .9538 -.0051 

0439 0359 1067 

26.48 73.36 82.91 

15.13 95.78 44.47 

14.69 77.25 60.77 

27.24 4773. 4386. 

.0085 .0007 -.0014 

.0086 .9462 -.0008 

.0145 4.999 4.837 

.0014 -.0016 .0044 

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WHGSD-WM-DP- I Î , REV.L

.:ai3'sis Report Summary Tue 07-18 -95 12:55:16 PM page 1 

.5rj:jDle ,Name File 

-- '----- — ------ ------ -------- 

I ICV 

ICB 

ICSA 

ICSAB 

I C.SAB 

n i'PRPBLKTJA 

S95 7 001072 L 

. 5 ^5T001072- 

? S957'001072 D 

U S?37'001072 A 

CCl' 

CC. 

s''ST001077 L 

r 5' ^'/'l' U 1 U 7 7 

''57001077 D 

"iTi.î>1077 

CC! :.. 

C CC?: 1 

95 0 71 8B 

950718B 

950718B 

9507138 

950718E 

950718B 

950718B 

950718B 

950718B 

9507188 

950718B 

950718B 

950718B 

950718B 

9507188 

9507188 

950718B 

950718E 

9507I8B 

950718B 

P]ethod Dace 

-------- --------- 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

ICP2 

i 

_o^ 0 

r-r.. 13 

07,1 

07/1 

07/1 

07/1 

07/1 

07/1 

07/1 

07/1 

07/1 

07/1 

07/1 

07/1 

071 I 

07/1 

07/1 

07/1 

07/1 

5 55 

5 5 

5 5 

5 

-1 cl `( SVToc)101l 

C49 

^d q 5 

Time 

----- 

OpID 

---- 

10:36 DKS 

10:40 DKS 

10:44 DKS 

10:47 DKS 

11:03 DKS 

11:08 DKS 

11:14 DKS 

11:18 DKS 

11:24 DKS 

11:29 DKS 

11:46 DKS 

11:50 DKS 

11:55 DKS 

11:59 DKS 

12:14 DKS 

12:19 DKS 

12:24 DKS 

12:28 DKS 

12:47 DKS 

12:51 DKS 

07/1, Af- 

Type 

---- 

Mode 

----- 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONIC 

CONC 

CONC 

CONC 

CONC 

CONC 

CONC 

covc 

CONC 

CONC 

CONC 

CONC 

covc 

CONC 

W 

Ix 

a 

C 

N 

2 

3

'.;:alysis Report Averages Tue 07-18-95 12:55:16 PM page 2 

--- 

Sample Name 

-------------------- 

Ag 

-------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

i ICI 4.939 4.918 5.005 4.873 4.916 5.079 

iC3 .0010 -.0052 .0012 .0052 0001 0001 

3 ICSA .0005 246.6 0371 0025 .0016 .0002 

4 ICSAB Q.4129 244.5 .0038 .0039 .4567 .4750 

ICSAB .9199 245.1 0121 0062 .4555 .4765 

:; ?;' rp BL.KTJA -.0097 -.0133 .0348 .0186 .0117 -.0001 

S?51'001072 L 1.961 18160. -45.60 212.4 70.26 -.8373 

S S95T001072- 12.18 17660. -30.48 243.2 66.70 .7886 

" .3 95T001072 D 

7718 19710. -27.97 285.5 72.01 1280 

!0 S95 7 001072 -A 4349. 21460. 5004. 4715. 4229. 4763. 

11 CCI - 4.974 4.935 5.104 4.884 4.927 5.101 

(,(3 .0011 -.0021 .0042 .0102 -.0001 .0000 

.7457'001077 L -54.35 2I460. -52.83 296.3 61.04 4.442 

3 ?57001077- -9.054 21370. -49.38 287.8 64.40 -.2494 

1:15 1001077 D 4.596 22680. 11.49 296.1 67.19 .3192 

c ?')7001077 -A 4827. 27050. 6253. 5772. 5194. 5821. 

i(';A - .0008 256.9 -.0385 -.0017 .0018 .0003 

',5 ICSA3 .9303 257.6 -.0306 -.0057 .4826 .5142 

i- CLI .1 4.944 4.906 5.012 4.865 4.865 5.030 

CC3 - 1 .0007 .0005 -.0063 .0050 .0000 -.0001 

- 

--- 

Sariule Name 

'------------- 

BI 

------ -------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

1 ICI' 4.931 5.048 4.974 5.047 5.010 5.025 

2 1C3 -.0295 -.0012 .0001 -.0092 -.0014 -.0015 

3 ICSA -.0453 239.5 .0005 .0011 -.0035 .0033 

ICSAB -.0701 245.0 .9416 .0078 .4632 .4753 

5 ICSAB -.0570 247.4 .9443 .0079 .4639 .4785 

6 PREPBLKTJA -.4911 .1613 -.0116 -.0677 -.0269 -.0184 

7 S95T001072 L 113100. 2370. -6.840 237.6 3.377 4415. 

S S95T001072- 111500. 2366. 7.721 250.6 29.62 4381. 

9 S95T001072 D 119500. 2135. 1.512 291.5 4.616 4746. 

10 .5957'001072-A 115000. 7864. 5084. 4714. 5031. 9502. 

.'1 CCV - 5.012 5.182 5.081 5.030 5.094 5.105 

1) CC3 .0053 -.0024 .0000 -.0058 -.0005 -.0008 

13 .5957'001077 L 131400. 1882. 1.351 -209.6 43.92 5194. 

S95T001077 130800. 1973. -6.501 176.4 29.88 5252. 

15 .S95T001077 D 135500. 1965. 2.908 302.2 37.60 5416. 

16 .5957'001077-A 141400. 8375. 6148. 5804. 6015. 11520. 

17 ICSA - -.0438 268.3 -.0002 .0089 -.0002 .0044 

1 S ICSAB -.0490 261.7 1.024 -.0031 .5023 .5127 

19 CCI 1 4.914 5.118 4.987 4.996 5.017 5.037 

20 CC3- 1 -.0294 .0025 .0012 .0089 -.0011 .0001 

--- 

Sample Name 

--- - ------------- 

Cu 

--- -------- 

Eli 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

1 ICI 4.890 .0061 4.997 4.832 4.972 4.999 

IC3 -.0006 -.0001 -.0013 -.3452 -.0008 -.0001 

ICS:1 -.0104 -.0081 91.15 .1398 -.0039 .0018 

ICSAB .4688 -.0160 91.83 -.0528 -.0038 .9503 

5 PCSA3 .4690 -.0221 92.43 .0096 -.0037 .9488 

650 

Î 

Î 

a O 

3G 

v x 

3

-- 

alysis Report Averages Tue 07-18-95 12:55:16 PM page 3 

Sample Name 

Cu 

-----------`--- ----- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

6 PnEPBLKTJA 0148 0244 4760 13250. 0156 0212 

7 S95T001072 L 113.6 31.83 98510. 5229e3 11.11 166.0 

S 5957001072- 73.13 11.06 95850. 4868e3 5.214 133.7 

9 S951'001072 D 55.20 10.51 121000. 5140e3 7.234 148.6 

10 S95T001072-A 4285. 30.87 100700. 4586e3 4351. 4051. 

11 CCv - 4.884 .0037 5.060 5.163 4.973 4.912 

! 2 CCB -.0004 -.0001 0008 0823 0006 0000 

7 ? S951'001077 L 76.54 -10.33 106100. 6344e3 -88.04 21.09 

1,: .S95T001077- 83.15 -.0321 105200. 6164e3 -25.59 36.15 

i5 S952 -001077 D 35.65 3.443 109700. 6044e3 -2.051 38.74 

7 6 S.0 5T001077-A 5273. 22.54 115800, 6145e3 5321. 5042. 

L? ICSA - -.0129 -.0499 100.6 -.0089 -.0046 .0047 

!:4 IC.S.4B .4884 -.0363 99.01 -.1905 -.0072 .9910 

' CCv 1 4.847 .0079 5.000 4.998 4.937 4.921 

i0 (;CB - .' -.0011 .0015 .0006 -.0021 .0005 .0016 

--- 

a : lame 

111 

-------------- ------ -------- 

;)n 

-------- 

A10 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

IC p 4.909 4.897 4.932 4.973 5.139 4.960 

1C3 -.0142 -.0001 -.0021 -.0027 -.0021 -.0003 

ICSA 247.6 -.0062 -.0119 194.0 .0006 -.0129 

ICSAG 246.3 .4461 -.0110 191.5 .0013 .9013 

ICSA3 247.1 .4468 -.0094 192.0 -.0000 .9033 

5 ?nEngLKTJ ,-1 -.0111 .0534 -.0246 4.372 -.0405 9.499 

.S951'001072 L 1430. 465.0 -106.4 1088e3 112.3 7489. 

3 S957'00I072 - 1193. 452.9 -19.70 1001e3 43.12 7349. 

? S957'001072 D 1199. 431.0 -41.71 I168e3 40.81 4186. 

i0 S957'001072 -A 5690. 5189. 4931. 935400. 4494. 12360. 

11 CCv - 4.906 4.931 5.049 4.924 5.129 5.063 

12 CCB -.0037 .0002 .0027 -.0004 -.0019 -.0103 

13 S95T001077 L 1197. 341.0 30.28 1283e3 -15.64 7031. 

14 S95T001077- 1217. 341.8 -3.533 1237e3 91.48 7I71. 

i5 S95T001077 D 1337. 346.3 7.006 1216e3 90.25 5215. 

16 S951'001077-A 6697. 5981. 5965. 1221e3 5490. 13520. 

17 ICSA - 264.1 -.0060 -.0059 196.2 -.0027 -.0343 

1S ICSAB 263.1 .4780 -.0041 202.4 -.0005 .9780 

19 CCv 1 4.911 4.893 4.983 4.931 5.107 4.982 

20 CCB-1 -.0116 .0005 -.0003 .0159 -.0049 .0002 

--- 

Sample Name 

P 

-------------- ------ -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 ICV 5.033 4.959 4.983 4.677 4.923 4.832 

2 ICB -.0032 -.0034 .0004 -.0033 .0031 .0043 

3 ICSA -.0194 .0221 -.0135 .0089 -.0347 .0182 

ICSAB -.0109 1.001 -.0403 .0173 .0027 .0001 

5 ICSAB -.0325 1.007 -.0324 -.0025 .0048 -.0024 

i PPEPBLK1'JA .0973 -.0638 .1668 -.0145 .1888 .3214 

.S95T001072 1. 147900. 1195. 75040. 78.85 -3222. 45070. 

S S95T001072 - 150800. 1092. 74860. -75.75 -3515. 44980. 

S95T001072_D 181400. 917.5 84840. -114.3 -4102. 50260. 

O .5957'001072 A 156000. 6294. 50140. 4541. 1751. 49820. 

?7 CCv - 4.977 5.063 5.027 4.767 4.981 4.954 

GZA 

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-------- 

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-------- 

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-------- --------d 

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7 a ged Wd 9T : SS : 677 96-ST-ZO art1 SagezanV a-Today STS A' TF?P,

....alysis Report Averages 

qi SaT..Iple ,Name V 

--- -------------------- -------- 

S ICS.1 3 .4954 

19 CCV 1 4.922 

n r,C:,- 1 .0030 

Tue 07-18-95 12:55:16 PM page 5 

Y Zn Zr 

-------- -------- -------- -------- -------- 

.0082 1.034 -.0023 

.0140 4.987 4.882 

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Y

WHC-SD-WM-DP-137, REV. 1 

THIS PAGE WAS INTENTIONALLY LEFT BLANK 

658

THE FOLLOWING ANALYSES ARE INCLUDED IN THE DATA PACKAGE BUT THE RESULTS HAVE 

NOT BEEN REPORTED IN THE FINAL SUMMARY REPORTS. 

65.9

THIS PAGE IIV'IOMONALLY 

LEFPBLANK 

J

06/14/95 12:58 age: I 

A-0004-I 


.nalyst: ^^CS^ w ^ Instrument: 

X 

ICPO'1` I. 

Book# `f pYM 

Method: LA-505-151 Rev/Mod Qt-1 n 

WHC SD-WM-DP- 3 ` , REV. 


5 Type Sample#R A Test Matrix Group Project 

















15 ICSAB @ICP-QC QC DATA 

16 CCV @ICP QC QC 




660 

liff USED 

IN PACKAGE

06/14/95 12:58 

A-0004-1 

WHC-SD-WM-DP- -1 ^L, REV 





P• (PWk TFq l- Y+' 

S67GO 1 6 1^_ J_ .5145-744) 

S1S70o/olk Ifk4f lf() 

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Sk O & A174_q .si14f 

m-;-Y ) (CS^rs^l^.S114 = 11`38' 

I^r (1s^r^d /si^4 

= y877 

19 (^°rrol/.S^zz Lyre/ 

-Di 100 10 77_k ,Yfkj-, 450 4( 0,0 1 4surs+os =007 

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661 

IM NOT TA 

^CKAGE 

Page: 2

Analysis Report Summary Tue 07-18-95 12:55:16 PM page 1 

# 

--- 

Sample Name 

--------------- 

File 

----- -------- 

Method 

-------- 

Date 

--------- 

Time 

----- 

OpID 

---- 

Type 

---- 

Mode 

----- 

ICV 950718B ICP2 07118195 10:36 DKS Q CONC 

2 ICB 950718B ICP2 07118195 10:40 DKS Q CONC 

3 ICSA 950718B ICP2 07118195 10:44 DKS Q CONC 

4 ICSAB 950718B ICP2 07118195 10:47 

ICP2 


5 ICSAB 950718B 07118195 

DKS Q CONC 

6 PP.EPBLKTJA 950718E ICP2 071 18195 11:08 DKS S CONC 


8 S95T001072 — 950718B ICP2 07118195 11:18 DKS S CONC 

9 S95T001072 D 950718B ICP2 07%18/95 11:24 DKS S CONC 

10 S95T001072 —A 950718B ICP2 07118195 11:29 DKS S CONC 

11 CCV — 950718B ICP2 07118195 II:46 DKS Q CONC 

12 CCB 950718B ICP2 071 18195 11:50 DKS pp CONC 


14 S95T001077— 950718B ICP2 07118195 11:59 DKS S CONC 

15 S95T001077 D 950718B ICP2 07118195 12:14 DKS S CONC 

16 S95T001077—A 950718B ICP2 07 18195 12:19 DKS S CONC 

17 ICSA — 950718B ICP2 07%18/95 12:24 DKS Q CONC 

18 ICSAB 950718B ICP2 071181 95 12:28 DKS Q CONC 

19 CCV I 950718B ICP2 071 18195 12:47 DKS Q CONC 

20 CCB- 1 950718B ICP2 07118195 12:51 DKS Q CONC 

J^ J^^ 

N 15- 

^ l^'f S9STo^l^y^ 

ssrr^ U Id 71 

# 65 s- 

GG2 

DATA 

NOT USED 

IN PASSE 

A 

W 

JI 

d 

O 

3 C3 

3

Analysis Report Averages Tue 07-18-95 12:55:16 PM page 2 

# 

--- 

Sample Name 

Ag 

----------------- --- -------- 

Al 

-------- 

As 

-------- 

B 

-------- 

Ba 

-------- 

Be 

-------- 

1 ICV 4.939 4.918 5.005 4.873 4.916 5.079 

2 ICB .0010 -.0052 .0012 .0052 -.0001 0001 

3 ICSA .0005 246.6 0371 0025 .0016 .0002 

4 ICSAB q.4129 244.5 .0038 .0039 .4567 .4750 

5 ICSAB .9199 245.1 0121 0062 .4555 .4765 

6 PP.EPBLKTJA -.0097 0133 .0348 0186 0117 -.0001 

7 S95T001072 L 1.961 18160. -45.60 212.4 70.26 -.8873 

8 S95T001072- 12.18 17660. -30.48 243.2 66.70 .7886 

9 S95T001072 D 7718 19710. -27.97 285.5 72.01 1280 

10 S95T001072-A 4349. 21460. 5004. 4715. 4229. 4763. 

11 CCV - 4.974 4.935 5.104 4.884 4.927 5.101 

12 CCB .00I1 -.0021 .0042 .0102 0001 0000 

13 S95T001077 L -54.35 21460. -52.83 296.3 61.04 4.442 

14 S95T001077- -9.054 21370. -49.38 287.8 64.40 2494 

15 S95T001077 D 4.596 22680. 11.49 296.1 67.19 .3192 

16 S95T001077-A 4827. 27050. 6253. 5772. 5194. 5821. 

17 ICSA - .0008 256.9 -.0385 -.0017 .0018 .0003 

18 ICSAB .9303 257.6 -.0306 -.0057 .4826 .5142 

19 CCV 1 4.944 4.906 5.012 4.865 4.865 5.030 

20 CCB 1 .0007 .0005 -.0063 .0050 .0000 -.0001 

# 

--- 

Sample Name 

Bi 

-------------- ------ -------- 

Ca 

-------- 

Cd 

-------- 

Ce 

-------- 

Co 

-------- 

Cr 

-------- 

1 ICV 4.931 5.048 4.974 5.047 5.010 5.025 

2 ICB -.0295 -.0012 .0001 -.0092 -.0014 0015 

3 ICSA -.0453 239.5 .0005 .0011 -.0035 .0033 

4 ICSAB -.0701 245.0 .9416 .0078 .4632 .4753 

5 ICSAB -.0570 247.4 .9443 .0079 .4639 .4785 

6 PREPBLKTJA 4911 1613 0116 0677 -.0269 0184 

7 S95T001072 L 113100. 2370. -6.840 237.6 3.377 4415. 

8 S95T001072- 111500. 2366. 7.721 250.6 29.62 4381. 

9 S95T001072 D 119500. 2135. 1.512 291.5 4.616 4746. 

10 S95T001072-A 115000. 7864. 5084, 4714. 5031. 9502. 

11 CCV - 5.012 5.182 5.081 5.030 5.094 5.105 

12 CCB .0053 -.0024 .0000 -.0058 0005 0008 

13 S95T001077 L 131400. 1882. 1.351 -209.6 43.92 5194. 

14 S95T001077- 130800. 1973. -6.501 176.4 29.88 5252. 

15 S95T001077 D 135500. 1965. 2.908 302.2 37.60 5416. 

16 S95T001077-A 141400. 8375. 6148. 5804. 6015. 11520. 

17 ICSA - -.0438 268.3 -.0002 .0089 -.0002 .0044 

18 ICSAB -.0490 261.7 1.024 -.0031 .5023 .5127 

19 CCV 1 4.914 5.118 4.987 4.996 5.017 5.037 

20 CCB - 1 -.0294 .0025 .0012 .0089 -.0011 .0001 

# 

--- 

Sample Name 

-------------- 

Cu 

------ -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

1 ICV 4.890 .0061 4.997 4.832 4.972 4.999 

2 ICB -.0006 -.0001 -.0013 -.3452 -.0008 0001 

3 ICSA -.0104 -.0081 91.15 .1398 -.0039 .0018 

4 ICSAB .4688 -.0160 91.83 -.0528 -.0038 .9503 

5 ICSAS .4690 -.0221 92.43 .0096 -.0037 .9488 

DATA 

nroTUs 

IN ft^^ 

663 

WI 

Q 

Î 

d 

O 

3 

0 

CO 

C? 

3

Lialysis Report Averages Tue 07-18-95 12:55:16 PM page 3 

# 

--- 

Sample Name 

Cu 

------------------ -- -------- 

Eu 

-------- 

Fe 

-------- 

K 

-------- 

La 

-------- 

Li 

-------- 

PP.EPBLKTJA 

S95T001072 L 

8 S95T001072 - 

9 S95T001072 D 

10 S95T001072 -A 

11 CCV - 

12 CCB 

13 S95T001077 L 

14 S95T001077- 

15 S95T001077 D 

16 S95T001077-A 

17 ICSA - 

I8 ICSAB 

19 CCV 1 

20 CCB- 1 

0148 

113.6 

73.13 

55.20 

4285. 

4.884 

0004 

76.54 

83.15 

85.65 

5273. 

0129 

4884 

4.847 

-.0011 

0244 

31.83 

11.06 

10.51 

30.87 

.0037 

0001 

-10.33 

-.0821 

3.443 

22.54 

-.0499 

0363 

.0079 

.0015 

4760 

98510. 

95850. 

121000. 

100700. 

5.060 

0008 

106100. 

105200. 

109700. 

II5800. 

100.6 

99.01 

5.000 

.0006 

13250. 

5229e3 

4868e3 

5140e3 

4586e3 

5.163 

0823 

6344e3 

6164e3 

6044e3 

6145e3 

-.0089 

-.1905 

4.998 

-.0021 

0156 

11.11 

5.214 

7.234 

4351. 

4.973 

0006 

-88.04 

-25.59 

-2.051 

5321. 

-.0046 

-.0072 

4.937 

.0005 

0212 

166.0 

133.7 

148.6 

4051. 

4.912 

0000 

21.09 

36.15 

38.74 

5042. 

.0047 

9910 

4.921 

.0016 

> 7 

W 

IN 

\^ 

0p 

3 

0 

U 

Î 

--- 

Sample Name 

--------------- ----- 

Mg 

-------- 

Mn 

-------- 

Mo 

-------- 

Na 

-------- 

Nd 

-------- 

Ni 

-------- 

1 ICV 4.909 4.897 4.982 4.973 5.139 4.960 

2 ICB -.0142 -.0001 -.0021 -.0027 -.0021 -.0003 

3 ICSA 247.6 -.0062 -.0119 194.0 .0006 -.0129 

4 ICSAB 246.3 .4461 -.0110 191.5 .0013 .9013 

5 ICSAB 247.1 .4468 -.0094 192.0 -.0000 .9033 

6 PPEPBLKTJA -.0111 .0534 -.0246 4.372 0405 9.499 

7 S95T001072 L 1430. 465.0 -106.4 1088e3 112.3 7489. 

3 S95T001072 - 1193. 452.9 -19.70 1001e3 43.12 7349. 

9 S95T001072 D 1199. 431.0 -41.71 1168e3 40.81 4186. 

10 S95T001072-A 5690. 5189. 4931. 935400. 4494. 12360. 

11 CCV - 4.906 4.981 5.049 4.924 5.129 5.063 

12 CCB -.0037 .0002 .0027 -.0004 -.0019 -.0108 

13 S95T001077 L 1197. 341.0 30.28 1283e3 -15.64 7032. 

14 S95T001077- 1217. 341.8 -3.533 1237e3 91.48 7171. 

Z5 S95T001077 D 1337. 346.3 7.006 1216e3 90.25 5225. 

S95T001077-A 6697. 5981. 5965. 1221e3 5490. 13520. 

ICSA - 264.1 -.0060 -.0059 196.2 -.0027 -.0343 

i8 ICSAB 263.1 .4780 -.0041 202.4 -.0005 .9780 

19 CCV 1 4.911 4.893 4.983 4.931 5.107 4.982 

20 CCB_1 -.0116 .0005 -.0003 .0159 -.0049 .0002 

# 

--- 

Sample Name 

P 

-------------- ------ -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

1 ICV 5.033 4.959 4.983 4.677 4.923 4.882 

2 ICB -.0032 -.0034 .0004 -.0033 .0031 .0043 

3 ICSA -.0194 .0221 -.0135 .0089 -.0347 .0182 

4 ICSAB -.0109 1.001 -.0403 .0173 .0027 .0001 

5 ICSAB 0325 1.007 0324 -.0025 .0048 0024 

6 PREPBLKTJA .0973 -.0638 .1668 -.0145 .1888 3214 

7 S95T001072 L 147900. 1195. 75040. 78.85 -3222. 45070. 

8 S95T001072- 150800. 1092. 74860. -75.75 -3515. 44980. 

9 S95T001072 D 181400. 917.5 84840. -114.3 -4102. 50260. 

10 S95T001072 -A 156000. 6294. 80140. 4541. 1751. 49820. 

11 CCV - 4.977 5.063 5.027 4.767 4.981 4.954 

Gv4 

, Af ^ys 

Usfp 

f

Analysis P,eport Averages Tue 07-18-95 12:55:16 PM page 4 

$ 

--- 

Sample Name 

---------------- 

P 

---- -------- 

Pb 

-------- 

S 

-------- 

Sb 

-------- 

Se 

-------- 

Si 

-------- 

12 CCB -.0024 -.0003 -.0109 -.0115 .0295 .0078 

13 S95T001077 L 174500. 287.8 82740. -259.1 -4602. 51820. 

14 S95T001077- 181800. 582.8 84280. -200.3 -4532. 52620. 

15 S95T001077 D 185700. 536.3 86840. -162.4 -4291. 53560. 

16 S95T001077-A 195300. 6913, 94050. 5560. 1917. 60510. 

17 ICSA - -.0205 .0479 -.0191 -.0040 .0573 .0267 

18 ICSAB -.0105 1.049 -.0380 -.0126 -.0019 -.0060 

19 CCV 1 4.885 5.045 4.933 4.682 4.947 4.897 

20 CCB - 1 .0011 .0213 -.0053 -.0034 .0256 .0104 

# 

--- 

Sam p le Name 

Sm 

--------------- ----- -------- 

Sr 

-------- 

Th 

-------- 

Ti 

-------- 

T1 

-------- 

U 

-------- 

1 ICV 4.994 4.901 .0065 4.815 4.869 9.956 

2 ICB .0014 -.0000 -.0045 -.0004 .0218 -.0046 

3 ICSA -.0085 .0019 -.0195 .0006 .0628 -.0827 

4 ICSAB -.0022 .0020 -.0114 .0011 .0925 -.1285 

5 ICSAB .0000 .0018 -.0069 .0015 .0773 -.1407 

6 PREPBLKTJA .2124 .0095 .0908 -.0039 .1698 -2.880 

7 S95T001072 L 409.2 1134. -31.61 139.3 9.364 16880. 

8 S95T001072- 158.9 1089. 50.57 122.5 6.723 14930. 

9 S95T001072 D 187.0 1172. 57.98 83.58 -31.33 17020. 

10 S95T001072-A 4551. 5309. 74.68 4557. 4759. 23000. 

11 CCV - 4.986 4.901 -.0273 4.815 4.948 9.911 

12 CCB .0008 .0000 -.0043 -.0002 .0259 -.0087 

13 S95T001077 L 47.53 1240. -264.2 76.94 545.5 11990. 

14 S95T001077T 125.5 1219. -71.44 71.13 24.32 11690. 

15 S95T001077 D 163.0 1247. -37.20 63.20 174.7 12260. 

16 S95T001077-A 5550. 6430. 17.64 5429. 5882. 22700. 

17 ICSA - .0175 .0018 -.0200 .0013 .0633 -.0111 

18 ICSAB .0032 .0018 -.0219 .0011 .0840 -.0189 

19 CCV 1 4.954 4.864 .0007 4.788 4.875 9.899 

20 CCB - 1 .0199 .0003 -.0032 -.0008 .0067 .0617 

If 

-- 

Sample Name 

------------- 

V 

------ -------- 

Y 

-------- 

Zn 

-------- 

1 ICV 4.926 .0131 4.95I 4.902 

2 ICB .0002 .0000 -.0010 .0010 

3 ICSA -.0000 .0074 .0010 -.0009 

4 ICSAB .4632 .0077 .9665 -.0011 

5 ICSAB .4654 .0079 .9684 .0002 

6 PREPBLKTJA .0583 .0125 .0290 .0396 

7 S95T001072 L 121.1 34.40 605.3 306.4 

8 S95T001072- 53.48 19.11 538.5 250.2 

9 S95T001072 D 55.46 21.81 563.4 281.5 

10 S95T001072-A 4839, 42.81 5652. 4811. 

11 CCV - 4.975 .0125 5.032 4.942 

12 CCB -.0001 .0001 .0006 .0004 

13 S95T001077 L 17.15 12.94 689.5 345.9 

14 S95T001077- 34.24 14.66 648.0 348.7 

15 S95T001077 D 41.90 17.33 662.8 370.2 

16 S95T001077-A 5741. 41.40 6711. 5871. 

17 ICSA - .0039 .0093 -.0022 .0011 

/N oryft 

Zr 

-------- -------- -------- 

pAC^ 

6G5 

\.I 

CL0 

3 

C3 

N 

C?

Analysis Report 

Averages 

# Sample Name V Y 

--- ------------------'- -------- ------- 

R ICSAB .4954 .0082 

.9 CCV 1 4.922 .0140 

20 CCB — I .0030 .0009 

JK A 

/1ff-Ys 

Tue 07-18-95 12:55:16 PM 

page 5 

Zn Zr 

-------- -------- -------- -------- 

1.034 -.0023 

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